CN107022431A - Industrial cleaning agent and preparation method thereof - Google Patents

Industrial cleaning agent and preparation method thereof Download PDF

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Publication number
CN107022431A
CN107022431A CN201710305143.7A CN201710305143A CN107022431A CN 107022431 A CN107022431 A CN 107022431A CN 201710305143 A CN201710305143 A CN 201710305143A CN 107022431 A CN107022431 A CN 107022431A
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China
Prior art keywords
cleaning agent
industrial cleaning
industrial
preparation
raw material
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Granted
Application number
CN201710305143.7A
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Chinese (zh)
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CN107022431B (en
Inventor
梁伟明
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Guangdong Laiya New Chemical Technology Co ltd
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GUANGDONG LAYA CHEMICAL CO Ltd
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Priority to CN201710305143.7A priority Critical patent/CN107022431B/en
Publication of CN107022431A publication Critical patent/CN107022431A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5004Organic solvents
    • C11D7/5022Organic solvents containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/266Esters or carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/28Organic compounds containing halogen
    • C11D7/30Halogenated hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to a kind of industrial cleaning agent and preparation method thereof.The industrial cleaning agent includes the raw material of following percentage by weight:One fluorine dichloroethanes 50% 90%, tetrachloro-ethylene 5% 20%, alcohol solvent of ether ester type 1% 15% and propellant 1% 15%.The industrial cleaning agent passes through the substantial amounts of creative specific species and proportioning for testing and studying screening alkane solvents, esters solvent and propellant, make the industrial freshener on the whole can be non-combustible, cleaning force is strong, volatility reduction and toxic residue is few, safety and environmental protection, and the not outer surface of part of damage, and there is certain maintenance action to the outer surface of part.

