CN112553014A - Electronic product charged antibacterial cleaning agent - Google Patents

Electronic product charged antibacterial cleaning agent Download PDF

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Publication number
CN112553014A
CN112553014A CN202011419610.7A CN202011419610A CN112553014A CN 112553014 A CN112553014 A CN 112553014A CN 202011419610 A CN202011419610 A CN 202011419610A CN 112553014 A CN112553014 A CN 112553014A
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cleaning agent
carbon atoms
cleaning
compound
antibacterial
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CN112553014B (en
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于泳
于晓霞
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Beijing Flying Fox Fish Intelligent Technology Co ltd
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Beijing Flying Fox Fish Intelligent Technology Co ltd
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Priority to PCT/CN2020/138045 priority patent/WO2022120937A1/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0073Anticorrosion compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/28Organic compounds containing halogen
    • C11D7/30Halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5004Organic solvents
    • C11D7/5018Halogenated solvents
    • C11D2111/14
    • C11D2111/16
    • C11D2111/22

Abstract

The application relates to the technical field of cleaning agents, and discloses an electronic product charged antibacterial cleaning agent which comprises 80-95 wt% of fluorine-containing hydrocarbon compounds with 2-5 carbon atoms and 5-20 wt% of alcohol with 2-3 carbon atoms. The electronic product electrified antibacterial cleaning agent disclosed by the embodiment of the disclosure is environment-friendly, has good cleaning performance and antibacterial performance, and can be electrified precise electronic products, such as handheld terminal electronic products like mobile phones and notebook computers. Meanwhile, the electrified antibacterial cleaning agent for the electronic products disclosed by the embodiment of the disclosure has the advantages of high resistivity, quick volatilization, low combustibility or incombustibility, good antibacterial property, no stimulation, no actual toxicity, no corrosion to most of rubber and plastics, and suitability for daily cleaning of the electronic products, such as daily cleaning of handheld electronic products such as mobile phones and notebook computers.

Description

Electronic product charged antibacterial cleaning agent
Technical Field
The application relates to the technical field of cleaning agents, for example to an electronic product charged antibacterial cleaning agent.
Background
In the long-term use of precision electronic products such as mobile phones and computers, screens and housings are stained with fingerprints, dust and grease are accumulated on receivers, earphone holes, loudspeakers, charger interfaces and the like, a large amount of bacteria are simultaneously parasitized on the parts, and therefore, diseases are spread, and the mobile phones, computers and other equipment need to be in a working state for a long time, so that the development of technologies for cleaning, bacteriostasis treatment and the like of the precision equipment such as the mobile phones, computers and the like in a live working state is very necessary.
The charged cleaning maintenance technology originated in the fortieth of the last century, belongs to a high and new technology with wide application and high technology content, and is divided into charged physical cleaning and chemical cleaning according to the cleaning method. The charged physical cleaning is to crush, decompose and peel off the dirt on the charged object surface by various mechanical external force and energy to achieve the cleaning effect, which can only clean the local dirt of the equipment, can not deeply clean the dirt such as acid, alkali, salt, oil and the like accumulated on the equipment surface, and has obvious defects in the aspects of operating conditions, cleaning effect and technical innovation, so the application is limited. Charged chemical cleaning is a method of removing dirt from charged equipment using one or more chemical agents. The development of the chemical charged cleaning technology is closely related to the development of the chemical technology in the world, each revolution of the chemical technology brings about the innovation of the charged cleaning technology, and the chemical charged cleaning technology has a larger development space and becomes the mainstream of the charged cleaning technology at present. The core of the chemical cleaning technology is cleaning agent, and in the beginning of the last 50 th century, people widely used cleaning solution mainly containing chlorohydrocarbon, such as dichloromethane, trichloroethane, carbon tetrachloride, trichloroethylene and tetrachloroethylene, and due to the high toxicity of the cleaning solution, chlorofluorocarbon cleaning agent such as trichlorotrifluoroethane (CFC-113) is developed. However, in the last 80 th century, it was found that the south-pole ozone hole has a direct relationship with the generation of chlorine atoms by the decomposition of chlorocarbons and chlorofluorocarbons, and it was called "ozone depletion enhancing substance (ODS)". In order to protect the ozone layer, the vienna convention on the protection of the ozone layer and the montreal protocol on the depletion of ozone layer substances are established to limit the application of ODS substances containing chlorocarbons and chlorofluorocarbons to electric cleaning, and at present, ODS cleaning agents are basically stopped in developed western countries. In recent 20 years, some chemical research institutes in japan and the usa developed a lot of non-ODS charged cleaning agents, such as 2, 3-dihydrodecafluoropentane, nonafluorobutyl methyl ether and nonafluorobutyl ethyl ether produced by 3M, which have zero Ozone Depletion Potential (ODP) and low Global Warming Potential (GWP), have the characteristics of no combustion, low toxicity, chemical stability, etc., and are widely used for charged cleaning and maintenance of precise instruments. At present, Vienna convention and Montreal protocol are comprehensively added in China, an integral elimination ODS plan in the China cleaning industry is provided, and the use of cleaning agents such as CFC-113 is completely stopped, so that domestic companies such as Lanxing and Qiwei are invested in a large amount of manpower and material resources to develop safe and environment-friendly electrified cleaning agents for precision equipment, and part of research results are applied to production practice.
In the process of implementing the embodiments of the present disclosure, it is found that at least the following problems exist in the related art: the existing charged cleaning agent has complex components and is not environment-friendly.
Disclosure of Invention
The following presents a simplified summary in order to provide a basic understanding of some aspects of the disclosed embodiments. This summary is not an extensive overview nor is intended to identify key/critical elements or to delineate the scope of such embodiments but rather as a prelude to the more detailed description that is presented later.
The embodiment of the disclosure provides an electronic product electrified antibacterial cleaning agent, which aims at cleaning a handheld electronic product and solves the problems of complex components and unfriendly environment of the existing electrified cleaning agent.
In some embodiments, the electronic product charged antibacterial cleaning agent comprises, by weight, 80% -95% of a fluorine-containing hydrocarbon compound with 2-5 carbon atoms and 5% -20% of alcohol with 2-3 carbon atoms.
The electrified antibacterial cleaning agent for the electronic product provided by the embodiment of the disclosure can realize the following technical effects:
the electronic product electrified antibacterial cleaning agent disclosed by the embodiment of the disclosure is environment-friendly, has good cleaning performance and antibacterial performance, and can be electrified precise electronic products, such as handheld terminal electronic products like mobile phones and notebook computers. Meanwhile, the electrified antibacterial cleaning agent for the electronic products disclosed by the embodiment of the disclosure has the advantages of high resistivity, quick volatilization, low or non-flammable combustibility, good antibacterial property, no stimulation, no actual toxicity, no corrosion to most of rubber and plastics, and suitability for daily cleaning of the electronic products, such as daily cleaning of handheld electronic products like mobile phones and notebook computers.
The foregoing general description and the following description are exemplary and explanatory only and are not restrictive of the application.
Detailed Description
So that the manner in which the features and technical contents of the embodiments of the present disclosure can be understood in detail, the embodiments of the present disclosure are described in detail below for illustrative purposes only and are not intended to limit the embodiments of the present disclosure. In the following description of the technology, for purposes of explanation, numerous details are set forth in order to provide a thorough understanding of the disclosed embodiments. However, one or more embodiments may be practiced without these details.
It should be noted that, in the case of no conflict, the embodiments and features in the embodiments of the present disclosure may be combined with each other.
The embodiment of the disclosure provides an electronic product charged antibacterial cleaning agent which is characterized by comprising 80-95 wt% of fluorine-containing hydrocarbon compound with 2-5 carbon atoms and 5-20 wt% of alcohol with 2-3 carbon atoms.
The charged antibacterial cleaning agent for the electronic product, disclosed by the embodiment of the disclosure, takes a fluorocarbon compound with 2-5 carbon atoms as a main solvent to play a cleaning role; the alcohol with 2-3 carbon atoms is used as an auxiliary solvent to play a role in inhibiting bacteria; the two materials supplement each other and act synergistically, so that the electronic product charged antibacterial cleaning solution which is environment-friendly, efficient, nontoxic, and good in cleaning performance and antibacterial performance is obtained. The electronic product can be a charged precise electronic product, such as a handheld electronic terminal of a mobile phone, a notebook computer and the like. The bacteriostatic cleaning agent disclosed by the embodiment of the disclosure has the following beneficial effects:
(1) the resistivity of the antibacterial cleaning agent is not lower than 2 MOmega cm, and the antibacterial cleaning agent can be used for cleaning electronic products under the condition of charged operation;
(2) the bacteriostatic cleaning agent has good cleaning effect and good dissolving and removing effects on common pollutants such as grease, dust and the like;
(3) the surface tension of the antibacterial cleaning agent is low, so that infiltration and permeation effects are easily generated on the surface of an electronic product, and the cleaning performance is enhanced; the density is high, the solubility to water is low, and the separation from pollutants is easy; meanwhile, the antibacterial cleaning agent is quick to volatilize, and the surface of an electronic product treated by the antibacterial cleaning agent is glossy and has no residue;
(4) the bacteriostatic cleaning agent has good bacteriostatic activity and has good bacteriostatic action on common Escherichia coli and staphylococcus aureus.
(5) The bacteriostatic cleaning agent has high chemical stability, and is not easy to decompose, deteriorate, reduce in performance and the like in the processes of storage, transportation and use.
(6) The bacteriostatic cleaning agent has good safety and environmental protection. The ozone layer destroying ability and the greenhouse effect of the solution components are low. The solution has no flash point or has high flash point, low or non-flammable combustibility, low toxicity (no actual toxicity) and no irritation.
(7) The bacteriostatic cleaning agent has good material compatibility, does not generate swelling, dissolving and deforming effects on most plastics and rubber, has little influence on characters, colors, paint coats and the like on equipment, and does not generate corrosion effect on most metals.
The bacteriostatic cleaning agent disclosed by the embodiment of the disclosure is prepared by uniformly mixing the fluorine-containing hydrocarbon compound and alcohol in proportion.
According to the bacteriostatic cleaning agent disclosed by the embodiment of the disclosure, the proportion of the fluorine-containing hydrocarbon compound and the lower alcohol is controlled, so that the cleaning agent has high resistivity, and meanwhile, the content of the alcohol is increased, and the effect of cleaning and bacteriostasis is ensured to be achieved.
In some embodiments, the bacteriostatic cleaning agent comprises 85-92 wt% of fluorine-containing hydrocarbon compound with 2-5 carbon atoms and 8-15 wt% of alcohol with 2-3 carbon atoms.
In some embodiments, the bacteriostatic cleaning agent comprises 90 wt% of fluorine-containing hydrocarbon compounds with 2-5 carbon atoms and 10 wt% of alcohol with 2-3 carbon atoms.
In some embodiments, the fluorocarbon compound having 2 to 5 carbon atoms has a resistivity of not less than 100 M.OMEGA.cm.
In some embodiments, the fluorine-containing hydrocarbon compound having 2 to 5 carbon atoms includes a fluoroalkane compound and/or a hydrofluoroether compound.
Alternatively, the fluoroalkane compound comprises pentafluorobutane and/or monofluorodichloroethane.
In the embodiment, the pentafluorobutane (HFC-365mfc) has high resistivity, the ozone consumption index of the solvent is zero, the greenhouse effect index of the solvent is close to that of fluorodichloroethane (HCFC-141b), the solvent has excellent solubility on pollutants such as grease and the like, spots are not easy to appear after volatilization, and the solvent has high applicability to most high molecular materials and metals and belongs to low-toxicity organic solution.
Monofluorodichloroethane (HCFC-141 b). The solvent is widely used in the field of cleaning, has high resistivity, is one tenth of CFC-113 in ozone depletion, has excellent solubility to pollutants such as grease and the like, is not easy to generate spots after volatilization, has high applicability to most of high polymer materials and metals, and belongs to low-toxicity and non-flammable liquid.
In this embodiment, when the fluoroalkane compound includes pentafluorobutane and monofluorodichloroethane, the two compounds cooperate with each other to improve the cleaning effect.
Optionally, the fluoroalkane compound comprises pentafluorobutane and monofluorodichloroethane, wherein the weight ratio of pentafluorobutane to monofluorodichloroethane is 0.2-6: 1. Optionally, the weight ratio of pentafluorobutane to monofluorodichloroethane is 1-6: 1. Optionally, the weight ratio of pentafluorobutane to monofluorodichloroethane is 2 to 5: 1. Alternatively, the weight ratio of pentafluorobutane to monofluorodichloroethane is 3: 1, 4: 1, etc.
Alternatively, the hydrofluoroether compound comprises 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether.
In this example, 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether (HFE-347), which has a high specific resistance, an ozone depletion index of zero, a low greenhouse effect, a high density, a low viscosity, a low surface tension, an excellent solubility for contaminants such as grease, a low tendency to form specks after volatilization, a high applicability for most of high molecular materials and metals, is a low-toxicity, nonflammable organic solution.
In some embodiments, the fluorocarbon compound with 2-5 carbon atoms comprises a fluoroalkane compound and a hydrofluoroether compound, and the weight ratio of the fluoroalkane compound to the hydrofluoroether compound is 0.2-6: 1. Optionally, the weight ratio of the fluoroalkane compound to the hydrofluoroether compound is 1-6: 1. Optionally, the weight ratio of the fluoroalkane compound to the hydrofluoroether compound is 2-5: 1. Alternatively, the weight ratio of the fluoroalkane compound to the hydrofluoroether compound is 3: 1, 4: 1, etc.
Alternatively, the fluoroalkane compound includes pentafluorobutane and/or monofluorodichloroethane. When the fluoroalkane compound comprises pentafluorobutane and monofluorodichloroethane, the weight ratio of pentafluorobutane to monofluorodichloroethane is 0.3-2: 1. Optionally, the weight ratio of pentafluorobutane to monofluorodichloroethane is 0.5 to 1.6: 1. Optionally, the weight ratio of pentafluorobutane to monofluorodichloroethane is 1-1.3: 1.
In the disclosed embodiment, three different detergents can be obtained depending on the main solvent, as follows:
the bacteriostatic cleaning agent I comprises 80-95 wt% of pentafluorobutane and 5-20 wt% of alcohol with 2-3 carbon atoms.
The bacteriostatic cleaning agent II comprises 80-95 wt% of monofluoro dichloroethane and 5-20 wt% of alcohol with 2-3 carbon atoms.
The bacteriostatic cleaning agent III comprises 80-95 wt% of mixed solution of pentafluorobutane and monofluorodichloroethane and 5-20 wt% of alcohol with 2-3 carbon atoms.
The bacteriostatic cleaning agent IV comprises 80-95 wt% of 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether and 5-20 wt% of alcohol with 2-3 carbon atoms.
The bacteriostatic cleaning agent V comprises 80-95 wt% of mixed solution of pentafluorobutane and 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether and 5-20 wt% of alcohol with 2-3 carbon atoms.
The bacteriostatic cleaning agent VI comprises 80-95 wt% of mixed solution of monofluorodichloroethane and 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether and 5-20 wt% of alcohol with 2-3 carbon atoms.
The antibacterial cleaning agent VII comprises, by weight, 80% -95% of mixed liquid of pentafluorobutane, monofluorodichloroethane and 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether and 5% -20% of alcohol with the carbon atom number of 2-3.
In some embodiments, the bacteriostatic cleaning agent comprises alcohol with 2-3 carbon atoms, wherein the alcohol comprises ethanol and/or isopropanol. The ethanol and the isopropanol have strong solubility and low toxicity to lipophilic substances, have good solubility in both the fluoroalkane compound and the hydrofluoroether compound, are blended with the fluoroalkane compound and/or the hydrofluoroether compound to have synergistic effect, improve the cleaning capability of the fluoroalkane compound and the hydrofluoroether compound and simultaneously play a role in bacteriostasis.
Optionally, the alcohol with 2-3 carbon atoms comprises ethanol and isopropanol. The mixing ratio of isopropyl alcohol and ethanol is not limited, and may be any ratio. Optionally, the weight ratio of isopropanol to ethanol is 1: 5: 1. Alternatively, the weight ratio of isopropanol to ethanol is 1: 1, 2: 1, 3: 1, 4: 1, 5: 1, or any other ratio.
Specific examples of the embodiments of the present disclosure are given below.
Example 1
The bacteriostatic cleaning agent I comprises 80-95 wt% of pentafluorobutane and 5-20 wt% of alcohol with 2-3 carbon atoms.
According to different weight percentages of pentafluorobutane and alcohol, the following different bacteriostatic cleaning agent I samples are obtained and corresponding performance tests are carried out, and the specific samples and the performances thereof are shown in the following Table 1.
TABLE 1
Figure BDA0002821721470000061
Figure BDA0002821721470000071
Specific volatilization rate (%): the volatilization speed of n-butyl acetate was defined as 100% based on the volatilization speed of n-butyl acetate, and the volatilization speeds of the other solvents were compared with the specific volatilization speed of n-butyl acetate.
According to the components in the table 1 and the respective weight percentages, the antibacterial cleaning agent I in the embodiment 1 is obtained by uniformly mixing pentafluorobutane with ethanol and/or isopropanol.
Example 2
The bacteriostatic cleaning agent II in the embodiment 2 comprises 80-95 wt% of monofluorodichloroethane and 5-20 wt% of alcohol with 2-3 carbon atoms.
According to different weight percentages of the monofluorodichloroethane and the alcohol, the following different samples of the bacteriostatic cleaning agent II are obtained and corresponding performance tests are carried out, and the specific samples and the performance thereof are shown in the following table 2.
TABLE 2
Figure BDA0002821721470000072
Specific volatilization rate (%): the volatilization speed of n-butyl acetate was defined as 100% based on the volatilization speed of n-butyl acetate, and the volatilization speeds of the other solvents were compared with the specific volatilization speed of n-butyl acetate.
Uniformly mixing monofluorodichloroethane with ethanol and/or isopropanol according to the components and the respective weight percentages in the table 2 to obtain the bacteriostatic cleaning agent II in the embodiment 2.
Example 3
The bacteriostatic cleaning agent III comprises 80-95 wt% of mixed solution of pentafluorobutane and monofluorodichloroethane and 5-20 wt% of alcohol with 2-3 carbon atoms.
According to different weight percentages of pentafluorobutane, monofluorodichloroethane and alcohol, the following different samples of the antibacterial detergent III are obtained and corresponding performance tests are carried out, and specific samples and performances thereof are shown in Table 3 below.
TABLE 3
Figure BDA0002821721470000081
Specific volatilization rate (%): the volatilization speed of n-butyl acetate was defined as 100% based on the volatilization speed of n-butyl acetate, and the volatilization speeds of the other solvents were compared with the specific volatilization speed of n-butyl acetate.
And uniformly mixing pentafluorobutane, monofluorodichloroethane, ethanol and/or isopropanol according to the components and the respective weight percentages in the table 3 to obtain the antibacterial cleaning agent III in the embodiment 3.
Example 4
The bacteriostatic cleaning agent iv of this embodiment 4 includes, by weight, 80% to 95% of 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether (abbreviated as tetrafluoroethyl-trifluoroethyl ether) and 5% to 20% of an alcohol having 2 to 3 carbon atoms.
According to different weight percentages of the tetrafluoroethyl-trifluoroethyl ether and the alcohol, the following different antibacterial detergent IV samples are obtained and corresponding performance tests are carried out, and specific samples and performances thereof are shown in the following table 4.
TABLE 4
Figure BDA0002821721470000082
Figure BDA0002821721470000091
Specific volatilization rate (%): the volatilization speed of n-butyl acetate was defined as 100% based on the volatilization speed of n-butyl acetate, and the volatilization speeds of the other solvents were compared with the specific volatilization speed of n-butyl acetate.
And (3) uniformly mixing the tetrafluoroethyl-trifluoroethyl ether with ethanol and/or isopropanol according to the components and the respective weight percentages in the table 4 to obtain the bacteriostatic cleaning agent IV of the embodiment 4.
Example 5
The bacteriostatic cleaning agent V comprises 80-95 wt% of mixed solution of pentafluorobutane and 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether (abbreviated as tetrafluoroethyl-trifluoroethyl ether) and 5-20 wt% of alcohol with 2-3 carbon atoms.
According to different weight percentages of pentafluorobutane, tetrafluoroethyl-trifluoroethyl ether and alcohol, the following different antibacterial detergent V samples are obtained and corresponding performance tests are carried out, and the specific samples and the performances thereof are shown in Table 5 below.
TABLE 5
Figure BDA0002821721470000092
Specific volatilization rate (%): the volatilization speed of n-butyl acetate was defined as 100% based on the volatilization speed of n-butyl acetate, and the volatilization speeds of the other solvents were compared with the specific volatilization speed of n-butyl acetate.
And (3) uniformly mixing pentafluorobutane, tetrafluoroethyl-trifluoroethyl ether, ethanol and/or isopropanol according to the components in the above table 5 and the respective weight percentages to obtain the antibacterial detergent V in the embodiment 5.
Example 6
The bacteriostatic cleaning agent vi in this embodiment 6 includes, by weight, 80% to 95% of a mixed solution of monofluorodichloroethane and 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether (abbreviated as tetrafluoroethyl-trifluoroethyl ether), and 5% to 20% of an alcohol having 2 to 3 carbon atoms.
According to different weight percentages of monofluorodichloroethane, tetrafluoroethyl-trifluoroethyl ether and alcohol, the following different samples of the antibacterial detergent VI are obtained and corresponding performance tests are carried out, and specific samples and the performances thereof are shown in the following table 6.
TABLE 6
Figure BDA0002821721470000101
Specific volatilization rate (%): the volatilization speed of n-butyl acetate was defined as 100% based on the volatilization speed of n-butyl acetate, and the volatilization speeds of the other solvents were compared with the specific volatilization speed of n-butyl acetate.
Uniformly mixing monofluorodichloroethane, tetrafluoroethyl-trifluoroethyl ether, ethanol and/or isopropanol according to the components in the weight percentage and the weight percentage of each component in the table 6 to obtain the bacteriostatic cleaning agent VI of the embodiment 6.
Example 7
In this embodiment 7, the antibacterial cleaning agent vii includes, by weight, 80% to 95% of a mixed solution of pentafluorobutane, monofluorodichloroethane, and 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether (abbreviated as tetrafluoroethyl-trifluoroethyl ether), and 5% to 20% of an alcohol having 2 to 3 carbon atoms.
According to different weight percentages of pentafluorobutane, monofluorodichloroethane, tetrafluoroethyl-trifluoroethyl ether and alcohol, the following different antibacterial cleaning agent VII samples are obtained and corresponding performance tests are carried out, and specific samples and performances thereof are shown in Table 7 below.
TABLE 7
Figure BDA0002821721470000102
Figure BDA0002821721470000111
Specific volatilization rate (%): the volatilization speed of n-butyl acetate was defined as 100% based on the volatilization speed of n-butyl acetate, and the volatilization speeds of the other solvents were compared with the specific volatilization speed of n-butyl acetate.
And mixing pentafluorobutane, monofluorodichloroethane, tetrafluoroethyl-trifluoroethyl ether, ethanol and/or isopropanol uniformly according to the components and the respective weight percentages in the table 7 to obtain the antibacterial cleaning agent VII in the embodiment 7.
In the embodiment of the disclosure, the flash point detection, the bacteriostatic effect detection and the toxicology test are respectively carried out on the bacteriostatic cleaning agent I-2 (sample I), the bacteriostatic cleaning agent II-2 (sample II) and the bacteriostatic cleaning agent IV-2 (sample III), and the test results are as follows:
1. according to the measurement of GB/T5208-2008 flash point: the samples I-III are detected by a rapid equilibrium closed cup method, and the samples have no flash point at the temperature of 55.0 ℃ or below. It can be seen that the bacteriostatic cleaning agent of the embodiment of the disclosure has a flash point of more than 55.0 ℃, even no flash point, and low or non-flammable flammability.
2. According to the 7.3-section bacteriostatic daily chemical product bacteriostatic effect test method (suspension quantitative method) in the evaluation method of the antibacterial bacteriostatic effect of QB/T2738-.
3. Toxicology tests were performed on the samples submitted for inspection, according to the "Disinfection Specification" (2002 edition). Wherein, the acute inhalation toxicity test result shows that: samples I-III acute inhaled half-Lethal (LC) dose in female and male KM mice50) The concentration is more than 10000mg/m3, and the samples are actually nontoxic according to the evaluation and classification of acute inhalation toxicity. The result of one complete skin irritation test shows that: the highest stimulation index of skin stimulation is 0, the skin stimulation intensity of the sample to the Japanese big ear white rabbit is graded according to the skin stimulation intensity of the disinfection product, and the sample has no stimulation. Thus, the bacteriostatic cleaning agents of the disclosed embodiments are practically non-toxic.
Based on this, the bacteriostatic cleaning agent disclosed by the embodiment of the disclosure has low flammability or incombustibility, good bacteriostatic property, no irritation, and no actual toxicity, and is suitable for daily cleaning of electronic products, such as handheld electronic products like mobile phones and notebook computers.
The above description sufficiently illustrates embodiments of the disclosure to enable those skilled in the art to practice them. Other embodiments may include structural and other changes. The examples merely typify possible variations. Individual components and functions are optional unless explicitly required, and the sequence of operations may vary. Portions and features of some embodiments may be included in or substituted for those of others. The embodiments of the present disclosure are not limited to the structures that have been described above, and various modifications and changes may be made without departing from the scope thereof. The scope of the present disclosure is limited only by the appended claims.

Claims (10)

1. An electronic product charged antibacterial cleaning agent is characterized by comprising 80-95 wt% of fluorine-containing hydrocarbon compounds with 2-5 carbon atoms and 5-20 wt% of alcohol with 2-3 carbon atoms.
2. The charged antibacterial cleaning agent as claimed in claim 1, which comprises 85-92% by weight of fluorine-containing hydrocarbon compound with 2-5 carbon atoms and 8-15% by weight of alcohol with 2-3 carbon atoms.
3. The charged antibacterial cleaning agent as claimed in claim 1, which comprises 90% by weight of fluorine-containing hydrocarbon compound with 2-5 carbon atoms and 10% by weight of alcohol with 2-3 carbon atoms.
4. The charged antibacterial cleaning agent as claimed in claim 1,2 or 3, wherein the resistivity of the fluorine-containing hydrocarbon compound having 2-5 carbon atoms is not less than 100M Ω -cm.
5. The charged bacteriostatic cleaning agent according to claim 1,2 or 3, wherein the fluorine-containing hydrocarbon compound with 2-5 carbon atoms comprises a fluoroalkane compound and/or a hydrofluoroether compound.
6. Charged bacteriostatic detergent according to claim 5, characterized in that the fluoroalkane compound comprises pentafluorobutane and/or monofluorodichloroethane.
7. The charged bacteriostatic detergent according to claim 6, wherein when the fluoroalkane compound comprises pentafluorobutane and monofluorodichloroethane, the weight ratio of the pentafluorobutane to the monofluorodichloroethane is 0.2-6: 1.
8. The charged bacteriostatic detergent according to claim 5, wherein the hydrofluoroether compound comprises 1,1,2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether.
9. The charged antibacterial cleaning agent according to claim 8, wherein the fluorocarbon compound having 2 to 5 carbon atoms comprises a fluoroalkane compound and a hydrofluoroether compound, and the weight ratio of the fluoroalkane compound to the hydrofluoroether compound is 0.2 to 6: 1.
10. The charged bacteriostatic cleaning agent according to claim 1,2 or 3, wherein the alcohol with 2-3 carbon atoms comprises ethanol and/or isopropanol.
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