CN109628235A - A kind of food grade liquid detergent and preparation method thereof - Google Patents

A kind of food grade liquid detergent and preparation method thereof Download PDF

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Publication number
CN109628235A
CN109628235A CN201811651414.5A CN201811651414A CN109628235A CN 109628235 A CN109628235 A CN 109628235A CN 201811651414 A CN201811651414 A CN 201811651414A CN 109628235 A CN109628235 A CN 109628235A
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China
Prior art keywords
liquid detergent
food grade
glycine betaine
grade liquid
polysiloxanes
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CN201811651414.5A
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Chinese (zh)
Inventor
黄玉真
韩菲桐
谢煌
杨海景
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China Gea Science And Technology (guangzhou) Co Ltd
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China Gea Science And Technology (guangzhou) Co Ltd
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Priority to CN201811651414.5A priority Critical patent/CN109628235A/en
Publication of CN109628235A publication Critical patent/CN109628235A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1233—Carbonates, e.g. calcite or dolomite
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/886—Ampholytes containing P

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides a kind of food grade liquid detergents and preparation method thereof, preparation process is the following steps are included: step 1: deionized water being added in blender, it is warming up to 50~80 DEG C, 20~35% (the first and second ethers) glycine betaine of polysiloxanes two and 2~10% cosurfactant are added in whipping process, stirring makes it after completely dissolution, is cooled to room temperature to obtain S1 solution；Step 2: 0.1~0.5% wetting agent is added into S1 solution again, after 0.5~1.5% fumet and 0.1~0.5% Chinese medicine preservative stir, it is eventually adding 3~10% rubbing agent, being sufficiently stirred keeps rubbing agent evenly dispersed in the above solution, and strong using the food grade liquid detergent washing dirt-removing power of this method preparation, dosage is few, to which discharge amount is low, not can cause environmental pollution, safety and environmental protection, will not damaging laundry and skin, the clothing of wash-off is bright in colour simultaneously to have faint scent.

Description

A kind of food grade liquid detergent and preparation method thereof
Technical field
The invention belongs to the preparation fields of cleaning chemical products, and in particular to a kind of food grade liquid detergent.
Background technique
It does washing, the most flat thing in life, in the product of clothes washing, washing powder is accounted for always mainly Position, but washing powder, using anionic surfactant, based on sodium alkyl sulfonate and odium stearate, PH is generally higher than 12, alkalinity is stronger, and then larger to the stimulation of skin and injury when in use, meanwhile, washing powder in use can not It is completely dissolved, residue is easy to cause clothing to damage, and is not easy to rinse.In order to improve these disadvantages of washing powder, make clothing Cleaning agent can quickly dissolve, easy to wash easy drift, reduce the injury to skin and clothing, it is raw that liquid detergent just slowly enters people Living, liquid detergent main component is nonionic surfactant, and dirt-removing power is strong, and plays and wash inside the deep enough clothes fiber of energy The effect of washing, decontamination is more thorough, and also partial neutral, formula mildly, are easy rinsing to pH value, but in order to improve the decontamination energy of liquid detergent Power, liquid detergent currently on the market mostly use concentrated type liquid detergent, and the concentration of surfactant is high in liquid detergent, and there are phosphorous Auxiliary agent pollutes the environment；Meanwhile current liquid detergent is deployed by chemical substance mostly, use for a long time can be to flesh Skin generates injury.
Summary of the invention
To solve problems of the prior art, the present invention provides a kind of food grade liquid detergent and preparation method thereof, should Food grade liquid detergent washing dirt-removing power is strong, the dosage of liquid detergent is reduced in washing process, to reduce table in liquid detergent The discharge of face activating agent, and reduction environmental pollution completely of degrading, meanwhile, the formula of liquid detergent uses food grade materials, is free of There is phosphorous assistant, nontoxic, safety and environmental protection will not be to human body and environmental pollution.
In order to achieve the above objectives, the technical scheme is that
A kind of food grade liquid detergent is made of following component by weight percentage:
Rubbing agent: 3~10%
Polysiloxanes two (the first and second ethers) glycine betaine: 20~35%
Cosurfactant: 2~10%
Fumet: 0.5~1.5%
Wetting agent: 0.1~0.5%
Chinese medicine preservative: 0.1~0.5%
Deionized water: surplus
The preparation process of polysiloxanes two (the first and second ethers) glycine betaine is as follows:
S1: polysiloxanes two (bromomethyl) front three amidogen ether is prepared by reaction equation (1)；
S2: polysiloxanes two (the first and second ethers) front three amidogen ether is prepared by reaction equation (2)；
S3: polysiloxanes two (the first and second ethers) glycine betaine is prepared by reaction equation (3).
In the present solution, using (the first and second ethers) glycine betaine of polysiloxanes two as surfactant, this surfactant It is the copolymer of polysiloxanes and glycine betaine, polysiloxane group has excellent lipophilicity, and glycine betaine extracts from natural plants In root, stem, leaf and fruit, natural environmental-protective, quaternary ammonium group and carboxyl in glycine betaine have excellent hydrophily, on quaternary ammonium group Methyl is replaced by ether, further increases the hydrophily of quaternary ammonium group, therefore this (the first and second ethers) glycine betaine of polysiloxanes two is made For surfactant, there is higher activity function, stronger decontamination than the surfactant in common liquid detergent in the market Ability, therefore the dosage of surfactant can be reduced, so that the discharge of surfactant is reduced, meanwhile, two (first of polysiloxanes Ether base) glycine betaine can be degradable in a short time, it avoids polluting water and environment；Friction is added in liquid detergent Agent is acted on by particle mechanical beating, is realized the removal of substrate surface blot, is further improved the washing energy of liquid detergent Power, the ingredient of rubbing agent are generally calcium salt and aluminium salt of particle etc., and liquid detergent of the invention is in alkalescent, so rubbing agent is being washed Chemical property in clothing liquid is relatively stable；Wetting agent has the effect of lubrication concurrently simultaneously, so that the clothing washed out is smooth, soft, close Skin, it is not crude, it has been not easy electrostatic；It using the extract of Chinese herbal medicine as preservative, has no toxic side effect, while according to every kind of medium-height grass The pharmacological action of medicine itself, the effects of can also invigorating blood circulation with seasoning flavouring, antibacterial anti-inflammatory, cleaning.
Food grade liquid detergent washing dirt-removing power of the invention is strong, and dosage is few, so that discharge amount is low, will not cause to environment Pollution, safety and environmental protection, will not damaging laundry and skin, the clothing of wash-off is bright in colour, and has faint scent.
Further, the cosurfactant is the lecithin and dodecyl dihydroxy ethyl beet that mass ratio is 1:1 The mixture of alkali,
Cosurfactant is increased in liquid detergent, further improves the dirt-removing power of liquid detergent, reduces liquid detergent Dosage and discharge amount, while according to the characteristic of surfactant itself, can as emulsifier, stabilizer, thickener work With lecithin is zwitterionic surfactant, extracts and gets usually from soybean, is a kind of excellent emulsifier, simultaneously It is also good dispersing agent and stabilizer, is used in liquid detergent, the compatibility for keeping the material in formula many is uniformly divided Cloth does not settle, safe and non-toxic, will not damage to clothing and human body, while keeping clothing softness not short-tempered；Dodecyl dihydroxy Ethyl glycine betaine is a kind of zwitterionic surfactant, has excellent stability and emulsibility, while the product have well Thickening property, dispersibility and wetability, be used in liquid detergent in, play synergy, kill mattress and antistatic property.
Further, the cosurfactant is the lecithin and octadecyl dihydroxy ethyl beet that mass ratio is 1:1 The mixture of alkali,
Cosurfactant is increased in liquid detergent, further improves the dirt-removing power of liquid detergent, reduces liquid detergent Dosage and discharge amount, while according to the characteristic of surfactant itself, can as emulsifier, stabilizer, thickener work With lecithin is zwitterionic surfactant, extracts and gets usually from soybean, is a kind of excellent emulsifier, simultaneously It is also good dispersing agent and stabilizer, is used in liquid detergent, the compatibility for keeping the material in formula many is uniformly divided Cloth does not settle, safe and non-toxic, will not damage to clothing and human body, while keeping clothing softness not short-tempered；Octadecyl dihydroxy Ethyl glycine betaine is a kind of zwitterionic surfactant, has excellent emulsibility, stability and thickening property, with other surfaces Activating agent is used in combination, and has good compatibility, nontoxic, irritation is small, foam is more, strong detergency, bactericidal properties, antistatic property By force.
Further, the rubbing agent be calcium carbonate granule or aluminum hydroxide particles,
As rubbing agent, the chemical property in liquid detergent is relatively stable for calcium carbonate granule or aluminum hydroxide particles, passes through The effect of particle mechanical beating, realizes the removal of substrate surface blot, further improves the washability of liquid detergent,
Further, the fumet is fragrant extract, Lignum Santali Albi extract, orange extract or the mint extract of changing,
The addition of fumet can effectively promote the smell of liquid detergent, so that washed clothing is had faint scent, mentioned using plant Take object as fumet, pleasant aroma is not pungent, and ingredient is natural, it has no toxic side effect, while according to plant self property, Titian Also there are other different effects, for example repeatedly perfume (or spice) mind can wake up clearly simultaneously, helps to alleviate brain fatigue, enhancing memory； Santal not only has pleasant fragrance, has extraordinary disinfection and sterilization effect, also has remarkable result to the illness of lung；Orange Seed extract can remove odors, and sterilizing promotes the production of body fluid to quench thirst, and lasting is permanent；Peppermint can be with sweating and heat resolving, and clear away heart-fire improving eyesight.
Further, the wetting agent is aloe extract,
Use aloe extract as wetting agent, ingredient is natural, not will cause stimulation and injury to skin and clothing, not only Wetting action is more preferable, moreover it is possible to play lubricant effect, improve the feel of clothing, while aloe extract can also bactericidal antiphlogistic, wash Clothing out is smooth, soft, pro-skin, not crude, has been not easy electrostatic.
Further, the Chinese medicine preservative be fruit of a cubeb litsea tree extract or Flos Caryophylli extract,
The extract of Chinese herbal medicine has no toxic side effect, usually using in range in sterilizing as antisepsis antistaling agent Meanwhile according to the pharmacological action of every kind of Chinese herbal medicine itself, other pharmacological actions can also be had both, are good for as Flos Caryophylli extract has Stomach alleviates the effect of abdominal bloating, and digestion power can be enhanced in smell, mitigates nausea and vomiting；Fruit of a cubeb litsea tree extract has fresh Lemon fruit flavor can also have stronger antioxidant activity with Titian while anti-corrosion.
Second technical solution of the invention is: a kind of preparation method of food grade liquid detergent includes the following steps:
Following component is mass percent,
Step 1: deionized water being added in blender, is warming up to 50~80 DEG C, 20~35% are added in whipping process (the first and second ethers) glycine betaine of polysiloxanes two and 2~10% cosurfactant, stirring so that it is cooled to room after completely dissolution Temperature obtains S1 solution；
Step 2: it is added 0.1~0.5% wetting agent into S1 solution again, 0.5~1.5% fumet and 0.1~ After 0.5% Chinese medicine preservative stirs, it is eventually adding 3~10% rubbing agent, being sufficiently stirred divides rubbing agent uniformly It dissipates in the above solution.
In the present solution, using (the first and second ethers) glycine betaine of polysiloxanes two as surfactant, this surfactant It is the copolymer of polysiloxanes and glycine betaine, polysiloxane group has excellent lipophilicity, and glycine betaine extracts from natural plants In root, stem, leaf and fruit, natural environmental-protective, quaternary ammonium group and carboxyl in glycine betaine have excellent hydrophily, on quaternary ammonium group Methyl is replaced by ether, further increases the hydrophily of quaternary ammonium group, therefore this (the first and second ethers) glycine betaine of polysiloxanes two is made For surfactant, there is higher activity function, stronger decontamination than the surfactant in common liquid detergent in the market Ability, therefore the dosage of surfactant can be reduced, so that the discharge of surfactant is reduced, meanwhile, two (first of polysiloxanes Ether base) glycine betaine can be degradable in a short time, it avoids polluting water and environment；Friction is added in liquid detergent Agent is acted on by particle mechanical beating, is realized the removal of substrate surface blot, is further improved the washing energy of liquid detergent Power, the ingredient of rubbing agent are generally calcium salt and aluminium salt of particle etc., and liquid detergent of the invention is in alkalescent, so rubbing agent is being washed Chemical property in clothing liquid is relatively stable, and wetting agent has the effect of lubrication concurrently simultaneously, so that the clothing washed out is smooth, soft, close Skin, it is not crude, it has been not easy electrostatic；It using the extract of Chinese herbal medicine as preservative, has no toxic side effect, while according to every kind of medium-height grass The pharmacological action of medicine itself, the effects of can also invigorating blood circulation with seasoning flavouring, antibacterial anti-inflammatory, cephalocathartic.
Strong using the food grade liquid detergent washing dirt-removing power of this method preparation, dosage is few, so that discharge amount is low, it will not be right Environment pollutes, safety and environmental protection, will not damaging laundry and skin, the clothing of wash-off is bright in colour, smooth, soft, pro-skin, no It is crude, not electrostatic, and there is faint scent.
Specific embodiment
The present invention will be described in further detail With reference to embodiment.
A kind of food grade liquid detergent, is prepared by following step:
Step 1: deionized water being added in blender, is warming up to 50~80 DEG C, 20~35% are added in whipping process (the first and second ethers) glycine betaine of polysiloxanes two and 2~10% cosurfactant, stirring so that it is cooled to room after completely dissolution Temperature obtains S1 solution；
Step 2: again into S1 solution be added 0.1~0.5% wetting agent, 0.5~1.5% fumet, 0.1~ After 0.5% wetting agent, 2.5~10.5% sodium acetates and 0.1~0.5% Chinese medicine preservative stir, it is eventually adding 3~ 10% rubbing agent, being sufficiently stirred keeps rubbing agent evenly dispersed in the above solution.
Temperature is as follows after heating up in each embodiment step 1:
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
70 65 50 80 60
The raw material and percentage of each embodiment are as follows:
The above ingredient is weight percentage.
The preparation process of polysiloxanes two (the first and second ethers) glycine betaine is as follows:
S1: polysiloxanes two (bromomethyl) front three amidogen ether is prepared by reaction equation (1)；
S2: polysiloxanes two (the first and second ethers) front three amidogen ether is prepared by reaction equation (2)；
S3: polysiloxanes two (the first and second ethers) glycine betaine is prepared by reaction equation (3.1) and (3.2). CLCH3COOH+ NaOH→CLCH3COONa+H2O(3.1)
In the present solution, using (the first and second ethers) glycine betaine of polysiloxanes two as surfactant, this surfactant It is the copolymer of polysiloxanes and glycine betaine, application of the silicone compounds in personal care product has been achieved for significant Increase, polysiloxane group has excellent lipophilicity, and glycine betaine extracts from root, stem, leaf and the fruit of natural plants, native annulus It protects, the quaternary ammonium group and carboxyl in glycine betaine have excellent hydrophily, and the methyl on quaternary ammonium group is replaced by ether, further increase The big hydrophily of quaternary ammonium group, therefore this (the first and second ethers) glycine betaine of polysiloxanes two is used as surfactant, it is more normal than in the market Surfactant in liquid detergent has higher activity function, stronger dirt-removing power, therefore it is living to reduce surface The dosage of property agent, so that the discharge of surfactant is reduced, meanwhile, polysiloxanes two (the first and second ethers) glycine betaine can be in short-term It is interior degradable, it avoids polluting water and environment；Cosurfactant is increased in liquid detergent, is further improved The dirt-removing power of liquid detergent reduces the dosage and discharge amount of liquid detergent, while according to the characteristic of surfactant itself, can double as For the effect of emulsifier, stabilizer, thickener, lecithin is zwitterionic surfactant, is usually extracted from soybean Come, is a kind of excellent emulsifier, while being also good dispersing agent and stabilizer, is used in liquid detergent, makes the object in formula Expect compatibility that can be many, is uniformly distributed, does not settle, it is safe and non-toxic, clothing and human body will not be damaged, while making clothing Object softness is not short-tempered；Dodecyl dihydroxy ethyl glycine betaine and octadecyl dihydroxy ethyl glycine betaine are that amphoteric ion surface is living Property agent, there is excellent stability and emulsibility, while the product have good thickening property, dispersibility and wetability, used in washing In clothing liquid, synergy, sterilization and antistatic property are played；Calcium carbonate granule is added in liquid detergent or aluminum hydroxide particles are used as and rub Liniment, the chemical property in liquid detergent is relatively stable, is acted on by particle mechanical beating, realizes going for substrate surface blot It removes, further improves the washability of liquid detergent, the addition of fumet can effectively promote the smell of liquid detergent, make washed Clothing has faint scent, and using plant extracts as fumet, pleasant aroma is not pungent, and ingredient is natural, is had no toxic side effect, simultaneously According to plant self property, effect that Titian while also has other different, such as repeatedly perfume (or spice) can clear mind wake up, help to delay Brain fatigue is solved, enhances memory, santal not only has pleasant fragrance, but also has particularly preferred function to urogenital system Effect has extraordinary disinfection and sterilization effect, also has remarkable result to the illness of lung, orange extract can remove different Taste, sterilizing promote the production of body fluid to quench thirst, and lasting is permanent, and peppermint can be with sweating and heat resolving, and clear away heart-fire improving eyesight；Use aloe extract as Wetting agent, ingredient is natural, not will cause stimulation and injury to skin and clothing, not only wetting action is more preferable, moreover it is possible to play lubrication Effect, improves the feel of clothing, at the same aloe extract can also bactericidal antiphlogistic, the clothing of wash-off is smooth, soft, pro-skin, no It is crude, it has been not easy electrostatic；The extract of Chinese herbal medicine has no toxic side effect, is killing usually using in range as antisepsis antistaling agent While bacterium sterilizes, according to the pharmacological action of every kind of Chinese herbal medicine itself, other pharmacological actions, such as Flos Caryophylli extract can also be had both Have effects that stomach invigorating, alleviate abdominal bloating, digestion power can be enhanced in smell, mitigates nausea and vomiting, fruit of a cubeb litsea tree extract tool There is a Fresh Lemon fruit flavor, anti-corrosion while can also have stronger antioxidant activity with Titian.
Food grade liquid detergent washing dirt-removing power of the invention is strong, and dosage is few, so that discharge amount is low, will not cause to environment Pollution, safety and environmental protection, will not damaging laundry and skin, the clothing of wash-off is bright in colour, and smooth, soft, pro-skin is not crude, no Electrostatic, and there is faint scent.

Claims (8)

1. a kind of food grade liquid detergent, it is characterised in that: by weight percentage, be made of following component: rubbing agent: 3~10%
Polysiloxanes two (the first and second ethers) glycine betaine: 20~35%
Cosurfactant: 2~10%
Fumet: 0.5~1.5%
Wetting agent: 0.1~0.5%
Chinese medicine preservative: 0.1~0.5%
Deionized water: surplus
The preparation process of polysiloxanes two (the first and second ethers) glycine betaine is as follows:
S1: polysiloxanes two (bromomethyl) front three amidogen ether is prepared by reaction equation (1)；
S2: polysiloxanes two (the first and second ethers) front three amidogen ether is prepared by reaction equation (2)；
S3: polysiloxanes two (the first and second ethers) glycine betaine is prepared by reaction equation (3.1) and (3.2).
2. food grade liquid detergent according to claim 1, it is characterised in that: it is 1 that the cosurfactant, which is mass ratio: 1 lecithin and the mixture of dodecyl dihydroxy ethyl glycine betaine.
3. food grade liquid detergent according to claim 1, it is characterised in that: it is 1 that the cosurfactant, which is mass ratio: 1 lecithin and the mixture of octadecyl dihydroxy ethyl glycine betaine.
4. food grade liquid detergent according to claim 1, it is characterised in that: the rubbing agent is calcium carbonate granule or hydrogen Alumina particle.
5. food grade liquid detergent according to claim 1, it is characterised in that: the fumet is repeatedly fragrant extract, wingceltis Fragrant extract, orange extract or mint extract.
6. food grade liquid detergent according to claim 1, it is characterised in that: the wetting agent is aloe extract.
7. food grade liquid detergent according to claim 1, it is characterised in that: the Chinese medicine preservative is fruit of a cubeb litsea tree extract Or Flos Caryophylli extract.
8. the preparation method of food grade liquid detergent according to claim 1, it is characterised in that: include the following steps:
Following component is mass percent,
Step 1: deionized water being added in blender, is warming up to 50~80 DEG C, 20~35% poly- silicon is added in whipping process (the first and second ethers) glycine betaine of oxygen alkane two and 2~10% cosurfactant, stirring be cooled to room temperature it after completely dissolution To S1 solution.
Step 2: 0.5~1.5% fumet, 0.1~0.5% wetting agent and 0.1~0.5% Chinese medicine is added into S1 solution again After preservative stirs, it is eventually adding 3~10% rubbing agent, is sufficiently stirred that be dispersed in rubbing agent above-mentioned molten In liquid.
CN201811651414.5A 2018-12-31 2018-12-31 A kind of food grade liquid detergent and preparation method thereof Pending CN109628235A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102020672A (en) * 2010-10-09 2011-04-20 华南理工大学 Alkoxy silicane functionalized betaine zwitterionic compound and preparation method and application thereof
CN104789383A (en) * 2015-05-19 2015-07-22 胡洪梅 Antibacterial washing liquid

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102020672A (en) * 2010-10-09 2011-04-20 华南理工大学 Alkoxy silicane functionalized betaine zwitterionic compound and preparation method and application thereof
CN104789383A (en) * 2015-05-19 2015-07-22 胡洪梅 Antibacterial washing liquid

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Application publication date: 20190416