Description

Industrial cleaning agent and preparation method thereof
Technical field
The present invention relates to cleaning agent field, more particularly to a kind of industrial cleaning agent and preparation method thereof.
Background technology
In the industrial production, cleaning is the indispensable process procedure in being processed, assembling, storing and repairing.Clearly Substantial amounts of industrial cleaning agent will be used by washing in process.But, the technique cleaning agent of conventional art is inflammable and explosive, using dangerous and Cleaning performance is bad.
The content of the invention
Based on this, it is necessary to provide it is a kind of it is nonflammable, cleaning efficiently and the industrial cleaning agent of safety and environmental protection and its preparation side Method.
A kind of industrial cleaning agent, includes the raw material of following percentage by weight:
In one of the embodiments, the industrial cleaning agent includes the raw material of following percentage by weight:
In one of the embodiments, the industrial cleaning agent includes the raw material of following percentage by weight:
In one of the embodiments, the alcohol solvent of ether ester type is propylene glycol methyl ether acetate.Propylene glycol monomethyl ether acetic acid The molecule of ester (PGMEA) includes ehter bond, carbonyl and alkyl, and wherein carbonyl forms ester structure.It is existing non-in its same molecule Polar portion, and polarized part, both mutually restriction was repelled for this two-part functional group, and its intrinsic effect is played again.The third two Alcohol methyl ether acetate is the environment-friendly type industrial solvent of function admirable, there is very strong dissolving energy to polarity and nonpolar material Power.
In one of the embodiments, the propellant is carbon dioxide or nitrogen.Carbon dioxide and nitrogen are can not Combustion gas body, ensure that flame retardant effect.
The industrial cleaning agent of the present invention by it is substantial amounts of it is creative test and research screening alkane solvents, esters solvent and The specific species and proportioning of propellant.One fluorine dichloroethanes has stronger cleaning force to pollutant, and volatility is relatively low, its with One fluorine dichloroethanes, which coordinates, can preferably remove the pollutant of metal surface, and alcohol solvent of ether ester type contains function groups, Neng Gourong Multiple pollutant is solved, is that a fluorine dichloroethanes and tetrachloro-ethylene provide cleaning reaction environment.A fluorine dichloroethanes in the present invention, Have between tetrachloro-ethylene and alcohol solvent of ether ester type and cooperate with facilitation, it is ensured that make the industrial freshener on the whole can not Combustion, cleaning force is strong, volatility reduction and toxic residue is few, safety and environmental protection.By the proportioning for controlling propellant, it is ensured that feed liquid can be with Preferably spray, the not outer surface of part of damage, and there is certain maintenance action to the outer surface of part.
Further, industrial cleaning agent of the invention is by screening a fluorine dichloroethanes, tetrachloro-ethylene, propylene glycol monomethyl ether vinegar The optimum ratio of acid esters and carbon dioxide, it is ensured that have between a fluorine dichloroethanes, tetrachloro-ethylene and propylene glycol methyl ether acetate Optimal collaboration facilitation, make integral formula cleaning performance more preferably, anti-flammability is stronger, and the industrial cleaning agent is employed Environment-friendly type raw material, small to the body-stimulating of user, toxic residue is few, more safety and environmental protection.
A kind of preparation method of industrial cleaning agent is provided in addition, there is a need to.
A kind of preparation method of industrial cleaning agent comprises the following steps:
Amounts of components according to above-mentioned industrial cleaning agent measures each component;
The tetrachloro-ethylene and the alcohol solvent of ether ester type are mixed under agitation, the chloroethene of a fluorine two is added Alkane, stirring mixing, obtains feed liquid;
The feed liquid is filled into tank body, plus valve, sealing, the propellant is filled, check weighing, water bath with thermostatic control is leaked hunting, Code is penetrated, is capped, produces.
The preparation method technique of the industrial cleaning agent is simple, it is easy to operates, is suitable for industrialization production, can extensive use.
Embodiment
For the ease of understanding the present invention, the present invention will be described more fully below.The present invention can be with many not With form realize, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is made to this The understanding of the disclosure of invention is more thorough comprehensive.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention The implication that technical staff is generally understood that is identical.Term used in the description of the invention herein is intended merely to description tool The purpose of the embodiment of body, it is not intended that in the limitation present invention.
Component used is commercially available mill run in the embodiment of the present invention.
Preferred embodiment is that the industrial cleaning agent of the present invention is further described in detail below, rather than to the present invention Limitation.
Embodiment 1
The present embodiment provides a kind of industrial cleaning agent, includes the raw material of following percentage by weight:
The preparation method of the industrial cleaning agent of the present embodiment, comprises the following steps:
Amounts of components according to above-mentioned industrial cleaning agent measures each component;
The tetrachloro-ethylene and the alcohol solvent of ether ester type are mixed under agitation, the chloroethene of a fluorine two is added Alkane, stirring mixing, obtains feed liquid;
The feed liquid is filled into tank body, plus valve, sealing, the propellant is filled, check weighing, water bath with thermostatic control is leaked hunting, Code is penetrated, is capped, produces.
Embodiment 2
The present embodiment provides a kind of industrial cleaning agent, includes the raw material of following percentage by weight:
The preparation method of the industrial cleaning agent of the present embodiment is identical with the preparation method of embodiment 1.
Embodiment 3
The present embodiment provides a kind of industrial cleaning agent, includes the raw material of following percentage by weight:
The preparation method of the industrial cleaning agent of the present embodiment is identical with the preparation method of embodiment 1.
Embodiment 4
The present embodiment provides a kind of industrial cleaning agent, includes the raw material of following percentage by weight:
The preparation method of the industrial cleaning agent of the present embodiment is identical with the preparation method of embodiment 1.
Embodiment 5
The present embodiment provides a kind of industrial cleaning agent, includes the raw material of following percentage by weight:
The preparation method of the industrial cleaning agent of the present embodiment is identical with the preparation method of embodiment 1.
Embodiment 6
The present embodiment provides a kind of industrial cleaning agent, includes the raw material of following percentage by weight:
The preparation method of the industrial cleaning agent of the present embodiment is identical with the preparation method of embodiment 1.
Comparative example 1
This comparative example provides a kind of industrial cleaning agent, includes the raw material of following percentage by weight:
The preparation method of the industrial cleaning agent of the present embodiment is identical with the preparation method of embodiment 1.
Comparative example 2
This comparative example provides a kind of industrial cleaning agent, includes the raw material of following percentage by weight:
The preparation method of the industrial cleaning agent of the present embodiment is identical with the preparation method of embodiment 1.
Comparative example 3
This comparative example provides a kind of industrial cleaning agent, includes the raw material of following percentage by weight:
The preparation method of the industrial cleaning agent of the present embodiment is identical with the preparation method of embodiment 1
Measure of merit
By the flammable implementations statistics of the industrial cleaning agent of embodiment 1 to 3 and comparative example 1 to 3 and for sample clean The statistics of cleaning force effect, as a result see the table below 1.
The flammable implementations statistics and the statistical form of the cleaning force effect for sample clean of the industrial cleaning agent of table 1
As shown in Table 1, compared with comparative example 1 to 3, the industrial cleaning agent of embodiment 1 to 3 is non-combustible, pacifies during use Quan Xinggao, and its spot cleaning rate is all higher than 95%, cleaning performance is good.When a fluorine dichloroethane content is high and tetrachloro-ethylene contains When measuring a low low or fluorine dichloroethane content and high content of tetrachloro-ethylene, overall formula system is flammable and cleaning force is poor.When When propellant is from non-combustible gas such as nitrogen and carbon dioxide, pressure during ejection can be improved, it is possible to increase overall formula The cleaning performance of system.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, the scope of this specification record is all considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that coming for one of ordinary skill in the art Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (6)

1. a kind of industrial cleaning agent, it is characterised in that include the raw material of following percentage by weight:
2. industrial cleaning agent according to claim 1, it is characterised in that include the raw material of following percentage by weight:
3. industrial cleaning agent according to claim 2, it is characterised in that include the raw material of following percentage by weight:
4. the industrial cleaning agent according to claim any one of 1-3, it is characterised in that the alcohol solvent of ether ester type is the third two Alcohol methyl ether acetate.
5. the industrial cleaning agent according to claim any one of 1-3, it is characterised in that the propellant be carbon dioxide or Nitrogen.
6. the preparation method of the industrial cleaning agent any one of a kind of claim 1 to 5, it is characterised in that including as follows Step:
Amounts of components according to industrial cleaning agent any one of claim 1 to 5 measures each component;
The tetrachloro-ethylene and the alcohol solvent of ether ester type are mixed under agitation, the fluorine dichloroethanes is added, Stirring mixing, obtains feed liquid;
The feed liquid is filled into tank body, plus valve, sealing, the propellant is filled, check weighing, water bath with thermostatic control is leaked hunting, and penetrates code, Capping, is produced.
CN201710305143.7A 2017-05-03 2017-05-03 Industrial cleaning agent and preparation method thereof Active CN107022431B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112553014A (en) * 2020-12-07 2021-03-26 北京飞狐鱼智能科技有限公司 Electronic product charged antibacterial cleaning agent
CN113004987A (en) * 2021-02-05 2021-06-22 广东莱雅新化工科技有限公司 Non-combustible environment-friendly cleaning agent and preparation method and application thereof
CN114015518A (en) * 2021-12-01 2022-02-08 重庆朗福环保科技有限公司 Carbon cleaning strong-effect gas cleaning agent and preparation and use methods thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1085945A (en) * 1992-10-20 1994-04-27 航空航天工业部第一研究院第一○一研究所 Degreased cleaning agent
CN1445352A (en) * 2002-10-16 2003-10-01 杭州贝尔通讯系统有限公司 Cleaning agent for electronics equipments
CN1861774A (en) * 2006-06-05 2006-11-15 太仓市宝马环境工程有限公司 Degreased cleaning agent
US20070203046A1 (en) * 2006-02-28 2007-08-30 Minor Barbara H Azeotropic compositions comprising fluorinated compounds for cleaning applications
CN101538514A (en) * 2009-03-11 2009-09-23 上海九盛实业有限公司 Electrical appliance cleaner and preparation thereof
CN102839067A (en) * 2012-09-07 2012-12-26 北京雅迪力特航空化学制品有限公司 Degumming composite, degumming aerosol and preparation method thereof
CN103013710A (en) * 2012-12-19 2013-04-03 长沙艾森设备维护技术有限公司 Static-eliminating cleaning agent for electronic device
CN105647695A (en) * 2016-02-24 2016-06-08 苏州龙腾万里化工科技有限公司 Solvent type efficient compound cleaning detergent
CN106574215A (en) * 2014-05-13 2017-04-19 科慕埃弗西有限公司 Compositions of methyl perfluoroheptene ethers, 1,1,1,2,2,3,4,5,5,5-decafluoropentane and trans-1,2-dichloroethylene and uses thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1085945A (en) * 1992-10-20 1994-04-27 航空航天工业部第一研究院第一○一研究所 Degreased cleaning agent
CN1445352A (en) * 2002-10-16 2003-10-01 杭州贝尔通讯系统有限公司 Cleaning agent for electronics equipments
US20070203046A1 (en) * 2006-02-28 2007-08-30 Minor Barbara H Azeotropic compositions comprising fluorinated compounds for cleaning applications
CN1861774A (en) * 2006-06-05 2006-11-15 太仓市宝马环境工程有限公司 Degreased cleaning agent
CN101538514A (en) * 2009-03-11 2009-09-23 上海九盛实业有限公司 Electrical appliance cleaner and preparation thereof
CN102839067A (en) * 2012-09-07 2012-12-26 北京雅迪力特航空化学制品有限公司 Degumming composite, degumming aerosol and preparation method thereof
CN103013710A (en) * 2012-12-19 2013-04-03 长沙艾森设备维护技术有限公司 Static-eliminating cleaning agent for electronic device
CN106574215A (en) * 2014-05-13 2017-04-19 科慕埃弗西有限公司 Compositions of methyl perfluoroheptene ethers, 1,1,1,2,2,3,4,5,5,5-decafluoropentane and trans-1,2-dichloroethylene and uses thereof
CN105647695A (en) * 2016-02-24 2016-06-08 苏州龙腾万里化工科技有限公司 Solvent type efficient compound cleaning detergent

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112553014A (en) * 2020-12-07 2021-03-26 北京飞狐鱼智能科技有限公司 Electronic product charged antibacterial cleaning agent
CN113004987A (en) * 2021-02-05 2021-06-22 广东莱雅新化工科技有限公司 Non-combustible environment-friendly cleaning agent and preparation method and application thereof
CN114015518A (en) * 2021-12-01 2022-02-08 重庆朗福环保科技有限公司 Carbon cleaning strong-effect gas cleaning agent and preparation and use methods thereof
CN114015518B (en) * 2021-12-01 2023-10-27 重庆朗福环保科技有限公司 Carbon-cleaning powerful gas cleaning agent and preparation and use methods thereof

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Effective date of registration: 20200319

Address after: 512026 South 7 Gantang Avenue, Xilian Town, Wujiang District, Shaoguan City, Guangdong Province

Applicant after: Guangdong Laiya New Chemical Technology Co.,Ltd.

Address before: 528333 Guangdong province Foshan city Shunde District Daliang Shunfengshan Industrial Zone

Applicant before: GUANGDONG LAYA CHEMICAL Co.,Ltd.

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PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Industrial cleaning agents and their preparation methods

Granted publication date: 20200421

Pledgee: China Postal Savings Bank Co.,Ltd. Shaoguan Branch

Pledgor: Guangdong Laiya New Chemical Technology Co.,Ltd.

Registration number: Y2024980012739

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