CN102719324B - Method for improving aroma and appearance stability in cleaning composition and cleaning composition - Google Patents
Method for improving aroma and appearance stability in cleaning composition and cleaning composition Download PDFInfo
- Publication number
- CN102719324B CN102719324B CN201210182408.6A CN201210182408A CN102719324B CN 102719324 B CN102719324 B CN 102719324B CN 201210182408 A CN201210182408 A CN 201210182408A CN 102719324 B CN102719324 B CN 102719324B
- Authority
- CN
- China
- Prior art keywords
- acid
- spices
- cleaning compositions
- hydroxyl
- stablizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses a method for improving aroma and appearance stability in a cleaning composition and the cleaning composition. The method for improving the aroma and appearance stability in the cleaning composition is realized by adding a phenolic compound with a structure shown in a formula (I) into the spice-containing cleaning composition with pH value of less than or equal to 3.0 as a spice stabilizer, wherein in the formula (I), R is anyone of hydroxyl, C1-C6 straight chain or branch chain alkoxy and C1-C12 ester; R1 is anyone of hydroxyl and C-C6 straight chain or branch chain alkoxy; and x is 1 or 2. The weight ratio of the spice stabilizer to the spice in a cleaning detergent is 1:(1-100). According to the invention, after the spice stabilizer is added, the aroma and appearance stability of the cleaning composition are obviously enhanced compared with those of the composition which is not added with the spice stabilizer, and experimental results show that the spice stabilizer adopted in the invention still can maintain the aroma and appearance to be constant after ageing is carried out for four weeks at the temperature of 54 DEG C, so that the quality of the cleaning composition is improved; and the formula (I) is shown in the specification..
Description
Technical field
The invention belongs to cleaning compositions field, be specifically related to a kind of method and cleaning compositions that improves fragrance and appearance stability in cleaning compositions.
Background technology
Acidic cleaning compositions is generally used for removing the dirt on crust.Crust refers to the surface that is common in lavatory, as toilet, washing basin, bathtub, shower cabinet, water tap and table top, wall, floor etc.The dirt existing on above-mentioned crust mainly contains urine dirt, incrustation scale, soap scum, rust stain.While using acidic cleaner to clean it, can react with dirt and generate soluble salt, thereby above-mentioned dirt is removed.
The activeconstituents of these acidic compositions is acidic components, and it makes acidic composition maintain lower pH value (generally in pH≤3).Utilize these acidic compositions to realize urinating the dissolving of dirt, incrustation scale, soap scum, rust stain.Simultaneously, in order to make acidic composition there is better performance, in acidic composition, toward contact, comprise some ancillary components, as tensio-active agent, fungicidal preservative, suds-stabilizing agent, thickening material, hydrotropic agent, inhibiter, water-softening agent, pigment etc., give the more function of acidic composition or improve its clean effect.
Yet, because the pH value of acidic composition is lower, often brought pungency or irritating smell, its application is restricted.Ways of addressing this issue, normally adopts and add spices in acidic cleaning compositions, gives composition specific fragrance.The wide material sources of these fragrance materials, mainly play flavouring and cover stimulation or the unhappy smell that acidic cleaning compositions brings.But generally, under low pH value, spices easily occurs to decompose or oxidation, often make the situations such as cleaning compositions appearance within a short period of time is spoiled, variable color, affect human consumer's clean experience and cleaning compositions result of use.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of method of improving fragrance and appearance stability in cleaning compositions is provided.The method, by acidic composition, is added specific spices stablizer and is improved the problem that spices is difficult to stable preservation under acidic conditions, and the fragrance of cleaning compositions and outward appearance can be kept for a long time, greatly improves the quality of acidic cleaning compositions.
Another object of the present invention is to provide a kind of cleaning compositions that contains above-mentioned spices stablizer.This cleaning compositions except can effectively remove pottery, plastics, stainless steel and (or) urine dirt, incrustation scale, soap scum, rust stain and other dirt in other similar surfaces, it is stable that its fragrance and outward appearance can keep in a long time.
Another object of the present invention is to provide the preparation method of described cleaning compositions.
Above-mentioned purpose of the present invention is achieved by following technical solution:
A kind of method of improving fragrance and appearance stability in cleaning compositions, it is characterized in that, in the cleaning compositions of pH value≤3.0 of containing spices, the phenolic compound that interpolation has structure shown in formula I is as spices stablizer, and in described spices stablizer and cleaning detergent, the weight ratio of spices is 1:1 ~ 1:100;
（Ⅰ）
In formula I, R is hydroxyl, C
1-C
6alkoxyl group, C
1-C
6straight or branched alkyl, C
1-C
12any one in ester group; R
1for hydroxyl, C
1-C
6a kind of in straight or branched alkyl; X is 1 or 2.
Through applicant's large quantity research, find, in the formula of acidic cleaning compositions, to add the phenolic compound with formula I structure as spices stablizer, can improve well fragrance and appearance stability in cleaning compositions.
, pH≤3.0 of described cleaning compositions, described cleaning compositions is comprised of the component counting by weight percentage as follows:
(1) 0.001 ~ 15% acidic component, described acidic component is mineral acid and/or organic acid;
(2) 0.001 ~ 1% spices;
(3) 0.001 ~ 1% spices stablizer, the weight ratio of described spices stablizer and spices is 1:1 ~ 100;
(4) 0 ~ 20% additive, described additive is one or more in tensio-active agent, fungicidal preservative, suds-stabilizing agent, thickening material, hydrotropic agent, inhibiter, water-softening agent, pigment;
(5) surplus is water;
Described spices stablizer is the phenolic compound with structure shown in formula I;
（Ⅰ）
In formula I, R is hydroxyl, C
1-C
6alkoxyl group, C
1-C
6straight or branched alkyl, C
1-C
12any one in ester group; R
1for hydroxyl, C
1-C
6a kind of in straight or branched alkyl; X is 1 or 2.
As a kind of preferred version, described spices stablizer is preferably a kind of or its combination in butylated hydroxy anisole, butylated hydroxytoluene, tertiarybutylhydroquinone or Tenox PG.
The effect of acidic component is pH value≤3.0 of guaranteeing cleaning compositions, to reach the cleaning effect of expection.Acidic component can be the conventional mineral acid in this area, organic acid or its mixture.The mixture that mineral acid can be comprised of one or more mineral acids, organic acid also can be by the mixture of one or more organic acid compositions.Preferably, described mineral acid is excellent is hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid or boric acid; Described organic acid is preferably formic acid, acetic acid, oxalic acid, propanedioic acid, succinic acid, citric acid, hexanodioic acid, Sorbic Acid, toxilic acid, thionamic acid, lactic acid, hydroxy-butanedioic acid, oxyacetic acid, methylsulphonic acid.
The existence of fragrance component is in order to give cleaning compositions special fragrance, is the conventional class raw material in this area.Described spices is volatile liquid or the essential oil of plant origin, or the spices of animal-origin, and the spices of animal-origin can be Moschus, grane ambra, civet or castoreum etc., or the spices of synthetic preparation.
As a kind of preferred version, described spices is preferably molecular weight and is less than a kind of or its combination in 300 alcohols, ester class, aldehydes, ethers, ketone fragrance.
Through applicant's repeatedly trial, find to adopt the phenolic compound of formula I structure as spices stablizer, can improve well fragrance and appearance stability in cleaning compositions.Spices is generally the chemical substance that aldehyde, ketone, ester etc. contain two keys, and these chemical substances are all more active, are easy to and oxygen generation oxidizing reaction, generate new chemical substance, thereby the fragrance of spices and outward appearance are changed; Especially in the acid system of pH value≤3.0, even the spices of comparatively stable alcohol class formation is also easy to occur oxygenizement.The phenolic compound of above-mentioned formula I structure can be automatically and oxygen generation oxygenizement, thereby the oxygen in elimination system is avoided spices and oxygen generation oxygenizement, reaches and keep spices fragrance and the constant object of appearance stablity.Although those skilled in the art know vitamins C and obtain application as antioxidant in food, in the acid system of pH value≤3.0, vitamins C is destroyed by strong acid soon very much, is difficult to bring into play oxidation resistant effect.And the phenolic compound of formula I structure can keep good stability in acid system, thereby can bring into play the effect of its stabilizing perfume fragrance and outward appearance.Because the phenolic compound of formula I structure need to misciblely just can join in cleaning compositions with essence is pre-afterwards, so the weight ratio of phenolic compound and spices can not be higher than 1:1, otherwise phenolic compound is difficult to be dissolved in completely in spices, in order to bring into play the effect of its stabilizing perfume fragrance and outward appearance, the weight ratio of phenolic compound and spices can not be lower than 1:100, so in the scope that the weight ratio that its addition is spices in spices stablizer and cleaning detergent is 1:1 ~ 1:100.
The auxiliary components such as tensio-active agent, fungicidal preservative, suds-stabilizing agent, thickening material, hydrotropic agent, inhibiter, water-softening agent, pigment, can give cleaning compositions abundanter function, as described in can also add one or more in cleaning compositions and can effectively promote oil removal tensio-active agent; Add fungicidal preservative bactericidal property can be provided; Thickening material can be given cleaning compositions and have certain viscosity, makes product be easy to topple over or extrude use; Add hydrotropic agent and can promote the dissolving situation of component in composition; Inhibiter can reduce the corrodibility of composition to clean surface; Water-softening agent can reduce water hardness; Pigment can give composition abundant color appearance.These materials are all the conventional additives in this area.
The preparation method of described cleaning compositions, is pre-mixed component (2) and (3) to make premixed solution, then this premixed solution and component (1) and (4) are under agitation added in component (5) with random order, until composition outward appearance evenly.
Compared with prior art, the present invention has following beneficial effect:
The present invention is after having added described spices stablizer, the fragrance of cleaning compositions and appearance stability have been compared significant lifting with the composition of perfuming stablizer not, the experiment proved that, spices stablizer of the present invention still can keep fragrance and outward appearance substantially constant at 54 ℃ after aging surrounding.Thereby improve the quality of cleaning compositions.
Embodiment
Below in conjunction with specific embodiment, further describe the present invention.Unless stated otherwise, the reagent that the embodiment of the present invention is addressed is the conventional reagent using of the art.
Whether the fragrance of composition and outward appearance be stable is evaluated by the member of panel of experts.Evaluation method is as follows: composition is placed in airtight Glass Containers, keeps the time of surrounding at 54 ℃.Sample after aging and the freshly prepared composition of same recipe are offered to the member of panel of experts and evaluate, evaluate fragrance and the outward appearance of the sample after aging and compare and whether change with the freshly prepared sample of same recipe.The member of panel of experts judges the stability of composition fragrance according to following standard: 1, unchanged; 2, substantially unchanged; 3, change; 4, obviously change.The stability of combination outward appearance is judged according to following standard: 1, unchanged; 2, substantially unchanged; 3, change; 4, obviously change, and describe changing conditions.Wherein 1,2 be all considered as qualified.
At room temperature, by Brookfield LVDV-I viscometer, adopt 4# rotor under 100rpm, to measure the viscosity of composition, use the pH value of METTLER TOLEDO Delta 320 type pH meter test composition.
embodiment 1 ~ 8
Cleaning compositions and the character thereof of embodiment 1 ~ 8 preparation are as shown in table 1:
Table 1
comparative example 1 ~ 8
Adopt the formula identical with embodiment 1 ~ 8, difference is not add spices stablizer of the present invention, prepares cleaning compositions, and its formula and character are as shown in table 2:
Table 2
By the comparison of embodiment and comparative example, can find out, added the fragrance of cleaning compositions of spices stablizer of the present invention and the stability of outward appearance obviously to strengthen, basic original fragrance and the outward appearance of keeping after surrounding at 54 ℃.
comparative example 9 ~ 16
Adopt the formula identical with embodiment 1 ~ 8, difference is not add spices stablizer of the present invention, and uses the antioxidant of other type, and its formula and character are as shown in table 3:
Table 3
By the comparison of embodiment and comparative example, can find out, after adding other common antioxidant as spices stablizer, the cleaning compositions fragrance after surrounding and outward appearance at 54 ℃ all obviously change, and other type antioxidant cannot reach the keep clean function of composition fragrance and appearance stablity of spices stablizer of the present invention.
Claims (8)
1. a method of improving fragrance and appearance stability in cleaning compositions, it is characterized in that, in the cleaning compositions of pH value≤3.0 of containing spices, the phenolic compound that interpolation has structure shown in formula I is as spices stablizer, and in described spices stablizer and cleaning detergent, the weight ratio of spices is 1:1 ~ 100;
（Ⅰ）
In formula I, R is hydroxyl, C
1-C
6alkoxyl group, C
1-C
6straight or branched alkyl, C
1-C
12any one in ester group; R
1for hydroxyl, C
1-C
6a kind of in straight or branched alkyl; X is 1 or 2;
Described R
1be positioned at the ortho position of hydroxyl.
2. a cleaning compositions, is characterized in that, pH≤3.0 of described cleaning compositions, and described cleaning compositions is comprised of the component counting by weight percentage as follows:
(1) 0.001 ~ 15% acidic component, described acidic component is mineral acid and/or organic acid;
(2) 0.001 ~ 1% spices;
(3) 0.001 ~ 1% spices stablizer, the weight ratio of described spices stablizer and spices is 1:1 ~ 100;
(4) 0 ~ 20% additive, described additive is one or more in tensio-active agent, fungicidal preservative, suds-stabilizing agent, thickening material, hydrotropic agent, inhibiter, water-softening agent, pigment;
(5) surplus is water;
Described spices stablizer is the phenolic compound with structure shown in formula I;
（Ⅰ）
In formula I, R is hydroxyl, C
1-C
6alkoxyl group, C
1-C
6straight or branched alkyl, C
1-C
12any one in ester group; R
1for hydroxyl, C
1-C
6a kind of in straight or branched alkyl; X is 1 or 2;
Described R
1be positioned at the ortho position of hydroxyl.
3. cleaning compositions as claimed in claim 2, is characterized in that, described spices stablizer is a kind of or its combination in butylated hydroxy anisole, butylated hydroxytoluene, tertiarybutylhydroquinone or Tenox PG.
4. cleaning compositions as claimed in claim 2, is characterized in that, described mineral acid is hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid or boric acid.
5. cleaning compositions as claimed in claim 2, it is characterized in that, described organic acid is formic acid, acetic acid, oxalic acid, propanedioic acid, succinic acid, citric acid, hexanodioic acid, Sorbic Acid, toxilic acid, thionamic acid, lactic acid, hydroxy-butanedioic acid, oxyacetic acid, methylsulphonic acid.
6. cleaning compositions as claimed in claim 2, is characterized in that the volatile liquid that described spices is plant origin or essential oil, or the spices of animal-origin, or the spices of synthetic.
7. cleaning compositions as claimed in claim 2, is characterized in that, described spices is that molecular weight is less than any one or its combination in 300 alcohols, ester class, aldehydes, ethers, ketone fragrance.
8. the preparation method of cleaning compositions described in any one claim in claim 2 ~ 7, it is characterized in that, comprise the steps: component (2) and (3) to be pre-mixed and to make premixed solution, again this premixed solution and component (1) and (4) are under agitation added in component (5) with random order, until composition outward appearance evenly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210182408.6A CN102719324B (en) | 2012-06-05 | 2012-06-05 | Method for improving aroma and appearance stability in cleaning composition and cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210182408.6A CN102719324B (en) | 2012-06-05 | 2012-06-05 | Method for improving aroma and appearance stability in cleaning composition and cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102719324A CN102719324A (en) | 2012-10-10 |
| CN102719324B true CN102719324B (en) | 2014-01-29 |
Family
ID=46945201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210182408.6A Active CN102719324B (en) | 2012-06-05 | 2012-06-05 | Method for improving aroma and appearance stability in cleaning composition and cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102719324B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110669593A (en) * | 2019-10-21 | 2020-01-10 | 北京石油化工学院 | Kitchen sewer pipeline dredging cleaning agent and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4138591A (en) * | 1976-11-06 | 1979-02-06 | Basf Aktiengesellschaft | Manufacture of alkylphenols |
| US4202199A (en) * | 1976-11-06 | 1980-05-13 | Basf Aktiengesellschaft | Manufacture of alkylphenol compounds |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA200605245B (en) * | 2003-12-11 | 2007-10-31 | Unilever Plc | Liquid detergent composition |
-
2012
- 2012-06-05 CN CN201210182408.6A patent/CN102719324B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4138591A (en) * | 1976-11-06 | 1979-02-06 | Basf Aktiengesellschaft | Manufacture of alkylphenols |
| US4202199A (en) * | 1976-11-06 | 1980-05-13 | Basf Aktiengesellschaft | Manufacture of alkylphenol compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102719324A (en) | 2012-10-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1594946B1 (en) | Hard surface cleaning compositions | |
| US7256167B2 (en) | Hard surface cleaner comprising suspended particles and oxidizing agent | |
| US20040186037A1 (en) | Organic compositions | |
| CN109666545B (en) | Efficient toilet cleaning foam aerosol and preparation method thereof | |
| US7288512B2 (en) | Hard surface cleaning compositions comprising suspended alginate inclusions | |
| WO2006131689A1 (en) | Improvements in or related to organic compositions | |
| AU2011200073A1 (en) | Hard surface cleaning composition | |
| CN103215144A (en) | Acidic lasting wall built-up type toilet bowl cleaner and preparation method thereof | |
| CN110042012A (en) | A kind of Bactericidal cleaner, preparation method and its application with color instruction function | |
| EP3502226A1 (en) | Gel composition | |
| CN102719324B (en) | Method for improving aroma and appearance stability in cleaning composition and cleaning composition | |
| JP5697514B2 (en) | Liquid fragrance cleaning composition for flush toilet | |
| CN110724607B (en) | Shower room cleaning cream and preparation method thereof | |
| CA2516731A1 (en) | Hard surface cleaning compositions | |
| CN112029593B (en) | Low-viscosity foam type toilet cleaning liquid composition with foam spraying effect and preparation method thereof | |
| JP2008156389A (en) | Treating agent for bio-film | |
| CN103087833B (en) | Furniture detergent | |
| JP2006143620A (en) | Antimicrobial agent | |
| WO2020085206A1 (en) | Gel detergent composition | |
| US7605114B2 (en) | Multi-purpose cleaner comprising blue iron powder | |
| JP5659087B2 (en) | Liquid detergent composition for hard surfaces | |
| JP2014132062A (en) | Liquid detergent composition for hard surface | |
| JP2005075873A (en) | Treating agent for biofilm | |
| TWI788435B (en) | Internal olefin sulfonate composition, and preservation method of internal olefin sulfonate | |
| US20140107011A1 (en) | Compositions and methods for cleaning surfaces |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |