CN108277102A - Efficient detergent for toilet of a kind of environmental protection deodorization and sterilization and preparation method thereof - Google Patents
Efficient detergent for toilet of a kind of environmental protection deodorization and sterilization and preparation method thereof Download PDFInfo
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- CN108277102A CN108277102A CN201810169546.8A CN201810169546A CN108277102A CN 108277102 A CN108277102 A CN 108277102A CN 201810169546 A CN201810169546 A CN 201810169546A CN 108277102 A CN108277102 A CN 108277102A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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Abstract
The invention discloses efficient detergent for toilet of a kind of environmentally friendly deodorization and sterilization and preparation method thereof, include the raw material of following parts by weight：46 parts of plants essential oil, 13 parts of sodium alginate, 10 16 parts of extracts of Chinese herbal medicine, 12 parts of odium stearate, 0.5 1 parts of methyl hydroxybenzoate, 10 20 parts of organic acid, 30 40 parts of solvent, 35 parts of chelating agent, 13 parts of neopelex, 12 parts of sodium carbonate, 24 parts of sodium chloride, 12 parts of surfactant.Corrosivity of the present invention is small, wall built-up effect is good, de-sludging strong detergency, stability are good, deodorizing flavouring excellent effect, product is mild environmentally friendly, nontoxic, have disinfection effect concurrently, the raw material components of the present invention are safe and reliable simultaneously, are easy to get, cost is relatively low, technique is concise, has higher practical value and good application prospect.
Description
Technical field
The present invention relates to environmental protection cleaning product technical fields, and in particular to a kind of efficient detergent for toilet of environmental protection deodorization and sterilization and its
Preparation method.
Background technology
Lavatory after a period of use, can deposit the dirts such as urine dirt, incrustation scale, iron rust, need to be removed using detergent for toilet.It is existing normal
The detergent for toilet product seen mainly is divided to two kinds, and one is the hydrochloric acid for using high concentration, have stronger volatility and irritation；One
Kind is to use hypochlorite, equally has certain irritation and harm to human body.In addition, in order to reinforce treatment effect, in detergent for toilet
It is also possible to added with oxidant constituents such as formaldehyde, hydrogen peroxide；Alcohol ether solvents etc. have the organic molten of volatility and genotoxic potential
Agent ingredient；There is apparent harm and banned in a certain range to environment containing Phosphorus, nonylphenol class, acid esters type plasticizer class etc.
The component only used；Activity larger enzyme classes formulation components affected by environment；To implements have the high concentration compared with strong corrosive without
Machine salt component.Acid ingredient is all added in common cleaning toilet extract formula.The main function of acid constituents is to discharge under conditions of use
Acid (H+), followed by plays building action.Acid medium condition is had been selected as due to the use of condition, therefore acid constituents must have
The acid ability of stronger release.It is cleaning toilet essence with hydrochloric acid and phosphoric acid by various factors such as counterbalance effect and safety
In common acid.Wherein, most common is exactly hydrochloric acid, and hydrogen chloride accounts for formula total amount 7-8%.Due to a large amount of uses of hydrochloric acid, make production
Product have too strong corrosivity, have corrosivity to the metal fittings above sanitary ware, also have corrosivity to ceramic surface,
The adamantine layer of especially ceramic surface will produce crackle after long-term corrosion, and the ceramic sanitary appliance of light color is caused " to be washed by cleaning toilet essence
Flower ".
In addition the detergent for toilet odor type with refresh function sold in the market is different, but is with organic compound such as virtue mostly
Fragrant compounds of group and some monoterpenes compounds etc. are equipped with what essence mixed again, by fragrant come covering smell, subtract
For light people to the uncomfortable feeling of peculiar smell, some of which synthetics, which are used for a long time, to generate harm to human body, cause nerve
Weak or upper respiratory tract system lesion, or even have injury to some immune systems, hemopoietic system, such as dimethylbenzene, ketone and aldehyde
Deng large dosage of use can cause to be poisoned.
Invention content
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization, this is clean
Lavatory agent corrosivity is small, wall built-up effect is good, de-sludging strong detergency, stability are good, deodorizing flavouring excellent effect, the mild environmental protection of product,
It is nontoxic, have disinfection effect concurrently, while the raw material components of the present invention are safe and reliable, are easy to get, cost is relatively low, technique letter
It is bright, there is higher practical value and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that：
The present invention provides a kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization, include the raw material of following parts by weight：
4-6 parts of plants essential oil, 1-3 parts of sodium alginate, 10-16 parts of extracts of Chinese herbal medicine, 1-2 parts of odium stearate, methyl hydroxybenzoate
0.5-1 parts, 10-20 parts of organic acid, 30-40 parts of solvent, 3-5 parts of chelating agent, 1-3 parts of neopelex, sodium carbonate 1-2
Part, 2-4 parts of sodium chloride, 1-2 parts of surfactant.
Preferably, the environmentally friendly efficient detergent for toilet of deodorization and sterilization includes the raw material of following parts by weight：
5 parts of plants essential oil, 13 parts of extracts of Chinese herbal medicine, 1.5 parts of odium stearate, 0.8 part of methyl hydroxybenzoate, has 2 parts of sodium alginate
15 parts of machine acid, 35 parts of solvent, 4 parts of chelating agent, 2 parts of neopelex, 1.5 parts of sodium carbonate, 3 parts of sodium chloride, surface are lived
1.5 parts of agent of property.
Preferably, the plants essential oil is honeysuckle essential oil, Peppermint essential oil, Lavender, rose ethereal oil according to weight
Measure ratio 3:2:1:The mixture of 1 composition.
Preferably, the chelating agent is polyphosphate, 1,3- diketone, polyamines according to weight ratio 3:1:The mixture of 2 compositions.
Preferably, the extracts of Chinese herbal medicine preparation method is：By aloe, tea root, folium artemisiae argyi, bitter dish, Folium Forsythia according to
Weight ratio 3:2:1:2:1 is rinsed well with clear water, is added in pulverizer and is crushed, and 10 times of water is added to be heated to 100 degrees Celsius, decocts 2
Hour, solid and liquid separation；Residue after first time water is carried again adds 6 times of amount water second of water of progress to carry, and extracts 1.5 hours, Gu,
Liquid detaches；Residue after second of water is carried again adds 4 times of amount water progress third time water to carry, and extracts 1.5 hours, solid and liquid separation；It closes
And aqueous extract three times, it concentrates to get extracts of Chinese herbal medicine.
Preferably, the organic acid is succinic acid, adipic acid, amino carboxylic acid, hydroxyacetic acid, citric acid according to weight ratio 3:
2:2:1:The mixture of 4 compositions.
Preferably, the surfactant is glycine betaine, fatty glyceride, coconut oil diethanol amide, alkyl glycosides
According to weight ratio 3:1:2:The mixture of 1 composition.
Preferably, the solvent is isoamyl alcohol, ethyl alcohol, deionized water according to weight ratio 1:2:The mixture of 30 compositions.
The present invention also provides a kind of preparation methods of the efficient detergent for toilet of environmentally friendly deodorization and sterilization, include the following steps：
Step 1 weighs prepare each component raw material as required；
Plants essential oil, extracts of Chinese herbal medicine, sodium alginate, odium stearate, chelating agent are mixed and ultrasonic wave stirring are added by step 2
It is stirred 10-14 minutes with frequency 20-30kHz in device, obtains mixed liquor A；
Solvent is added in water-bath step 3, maintains the temperature at 30-34 DEG C, and methyl hydroxybenzoate, chelating agent, dodecane is added
Base benzene sulfonic acid sodium salt, sodium carbonate, sodium chloride, using constant temperature blender with magnetic force, constant temperature stirs 40-50 minutes, and mixed liquid B is made；
Mixed liquid B made from mixed liquor A made from step 2 and step 3, organic acid in bath temperature are 40-50 by step 4
It is mixed using constant temperature blender with magnetic force under the conditions of DEG C, constant temperature stirs 20-30min, adds in homogenizer, is in homogenization pressure
The efficient cleaning toilet of environmentally friendly deodorization and sterilization of invention is made in 12-14MPa, speed of agitator 6000-7000r/min, homogeneous 5-7 minutes
Agent.
Preferably, the preparation process of the efficient detergent for toilet of the environmentally friendly deodorization and sterilization is：
Step 1 weighs prepare each component raw material as required；
Plants essential oil, extracts of Chinese herbal medicine, sodium alginate, odium stearate, chelating agent are mixed and ultrasonic wave stirring are added by step 2
It is stirred 12 minutes with frequency 25kHz in device, obtains mixed liquor A；
Solvent is added in water-bath step 3, maintains the temperature at 32 DEG C, and methyl hydroxybenzoate, chelating agent, detergent alkylate is added
Sodium sulfonate, sodium carbonate, sodium chloride, using constant temperature blender with magnetic force, constant temperature stirs 45 minutes, and mixed liquid B is made；
Mixed liquid B made from mixed liquor A made from step 2 and step 3, organic acid in bath temperature are 45 DEG C by step 4
Under the conditions of mixed using constant temperature blender with magnetic force, constant temperature stir 25min, add in homogenizer, homogenization pressure be 13MPa,
Speed of agitator is 6500r/min, and the efficient detergent for toilet of environmentally friendly deodorization and sterilization of invention is made in homogeneous 6 minutes.
Compared with prior art, the present invention has following advantageous effect：
（1）The plants essential oil added in a kind of environmentally friendly efficient detergent for toilet of deodorization and sterilization of the present invention is mainly honeysuckle essential oil, thin
Lotus essential oil, Lavender, rose ethereal oil, on the one hand a few person's cools are pleasant, have pleasant fragrance of a flower fragrance, energy
The peculiar smell being enough effectively improved in closestool urinal, on the other hand several persons are plant extraction liquid, and avoiding compound essence may be to people
The harm that body generates.
（2）Used in a kind of environmentally friendly efficient detergent for toilet of deodorization and sterilization of the present invention extracts of Chinese herbal medicine for aloe, tea root,
Folium artemisiae argyi, bitter dish, Folium Forsythia have bactericidal effect, with the use of to coccus and most of Grain-negative bars by purifying repeatedly
Bacterium has inhibiting effect, to staphylococcus aureus, beta hemolytic streptococcus, Escherichia coli, proteus, corynebacterium diphtheriae,
Typhoid fever and paratyphosum Bacterium, Pseudomonas aeruginosa, hay bacillus, Bacillus alcaligenes and Bacillus tuberculosis etc. have killing or inhibit to make
With, to a variety of pathogenic fungus also have bacteriostasis and meanwhile have the effect of improve air quality, pleasant mental and body.
（3）The organic acid that a kind of environmentally friendly efficient detergent for toilet of deodorization and sterilization of the present invention uses be mainly succinic acid, adipic acid,
Amino carboxylic acid, hydroxyacetic acid, citric acid, both ensure that good scale removal effect, while its inorganic acid such as hydrochloric acid for avoiding again
Deng to the possible corrosivity of closestool urinal；The surfactant of addition is glycine betaine, fatty glyceride, coconut oil diethyl simultaneously
Alkylolamides, alkyl glycosides can play synergistic effect, increase dirt-removing power.
（4）The sodium alginate, stearic acid sodium, dioxane that a kind of environmentally friendly efficient detergent for toilet of deodorization and sterilization of the present invention passes through addition
Base benzene sulfonic acid sodium salt, chelating agent auxiliary other compositions form cross-linked structure, effectively increase the wall built-up performance of detergent for toilet, can
Enough times of contact increased with dirt, using effect is enhanced, the service efficiency of detergent for toilet is substantially increased.
（5）A kind of efficient detergent for toilet corrosivity of environmentally friendly deodorization and sterilization of the present invention is small, wall built-up effect is good, de-sludging detergency
By force, stability is good, deodorizing flavouring excellent effect, the mild environmental protection of product, nontoxic, has disinfection effect, while this hair concurrently
Bright raw material components are safe and reliable, are easy to get, and cost is relatively low, and technique is concise, before having higher practical value and good application
Scape.
Specific implementation mode
With reference to specific embodiment, technical scheme in the embodiment of the invention is clearly and completely described, shows
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization of the present embodiment, includes the raw material of following parts by weight：
It is 4 parts of plants essential oil, 1 part of sodium alginate, 10 parts of extracts of Chinese herbal medicine, 1 part of odium stearate, 0.5 part of methyl hydroxybenzoate, organic
10 parts of acid, 30 parts of solvent, 3 parts of chelating agent, 1 part of neopelex, 1 part of sodium carbonate, 2 parts of sodium chloride, surfactant 1
Part.
Essential oil in the present embodiment is honeysuckle essential oil, Peppermint essential oil, Lavender, rose ethereal oil according to weight ratio
3:2:1:The mixture of 1 composition.
Chelating agent in the present embodiment is polyphosphate, 1,3- diketone, polyamines according to weight ratio 3:1:The mixing of 2 compositions
Object.
Extracts of Chinese herbal medicine preparation method in the present embodiment is：By aloe, tea root, folium artemisiae argyi, bitter dish, Folium Forsythia according to
Weight ratio 3:2:1:2:1 is rinsed well with clear water, is added in pulverizer and is crushed, and 10 times of water is added to be heated to 100 degrees Celsius, decocts 2
Hour, solid and liquid separation；Residue after first time water is carried again adds 6 times of amount water second of water of progress to carry, and extracts 1.5 hours, Gu,
Liquid detaches；Residue after second of water is carried again adds 4 times of amount water progress third time water to carry, and extracts 1.5 hours, solid and liquid separation；It closes
And aqueous extract three times, it concentrates to get extracts of Chinese herbal medicine.
Organic acid in the present embodiment is succinic acid, adipic acid, amino carboxylic acid, hydroxyacetic acid, citric acid according to weight ratio
3:2:2:1:The mixture of 4 compositions.
Surfactant in the present embodiment is glycine betaine, fatty glyceride, coconut oil diethanol amide, alkyl glycosides
According to weight ratio 3:1:2:The mixture of 1 composition.
Solvent in the present embodiment is isoamyl alcohol, ethyl alcohol, deionized water according to weight ratio 1:2:The mixture of 30 compositions.
A kind of preparation method of the efficient detergent for toilet of environmentally friendly deodorization and sterilization of the present embodiment, includes the following steps：
Step 1 weighs prepare each component raw material as required；
Plants essential oil, extracts of Chinese herbal medicine, sodium alginate, odium stearate, chelating agent are mixed and ultrasonic wave stirring are added by step 2
It is stirred 10 minutes with frequency 20kHz in device, obtains mixed liquor A；
Solvent is added in water-bath step 3, maintains the temperature at 30 DEG C, and methyl hydroxybenzoate, chelating agent, detergent alkylate is added
Sodium sulfonate, sodium carbonate, sodium chloride, using constant temperature blender with magnetic force, constant temperature stirs 40 minutes, and mixed liquid B is made；
Mixed liquid B made from mixed liquor A made from step 2 and step 3, organic acid in bath temperature are 40 DEG C by step 4
Under the conditions of mixed using constant temperature blender with magnetic force, constant temperature stir 20min, add in homogenizer, homogenization pressure be 12MPa,
Speed of agitator is 6000r/min, and the efficient detergent for toilet of environmentally friendly deodorization and sterilization of invention is made in homogeneous 5 minutes.
Embodiment 2.
A kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization of the present embodiment, includes the raw material of following parts by weight：
6 parts of plants essential oil, 3 parts of sodium alginate, 16 parts of extracts of Chinese herbal medicine, 2 parts of odium stearate, 1 part of methyl hydroxybenzoate, organic acid
20 parts, 40 parts of solvent, 5 parts of chelating agent, 3 parts of neopelex, 2 parts of sodium carbonate, 4 parts of sodium chloride, surfactant 2
Part.
Essential oil in the present embodiment is honeysuckle essential oil, Peppermint essential oil, Lavender, rose ethereal oil according to weight ratio
3:2:1:The mixture of 1 composition.
Chelating agent in the present embodiment is polyphosphate, 1,3- diketone, polyamines according to weight ratio 3:1:The mixing of 2 compositions
Object.
Extracts of Chinese herbal medicine preparation method in the present embodiment is：By aloe, tea root, folium artemisiae argyi, bitter dish, Folium Forsythia according to
Weight ratio 3:2:1:2:1 is rinsed well with clear water, is added in pulverizer and is crushed, and 10 times of water is added to be heated to 100 degrees Celsius, decocts 2
Hour, solid and liquid separation；Residue after first time water is carried again adds 6 times of amount water second of water of progress to carry, and extracts 1.5 hours, Gu,
Liquid detaches；Residue after second of water is carried again adds 4 times of amount water progress third time water to carry, and extracts 1.5 hours, solid and liquid separation；It closes
And aqueous extract three times, it concentrates to get extracts of Chinese herbal medicine.
Organic acid in the present embodiment is succinic acid, adipic acid, amino carboxylic acid, hydroxyacetic acid, citric acid according to weight ratio
3:2:2:1:The mixture of 4 compositions.
Surfactant in the present embodiment is glycine betaine, fatty glyceride, coconut oil diethanol amide, alkyl glycosides
According to weight ratio 3:1:2:The mixture of 1 composition.
Solvent in the present embodiment is isoamyl alcohol, ethyl alcohol, deionized water according to weight ratio 1:2:The mixture of 30 compositions.
A kind of preparation method of the efficient detergent for toilet of environmentally friendly deodorization and sterilization of the present embodiment, includes the following steps：
Step 1 weighs prepare each component raw material as required；
Plants essential oil, extracts of Chinese herbal medicine, sodium alginate, odium stearate, chelating agent are mixed and ultrasonic wave stirring are added by step 2
It is stirred 14 minutes with frequency 30kHz in device, obtains mixed liquor A；
Solvent is added in water-bath step 3, maintains the temperature at 34 DEG C, and methyl hydroxybenzoate, chelating agent, detergent alkylate is added
Sodium sulfonate, sodium carbonate, sodium chloride, using constant temperature blender with magnetic force, constant temperature stirs 50 minutes, and mixed liquid B is made；
Mixed liquid B made from mixed liquor A made from step 2 and step 3, organic acid in bath temperature are 50 DEG C by step 4
Under the conditions of mixed using constant temperature blender with magnetic force, constant temperature stir 30min, add in homogenizer, homogenization pressure be 14MPa,
Speed of agitator is 7000r/min, and the efficient detergent for toilet of environmentally friendly deodorization and sterilization of invention is made in homogeneous 7 minutes.
Embodiment 3.
A kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization of the present embodiment, includes the raw material of following parts by weight：
5 parts of plants essential oil, 13 parts of extracts of Chinese herbal medicine, 1.5 parts of odium stearate, 0.8 part of methyl hydroxybenzoate, has 2 parts of sodium alginate
15 parts of machine acid, 35 parts of solvent, 4 parts of chelating agent, 2 parts of neopelex, 1.5 parts of sodium carbonate, 3 parts of sodium chloride, surface are lived
1.5 parts of agent of property.
Essential oil in the present embodiment is honeysuckle essential oil, Peppermint essential oil, Lavender, rose ethereal oil according to weight ratio
3:2:1:The mixture of 1 composition.
Chelating agent in the present embodiment is polyphosphate, 1,3- diketone, polyamines according to weight ratio 3:1:The mixing of 2 compositions
Object.
Extracts of Chinese herbal medicine preparation method in the present embodiment is：By aloe, tea root, folium artemisiae argyi, bitter dish, Folium Forsythia according to
Weight ratio 3:2:1:2:1 is rinsed well with clear water, is added in pulverizer and is crushed, and 10 times of water is added to be heated to 100 degrees Celsius, decocts 2
Hour, solid and liquid separation；Residue after first time water is carried again adds 6 times of amount water second of water of progress to carry, and extracts 1.5 hours, Gu,
Liquid detaches；Residue after second of water is carried again adds 4 times of amount water progress third time water to carry, and extracts 1.5 hours, solid and liquid separation；It closes
And aqueous extract three times, it concentrates to get extracts of Chinese herbal medicine.
Organic acid in the present embodiment is succinic acid, adipic acid, amino carboxylic acid, hydroxyacetic acid, citric acid according to weight ratio
3:2:2:1:The mixture of 4 compositions.
Surfactant in the present embodiment is glycine betaine, fatty glyceride, coconut oil diethanol amide, alkyl glycosides
According to weight ratio 3:1:2:The mixture of 1 composition.
Solvent in the present embodiment is isoamyl alcohol, ethyl alcohol, deionized water according to weight ratio 1:2:The mixture of 30 compositions.
A kind of preparation method of the efficient detergent for toilet of environmentally friendly deodorization and sterilization of the present embodiment, includes the following steps：
Step 1 weighs prepare each component raw material as required；
Plants essential oil, extracts of Chinese herbal medicine, sodium alginate, odium stearate, chelating agent are mixed and ultrasonic wave stirring are added by step 2
It is stirred 12 minutes with frequency 25kHz in device, obtains mixed liquor A；
Solvent is added in water-bath step 3, maintains the temperature at 32 DEG C, and methyl hydroxybenzoate, chelating agent, detergent alkylate is added
Sodium sulfonate, sodium carbonate, sodium chloride, using constant temperature blender with magnetic force, constant temperature stirs 45 minutes, and mixed liquid B is made；
Mixed liquid B made from mixed liquor A made from step 2 and step 3, organic acid in bath temperature are 45 DEG C by step 4
Under the conditions of mixed using constant temperature blender with magnetic force, constant temperature stir 25min, add in homogenizer, homogenization pressure be 13MPa,
Speed of agitator is 6500r/min, and the efficient detergent for toilet of environmentally friendly deodorization and sterilization of invention is made in homogeneous 6 minutes.
A kind of environmentally friendly efficient detergent for toilet corrosivity of deodorization and sterilization of the present invention is small, wall built-up effect is good, de-sludging strong detergency, steady
Qualitative good, deodorizing flavouring excellent effect, product is mild environmentally friendly, nontoxic, has disinfection effect, while the original of the present invention concurrently
Material component is safe and reliable, is easy to get, and cost is relatively low, and technique is concise, has higher practical value and good application prospect.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (10)
1. a kind of efficient detergent for toilet of environmental protection deodorization and sterilization, which is characterized in that include the raw material of following parts by weight：
4-6 parts of plants essential oil, 1-3 parts of sodium alginate, 10-16 parts of extracts of Chinese herbal medicine, 1-2 parts of odium stearate, methyl hydroxybenzoate
0.5-1 parts, 10-20 parts of organic acid, 30-40 parts of solvent, 3-5 parts of chelating agent, 1-3 parts of neopelex, sodium carbonate 1-2
Part, 2-4 parts of sodium chloride, 1-2 parts of surfactant.
2. a kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization according to claim 1, which is characterized in that the environmental protection sterilization removes
Smelly efficient detergent for toilet includes the raw material of following parts by weight：
5 parts of plants essential oil, 13 parts of extracts of Chinese herbal medicine, 1.5 parts of odium stearate, 0.8 part of methyl hydroxybenzoate, has 2 parts of sodium alginate
15 parts of machine acid, 35 parts of solvent, 4 parts of chelating agent, 2 parts of neopelex, 1.5 parts of sodium carbonate, 3 parts of sodium chloride, surface are lived
1.5 parts of agent of property.
3. a kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization according to claim 1 or 2, which is characterized in that the plant essence
Oil is honeysuckle essential oil, Peppermint essential oil, Lavender, rose ethereal oil according to weight ratio 3:2:1:The mixture of 1 composition.
4. a kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization according to claim 1 or 2, which is characterized in that the chelating agent
It is polyphosphate, 1,3- diketone, polyamines according to weight ratio 3:1:The mixture of 2 compositions.
5. a kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization according to claim 1 or 2, which is characterized in that the Chinese herbal medicine
Extracting liquid and preparation method thereof is：By aloe, tea root, folium artemisiae argyi, bitter dish, Folium Forsythia according to weight ratio 3:2:1:2:1 is rinsed with clear water
Totally, it is added in pulverizer and crushes, 10 times of water is added to be heated to 100 degrees Celsius, decoct 2 hours, solid and liquid separation；It again will be for the first time
Residue after water carries adds 6 times of amount water second of water of progress to carry, and extracts 1.5 hours, solid and liquid separation；After second of water is carried again
Residue adds 4 times of amount water progress third time water to carry, and extracts 1.5 hours, solid and liquid separation；Merge aqueous extract three times, concentration to get
Extracts of Chinese herbal medicine.
6. a kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization according to claim 1 or 2, which is characterized in that the organic acid
It is succinic acid, adipic acid, amino carboxylic acid, hydroxyacetic acid, citric acid according to weight ratio 3:2:2:1:The mixture of 4 compositions.
7. a kind of efficient detergent for toilet of environmentally friendly deodorization and sterilization according to claim 1 or 2, which is characterized in that live on the surface
Property agent be glycine betaine, fatty glyceride, coconut oil diethanol amide, alkyl glycosides is according to weight ratio 3:1:2:1 composition mixes
Close object.
8. a kind of environmentally friendly efficient detergent for toilet of deodorization and sterilization according to claim 1 or 2, which is characterized in that the solvent is
Isoamyl alcohol, ethyl alcohol, deionized water are according to weight ratio 1:2:The mixture of 30 compositions.
9. a kind of method preparing the efficient detergent for toilet of environmentally friendly deodorization and sterilization as claimed in claim 1 or 2, which is characterized in that packet
Include following steps：
Step 1 weighs prepare each component raw material as required；
Plants essential oil, extracts of Chinese herbal medicine, sodium alginate, odium stearate, chelating agent are mixed and ultrasonic wave stirring are added by step 2
It is stirred 10-14 minutes with frequency 20-30kHz in device, obtains mixed liquor A；
Solvent is added in water-bath step 3, maintains the temperature at 30-34 DEG C, and methyl hydroxybenzoate, chelating agent, dodecane is added
Base benzene sulfonic acid sodium salt, sodium carbonate, sodium chloride, using constant temperature blender with magnetic force, constant temperature stirs 40-50 minutes, and mixed liquid B is made；
Mixed liquid B made from mixed liquor A made from step 2 and step 3, organic acid in bath temperature are 40-50 by step 4
It is mixed using constant temperature blender with magnetic force under the conditions of DEG C, constant temperature stirs 20-30min, adds in homogenizer, is in homogenization pressure
The efficient cleaning toilet of environmentally friendly deodorization and sterilization of invention is made in 12-14MPa, speed of agitator 6000-7000r/min, homogeneous 5-7 minutes
Agent.
10. a kind of preparation method of the efficient detergent for toilet of environmentally friendly deodorization and sterilization according to claim 9, which is characterized in that institute
Stating step is：
Step 1 weighs prepare each component raw material as required；
Plants essential oil, extracts of Chinese herbal medicine, sodium alginate, odium stearate, chelating agent are mixed and ultrasonic wave stirring are added by step 2
It is stirred 12 minutes with frequency 25kHz in device, obtains mixed liquor A；
Solvent is added in water-bath step 3, maintains the temperature at 32 DEG C, and methyl hydroxybenzoate, chelating agent, detergent alkylate is added
Sodium sulfonate, sodium carbonate, sodium chloride, using constant temperature blender with magnetic force, constant temperature stirs 45 minutes, and mixed liquid B is made；
Mixed liquid B made from mixed liquor A made from step 2 and step 3, organic acid in bath temperature are 45 DEG C by step 4
Under the conditions of mixed using constant temperature blender with magnetic force, constant temperature stir 25min, add in homogenizer, homogenization pressure be 13MPa,
Speed of agitator is 6500r/min, and the efficient detergent for toilet of environmentally friendly deodorization and sterilization of invention is made in homogeneous 6 minutes.
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| CN201810169546.8A CN108277102A (en) | 2018-03-01 | 2018-03-01 | Efficient detergent for toilet of a kind of environmental protection deodorization and sterilization and preparation method thereof |
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