CN109638382A - A kind of micro-channel flat and the compound rectangular/soft-package battery grouping method of phase-change material - Google Patents

A kind of micro-channel flat and the compound rectangular/soft-package battery grouping method of phase-change material Download PDF

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Publication number
CN109638382A
CN109638382A CN201811538267.0A CN201811538267A CN109638382A CN 109638382 A CN109638382 A CN 109638382A CN 201811538267 A CN201811538267 A CN 201811538267A CN 109638382 A CN109638382 A CN 109638382A
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battery
phase
change material
temperature
cooling
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CN201811538267.0A
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冯能莲
李德壮
丰收
王静
董士康
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Beijing University of Technology
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Beijing University of Technology
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/613Cooling or keeping cold
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/482Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for several batteries or cells simultaneously or sequentially
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/62Heating or cooling; Temperature control specially adapted for specific applications
    • H01M10/625Vehicles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/63Control systems
    • H01M10/633Control systems characterised by algorithms, flow charts, software details or the like
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/63Control systems
    • H01M10/635Control systems based on ambient temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6554Rods or plates
    • H01M10/6555Rods or plates arranged between the cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/656Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
    • H01M10/6567Liquids
    • H01M10/6568Liquids characterised by flow circuits, e.g. loops, located externally to the cells or cell casings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/659Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/20Batteries in motive systems, e.g. vehicle, ship, plane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Automation & Control Theory (AREA)
  • Secondary Cells (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

A kind of Compound cooling/heating means of rectangular/soft-package battery are related to the field of heat management of battery.The heat management grouping method that one kind meets domestic electric car (pure electric automobile, hybrid vehicle) is devised for rectangular/soft-package battery.The compound microchannel liquid cooling of this method and two kinds of types of cooling of phase-change material, microchannel and phase-change material distribute alternately in Compound cooling cold plate, and the cooling/heating to battery is realized by the compound action of heat transfer medium and phase-change material in microchannel.This method, which is easy to adjust the type of cooling according to heat management design requirement, extends the service life of battery system, and can improve the safety of battery system to enhance the heat transfer effect of heat transfer medium and battery.

Description

A kind of micro-channel flat and the compound rectangular/soft-package battery grouping method of phase-change material
Technical field
The present invention relates to electric car (pure electric automobile, hybrid vehicle) it is rectangular/soft-package battery field of heat management.
Background technique
In the increasing situation of the environmental problems such as energy crisis, global warming, environmental pollution, electric car is increasingly Developing direction as future automobile.With going deep into for electric car research, a critical component of the battery as electric car It is increasingly becoming the hot spot of research, and the quality of battery performance is then a key factor of Development of Electric Vehicles.
The principal element for influencing battery has charge-discharge magnification, charge and discharge blanking voltage, shelves condition, using temperature etc., this Several factors mutually restrict, and influence each other.But with regard to using for temperature, current battery cell in low temperature (being lower than -30 DEG C) and High temperature all can not work normally in the environment of (being higher than 50 DEG C), and causing at this time also can not be normal by the vehicle in energy source of battery Work, makes that vehicle is unable to reach the requirement of round-the-clock running and orthodox car compares its use and has biggish limitation.
In addition, electric car, in starting climbing or acceleration suddenly, the battery in middle position accumulates heat, battery temperature It steeply rises, battery electrode material, diaphragm and electrolyte etc. will decompose, and generate gas and increase inside battery air pressure, produce Heat out-of-control phenomenon.When situation is serious, or even liquid leakage can be caused, the major accidents such as explosion occur, are made to the operation of vehicle At security risk.
The development and popularization of electric car are seriously constrained using the presence of temperature problem, therefore, battery temperature controls mesh Before have become new-energy automobile development bottleneck.How by battery temperature control be still in a certain range one in a short time Insoluble problem.
Summary of the invention
The present invention is directed to rectangular/soft-package battery, devises a kind of Compound cooling/heating means.This method is easy to according to heat Management design demand adjusts the type of cooling of rectangular/soft-package battery, to enhance the heat transfer effect of heat transfer medium and battery, extends The service life of battery system, and the safety of battery system can be improved.
A kind of method for composite cooling of rectangular/soft-package battery, it is characterised in that: rectangular/Soft Roll electricity of the Compound cooling Pond modular array includes the battery mould of water inlet pipe, water inlet end, return pipe, Setting MARC, Compound cooling cold plate and several arrays Group, if battery modules block cooperation is equipped with dry temperature sensor, if the dry temperature sensor is respectively connected to external temperature control The both ends of mechanism, the external temperature control mechanism pass through piping connection to water inlet pipe and return pipe.Microchannel and phase-change material are multiple It closes and distributes alternately in cooled cold plate, realized by the compound action of heat transfer medium and phase-change material in microchannel to the cold of battery But/heating.
Distributing alternately is exactly to be separated by distribution, i.e., microchannel, phase-change material, microchannel, phase-change material ... .. are spaced such that Distribution.
Further, it is equipped between rectangular/packaging of soft packaged monomer in battery modules, between battery modules and Compound cooling cold plate Several heat conductive pads.
Further, the quantity of water inlet pipe and return pipe, position can be determined according to thermal management requirements.
Further, which is characterized in that the structure of water inlet end and water outlet end can be integral feed-through type, also can be separate chamber Body formula, individual cavity formula structure is corresponding with more water inlet pipes/outlet pipe scheme, can be according to the fever feelings of battery modules different location Condition reasonable distribution flow, guarantees the temperature consistency of battery modules.
Further, phase-change material distributes alternately with microchannel in Compound cooling cold plate, and phase-change material is multilayer sandwiched knot Structure, arrangement high thermal conductivity substrate is to increase the thermal coefficient of phase-change material between volume of phase-change material, so as to faster by the heat of absorption Amount is shed by the coolant liquid in microchannel, guarantees the lasting decalescence process of phase-change material.
Further, the method for composite cooling the following steps are included:
Step 1: control mechanism is instructed, and controller is opened;
Step 2: controller issues instruction, and battery system is started to work, while controller control temperature sensor acquisition electricity Pond temperature data;
Step 3: current temperature data is judged, if battery module maximum temperature is less than phase-change material transition temperature range T1~ T2In T2, then follow the steps 4;If temperature is more than or equal to T2And it is less than T3, then follow the steps 5;If temperature is greater than T3And it is less than Tmax, then follow the steps 6;If temperature is greater than Tmax, then follow the steps 7;
Step 4: controller closes inlet tube and outlet tube, cools down battery, while mistake merely with the latent heat of phase change of phase-change material at this time The temperature of battery modules block is detected in journey, if temperature is greater than T2, return step 3;
Step 5: controller controls temperature control mechanism, opens inlet tube and outlet tube and realizes microchannel and phase-change material Compound cooling, but Only realize that the circulation of coolant liquid, coolant liquid are not connected to external forced heat-exchanger rig by water circulating pump at this time;
Step 6: coolant liquid is connect with external forced heat-exchanger rig, and the heat of coolant liquid is exchanged by forced heat-exchanging device To the external world;
Step 7: controller issues excess temperature early warning, and the connection of cutoff high system is communicated with entire car controller.Wherein: T1 ~T2: 40~45 DEG C;Wherein T3The value in 45~50 DEG C;TmaxThe value in 50~60 DEG C, and T3Less than Tmax.This field skill Art personnel are specifically adjusted according to thermal management requirements, to temperature.Such as T3It is 50 DEG C, TmaxIt is 60 DEG C.
Further, under low temperature environment, when carrying out hydronic to battery, phase-change material can absorb partial heat, and The heat that battery generates when driving can also be absorbed by phase-change material, play insulation effect, guarantee battery in worst cold case Under normal operation.
Microchannel designed by this paper is arranged in battery module structure several with phase-change material Compound cooling/heating means Battery modules block, the quantity of single battery can be determined according to series-parallel and cooling requirement in battery modules block.This method is easy to root The type of cooling of battery is determined according to heat management design requirement: when rectangular/soft-package battery calorific value is smaller, battery temperature is lower than phase transformation When the transition temperature range of material, only with the cooling battery of latent heat of phase change of phase-change material;When rectangular/soft-package battery calorific value compared with Greatly, when temperature is higher than the phase transition temperature of phase-change material, using the cooling electricity of the compound type of cooling of micro-channel flat and phase-change material Pond makes battery work in the normal temperature range.
Detailed description of the invention
Fig. 1 battery modules explosive view
Fig. 2 Compound cooling cold plate front view
Fig. 3 Compound cooling cold plate A-A diagrammatic cross-section
Fig. 4 phase-change material seal configuration schematic diagram
Fig. 5 composite phase-change material explosive view
Fig. 6 water-in and water-out end structure schematic diagram
Wherein:
1. 2. Setting MARC of end, 3. Compound cooling cold plate of intaking
4. 5. water inlet pipe of battery modules block, 6. return pipe
7. 8. microchannel of phase-change material sealing element, 9. phase-change material, 10. high thermal conductivity substrate
Specific embodiment
The embodiment of the present invention is as shown in Fig. 1.
Herein for rectangular/soft-package battery, a kind of Compound cooling/heating means are devised.This method is easy to according to heat pipe Reason design requirement adjusts the type of cooling of rectangular/soft-package battery, to enhance the heat transfer effect of heat transfer medium and battery, extends electricity The service life of cell system, and the safety of battery system can be improved.
A kind of method for composite cooling of rectangular/soft-package battery, it is characterised in that: rectangular/Soft Roll electricity of the Compound cooling Pond modular array includes the battery mould of water inlet pipe, water inlet end, return pipe, Setting MARC, Compound cooling cold plate and several arrays Group, if battery modules block cooperation is equipped with dry temperature sensor, if the dry temperature sensor is respectively connected to external temperature control The both ends of mechanism, the external temperature control mechanism pass through piping connection to water inlet pipe and return pipe.Microchannel and phase-change material are multiple It closes and distributes alternately in cooled cold plate, realized by the compound action of heat transfer medium and phase-change material in microchannel to the cold of battery But/heating.
Further, it is equipped between rectangular/packaging of soft packaged monomer in battery modules, between battery modules and Compound cooling cold plate Several heat conductive pads.
Further, the quantity of water inlet pipe and return pipe, position can be determined according to thermal management requirements.
Further, which is characterized in that the structure of water inlet end and water outlet end can be integral feed-through type, also can be separate chamber Body formula, individual cavity formula structure is corresponding with more water inlet pipes/outlet pipe scheme, can be according to the fever feelings of battery modules different location Condition reasonable distribution flow, guarantees the temperature consistency of battery modules.
Further, phase-change material distributes alternately with microchannel in Compound cooling cold plate, and phase-change material is multilayer sandwiched knot Structure, arrangement high thermal conductivity substrate is to increase the thermal coefficient of phase-change material between volume of phase-change material, so as to faster by the heat of absorption Amount is shed by the coolant liquid in microchannel, guarantees the lasting decalescence process of phase-change material.
Further, the method for composite cooling the following steps are included:
Step 1: control mechanism is instructed, and controller is opened;
Step 2: controller issues instruction, and battery system is started to work, while controller control temperature sensor acquisition electricity Pond temperature data;
Step 3: current temperature data is judged, if battery module maximum temperature is less than phase-change material transition temperature range T1~ T2, then follow the steps 4;If temperature is more than or equal to T2And it is less than T3, then follow the steps 5;If temperature is greater than T3And it is less than Tmax, then hold Row step 6;If temperature is greater than Tmax, then follow the steps 7;
Step 4: controller closes inlet tube and outlet tube, cools down battery, while mistake merely with the latent heat of phase change of phase-change material at this time The temperature of battery modules block is detected in journey, if temperature is greater than T2, return step 3;
Step 5: controller controls temperature control mechanism, opens inlet tube and outlet tube and realizes microchannel and phase-change material Compound cooling, but Only realize that the circulation of coolant liquid, coolant liquid are not connected to external forced heat-exchanger rig by water circulating pump at this time;
Step 6: coolant liquid is connect with external forced heat-exchanger rig, and the heat of coolant liquid is exchanged by forced heat-exchanging device To the external world;
Step 7: controller issues excess temperature early warning, and the connection of cutoff high system is communicated with entire car controller.
Further, under low temperature environment, when carrying out hydronic to battery, phase-change material can absorb partial heat, and The heat that battery generates when driving can also be absorbed by phase-change material, play insulation effect, guarantee battery in worst cold case Under normal operation.
Microchannel designed by this paper is arranged in battery module structure several with phase-change material Compound cooling/heating means Battery modules block, the quantity of single battery can be determined according to series-parallel and cooling requirement in battery modules block.This method is easy to root The type of cooling of battery is determined according to heat management design requirement: when rectangular/soft-package battery calorific value is smaller, battery temperature is lower than phase transformation When the transition temperature range of material, only with the cooling battery of latent heat of phase change of phase-change material;When rectangular/soft-package battery calorific value compared with Greatly, when temperature is higher than the phase transition temperature of phase-change material, using the cooling electricity of the compound type of cooling of micro-channel flat and phase-change material Pond makes battery work in the normal temperature range.

Claims (6)

1. a kind of method for composite cooling of rectangular/soft-package battery, it is characterised in that: rectangular/soft-package battery includes water inlet pipe, water inlet End, return pipe, Setting MARC, Compound cooling cold plate and several arrays battery modules, the battery modules block cooperation sets If there is dry temperature sensor, if the dry temperature sensor is respectively connected to external temperature control mechanism, the external temperature control mechanism Both ends pass through piping connection to water inlet pipe and return pipe;Microchannel and phase-change material are distributed in Compound cooling cold plate, by micro- The compound action of heat transfer medium and phase-change material in channel realizes the cooling/heating to battery.
2. method according to claim 1, between rectangular/packaging of soft packaged monomer in battery modules, battery modules and composite cold But several heat conductive pads are equipped between cold plate.
3. method according to claim 1, which is characterized in that the structure of water inlet end and water outlet end is integral feed-through type, Or be individual cavity formula, individual cavity formula structure is corresponding with more water inlet pipes/outlet pipe scheme.
4. method according to claim 1, which is characterized in that phase-change material is multilayer sandwiched structure, between volume of phase-change material Heat conducting base material is arranged to increase the thermal coefficient of phase-change material.
5. method described in any one according to claim 1~4, it is characterised in that: the method for composite cooling includes following Step:
Step 1: control mechanism is instructed, and controller is opened;
Step 2: controller issues instruction, and battery system is started to work, while controller control temperature sensor acquires battery temperature Degree evidence;
Step 3: current temperature data is judged, if battery module maximum temperature is less than phase-change material transition temperature range T1~T2In T2, then follow the steps 4;If temperature is more than or equal to T2And it is less than T3, then follow the steps 5;If temperature is greater than T3And it is less than Tmax, then Execute step 6;If temperature is greater than Tmax, then follow the steps 7;
Step 4: controller closes inlet tube and outlet tube, at this time merely with the cooling battery of the latent heat of phase change of phase-change material, while in the process The temperature of battery modules block is detected, if temperature is greater than T2, return step 3;
Step 5: controller controls temperature control mechanism, opens inlet tube and outlet tube and realizes microchannel and phase-change material Compound cooling, but at this time Only realize that the circulation of coolant liquid, coolant liquid are not connected to external forced heat-exchanger rig by water circulating pump;
Step 6: coolant liquid is connect with external forced heat-exchanger rig, and the heat of coolant liquid is exchanged by forced heat-exchanging device to outer Boundary;
Step 7: controller issues excess temperature early warning, and the connection of cutoff high system is communicated with entire car controller;
Wherein T3The value in 45~50 DEG C;TmaxThe value in 50~60 DEG C, and T3Less than Tmax
6. method according to claim 1, which is characterized in that under low temperature environment, when carrying out hydronic to battery, phase Partial heat can be absorbed by becoming material, and the heat that battery generates when driving can also be absorbed by phase-change material, play heat preservation Effect guarantees normal operation of the battery under worst cold case.
CN201811538267.0A 2018-12-16 2018-12-16 A kind of micro-channel flat and the compound rectangular/soft-package battery grouping method of phase-change material Pending CN109638382A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110247001A (en) * 2019-04-23 2019-09-17 广东工业大学 A kind of heat management battery combination device
CN110676411A (en) * 2019-10-25 2020-01-10 广东汽车检测中心有限公司 Battery heat abstractor
CN110994070A (en) * 2019-12-06 2020-04-10 上海理工大学 Thermal management and thermal runaway prevention device for soft package battery
CN111081937A (en) * 2019-12-30 2020-04-28 中国矿业大学 Battery system with emergency treatment and post-treatment device
CN112366388A (en) * 2020-11-09 2021-02-12 上海电力大学 Combined type battery cooling device based on phase change material and microchannel
CN113306176A (en) * 2021-05-19 2021-08-27 重庆理工大学 Microchannel thermoplastic composite material and preparation method thereof
CN113415125A (en) * 2021-07-27 2021-09-21 广州小鹏汽车科技有限公司 Battery thermal management method and device, vehicle and storage medium
CN116722273A (en) * 2023-08-01 2023-09-08 西安奇点能源股份有限公司 Phase-change direct-cooling battery pack

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CN102832425A (en) * 2012-05-04 2012-12-19 奇瑞汽车股份有限公司 Thermal management system and thermal management method of battery pack of electric automobile
CN107579306A (en) * 2017-08-22 2018-01-12 合肥国轩高科动力能源有限公司 A kind of battery module cooled down based on air and phase-change material
CN108736092A (en) * 2018-03-21 2018-11-02 北京工业大学 A kind of micro-channel flat and the compound rectangular/soft-package battery grouping method of phase-change material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102832425A (en) * 2012-05-04 2012-12-19 奇瑞汽车股份有限公司 Thermal management system and thermal management method of battery pack of electric automobile
CN107579306A (en) * 2017-08-22 2018-01-12 合肥国轩高科动力能源有限公司 A kind of battery module cooled down based on air and phase-change material
CN108736092A (en) * 2018-03-21 2018-11-02 北京工业大学 A kind of micro-channel flat and the compound rectangular/soft-package battery grouping method of phase-change material

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110247001A (en) * 2019-04-23 2019-09-17 广东工业大学 A kind of heat management battery combination device
CN110676411A (en) * 2019-10-25 2020-01-10 广东汽车检测中心有限公司 Battery heat abstractor
CN110994070A (en) * 2019-12-06 2020-04-10 上海理工大学 Thermal management and thermal runaway prevention device for soft package battery
CN111081937A (en) * 2019-12-30 2020-04-28 中国矿业大学 Battery system with emergency treatment and post-treatment device
CN112366388A (en) * 2020-11-09 2021-02-12 上海电力大学 Combined type battery cooling device based on phase change material and microchannel
CN113306176A (en) * 2021-05-19 2021-08-27 重庆理工大学 Microchannel thermoplastic composite material and preparation method thereof
CN113415125A (en) * 2021-07-27 2021-09-21 广州小鹏汽车科技有限公司 Battery thermal management method and device, vehicle and storage medium
CN113415125B (en) * 2021-07-27 2023-09-12 广州小鹏汽车科技有限公司 Battery thermal management method, device, vehicle and storage medium
CN116722273A (en) * 2023-08-01 2023-09-08 西安奇点能源股份有限公司 Phase-change direct-cooling battery pack

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RJ01 Rejection of invention patent application after publication

Application publication date: 20190416

RJ01 Rejection of invention patent application after publication