CN112680290B - Long-acting foam-stabilizing wall-mounted toilet cleaning block and preparation method thereof - Google Patents
Long-acting foam-stabilizing wall-mounted toilet cleaning block and preparation method thereof Download PDFInfo
- Publication number
- CN112680290B CN112680290B CN202011565236.1A CN202011565236A CN112680290B CN 112680290 B CN112680290 B CN 112680290B CN 202011565236 A CN202011565236 A CN 202011565236A CN 112680290 B CN112680290 B CN 112680290B
- Authority
- CN
- China
- Prior art keywords
- parts
- foam
- long
- cleaning block
- toilet cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a long-acting foam-stabilizing wall-mounted toilet cleaning block and a preparation method thereof, wherein the long-acting foam-stabilizing wall-mounted toilet cleaning block comprises, by mass, 10-40 parts of sodium dodecyl benzene sulfonate, 0-40 parts of sodium dodecyl sulfate, 10-60 parts of alpha-alkenyl sodium sulfonate, 0-50 parts of sodium sulfate, 1-6 parts of tea saponin, 1-10 parts of silicone polyether, 0.5-5 parts of lemon oil, 0.5-5 parts of acid lake blue, 0.5-5 parts of water and 0.01-1 part of parachlorometaxylenol. The long-acting foam-stabilizing wall-mounted toilet cleaning block provided by the invention can maintain the liquid surface foam covering state for 4-8 hours, is suitable for sitting type flush toilets and waterless urinals in families and public toilets, and has the functions of abundant and lasting foam, water splashing prevention and odor reduction.
Description
Technical Field
The invention belongs to the field of daily chemicals, and particularly relates to a long-acting foam-stabilizing wall-mounted toilet cleaning block and a preparation method thereof.
Background
Toilet cleaning blocks are widely used in flush toilets and can be classified into an immersion type and a wall-hanging type according to their usage. The immersed toilet cleaning block is immersed in the water tank, slowly releases effective substances such as cleaning and sterilizing substance components, pigments and the like, and is stored in the water tank for later use. The disadvantages are that the dissolution rate of the immersed toilet cleaning block in water is relatively constant, the release amount of active substances in a water tank is insufficient when the toilet cleaning block is frequently used, and the cleaning and sterilizing effects of the toilet cleaning block are weakened; when the use interval is longer, the effective substances are excessively dissolved out in the water tank, and the use times are reduced. The wall-mounted toilet cleaning block is hung at the water outlet of the toilet, and partial effective substances are dissolved by utilizing water flow during flushing. Because the flushing water quantity is basically constant, the loss of the wall-mounted toilet cleaning block at each time is also basically constant, so that the using times of each toilet cleaning block are equivalent.
Currently, the main function of a toilet block is to provide toilet bowl cleaning, disinfecting and fragrancing, but the function of a foam layer covering the water surface is ignored. The abundant foam layer can effectively inhibit water splash of the water accumulation layer during toileting and weaken odor diffused by the sewer line. However, most toilet blocks have adequate lather stability and lack foam stability, and the foam layer has disappeared during both uses.
On the basis, how to improve the long-acting stability of the foam layer after the toilet cleaning block is used is one of the key fields for improving the development and production technology of the existing toilet cleaning block.
Disclosure of Invention
This section is for the purpose of summarizing some aspects of embodiments of the invention and to briefly introduce some preferred embodiments. In this section, as well as in the abstract and the title of the invention of this application, simplifications or omissions may be made to avoid obscuring the purpose of the section, the abstract and the title, and such simplifications or omissions are not intended to limit the scope of the invention.
The present invention has been made keeping in mind the above and/or other problems occurring in the prior art.
Therefore, the invention aims to overcome the defects in the prior art and provide a long-acting foam-stabilizing wall-mounted toilet cleaning block.
In order to solve the technical problems, the invention provides the following technical scheme: a long-acting foam-stabilizing wall-mounted toilet cleaning block comprises sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, alpha-alkenyl sodium sulfonate, sodium sulfate, tea saponin, silicone polyether, lemon oil, acid lake blue, p-chloro-m-xylenol and deionized water; the water-soluble tea saponin is prepared from 10-40 parts by mass of sodium dodecyl benzene sulfonate, 0-40 parts by mass of sodium dodecyl sulfate, 10-60 parts by mass of alpha-alkenyl sodium sulfonate, 0-50 parts by mass of sodium sulfate, 1-10 parts by mass of tea saponin, 1-10 parts by mass of silicone polyether, 0.5-5 parts by mass of lemon oil, 0.5-5 parts by mass of acid lake blue, 0.01-1 part by mass of parachlorometaxylenol and 0.5-5 parts by mass of deionized water.
As a preferred scheme of the long-acting foam-stabilizing wall-mounted toilet cleaning block, the long-acting foam-stabilizing wall-mounted toilet cleaning block comprises the following steps: the detergent composition comprises, by mass, 25-35 parts of sodium dodecyl benzene sulfonate, 50-70 parts of alpha-alkenyl sodium sulfonate, 6-10 parts of sodium sulfate, 2-4 parts of tea saponin, 1-2 parts of silicone polyether, 1-2 parts of lemon oil, 1-2 parts of acid lake blue, 0.08-0.12 part of parachlorometaxylenol and 0.5-2 parts of deionized water.
As a preferred scheme of the long-acting foam-stabilizing wall-mounted toilet cleaning block, the long-acting foam-stabilizing wall-mounted toilet cleaning block comprises the following steps: the detergent comprises, by mass, 28 parts of sodium dodecyl benzene sulfonate, 56 parts of alpha-sodium alkenyl sulfonate, 8 parts of sodium sulfate, 2.8 parts of tea saponin, 1.4 parts of silicone polyether, 1 part of lemon oil, 1 part of acid lake blue, 0.1 part of parachlorometaxylenol and 1.7 parts of deionized water.
The invention further aims to overcome the defects in the prior art and provide a preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block.
In order to solve the technical problems, the invention provides the following technical scheme: a preparation method of a long-acting foam-stabilizing wall-mounted toilet cleaning block comprises accurately weighing sodium dodecyl benzene sulfonate, alpha-sodium alkenyl sulfonate, sodium sulfate, tea saponin, acid lake blue and parachlorometaxylenol, and uniformly mixing in a powder mixer; sequentially adding water, silicone polyether and lemon oil into the powder mixer, and uniformly mixing; and taking out the mixed material from the powder mixer, and pressing and molding the mixed material in a mold by using a briquetting machine to obtain the long-acting foam-stabilizing wall-mounted toilet cleaning block.
As a preferred scheme of the preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block, the preparation method comprises the following steps: the water-soluble tea saponin is prepared from 10-40 parts by mass of sodium dodecyl benzene sulfonate, 0-40 parts by mass of sodium dodecyl sulfate, 10-60 parts by mass of alpha-alkenyl sodium sulfonate, 0-50 parts by mass of sodium sulfate, 1-10 parts by mass of tea saponin, 1-10 parts by mass of silicone polyether, 0.5-5 parts by mass of lemon oil, 0.5-5 parts by mass of acid lake blue, 0.01-1 part by mass of parachlorometaxylenol and 0.5-5 parts by mass of deionized water.
As a preferred scheme of the preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block, the preparation method comprises the following steps: the detergent composition comprises, by mass, 25-35 parts of sodium dodecyl benzene sulfonate, 50-70 parts of alpha-alkenyl sodium sulfonate, 6-10 parts of sodium sulfate, 2-4 parts of tea saponin, 1-2 parts of silicone polyether, 1-2 parts of lemon oil, 1-2 parts of acid lake blue, 0.08-0.12 part of parachlorometaxylenol and 0.5-2 parts of deionized water.
As a preferred scheme of the preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block, the preparation method comprises the following steps: the detergent comprises, by mass, 28 parts of sodium dodecyl benzene sulfonate, 56 parts of alpha-sodium alkenyl sulfonate, 8 parts of sodium sulfate, 2.8 parts of tea saponin, 1.4 parts of silicone polyether, 1 part of lemon oil, 1 part of acid lake blue, 0.1 part of parachlorometaxylenol and 1.7 parts of deionized water.
As a preferred scheme of the preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block, the preparation method comprises the following steps: and uniformly mixing the materials in a powder mixer, wherein the time is 5-10 minutes.
As a preferred scheme of the preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block, the preparation method comprises the following steps: and sequentially adding water, silicone polyether and lemon oil into the powder mixer, and uniformly mixing for 10-15 minutes.
As a preferred scheme of the preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block, the preparation method comprises the following steps: the long-acting foam stabilizing method comprises the step of using the wall-hanging mode in the rotational flow siphon type flush toilet, and the foam layer is maintained for not less than 4 hours in a natural state after the foam layer is used.
The invention has the beneficial effects that:
(1) the invention provides a long-acting foam-stabilizing wall-mounted toilet cleaning block, which can maintain the foam coverage state of the water accumulation liquid surface of a toilet bowl for 4-8 hours, is suitable for sitting type toilet bowls in families and public toilets, plays roles in preventing water splashing and reducing odor, and can reduce or cancel the use of an aromatic by utilizing the long-term foam stabilizing and odor reducing effects of the long-acting foam stabilizing and odor reducing block when a small amount of foam is added into a waterless urinal.
(2) When the long-acting foam-stabilizing wall-mounted toilet cleaning block formula is compounded with LAS, AOS has large influence on foaming and foam stabilizing performance, and properly increasing the ratio of AOS is beneficial to foaming and foam stabilizing, but when the ratio of AOS is too high, the stability of a foam system tends to a system only adding AOS, and the foam stabilizing is not beneficial. The foam system must be added with LAS to a certain amount so that the two can achieve the best synergistic foam stabilizing effect. Wherein LAS, AOS is 1:2, which is the best synergic foam stabilizing proportion; the silicon resin polyether serving as the foam stabilizer contains water, the active matter content is generally 50-70%, a good foam stabilizing effect is achieved, the required addition amount is high when the silicon resin polyether is used alone, the tea saponin serving as the foam stabilizer is a natural surfactant, has certain foaming capacity, and is beneficial to the foaming performance of a product when the ratio of the tea saponin to the foam stabilizer is increased, but when the tea saponin content is too high, the silicon resin polyether serving as the natural surfactant starts to influence a balanced synergistic effect consisting of LAS and AOS, although the foaming performance is slightly improved, the foam stability is reduced on the contrary, and the mass part ratio of the silicon resin polyether to the tea saponin is 1: 2. The invention preferably selects the formula of the foaming agent and the foam stabilizer, and realizes the best long-acting foam stabilizing effect of the wall-hanging toilet cleaning block.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without inventive exercise. Wherein:
FIG. 1 is a graph comparing the foaming and foam stabilizing capabilities of a single blowing agent of the invention of example 1.
FIG. 2 is a graph comparing the foaming and foam stabilizing capabilities of the blowing agent combination system of example 1 of the present invention.
FIG. 3 is a graph comparing the effect of the ratio of the blowing agent combination of example 1 of the present invention on the foaming and foam stabilizing ability.
FIG. 4 is a graph comparing the effect of MPS on foaming and foam stabilizing ability in example 2 of the present invention.
FIG. 5 is a graph comparing the effect of TS on foamability and foam stabilizing ability in example 2 of the present invention.
FIG. 6 is a graph comparing the effect of the combination ratio of foam stabilizers on foaming and foam stabilizing ability in example 2 of the present invention.
FIG. 7 is a graph comparing the foaming and foam stabilizing capabilities of three commercially available samples and optimized formulations of example 3 of the present invention.
FIG. 8 is a graph of the 8h foam stabilizing effect of three commercially available samples and optimized formulations of example 3 of the present invention.
Detailed Description
In order to make the aforementioned objects, features and advantages of the present invention more comprehensible, specific embodiments thereof are described in detail below with reference to examples of the specification.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention, but the present invention may be practiced in other ways than those specifically described and will be readily apparent to those of ordinary skill in the art without departing from the spirit of the present invention, and therefore the present invention is not limited to the specific embodiments disclosed below.
Furthermore, reference herein to "one embodiment" or "an embodiment" means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one implementation of the invention. The appearances of the phrase "in one embodiment" in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments.
The hard water preparation method of the invention comprises the following steps:
accurately weighing 0.304g of anhydrous calcium chloride, and completely dissolving with 200mL of deionized water;
accurately weighing 0.139g of magnesium chloride hexahydrate, and completely dissolving the magnesium chloride hexahydrate in 200mL of deionized water;
the calcium ion solution and the magnesium ion solution are transferred to a 1000mL volumetric flask, and the container is rinsed with deionized water and the volume is constant.
The foaming property and foam stability test method of the invention comprises the following steps:
accurately weighing an object to be detected, dissolving the object in hard water, and diluting the object to be detected to the mass concentration of 0.05% by using the hard water;
adding 20mL of the solution into a 100mL measuring cylinder with a plug, repeatedly reversing for ten times, taking out the plug, and standing to observe a foam layer;
the amount of foam is expressed as the value indicated by the graduated cylinder minus the volume of liquid;
and (4) expressing the foaming and foam stabilizing performance of the object to be tested according to the amount of foam under different standing times.
Example 1
The embodiment provides a long-acting foam-stabilizing wall-mounted toilet cleaning block, which comprises the following components in part by weight:
(1) foaming agent: sodium dodecyl benzene sulfonate (LAS), sodium alpha-alkenyl sulfonate (AOS);
(2) filling agent: sodium sulfate;
(3) foam stabilizer: tea saponin, silicone polyether;
(4) essence: the lemon oil is prepared from lemon oil,
(5) pigment: the acid lake blue is obtained by the method,
(6) and (3) bactericide: the reaction product of p-chloro-m-xylenol,
(5) wetting agent: and (3) water.
The combination and proportion optimization test of the foaming agent is as follows:
1) foaming and foam stabilizing capabilities of a single blowing agent
Controlling the foaming agent concentration to be 0.05%, comparing the foaming agent: sodium dodecylbenzene sulfonate (LAS), Sodium Dodecyl Sulfate (SDS), and sodium alpha-alkenyl sulfonate (AOS);
the results are shown in FIG. 1. It can be seen that AOS has the best foaming and foam stabilizing ability, and SDS is the worst.
2) Foaming and foam stabilizing capability of the blowing agent combination system
Controlling the total concentration of foaming agents to be 0.05%, combining the foaming agents according to the mass ratio of 1:1, and comparing the foaming and foam stabilizing capacities of the combined foaming agent system;
the results are shown in FIG. 2. It can be seen that the foaming capacity is improved when AOS is combined with LAS.
3) Optimization of ratio of sodium dodecyl benzene sulfonate to sodium alpha-alkenyl sulfonate
Controlling the total concentration of the foaming agent to be 0.05%, respectively combining LAS and AOS according to the mass ratio of 5:1, 2:1, 1:2 and 1:5, and comparing the foaming and foam stabilizing capacities of the combined foaming agent system;
the results are shown in FIG. 3. Obviously, foaming and foam stabilizing ability are similar and optimal when the mass ratio of LAS to AOS is 1:2 and 1:5, and it is preferable to select a system of LAS: AOS ═ 1:2 in view of production cost.
Example 2
The dosage and combination of the foam stabilizer are optimized as follows:
(1) optimization of the amount of silicone polyether (MPS)
The total concentration of the foaming agent and the foam stabilizer is controlled to be 0.05%, the mass ratio LAS to AOS is 1:2, the foaming agent MPS is 50:1, 25:1, 20:1, 10:1 and 5:1, and the foaming and foam stabilizing capabilities of the combined composite system are compared, and the result is shown in FIG. 4.
It can be seen that the addition of MPS contributes to foaming and foam stabilization, but must be controlled between 20:1 and 10: 1.
(2) Dosage optimization of Tea Saponin (TS)
The total concentration of the foaming agent and the foam stabilizer is controlled to be 0.05%, the mass ratio LAS to AOS is 1:2, the foaming agent TS is adjusted to be 50:1, 25:1, 20:1, 10:1 and 5:1, and the foaming and foam stabilizing capabilities of the combined composite system are compared, and the result is shown in FIG. 5.
It can be seen that the addition of TS contributes to foaming and foam stabilization, but must be controlled between 25:1 and 20: 1.
(3) Optimization of proportion of silicone polyether and tea saponin
The total concentration of the foaming agent and the foam stabilizer is controlled to be 0.05%, the mass ratio LAS: AOS is 1:2, the mass ratio of the foaming agent to the foam stabilizer is 20:1, the mass ratio TS is 5:1, 2:1, 1:2 and 1:5, and the foaming and foam stabilizing capabilities of the combined composite system are compared, and the result is shown in FIG. 6.
It can be seen that the foaming and foam stabilizing effect is simultaneously optimal at a mass ratio of MPS to TS of 1: 2.
Example 3
(1) The embodiment provides a long-acting foam-stabilizing wall-mounted toilet cleaning block formula:
sodium dodecyl benzene sulfonate, alpha-sodium alkenyl sulfonate, sodium sulfate, tea saponin, silicone polyether, lemon oil, acid lake blue, p-chloro-m-xylenol and deionized water;
the detergent comprises, by mass, 28 parts of sodium dodecyl benzene sulfonate, 56 parts of alpha-sodium alkenyl sulfonate, 8 parts of sodium sulfate, 2.8 parts of tea saponin, 1.4 parts of silicone polyether, 1 part of lemon oil, 1 part of acid lake blue, 0.1 part of parachlorometaxylenol and 1.7 parts of deionized water.
(2) The preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block comprises the following steps:
accurately weighing sodium dodecyl benzene sulfonate, alpha-sodium alkenyl sulfonate, sodium sulfate, tea saponin, acid lake blue and parachlorometaxylenol, and uniformly mixing in a powder mixer for 10 minutes;
sequentially adding water, silicone polyether and lemon oil into the powder mixer, and uniformly mixing for 15 minutes;
and taking out the mixed material from the powder mixer, and pressing and molding the mixed material in a mold by using a briquetting machine to obtain the long-acting foam-stabilizing wall-mounted toilet cleaning block.
The product of the example and a commercially available toilet cleaning block (three commercially available samples, in order, Italy WCNET suspended type toilet cleaning block, Bref Miao force import toilet cleaning block and Germany Domests suspended type wall-mounted toilet cleaning block) are respectively dissolved in hard water, the concentration of the solution is controlled to be 0.05 percent, 20mL of the solution is added into a 100mL measuring cylinder with a plug, the solution is repeatedly inverted for ten times, the plug is taken out, and the volumes of the foams of 0h, 4h and 8h are compared after standing observation.
The results are shown in FIG. 7, and the foam stabilizing effect after 8 hours of use is shown in FIG. 8. The foam stability is good, the foam covering state of the accumulated water liquid surface of the toilet bowl can be maintained for 4-8 hours, and the foam is suitable for sitting type toilet bowls of families and public toilets and has the functions of water splashing prevention and odor reduction.
Examples 4 to 6
The formulations of examples 4-6 are shown in Table 1, and the preparation process is the same as in example 3. The prepared toilet blocks are respectively dissolved in hard water, the concentration of the solution is controlled to be 0.05%, 20mL of the solution is added into a 100mL measuring cylinder with a plug, the plug is taken out after being repeatedly inverted for ten times, the plug is kept stand and observed, and the capacities of foams of 0h, 4h and 8h are compared, and the result is shown in Table 1.
TABLE 1
As can be seen from Table 1, when only one foaming agent was added, the surfactant did not synergistically stabilize the foam, so the foam stabilizing property was insufficient, and Sodium Dodecyl Sulfate (SDS) was inferior to sodium alpha-alkenyl sulfonate (AOS) and sodium dodecyl benzene sulfonate (LAS) in both foamability and foam stabilizing property.
Examples 7 to 9
The formulations of examples 7-9 are shown in Table 2, and the preparation process is the same as in example 3. The prepared toilet blocks are respectively dissolved in hard water, the concentration of the solution is controlled to be 0.05%, 20mL of the solution is added into a 100mL measuring cylinder with a plug, the plug is taken out after being repeatedly inverted for ten times, the plug is kept stand and observed, and the capacities of foams of 0h, 4h and 8h are compared, and the result is shown in Table 2.
TABLE 2
It can be seen that the AOS has a greater impact on foaming and foam stabilizing properties when compounded with LAS, and therefore, a suitable increase in the proportion of AOS contributes to foaming and foam stabilization. However, when the AOS ratio is too high, the stability of the foam system tends to be poor for foam stabilization in the AOS only system of example 4. The foam system must be added with LAS to a certain amount so that the two can achieve the best synergistic foam stabilizing effect. Wherein LAS: AOS ═ 1:2 is the optimal synergistic foam stabilizing ratio.
Examples 10 to 12
The formulations of examples 10-12 are shown in Table 3, and the preparation process is the same as example 3. The prepared toilet blocks are respectively dissolved in hard water, the concentration of the solution is controlled to be 0.05%, 20mL of the solution is added into a 100mL measuring cylinder with a plug, the plug is taken out after being repeatedly inverted for ten times, the plug is kept stand and observed, and the capacities of foams of 0h, 4h and 8h are compared, and the result is shown in Table 3.
TABLE 3
As can be seen, the silicone polyether serving as the foam stabilizer contains water, the content of active substances is generally between 50% and 70%, and the required addition amount is high when the silicone polyether is used alone in order to achieve a good foam stabilizing effect. The tea saponin used as the foam stabilizer is a surfactant which is a natural source, has certain foaming capacity, and is beneficial to the foaming performance of the product by improving the proportion. However, when the content of tea saponin is too high, as a natural surfactant, the balanced synergistic effect of LAS and AOS starts to be affected, and although foamability is slightly improved, foamability is rather lowered. Therefore, the mass part ratio of the silicon resin polyether to the tea saponin is 1: 2.
Examples 13 to 15
The formulations of examples 13-15 are shown in Table 4, and the preparation process is the same as in example 3. The obtained toilet blocks are respectively dissolved in hard water, the concentration of the solution is controlled to be 0.05%, 20mL of the solution is added into a 100mL measuring cylinder with a plug, the plug is taken out after being repeatedly inverted for ten times, the plug is kept stand and observed, and the capacities of foams of 0h, 4h and 8h are compared, and the results are shown in Table 4.
TABLE 4
It can be seen that the foam stabilizing performance of the product is remarkably reduced after the addition amount of the foam stabilizer is reduced. It is worth noting that the foaming performance of the product is improved to a certain extent after the addition amount of the foam stabilizer is increased, because the content of the tea saponin is greatly increased. However, as shown in example 12, the improvement of tea saponin does not necessarily enhance the foam stability, but in example 15, the foam amount of the product after 8 hours is reduced by more than half, and the improvement of the addition amount of the foam stabilizer is not advantageous from the viewpoint of the performance and cost ratio of the product, and example 15. In example 15, since the amount of silicone polyether added was increased, the moisture carried in the product was also increased, the hardness of the product was decreased, and blocking was likely to occur during mold release.
When the long-acting foam-stabilizing wall-mounted toilet cleaning block formula is compounded with LAS, AOS has large influence on foaming and foam stabilizing performance, and properly increasing the ratio of AOS is beneficial to foaming and foam stabilizing, but when the ratio of AOS is too high, the stability of a foam system tends to a system only adding AOS, and the foam stabilizing is not beneficial. The foam system must be added with LAS to a certain amount so that the two can achieve the best synergistic foam stabilizing effect. Wherein LAS, AOS is 1:2, which is the best synergic foam stabilizing proportion; the silicon resin polyether serving as the foam stabilizer contains water, the active matter content is generally 50-70%, a good foam stabilizing effect is achieved, the required addition amount is high when the silicon resin polyether is used alone, the tea saponin serving as the foam stabilizer is a natural surfactant, has certain foaming capacity, and is beneficial to the foaming performance of a product when the ratio of the tea saponin to the foam stabilizer is increased, but when the tea saponin content is too high, the silicon resin polyether serving as the natural surfactant starts to influence a balanced synergistic effect consisting of LAS and AOS, although the foaming performance is slightly improved, the foam stability is reduced on the contrary, and the mass part ratio of the silicon resin polyether to the tea saponin is 1: 2. The invention preferably selects the formula of the foaming agent and the foam stabilizer, and realizes the best long-acting foam stabilizing effect of the wall-hanging toilet cleaning block.
It should be noted that the above-mentioned embodiments are only for illustrating the technical solutions of the present invention and not for limiting, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, which should be covered by the claims of the present invention.
Claims (6)
1. The long-acting foam-stabilizing wall-mounted toilet cleaning block is characterized in that:
the long-acting foam-stabilizing wall-mounted toilet cleaning block consists of sodium dodecyl benzene sulfonate, alpha-alkenyl sodium sulfonate, sodium sulfate, tea saponin, silicone polyether, lemon oil, acid lake blue, parachlorometaxylenol and deionized water;
the high-efficiency and high-efficiency water-based paint comprises, by mass, 25-35 parts of sodium dodecyl benzene sulfonate, 50-70 parts of alpha-alkenyl sodium sulfonate, 6-10 parts of sodium sulfate, 2-4 parts of tea saponin, 1-2 parts of silicone polyether, 1-2 parts of lemon oil, 1-2 parts of acid lake blue, 0.08-0.12 part of parachlorometaxylenol and 0.5-2 parts of deionized water.
2. The long-acting foam-stabilizing wall-mounted toilet cleaning block as claimed in claim 1, which is characterized in that: the detergent comprises, by mass, 28 parts of sodium dodecyl benzene sulfonate, 56 parts of a-sodium alkenyl sulfonate, 8 parts of sodium sulfate, 2.8 parts of tea saponin, 1.4 parts of silicone polyether, 1 part of lemon oil, 1 part of acid lake blue, 0.1 part of parachlorometaxylenol and 1.7 parts of deionized water.
3. The preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block as claimed in claim 1 or 2, is characterized in that: the preparation method comprises the following steps:
accurately weighing sodium dodecyl benzene sulfonate, sodium a-alkenyl sulfonate, sodium sulfate, tea saponin, acid lake blue and parachlorometaxylenol, and uniformly mixing in a powder mixer;
sequentially adding water, silicone polyether and lemon oil into the powder mixer, and uniformly mixing;
and taking out the mixed material from the powder mixer, and pressing and molding the mixed material in a mold by using a briquetting machine to obtain the long-acting foam-stabilizing wall-mounted toilet cleaning block.
4. The preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block as claimed in claim 3, characterized in that: and uniformly mixing the materials in a powder mixer, wherein the mixing time is 5-10 minutes.
5. The preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block as claimed in claim 3, characterized in that: and sequentially adding water, silicone polyether and lemon oil into the powder mixer, and uniformly mixing, wherein the mixing time is 10-15 minutes.
6. The preparation method of the long-acting foam-stabilizing wall-mounted toilet cleaning block as claimed in claim 3, characterized in that: the long-acting foam stabilizing method comprises the step of using the wall-hanging mode in the rotational flow siphon type flush toilet, and the foam layer is maintained for not less than 4 hours in a natural state after the foam layer is used.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011565236.1A CN112680290B (en) | 2020-12-25 | 2020-12-25 | Long-acting foam-stabilizing wall-mounted toilet cleaning block and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011565236.1A CN112680290B (en) | 2020-12-25 | 2020-12-25 | Long-acting foam-stabilizing wall-mounted toilet cleaning block and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112680290A CN112680290A (en) | 2021-04-20 |
| CN112680290B true CN112680290B (en) | 2021-09-10 |
Family
ID=75453349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011565236.1A Active CN112680290B (en) | 2020-12-25 | 2020-12-25 | Long-acting foam-stabilizing wall-mounted toilet cleaning block and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112680290B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117016559A (en) * | 2023-07-05 | 2023-11-10 | 箭牌家居集团股份有限公司 | Foaming agent with bactericidal property and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049182A (en) * | 1990-03-03 | 1991-02-13 | 于树荫 | Alkylbenzene sulfonate solid antiscale deodorant cleaning agent, method for making and uses thereof device |
| CN102421885A (en) * | 2009-05-13 | 2012-04-18 | 汉高股份有限及两合公司 | Spherical toilet cleaner blocks, method for the production thereof, and cleaning holder comprising spherical toilet cleaner blocks |
| CN104559921A (en) * | 2014-06-17 | 2015-04-29 | 李震 | Splash-proof agent and preparation method thereof |
| CN105154247A (en) * | 2015-10-16 | 2015-12-16 | 青岛海之星生物科技有限公司 | Rich-foam toilet cleaning block |
| CN108277102A (en) * | 2018-03-01 | 2018-07-13 | 合肥峰腾节能科技有限公司 | Efficient detergent for toilet of a kind of environmental protection deodorization and sterilization and preparation method thereof |
-
2020
- 2020-12-25 CN CN202011565236.1A patent/CN112680290B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049182A (en) * | 1990-03-03 | 1991-02-13 | 于树荫 | Alkylbenzene sulfonate solid antiscale deodorant cleaning agent, method for making and uses thereof device |
| CN102421885A (en) * | 2009-05-13 | 2012-04-18 | 汉高股份有限及两合公司 | Spherical toilet cleaner blocks, method for the production thereof, and cleaning holder comprising spherical toilet cleaner blocks |
| CN104559921A (en) * | 2014-06-17 | 2015-04-29 | 李震 | Splash-proof agent and preparation method thereof |
| CN105154247A (en) * | 2015-10-16 | 2015-12-16 | 青岛海之星生物科技有限公司 | Rich-foam toilet cleaning block |
| CN108277102A (en) * | 2018-03-01 | 2018-07-13 | 合肥峰腾节能科技有限公司 | Efficient detergent for toilet of a kind of environmental protection deodorization and sterilization and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN112680290A (en) | 2021-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR0158700B1 (en) | An improved cleaning method and composition for the domestic water closet | |
| US4820449A (en) | Cleaning block for flush toilet tanks | |
| JP5697124B2 (en) | Gel detergent composition for toilet | |
| CN112680290B (en) | Long-acting foam-stabilizing wall-mounted toilet cleaning block and preparation method thereof | |
| CN104762141B (en) | A kind of solid toilet cleaning agent and preparation method thereof | |
| JPH06504298A (en) | Toilet cleaning agent | |
| WO2007021617A3 (en) | Dosage efficient, storage stable compositions for reducing chromium (vi) in cement | |
| EP0341836B1 (en) | Lavatory cleansing blocks | |
| TW201245440A (en) | Stueckfoermiges sanitaermittel | |
| US4755354A (en) | Bromide activated hypochlorite cleaning of soiled toilet bowls | |
| CN111101572A (en) | Method for slowly releasing toilet cleaning product | |
| JPH0243299A (en) | Liquid cleaner composition having a non-ionic surfactant with bleaching agent stability for automatic dish washing | |
| EP1299519B1 (en) | Lavatory freshening and/or cleaning system and method | |
| US7048205B2 (en) | Lavatory freshening and/or cleaning system and method | |
| AU2001273339A1 (en) | Lavatory freshening and/or cleaning system and method | |
| CN105695130A (en) | Sanitary fitting traceless neutral cleaning paste and preparation method thereof | |
| JP7240105B2 (en) | Effervescent composition | |
| US6291411B1 (en) | Cleaning of toilet bowls using liquid hypochlorite compositions | |
| US4587069A (en) | Process for producing color display means | |
| JP7032496B2 (en) | Solid detergent and cleaning method using the solid detergent | |
| JP2017128558A (en) | Aqueous solution microbicidal composition using povidone iodine as main component | |
| JP3574652B1 (en) | Solid cleaning agent for toilet | |
| JP2003313060A (en) | Foaming agent for hydraulic composition | |
| JP3635221B2 (en) | Washing soap | |
| CN102719324B (en) | Method for improving aroma and appearance stability in cleaning composition and cleaning composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |