CN109638147A - A kind of production method of collection of energy heat-protecting glass - Google Patents
A kind of production method of collection of energy heat-protecting glass Download PDFInfo
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- CN109638147A CN109638147A CN201910066805.9A CN201910066805A CN109638147A CN 109638147 A CN109638147 A CN 109638147A CN 201910066805 A CN201910066805 A CN 201910066805A CN 109638147 A CN109638147 A CN 109638147A
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- 239000011521 glass Substances 0.000 title claims abstract description 75
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 45
- 229910052751 metal Inorganic materials 0.000 claims abstract description 24
- 239000002184 metal Substances 0.000 claims abstract description 24
- 239000000758 substrate Substances 0.000 claims abstract description 24
- 238000010521 absorption reaction Methods 0.000 claims abstract description 17
- 238000007747 plating Methods 0.000 claims abstract description 14
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 19
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 19
- 229910052792 caesium Inorganic materials 0.000 claims description 9
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 9
- 230000005619 thermoelectricity Effects 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 239000003973 paint Substances 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 239000006104 solid solution Substances 0.000 claims description 6
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 5
- 238000005516 engineering process Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000007641 inkjet printing Methods 0.000 claims description 3
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 238000009738 saturating Methods 0.000 claims description 3
- 239000005368 silicate glass Substances 0.000 claims description 3
- 239000005341 toughened glass Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004642 Polyimide Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 239000004020 conductor Substances 0.000 claims description 2
- 229920000547 conjugated polymer Polymers 0.000 claims description 2
- 229910000765 intermetallic Inorganic materials 0.000 claims description 2
- 229910052745 lead Inorganic materials 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000002103 nanocoating Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 238000007650 screen-printing Methods 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 claims description 2
- 238000007740 vapor deposition Methods 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- 229920005372 Plexiglas® Polymers 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 238000005553 drilling Methods 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 229920000139 polyethylene terephthalate Polymers 0.000 claims 1
- 239000005020 polyethylene terephthalate Substances 0.000 claims 1
- 230000004888 barrier function Effects 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 238000010248 power generation Methods 0.000 description 7
- 230000008901 benefit Effects 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002305 electric material Substances 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- YBNMDCCMCLUHBL-UHFFFAOYSA-N (2,5-dioxopyrrolidin-1-yl) 4-pyren-1-ylbutanoate Chemical compound C=1C=C(C2=C34)C=CC3=CC=CC4=CC=C2C=1CCCC(=O)ON1C(=O)CCC1=O YBNMDCCMCLUHBL-UHFFFAOYSA-N 0.000 description 1
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical class O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 description 1
- 229910016312 BiSb Inorganic materials 0.000 description 1
- 229910002665 PbTe Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- JYMITAMFTJDTAE-UHFFFAOYSA-N aluminum zinc oxygen(2-) Chemical compound [O-2].[Al+3].[Zn+2] JYMITAMFTJDTAE-UHFFFAOYSA-N 0.000 description 1
- 238000003877 atomic layer epitaxy Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OCGWQDWYSQAFTO-UHFFFAOYSA-N tellanylidenelead Chemical compound [Pb]=[Te] OCGWQDWYSQAFTO-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/01—Manufacture or treatment
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/80—Constructional details
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/80—Constructional details
- H10N10/85—Thermoelectric active materials
- H10N10/851—Thermoelectric active materials comprising inorganic compositions
- H10N10/852—Thermoelectric active materials comprising inorganic compositions comprising tellurium, selenium or sulfur
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/219—CrOx, MoOx, WOx
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/24—Doped oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The production method that the present invention discloses a kind of collection of energy heat-protecting glass, it is characterized by: the infrared absorption layer of the incident one side attachment visible transparent of sunlight in glass, post strip-shaped flexible thermoelectric element in glass side, p-type thermoelectric material route and N-type thermoelectric material route are printed respectively in the insulating substrate two sides of flexible thermoelectric element, thermoelectric material route is arranged along glass planar normal direction, an exhausting hole is respectively bored at flexible insulating substrate edge, plating metal in through-holes, the alternating series circuit structure that the line layer on two sides connects into N-P-N-P by the through-hole that both ends are coated with metal ..., when sunlight incidence, adhere to the glass of infrared absorption layer to visible transparent, the incident one side of glass solar light absorbs infrared ray heating, and sunlight outgoing is on one side by infrared reflection, glass two sides generates the temperature difference, with alternately concatenated thermoelectric material Potential difference is generated in the flexible thermoelectric element of route, the temperature difference can be converted into the external output power of electric energy.
Description
Technical field
The present invention relates to a kind of production methods of collection of energy heat-protecting glass, and the invention belongs to photoelectric functional materials and device
Technical field.
Background technique
Infrared light especially near-infrared has apparent fuel factor, easily leads to temperature heating, to cause such as indoor or vehicle
Interior temperature increases.Presently disclosed infrared barrier material, which generally refers to have, relatively to be absorbed or reflects by force infrared light and do not influence
A kind of functional material of its visible light-transmissive.In various fields such as building glass, car and boat glass, both need to guarantee that light has
Effect penetrates, and needs effectively to obstruct inside and outside heat transfer.About 50% heat comes from infrared ray in natural light radiation, therefore,
Realize that infrared barrier has important impetus for energy-saving on visible transparent carrier.
Thermoelectric material is a kind of in the solid state by the transmission realization thermal energy of the carrier of itself (hole or electronics)
The material mutually converted with electric energy.Thermoelectric generation technology due to it is small in size, without friction, noiseless, pollution-free, without abrasion,
Movement-less part, it is non-maintaining, pollution-free the features such as, the unique advantage that has in terms of heat energy utilization.Patent of invention
(201710449930.9) a kind of production method of novel flexible thermoelectric element is proposed, the flexible thermoelectricity for obtaining planar structure turns
Change element.Electric energy, Ke Yiwei are converted by the dissipation energy that flexible thermoelectric conversion element is used to collect infrared barrier transparent glass
A variety of electronic equipments provide the energy, promote the power savings advantages of the carriers such as building and car and boat, and lay the foundation for intelligent development.
Summary of the invention
In view of the deficiencies of the prior art, the production method that the present invention proposes a kind of collection of energy heat-protecting glass, feature exist
In: adhere to the infrared absorption layer of visible transparent in the incident one side of the sunlight of glass, strip-shaped flexible thermoelectricity is posted in glass side
P-type thermoelectric material route and N-type thermoelectric material route, thermoelectricity are printed in element, the insulating substrate two sides of flexible thermoelectric element respectively
Line of material is arranged along glass planar normal direction, respectively bores an exhausting hole at flexible insulating substrate edge, in through-holes plating metal, two sides
Line layer N-P-N-P is connected by the through-hole that both ends are coated with metal ... alternating series circuit structure, when sunlight incidence,
Adhere to the glass of infrared absorption layer to visible transparent, the incident one side of glass solar light absorbs infrared ray heating, and sunlight goes out
One side is penetrated by infrared reflection, glass two sides generates the temperature difference, has the flexible thermoelectric element of alternately concatenated thermoelectric material route
The temperature difference can be converted into the external output power of electric energy by middle generation potential difference.
The glass includes normal silicate glass, quartz glass, tempered glass, doubling glass, poly-methyl methacrylate
One of ester organic glass, thickness are not less than 5mm.
The infrared absorption layer of the attachment visible transparent includes the infrared absorption nano coating for applying visible transparent, glues
It pastes one or both of the infrared absorption polymers film of visible transparent method and combines dual-purpose；Infrared absorption nano paint is with oxygen
Changing one of tungsten, natrium doping tungsten oxide, caesium doped tungsten oxide, caesium doped tungsten oxide or combinations thereof is functional component, is uniformly applied
It applies on glass；The polymeric matrix of visible transparent infrared absorption polymers film is polyethylene, polypropylene, poly terephthalic acid
One of glycol ester, polymethyl methacrylate, polyimides or its blend, functional component are tungsten oxide, natrium doping
One of tungsten oxide, caesium doped tungsten oxide, caesium doped tungsten oxide or combinations thereof.
The infrared absorption layer visible light transmittance of the visible transparent is greater than 85%, and infrared ray rejection rate is greater than 90%.
The production method of the strip-shaped flexible thermoelectric element is to print N-type and P respectively on strip-shaped flexible insulating substrate two sides
The line layer of type thermoelectric material respectively bores an exhausting hole at flexible insulating substrate edge, and the line layer of plating metal in through-hole, two sides is logical
The alternating series circuit structure crossed both ends and be coated with the through-hole of metal and connect into N-P-N-P ..., obtains strip-shaped flexible thermoelectric element；It will
The flexible insulating substrate that p-type thermoelectric material slurry and N-type thermoelectric material slurry are printed in multiple two sides respectively bonds that form multilayer soft
Property wiring board, plating metal is coupled the route on multiple wiring boards through holes drilled through and in hole, obtains higher heat to electricity conversion effect
Rate.
The 30 μ Wm of room-temperature conductivity > 100Scm, power factor > of the p-type thermoelectric material-1K-2, N-type thermoelectric material
30 μ Wm of room-temperature conductivity > 100Scm, power factor >-1K-2, route be made mode include silk-screen printing, mask vacuum vapor deposition,
One of exposure mask magnetron sputtering, atomic layer epitaxy plated film, inkjet printing.
The thermoelectric material includes (Bi, Sb)2(Se, Te)3And its element doping solid solution, (Pb, Sn) (Se, Te) and its
Element doping solid solution, skutterudite compound, Jin Teer phase intermetallic compound and its element doping solid solution, conjugated polymer
One of base composite conducting material.
Metal is coated in the flexible insulating substrate through-hole, technology mode is plating, and the metal includes copper, silver, Jin Zhong
One kind, the coat of metal is connected with the N-type thermoelectricity route on substrate two sides with p-type thermoelectricity connection respectively in through-hole.
The present invention keeps visible light saturating using the infrared ray in outer layer absorption-type infrared transparent coating barrier sunlight
It is bright, meanwhile, it is collected using flexible thermoelectric element and absorbs the converting heat of infrared ray on glass for electric energy.Collection of energy of the present invention every
The production method technical process of hot glass can modular operation, be easy to technology realize and cost control, building and car and boat can be promoted
The power savings advantages of equal carriers, and lay the foundation for intelligent development.
The contents of the present invention and feature have revealed that as above, however the present invention that describes of front only briefly or pertains only to this
The specific part of invention, feature of the invention may be more than what content disclosed herein was related to.Therefore, protection model of the invention
The revealed content of embodiment should be not limited to by enclosing, and should include the combination of all the elements embodied in different piece, with
And it is various without departing substantially from replacement and modification of the invention, and covered by claims of the present invention.
Detailed description of the invention
The schematic diagram for the solar power generation heat-protecting glass that Fig. 1 is made of the present invention.Outside A- glass chamber, sunlight is injected,
Coat the transparent infrared barrier coating of absorption-type；B- flexible thermal electric line veneer mounts flexible thermal electric line paste layer；In C- glass chamber
Face, light outgoing plane.
The side flexible thermal electric line paste layer schematic diagram for the solar power generation heat-protecting glass that Fig. 2 is made of the present invention.1-
Flexible base board；The front 2- N-type thermoelectric material route；The back side 3- p-type thermoelectric material route；4- through-hole is coated with metal on through-hole.
The side flexible thermal electric line paste layer through hole section for the solar power generation heat-protecting glass that Fig. 3 is made of the present invention
Structural schematic diagram.1- flexible base board；The front 2- N-type thermoelectric material route；The back side 3- p-type thermoelectric material route；4- through-hole, through-hole
On be coated with metal.
Specific embodiment
Embodiment 1:
It is applied in the incident one side coating natrium doping tungsten oxide absorption-type infrared barrier nanometer of normal silicate glass pane sunlight
Material, glass side edge are power generation line layer, and structure is as shown in Figure 1.Post strip-shaped flexible thermoelectric element, flexible thermoelectricity in glass side
P-type Bi is deposited in the insulating substrate two sides difference mask vacuum of element2Te2.7Se0.3Thermoelectric material route and N-type Bi0.5Sb1.5Te3Heat
Electric material route, thermoelectric material route are arranged along glass planar normal direction, respectively bore an exhausting hole at flexible insulating substrate edge, logical
The alternating series line that plating metal silver, the line layer on two sides connect into N-P-N-P by the through-hole that both ends are coated with metallic silver in hole ...
Line structure, as shown in Figures 2 and 3.When sunlight incidence, glass absorbs red on one side to visible transparent, the incidence of glass solar light
Outside line heating, glass two sides generate the temperature difference, alternately generate potential difference in concatenated thermoelectric material line construction, can convert the temperature difference
At the external output power of electric energy.
Embodiment 2:
In the incident one side coating blue tungsten oxide absorption-type infrared barrier nano paint of quartz window glass solar light, glass side
Edge is power generation line layer, and structure is as shown in Figure 1.Strip-shaped flexible thermoelectric element is posted in glass side, flexible thermoelectric element it is exhausted
Distinguish exposure mask magnetron sputtering p-type PbSe thermoelectric material route and N-type PbTe thermoelectric material route, thermoelectric material line in edge substrate two sides
The arrangement of curb glass planar normal direction, respectively bores an exhausting hole at flexible insulating substrate edge, in through-holes plating metal copper, the line on two sides
The alternating series circuit structure that road floor connects into N-P-N-P by the through-hole that both ends are coated with metallic copper ..., as shown in Figures 2 and 3.
When sunlight incidence, glass absorbs infrared ray heating to visible transparent, the incident one side of glass solar light, and glass two sides generates temperature
Difference alternately generates potential difference in concatenated thermoelectric material line construction, the temperature difference can be converted into the external output power of electric energy.
Embodiment 3:
In the incident one side coating caesium doped tungsten oxide absorption-type infrared barrier nano paint of tempered glass sunlight, the sun
Light outgoing one side coating zinc oxide aluminum reflection-type infrared barrier nano paint, glass side edge is power generation line layer, structure such as Fig. 1
It is shown.Strip-shaped flexible thermoelectric element is posted in glass side, and inkjet printing p-type stone is distinguished on the insulating substrate two sides of flexible thermoelectric element
Black alkene filling polyphenyl pyrroles thermoelectric material route and N-type poly- 3,4 ethylenedioxy thiophenes: diallyl dimethyl ammoniumchloride heat
Electric material route, thermoelectric material route are arranged along glass planar normal direction, respectively bore an exhausting hole at flexible insulating substrate edge, logical
The alternating series line that plating metal silver, the line layer on two sides connect into N-P-N-P by the through-hole that both ends are coated with metallic silver in hole ...
Line structure, as shown in Figures 2 and 3.When sunlight incidence, glass absorbs red on one side to visible transparent, the incidence of glass solar light
Outside line heating, and sunlight outgoing is on one side by infrared reflection, the glass two sides generation temperature difference, the concatenated thermoelectric material route of alternating
Potential difference is generated in structure, and the temperature difference can be converted into the external output power of electric energy.
Embodiment 4:
In the incident one side coating potassium doped tungsten oxide absorption-type infrared barrier nano paint of doubling glass pane sunlight, glass
Side edge is power generation line layer, and structure is as shown in Figure 1.Strip-shaped flexible thermoelectric element is posted in glass side, flexible thermoelectric element
Distinguish exposure mask chemical plating p-type BiSb thermoelectric material route and N-type Bi thermoelectric material route, thermoelectric material route in insulating substrate two sides
It is arranged along glass planar normal direction, respectively bores an exhausting hole at flexible insulating substrate edge, in through-holes plating metal copper, the route on two sides
The alternating series circuit structure that layer connects into N-P-N-P by the through-hole that both ends are coated with metallic copper ..., as shown in Figures 2 and 3.When
When sunlight incidence, glass absorbs infrared ray heating to visible transparent, the incident one side of glass solar light, and glass two sides generates temperature
Difference alternately generates potential difference in concatenated thermoelectric material line construction, the temperature difference can be converted into the external output power of electric energy.
Claims (9)
1. a kind of production method of collection of energy heat-protecting glass, it is characterised in that: adhering in the incident one side of the sunlight of glass can
Strip-shaped flexible thermoelectric element, the insulating substrate two sides of flexible thermoelectric element are posted in light-exposed transparent infrared absorption layer, glass side
P-type thermoelectric material route and N-type thermoelectric material route are printed respectively, and thermoelectric material route is arranged along glass planar normal direction, soft
Property insulating substrate edge respectively bores an exhausting hole, and plating metal, the line layer on two sides are coated with the through-hole of metal by both ends in through-holes
The alternating series circuit structure for connecting into N-P-N-P ..., when sunlight incidence, the glass for adhering to infrared absorption layer is saturating to visible light
Bright, the incident one side of glass solar light absorbs infrared ray heating, and sunlight is emitted one side for infrared reflection, and glass two sides generates
The temperature difference has in the alternately flexible thermoelectric element of concatenated thermoelectric material route and generates potential difference, the temperature difference can be converted into electric energy
External output power.
2. a kind of production method of collection of energy heat-protecting glass according to claim 1, which is characterized in that the glass includes
One of normal silicate glass, quartz glass, tempered glass, doubling glass, plexiglass are thick
Degree is not less than 5mm.
3. a kind of production method of collection of energy heat-protecting glass according to claim 1, which is characterized in that the attachment is visible
The transparent infrared absorption layer of light includes the infrared absorption nano coating for applying visible transparent, the infrared suction for pasting visible transparent
One or both of pinching compound film method combines dual-purpose；Infrared absorption nano paint is with tungsten oxide, natrium doping tungsten oxide, caesium
One of doped tungsten oxide, caesium doped tungsten oxide or combinations thereof are functional component, and even application is on glass；Visible transparent
The polymeric matrix of infrared absorption polymers film is polyethylene, polypropylene, polyethylene terephthalate, polymethylacrylic acid
One of methyl esters, polyimides or its blend, functional component are tungsten oxide, natrium doping tungsten oxide, caesium doped tungsten oxide, caesium
One of doped tungsten oxide or combinations thereof.
4. a kind of production method of collection of energy heat-protecting glass according to claim 1, which is characterized in that the visible light is saturating
Bright infrared absorption layer visible light transmittance is greater than 85%, and infrared ray rejection rate is greater than 90%.
5. a kind of production method of collection of energy heat-protecting glass according to claim 1, which is characterized in that the strip-shaped flexible
The production method of thermoelectric element is to print the line layer of N-type and p-type thermoelectric material respectively on strip-shaped flexible insulating substrate two sides,
An exhausting hole is respectively bored at flexible insulating substrate edge, the line layer of plating metal in through-hole, two sides is coated with the logical of metal by both ends
The alternating series circuit structure that hole connects into N-P-N-P ..., obtains strip-shaped flexible thermoelectric element；P is printed on multiple two sides respectively
The flexible insulating substrate of type thermoelectric material slurry and N-type thermoelectric material slurry bonds to form multi-layer flexible circuit board, by drilling through
Hole and plating metal is coupled the route on multiple wiring boards in hole, obtains higher conversion efficiency of thermoelectric.
6. a kind of production method of collection of energy heat-protecting glass according to claim 1, which is characterized in that the p-type thermoelectricity
The 30 μ Wm of room-temperature conductivity > 100Scm, power factor > of material-1K-2, the room-temperature conductivity > 100Scm of N-type thermoelectric material,
30 μ Wm of power factor >-1K-2, it includes silk-screen printing, mask vacuum vapor deposition, exposure mask magnetron sputtering, atomic layer that mode, which is made, in route
One of extension plated film, inkjet printing.
7. a kind of production method of collection of energy heat-protecting glass according to claim 1, which is characterized in that the thermoelectric material
Including (Bi, Sb)2(Se, Te)3And its element doping solid solution, (Pb, Sn) (Se, Te) and its element doping solid solution, skutterudite
One in compound, Jin Teer phase intermetallic compound and its element doping solid solution, conjugated polymer base composite conducting material
Kind.
8. a kind of production method of collection of energy heat-protecting glass according to claim 1, which is characterized in that the flexible insulation
Metal is coated in substrate through-hole, technology mode is plating, and the metal includes one of copper, silver, gold, the coat of metal in through-hole
It is connected respectively with the N-type thermoelectricity route on substrate two sides with p-type thermoelectricity connection.
9. energy made by a kind of production method of the collection of energy heat-protecting glass as described in claim 1~8 any one
Collect heat-protecting glass.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110350040A (en) * | 2019-06-28 | 2019-10-18 | 淮阴工学院 | It absorbs the high thermal conductivity coating of infrared light and its is improving the application in solar cell power generation efficiency |
| CN110534018A (en) * | 2019-08-30 | 2019-12-03 | 天马微电子股份有限公司 | A kind of transparent display |
| CN114675457A (en) * | 2020-12-24 | 2022-06-28 | 中国科学院上海硅酸盐研究所 | Passive self-bias electrochromic intelligent window |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101661963A (en) * | 2009-09-18 | 2010-03-03 | 信义超薄玻璃(东莞)有限公司 | Heat insulation type film solar battery structure |
| TW201622988A (en) * | 2014-12-16 | 2016-07-01 | Sunvalue Co Ltd | Temperature regulation film and manufacture method thereof |
| CN107293634A (en) * | 2017-06-14 | 2017-10-24 | 上海萃励电子科技有限公司 | A kind of preparation method of novel flexible thermoelectric element |
| CN108417651A (en) * | 2018-03-07 | 2018-08-17 | 宁波山迪光能技术有限公司 | Thin-film solar cells, production method and heat-insulated solar energy doubling glass |
-
2019
- 2019-01-22 CN CN201910066805.9A patent/CN109638147A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101661963A (en) * | 2009-09-18 | 2010-03-03 | 信义超薄玻璃(东莞)有限公司 | Heat insulation type film solar battery structure |
| TW201622988A (en) * | 2014-12-16 | 2016-07-01 | Sunvalue Co Ltd | Temperature regulation film and manufacture method thereof |
| CN107293634A (en) * | 2017-06-14 | 2017-10-24 | 上海萃励电子科技有限公司 | A kind of preparation method of novel flexible thermoelectric element |
| CN108417651A (en) * | 2018-03-07 | 2018-08-17 | 宁波山迪光能技术有限公司 | Thin-film solar cells, production method and heat-insulated solar energy doubling glass |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110350040A (en) * | 2019-06-28 | 2019-10-18 | 淮阴工学院 | It absorbs the high thermal conductivity coating of infrared light and its is improving the application in solar cell power generation efficiency |
| CN110534018A (en) * | 2019-08-30 | 2019-12-03 | 天马微电子股份有限公司 | A kind of transparent display |
| CN110534018B (en) * | 2019-08-30 | 2022-02-01 | 天马微电子股份有限公司 | Transparent display device |
| CN114675457A (en) * | 2020-12-24 | 2022-06-28 | 中国科学院上海硅酸盐研究所 | Passive self-bias electrochromic intelligent window |
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Application publication date: 20190416 |