CN110358640B - High-speed rail insulator cleaning protective agent - Google Patents

High-speed rail insulator cleaning protective agent Download PDF

Info

Publication number
CN110358640B
CN110358640B CN201910723738.3A CN201910723738A CN110358640B CN 110358640 B CN110358640 B CN 110358640B CN 201910723738 A CN201910723738 A CN 201910723738A CN 110358640 B CN110358640 B CN 110358640B
Authority
CN
China
Prior art keywords
ratio
cleaning
insulator
proportion
protective agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201910723738.3A
Other languages
Chinese (zh)
Other versions
CN110358640A (en
Inventor
辛高峰
王义春
鹿大方
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhengzhou Zhongyuan Lida New Material Co ltd
Original Assignee
Zhengzhou Zhongyuan Lida New Material Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhengzhou Zhongyuan Lida New Material Co ltd filed Critical Zhengzhou Zhongyuan Lida New Material Co ltd
Priority to CN201910723738.3A priority Critical patent/CN110358640B/en
Publication of CN110358640A publication Critical patent/CN110358640A/en
Application granted granted Critical
Publication of CN110358640B publication Critical patent/CN110358640B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0073Anticorrosion compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/78Neutral esters of acids of phosphorus
    • C11D2111/20

Abstract

The invention discloses a high-speed rail train insulator cleaning protective agent which is liquid and comprises, by weight, a detergent, a corrosion inhibitor, a solubilizer, a metal complexing agent, a pH value regulator, a nano material and deionized water, wherein the detergent is a multi-component combined nonionic surfactant and comprises 1-2.5%, the corrosion inhibitor comprises 0.3-1%, the solubilizer comprises 3-9%, the metal complexing agent comprises 0.1-0.8%, the pH regulator is determined according to actual conditions, the nano material is solid nano particles and comprises 0.01-3%, and the balance is deionized water. The cleaning machine not only enables the insulator to be bright as new after cleaning, but also forms a layer of protective film on the surface of the insulator, so that the insulator is not easy to be secondarily polluted, and the time for cleaning again is prolonged.

Description

High-speed rail insulator cleaning protective agent
Technical Field
The invention relates to the technical field of insulator cleaning for high-speed rail trains, in particular to a high-speed rail train insulator cleaning protective agent.
Background
The insulator is a key part of a high-speed rail train contact power grid supporting and suspending device, is positioned at the top of the high-speed rail train, and plays roles of electrically isolating a strip point part and an insulating part in the suspending device, supporting the suspending device and the like. In a natural environment, the high-speed train insulator is easily polluted by metal dust generated by a bow net system and granular dust in the environment, and a pollution layer is formed on the surface of the high-speed train insulator, so that the surface insulativity of the high-speed train insulator is reduced, and the high-speed train insulator is easily polluted and flashed in a humid weather. Pollution flashover can damage electrical equipment and seriously affect the running safety of high-speed trains.
Due to the particularity of the structure and the position of the insulator of the high-speed train, the current anti-pollution flashover measures mainly adopt a cleaning agent for manual cleaning. The currently adopted cleaning agents only need to be of two types: one type is a solvent type cleaning agent, the cleaning speed of the cleaning agent is high, the cleaning efficiency is high, but volatile gases have certain toxicity, the human body can be injured by long-time contact, the combustion is easy, and the potential safety hazard exists in storage and use; one type is a water-based cleaning agent, the cleaning speed of the cleaning agent is low, the cleaning of all insulators is difficult to complete within a certain maintenance time, the cleaning efficiency is low, residues are easy to exist, and secondary pollution of the insulators is caused.
Disclosure of Invention
In view of the above, the technical scheme of the invention is designed to solve the problem that the cleaning agent is selected for the high-speed train insulator.
The invention provides a high-speed rail train insulator cleaning protective agent which mainly comprises a detergent, a corrosion inhibitor, a solubilizer, a metal complexing agent, a pH value regulator, a nano material and the like. The detergent mainly removes dirt from the surface of the insulator, and comprises three nonionic surfactants A, B and C, the slow release agent mainly prevents the cleaning agent from being sprayed to the parts outside the insulator to corrode the cleaning agent and particularly metal, the solubilizer mainly increases the solubility of the fallen dirt and other components in the cleaning agent in a solution, the metal complexing agent mainly complexes metal ions in the dirt to prevent the dirt from being deposited on the surface of the insulator again, and the pH regulator mainly regulates the pH value of the cleaning agent to control the pH value of the cleaning agent to be below 9; the nanometer material mainly increases the brightness of the insulated and cleaned material and is not easy to be secondarily polluted.
The high-speed rail train insulator cleaning protective agent is liquid and comprises, by weight, a detergent, a corrosion inhibitor, a solubilizer, a metal complexing agent, a pH value regulator, a nano material and deionized water, wherein the detergent is a multi-component combined nonionic surfactant and comprises 1-2.5%, the corrosion inhibitor comprises 0.3-1%, the solubilizer comprises 3-9%, the metal complexing agent comprises 0.1-0.8%, the pH regulator comprises solid nano particles which comprise 0.01-3%, and the balance is deionized water.
The detergent is a multi-component combined nonionic surfactant, and comprises A, B, C three nonionic surfactants, wherein the ratio of the surfactants is A: B: C =1:1.5-3: 1.
The corrosion inhibitor is preferably sodium metasilicate, and the proportion of the corrosion inhibitor is preferably 0.3-0.6%.
The solubilizer is preferably ethanol, and the proportion is preferably 3-7%.
The metal complexing agent is preferably sodium citrate, and the proportion is preferably 0.2-0.6%.
The pH regulator is preferably triethanolamine.
The nano material is nano silicon dioxide, preferably accounts for 0.1-1%,
further, A, B, C the three nonionic surfactants are polymer of isomeric alcohol and ethylene oxide (1310), isopropanol amide (DX 6508) and lauryl alcohol phosphate (dodecyl phosphate monoester).
The high-speed rail train insulator cleaning protective agent comprises the following components, wherein the components are weighed according to a ratio, deionized water is poured into a stirring container, then a detergent, a solubilizer, a corrosion inhibitor, a metal complexing agent and a nano material are sequentially added, finally a pH value regulator is added to regulate the pH value of a solution to enable the pH value of the solution to be below 9 and to be alkalescent, after one component is added, the next component is added after the component is required to be completely dissolved and stirred uniformly, and after all the components are added, the mixture is stirred for 30-60 minutes to obtain a finished product.
When the insulator is cleaned, the insulator cleaning agent stock solution is uniformly sprayed on the insulator by using a spray can, and after the insulators on a train carriage are continuously sprayed, the sprayed insulators are lightly wiped by using a cleaning cloth according to the spraying sequence. The insulator wiped by the rag is not clean, and needs to be cleaned for the second time according to the cleaning mode, so that the clean standard can be reached.
Compared with the existing cleaning agent, the cleaning agent has the beneficial effects that:
1. the insulator cleaning protective agent for the high-speed rail train insulator disclosed by the invention has the advantages that the insulator after cleaning is high in breakdown voltage resistance and can resist the breakdown voltage of 135 KV.
2. The cleaning protective agent for the high-speed rail train insulator is easy to volatilize and high in cleaning speed, can be completely volatilized after being lightly wiped by a rag after being sprayed, and has no residue after 2 min.
3. The cleaning protective agent for the high-speed rail train insulator is strong in dirt-removing capacity and high in efficiency, and the cleaning agent is lightly wiped by a cleaning cloth 2min after being sprayed, so that the dirt removal rate can reach over 95%.
4. According to the high-speed rail train insulator cleaning protective agent disclosed by the invention, all reagents selected by the cleaning agent are environment-friendly, are easy to decompose and do no harm to the environment.
5. According to the high-speed rail train insulator cleaning protective agent, the special nano material is added into the cleaning agent, so that the insulator is bright as new after being cleaned, a layer of protective film is formed on the surface of the insulator, the insulator is not easy to be secondarily polluted, and the time for cleaning again is prolonged.
6. The cleaning agent is water-based, can be diluted with water in any proportion, is non-combustible, and is safe to store and use, and volatile matters of the cleaning agent are odorless and harmless to human bodies.
Detailed Description
The present invention is illustrated in detail below by means of examples, which are illustrative and not limitative, and the scope of protection of the present invention is not limited thereby.
Example (b):
a high-speed rail train insulator cleaning protective agent is liquid, according to the weight percentage, a decontaminating agent is a polymer (1310) of isomeric alcohol and ethylene oxide, isopropanol amide (DX 6508) and lauryl alcohol phosphate (dodecyl phosphate monoester) are prepared into a multi-component combined nonionic surfactant according to the proportion of 1:2:1, the corrosion inhibitor is sodium metasilicate with the proportion of 0.5%, a solubilizing agent is ethanol with the proportion of 5%, a metal complexing agent is sodium citrate with the proportion of 0.3%, the addition amount of a PH regulator is about 0.5%, the nano material is silicon dioxide with the proportion of 0.3%, and the balance is deionized water.
The finished high-speed rail train insulator cleaning protective agent with the proportion has the pH value of 8.7, is practically used in a motor train application, cleans a standard five-action three-drag high-speed rail train, has no more than 2 insulators needing secondary cleaning after primary cleaning, and finds that the high-speed rail train has no seriously polluted insulators after primary cleaning and when secondary cleaning.
After cleaning the waste insulator detached from the high-speed rail train, carrying out a withstand voltage test according to the national standard of GB/T1695-2005, wherein the cleaned insulator can resist the breakdown voltage of 135 KV.
Finally, the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting, and other modifications or equivalent substitutions made by the technical solutions of the present invention by those of ordinary skill in the art should be covered within the scope of the claims of the present invention as long as they do not depart from the spirit and scope of the technical solutions of the present invention.

Claims (3)

1. The high-speed rail train insulator cleaning protective agent is liquid and is characterized in that the protective agent is prepared from the following components in percentage by weight: the detergent is a multi-component combined nonionic surfactant and comprises A, B, C three nonionic surfactants, the ratio of A: B: C =1:1.5-3:1, the A, B, C three nonionic surfactants are respectively polymer 1310 of isomeric alcohol and ethylene oxide, isopropanolamide DX6508 and lauryl alcohol phosphate ester, the proportion is 1-2.5%, the corrosion inhibitor is sodium metasilicate, the proportion is 0.3-1%, the solubilizer is ethanol, the proportion is 3-9%, the metal complexing agent is sodium citrate, the proportion is 0.1-0.8%, the pH regulator is triethanolamine, the proportion is determined according to actual conditions, the nano material is nano silicon dioxide, the proportion is 0.01-3%, the remainder was deionized water.
2. The high-speed train insulator cleaning protective agent according to claim 1, characterized in that: the detergent is a multi-component combined nonionic surfactant and comprises A, B, C three nonionic surfactants, the ratio of A: B: C =1:1.8-2.5:1, the A, B, C three nonionic surfactants are respectively polymer 1310 of isomeric alcohol and ethylene oxide, isopropanolamide DX6508 and lauryl alcohol phosphate in a ratio of 1-2.5%, the corrosion inhibitor is sodium metasilicate in a ratio of 0.3-0.6%, the solubilizer is ethanol in a ratio of 3-7%, the metal complexing agent is sodium citrate in a ratio of 0.2-0.6%, the pH regulator is triethanolamine in a ratio determined according to actual conditions, the nano material is nano silicon dioxide in a ratio of 0.1-1%, the remainder was deionized water.
3. The high-speed train insulator cleaning protective agent according to claim 2, characterized in that: the detergent is a polymer 1310 of isomeric alcohol and ethylene oxide, the isopropanolamide DX6508 and lauryl alcohol phosphate are prepared into a multi-component combined nonionic surfactant according to the ratio of 1:2:1, the corrosion inhibitor is sodium metasilicate with the ratio of 0.5%, the solubilizer is ethanol with the ratio of 5%, the metal complexing agent is sodium citrate with the ratio of 0.3%, the addition amount of the PH regulator is 0.5%, the nano material is silicon dioxide with the ratio of 0.3%, and the balance is deionized water.
CN201910723738.3A 2019-08-07 2019-08-07 High-speed rail insulator cleaning protective agent Active CN110358640B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910723738.3A CN110358640B (en) 2019-08-07 2019-08-07 High-speed rail insulator cleaning protective agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910723738.3A CN110358640B (en) 2019-08-07 2019-08-07 High-speed rail insulator cleaning protective agent

Publications (2)

Publication Number Publication Date
CN110358640A CN110358640A (en) 2019-10-22
CN110358640B true CN110358640B (en) 2021-06-29

Family

ID=68222171

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910723738.3A Active CN110358640B (en) 2019-08-07 2019-08-07 High-speed rail insulator cleaning protective agent

Country Status (1)

Country Link
CN (1) CN110358640B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114702977B (en) * 2022-03-28 2024-03-19 江苏天鹏龙辉环境科技有限公司 Method for treating difficult-to-treat oil sludge in petrochemical enterprise electric desalting tank
CN115651775B (en) * 2022-11-15 2024-04-09 中铁伟业(北京)新技术有限公司 Preparation method and application of environment-friendly aqueous electric mechanical cleaning agent
CN115651776B (en) * 2022-11-15 2024-04-16 中铁伟业(北京)新技术有限公司 Preparation method and application of environment-friendly water-based cleaning agent special for motor car insulator
CN116376642B (en) * 2023-04-10 2024-03-22 北京中铁科新材料技术有限公司 Environment-friendly nano insulator cleaning agent and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102492566A (en) * 2011-12-09 2012-06-13 江西瑞思博化工有限公司 Surface cleaning agent for vehicle body
CN103740487A (en) * 2013-12-24 2014-04-23 长沙艾森设备维护技术有限公司 Outer surface cleaning agent for high-speed trains and using method thereof
CN104651071A (en) * 2013-11-21 2015-05-27 天津博莱恩科技发展有限公司 Internal combustion locomotive carriage external body surface cleaning agent
CN105296244A (en) * 2015-11-17 2016-02-03 杨超 Insulator electrified cleaning agent
CN107541359A (en) * 2017-10-23 2018-01-05 国网河南省电力公司桐柏县供电公司 Antifouling flash coating layer cleaning agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102492566A (en) * 2011-12-09 2012-06-13 江西瑞思博化工有限公司 Surface cleaning agent for vehicle body
CN104651071A (en) * 2013-11-21 2015-05-27 天津博莱恩科技发展有限公司 Internal combustion locomotive carriage external body surface cleaning agent
CN103740487A (en) * 2013-12-24 2014-04-23 长沙艾森设备维护技术有限公司 Outer surface cleaning agent for high-speed trains and using method thereof
CN105296244A (en) * 2015-11-17 2016-02-03 杨超 Insulator electrified cleaning agent
CN107541359A (en) * 2017-10-23 2018-01-05 国网河南省电力公司桐柏县供电公司 Antifouling flash coating layer cleaning agent

Also Published As

Publication number Publication date
CN110358640A (en) 2019-10-22

Similar Documents

Publication Publication Date Title
CN110358640B (en) High-speed rail insulator cleaning protective agent
CN102559410B (en) High-voltage insulator electrified cleaning agent
CN102580937B (en) Method for realizing live cleaning of secondary equipment
CN105296244A (en) Insulator electrified cleaning agent
CN101337229B (en) Electric insulation cleaning method of high-pressure electric power apparatus
CN107541359B (en) Pollution flashover-preventing coating cleaning agent
CN105419962A (en) High pressure anti-pollution-flashover cleaner
CN115651776B (en) Preparation method and application of environment-friendly water-based cleaning agent special for motor car insulator
CN103589545A (en) Electrified insulation cleaning agent of high voltage equipment
CN110628524B (en) Composite cleaning agent for electrified insulating equipment
CN111171623B (en) Water-based cleaning agent for RTV (room temperature vulcanized) organic silicon coating for insulator
CN104148336A (en) Special tool for electrically cleaning support vase
CN103272795B (en) The charged cleaning method of macromolecule of converting station electric power equipment
CN113201413A (en) Water-based cleaning and repairing agent for surface of silicon rubber insulator and preparation method thereof
CN112011412A (en) Neutral water-based cleaning agent for insulator
CN106076937A (en) Electric insulation cleaning method of high-pressure electric power apparatus
CN101629129A (en) Special cleaning agent for insulators and preparation method thereof
CN1884465A (en) Precision electronic device on-line detergent and its production method
CN103923768A (en) Composite flame-retardant organic detergent for charged insulating equipment
CN104087433A (en) Greasy dirt scavenger
CN111073764A (en) Environment-friendly cleaning and repairing agent for composite insulator
KR101877379B1 (en) Detergent Compositon And Cleaning Apparatus
CN114181780A (en) Transformer substation insulator descaling agent, application thereof and cleaning method for surface dirt of transformer substation insulator
CN102513284A (en) Coating method for insulator antifouling flashover coating
CN109652240B (en) Low-cooling-gradient cleaning agent for live working and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant