CN103215144B - Acidic lasting wall built-up type toilet bowl cleaner and preparation method thereof - Google Patents
Acidic lasting wall built-up type toilet bowl cleaner and preparation method thereof Download PDFInfo
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- CN103215144B CN103215144B CN201310094690.7A CN201310094690A CN103215144B CN 103215144 B CN103215144 B CN 103215144B CN 201310094690 A CN201310094690 A CN 201310094690A CN 103215144 B CN103215144 B CN 103215144B
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- acid
- polyoxyethylene ether
- fatty alcohol
- water
- colorant
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- 230000002045 lasting effect Effects 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 title abstract description 10
- 230000002378 acidificating effect Effects 0.000 title abstract description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 61
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 61
- 239000002253 acid Substances 0.000 claims abstract description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 29
- 238000003756 stirring Methods 0.000 claims abstract description 26
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 30
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 29
- 239000003086 colorant Substances 0.000 claims description 28
- 239000002994 raw material Substances 0.000 claims description 16
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 12
- VPTUPAVOBUEXMZ-UHFFFAOYSA-N (1-hydroxy-2-phosphonoethyl)phosphonic acid Chemical compound OP(=O)(O)C(O)CP(O)(O)=O VPTUPAVOBUEXMZ-UHFFFAOYSA-N 0.000 claims description 10
- 150000008431 aliphatic amides Chemical class 0.000 claims description 10
- 150000002191 fatty alcohols Chemical class 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 8
- 238000001514 detection method Methods 0.000 claims description 8
- 238000012856 packing Methods 0.000 claims description 8
- 230000005070 ripening Effects 0.000 claims description 8
- 238000005070 sampling Methods 0.000 claims description 8
- 239000004310 lactic acid Substances 0.000 claims description 6
- 235000014655 lactic acid Nutrition 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 7
- 230000007797 corrosion Effects 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 6
- 230000005764 inhibitory process Effects 0.000 abstract description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 4
- 241000191967 Staphylococcus aureus Species 0.000 abstract description 3
- 150000001412 amines Chemical class 0.000 abstract description 3
- 238000005202 decontamination Methods 0.000 abstract description 3
- 230000003588 decontaminative effect Effects 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- 230000009974 thixotropic effect Effects 0.000 abstract description 2
- 241000588724 Escherichia coli Species 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 238000013019 agitation Methods 0.000 abstract 1
- 239000002781 deodorant agent Substances 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000011265 semifinished product Substances 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- 229920002125 Sokalan® Polymers 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 229910000147 aluminium phosphate Chemical class 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 210000002700 urine Anatomy 0.000 description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 235000019253 formic acid Nutrition 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- ZNRSXPDDVNZGEN-UHFFFAOYSA-K trisodium;chloride;sulfate Chemical compound [Na+].[Na+].[Na+].[Cl-].[O-]S([O-])(=O)=O ZNRSXPDDVNZGEN-UHFFFAOYSA-K 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000000968 intestinal effect Effects 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- YFDKVXNMRLLVSL-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O YFDKVXNMRLLVSL-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical class N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 1
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229960001708 magnesium carbonate Drugs 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to an acidic lasting wall built-up type toilet bowl cleaner and a preparation method thereof. Ordinary toilet bowl cleaners are large in use amount, poor in decontamination effect, and poor in corrosion inhibition, and may cause corrosion to sewer lines. The preparation method includes adding water, pigment and an acrylic polymer, stirring and adding acid to completely dissolve, adding fatty amine polyethenoxy ether under agitation until dissolving, continuously stirring and adding fatty alcohol-polyoxyethylene ether, inorganic salts, 1-Hydroxyethylidene-1,1-diphosphonic and essence, and ageing semi-finished products to give the desired products. The cleaner ensures good thixotropic properties on a perpendicular surface, also has good corrosion inhibition and anti-dirt redeposition properties, has a strong inhibitory effect on escherichia coli and staphylococcus aureus, has fragrant and deodorant performances, and achieves the application purpose of multi-effect in one.
Description
Technical field
The present invention relates to a kind of liquid ceanser of ceramic sanitary appliance, be specifically related to a kind of acid lasting wall built-up type water closet pan clean-out system and preparation method thereof.
Background technology
Dirt on urinal and toilet mainly contains just dirt, hard scale, iron rust and dust deposit thing etc. of stool and urine, stool just dirty and dust deposit thing is easily washed away by water, urine just dirt, hard scale and iron rust is difficult to wash away, long tending at the yellow dirt of closet surface formation one deck of time one.Urine just dirt mainly for a long time contact with air and forms precipitation with organism by the inorganic salt in urine, is closely deposited on closet surperficial formation, and main component is calcium, the magnesium salts of uric acid, carbonic acid and phosphoric acid.When hard scale and iron rust mainly flow through closet surface for a long time by tap water, calcium, magnesium and the ferrous plasma in water and closet surface and air effect form, and its main component is calcium carbonate, magnesiumcarbonate, ferric oxide and silicate etc.As can be seen here, on closet, common dirt is all some indissoluble salts or oxide compound, and dissolving and removing them needs certain acidity, and therefore common lavatory clean-out system contains certain acidic component more.
Common water closet pan clean-out system, although also can remove the dirt on toilet ceramic sanitary appliance, but consumption is large, poor removal effect, and in use quite a few acidic components does not play a role and is flushed away, and not only causes waste, and because corrosion inhibition is poor, can cause the corrosion to sewer line, simultaneously due to function singleness, cause and have to use multiple product to reach the effect of sanitation and hygiene.Therefore, people expect that developing one can meet environmental requirement, have again the Multifunctional toilet bowl clean-out system of better cost performance simultaneously, can effectively decompose the spots such as urine dirt and iron rust, do not damage again toilet and porcelain tool surface; There is good wall built-up performance, prevent decontamination ingredients from lossing, the abundant decontamination of dauer effect; Effectively prevent from polluting, permanent maintenance, is not dirt and fouling by ceramic surface again, effectively reduces and cleans the frequency; There is good bacteria resistance function, effectively suppress intestinal bacteria and streptococcus aureus, protection household health; After using, there is lasting aroma retaining effect simultaneously, ensure the clean and health of toilet, but not yet have up to now such liquid ceanser with excellent cleaning performance and nursing function openly to report.
Summary of the invention
The object of this invention is to provide the lasting wall built-up type of acidity water closet pan clean-out system of a kind of strong detergency, good, the lasting wall built-up of rheological characteristics and preparation method thereof.
The technical solution adopted in the present invention is:
A kind of acid lasting wall built-up type water closet pan clean-out system, is characterized in that:
Component by following mass percent is made:
Aliphatic amine polyoxyethylene ether 1-10%;
Fatty alcohol-polyoxyethylene ether 0.01-1%;
Acid 1-10%;
Acrylic polymers 0.1-1%;
Inorganic salt 1-5%;
Hydroxyl ethylene-diphosphonic acid 0.1-1%;
Essence 0.1-0.5%;
Colorant 0.00001-0.01%;
Water surplus
.
Described aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5.
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10.
Described acid is selected from hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, thionamic acid, formic acid, acetic acid, citric acid, oxyacetic acid, lactic acid.
Described acrylic polymers is selected from Sokalan
?hP 70, Mirapol SURF-S500.
Described inorganic salt are selected from sodium-chlor, sodium sulfate.
Described colorant is acid lake blue.
Described water is deionized water or softening water.
A preparation method for the lasting wall built-up type of acidity water closet pan clean-out system, is characterized in that:
Realized by following steps:
Step 1: by following mass percent raw material is got the raw materials ready:
Aliphatic amine polyoxyethylene ether 1-10%;
Fatty alcohol-polyoxyethylene ether 0.01-1%;
Acid 1-10%;
Acrylic polymers 0.1-1%;
Inorganic salt 1-5%;
Hydroxyl ethylene-diphosphonic acid 0.1-1%;
Essence 0.1-0.5%;
Colorant 0.00001-0.01%;
Water surplus
;
Step 2: add water, colorant and acrylic polymers in batch tank, and stir, then add acid, be stirred to completely and dissolve;
Step 3: in the situation that stirring, add aliphatic amine polyoxyethylene ether, until dissolve completely;
Step 4: in the situation that continuing to stir, add fatty alcohol-polyoxyethylene ether, inorganic salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and essence;
Step 5: work in-process carry out ripening;
Step 6: sampling Detection, finished product packing.
Described aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5;
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10;
Described acid is selected from hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, thionamic acid, formic acid, acetic acid, citric acid, oxyacetic acid, lactic acid;
Described acrylic polymers is selected from Sokalan
?hP 70, Mirapol SURF-S500;
Described inorganic salt are selected from sodium-chlor, sodium sulfate;
Described colorant is acid lake blue;
Described water is deionized water or softening water.
The present invention has the following advantages:
1, the present invention is the thick clean-out system of a kind of fatty amine Soxylat A 25-7 and acrylate copolymer, not only ensure to there is good thixotropic behavior in vertical surface, and there is good inhibition, anti-dirt deposition properties again, intestinal bacteria and streptococcus aureus are all had to stronger bacteriostatic action, there is deodorizing long lasting quality simultaneously, reached the application purpose of multiple-effect unification.
2, clean-out system of the present invention is blue transparent liquid, in formula, do not contain branched dodecylbenzene sulfonic acid sodium,, alkylphenol polyoxyethylene, nitrilotriacetic acid and salt thereof, without white dyes, meet household detergent environmental labelling product technical requirements (HJ 458-2009), there is technique simple, easy to prepare, be easy to batch production, the features such as shelf-life is long, product cost ideal, can be widely used in the cleaning of the various ceramic sanitary appliances in toilet.
Embodiment
Below in conjunction with embodiment, the present invention will be described in detail.
The preparation method of the lasting wall built-up type of a kind of acidity water closet pan clean-out system involved in the present invention, is characterized in that:
Realized by following steps:
Step 1: by following mass percent raw material is got the raw materials ready:
Aliphatic amine polyoxyethylene ether 1-10%;
Fatty alcohol-polyoxyethylene ether 0.01-1%;
Acid 1-10%;
Acrylic polymers 0.1-1%;
Inorganic salt 1-5%;
Hydroxyl ethylene-diphosphonic acid 0.1-1%;
Essence 0.1-0.5%;
Colorant 0.00001-0.01%;
Water surplus
;
Step 2: add water, colorant and acrylic polymers in batch tank, and stir, then add acid, be stirred to completely and dissolve;
Step 3: in the situation that stirring, add aliphatic amine polyoxyethylene ether, until dissolve completely;
Step 4: in the situation that continuing to stir, add fatty alcohol-polyoxyethylene ether, inorganic salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and essence;
Step 5: work in-process carry out ripening;
Step 6: sampling Detection, finished product packing.
Wherein:
Described aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5;
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10;
Described acid is selected from hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, thionamic acid, formic acid, acetic acid, citric acid, oxyacetic acid, lactic acid;
Described acrylic polymers is selected from Sokalan
?hP 70, Mirapol SURF-S500;
Described inorganic salt are selected from sodium-chlor, sodium sulfate;
Described colorant is acid lake blue;
Described water is deionized water or softening water.
Embodiment 1:
Step 1: by following mass percent raw material is got the raw materials ready:
Aliphatic amine polyoxyethylene ether 1%;
Fatty alcohol-polyoxyethylene ether 0.01%;
Acid 1%;
Acrylic polymers 0.1%;
Inorganic salt 1%;
Hydroxyl ethylene-diphosphonic acid 0.1%;
Essence 0.1%;
Colorant 0.00001%;
Water surplus
;
Step 2: add water, colorant and acrylic polymers in batch tank, and stir, then add acid, be stirred to completely and dissolve;
Step 3: in the situation that stirring, add aliphatic amine polyoxyethylene ether, until dissolve completely;
Step 4: in the situation that continuing to stir, add fatty alcohol-polyoxyethylene ether, inorganic salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and essence;
Step 5: work in-process carry out ripening;
Step 6: sampling Detection, finished product packing.
Wherein:
Described aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5;
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10;
Described acid is selected from hydrochloric acid, sulfuric acid;
Described acrylic polymers is chosen Sokalan
?hP 70;
Described inorganic salt are chosen sodium-chlor;
Described colorant is acid lake blue;
Described water is deionized water.
Embodiment 2:
Step 1: by following mass percent raw material is got the raw materials ready:
Aliphatic amine polyoxyethylene ether 4%;
Fatty alcohol-polyoxyethylene ether 0.4%;
Acid 4%;
Acrylic polymers 0.4%;
Inorganic salt 2%;
Hydroxyl ethylene-diphosphonic acid 0.4%;
Essence 0.2%;
Colorant 0.004%;
Water surplus
;
Step 2: add water, colorant and acrylic polymers in batch tank, and stir, then add acid, be stirred to completely and dissolve;
Step 3: in the situation that stirring, add aliphatic amine polyoxyethylene ether, until dissolve completely;
Step 4: in the situation that continuing to stir, add fatty alcohol-polyoxyethylene ether, inorganic salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and essence;
Step 5: work in-process carry out ripening;
Step 6: sampling Detection, finished product packing.
Wherein:
Described aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5;
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10;
Described acid is selected from nitric acid, phosphoric acid;
Described acrylic polymers is chosen Sokalan
?hP 70;
Described inorganic salt are chosen sodium-chlor;
Described colorant is acid lake blue;
Described water is deionized water.
Embodiment 3:
Step 1: by following mass percent raw material is got the raw materials ready:
Aliphatic amine polyoxyethylene ether 6%;
Fatty alcohol-polyoxyethylene ether 0.6%;
Acid 6%;
Acrylic polymers 0.6%;
Inorganic salt 3%;
Hydroxyl ethylene-diphosphonic acid 0.6%;
Essence 0.3%;
Colorant 0.006%;
Water surplus
;
Step 2: add water, colorant and acrylic polymers in batch tank, and stir, then add acid, be stirred to completely and dissolve;
Step 3: in the situation that stirring, add aliphatic amine polyoxyethylene ether, until dissolve completely;
Step 4: in the situation that continuing to stir, add fatty alcohol-polyoxyethylene ether, inorganic salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and essence;
Step 5: work in-process carry out ripening;
Step 6: sampling Detection, finished product packing.
Wherein:
Described aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5;
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10;
Described acid is selected from thionamic acid, formic acid;
Described acrylic polymers is chosen Sokalan
?hP 70;
Described inorganic salt are chosen sodium-chlor;
Described colorant is acid lake blue;
Described water is deionized water.
Embodiment 4:
Step 1: by following mass percent raw material is got the raw materials ready:
Aliphatic amine polyoxyethylene ether 8%;
Fatty alcohol-polyoxyethylene ether 0.8%;
Acid 8%;
Acrylic polymers 0.8%;
Inorganic salt 4%;
Hydroxyl ethylene-diphosphonic acid 0.8%;
Essence 0.4%;
Colorant 0.008%;
Water surplus
;
Step 2: add water, colorant and acrylic polymers in batch tank, and stir, then add acid, be stirred to completely and dissolve;
Step 3: in the situation that stirring, add aliphatic amine polyoxyethylene ether, until dissolve completely;
Step 4: in the situation that continuing to stir, add fatty alcohol-polyoxyethylene ether, inorganic salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and essence;
Step 5: work in-process carry out ripening;
Step 6: sampling Detection, finished product packing.
Wherein:
Described aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5;
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10;
Described acid is selected from acetic acid, citric acid;
Described acrylic polymers is chosen Mirapol SURF-S500;
Described inorganic salt are chosen sodium sulfate;
Described colorant is acid lake blue;
Described water is softening water.
Embodiment 5:
Step 1: by following mass percent raw material is got the raw materials ready:
Aliphatic amine polyoxyethylene ether 10%;
Fatty alcohol-polyoxyethylene ether 1%;
Acid 10%;
Acrylic polymers 1%;
Inorganic salt 5%;
Hydroxyl ethylene-diphosphonic acid 1%;
Essence 0.5%;
Colorant 0.01%;
Water surplus
;
Step 2: add water, colorant and acrylic polymers in batch tank, and stir, then add acid, be stirred to completely and dissolve;
Step 3: in the situation that stirring, add aliphatic amine polyoxyethylene ether, until dissolve completely;
Step 4: in the situation that continuing to stir, add fatty alcohol-polyoxyethylene ether, inorganic salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and essence;
Step 5: work in-process carry out ripening;
Step 6: sampling Detection, finished product packing.
Wherein:
Described aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5;
Described fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10;
Described acid is selected from oxyacetic acid, lactic acid;
Described acrylic polymers is chosen Mirapol SURF-S500;
Described inorganic salt are chosen sodium sulfate;
Described colorant is acid lake blue;
Described water is softening water.
In the present invention, aliphatic amine polyoxyethylene ether is a kind of organic amine tensio-active agent, mainly as the thickening material of acid system, prevents acid gas effusion.It is water insoluble, is soluble in the organic solvent such as alcohol, ether.To all having obvious thickening effectiveness containing the system of organic acid, mineral acid; and there is good corrosion inhibition; there is to powerful provide protection pottery, metallic surface; and have infiltration, emulsification and cleanup action concurrently; can reduce the generation of acid mist, thereby reduce the pungency to human body sense of smell and skin, it can make acids cleaning products extend in the surperficial residence time of dirt simultaneously; thereby raising cleaning performance, and can improve the surface smoothness after cleaning.The present invention carries out compatibility by adopting with fatty alcohol-polyoxyethylene ether, and adopts the operational path of science, has effectively solved the application problem of aliphatic amine polyoxyethylene ether at acid system.
Fatty alcohol-polyoxyethylene ether: there is good clearing power, good to the detersive power of oily dirt.The electrolytical ability of stability in hard water and resisting high-concentration is all more intense.The advantage of polyoxyethylene nonionogenic tenside maximum is the adjustability of hydrophobic group and hydrophilic group part.By selecting different EO numbers to adapt to various kinds of substrates, reach best clearing power, there is in addition good cold washing.In the present invention, pass through to adopt straight or branched, carbon number is C12---C14, EO mean number is the rheological characteristics that the nonionogenic tenside of 5---10 is adjusted formula, the especially flowability problem under cold condition, thus ensure that product has good application performance.
The wall built-up Performance Ratio of the acid lasting wall built-up type water closet pan clean-out system of the present invention and commercially available prod is:
1, condition:
1) wall brick of 25*33cm, surface should keep smooth (liquid linearly flows);
2) consumption of every kind of test sample is 0.4 ± 0.01 gram;
3) timing register stopwatch;
4) 20 DEG C of temperature;
2, method:
One end by the sample drop of specified amount at wall brick, then near vertical is placed on desktop, and timing immediately, until be left to bottom, writing time;
3, result:
4, conclusion:
Water closet pan clean-out system of the present invention has outstanding wall built-up performance, has been far superior to commercially available product, can ensure, under the condition of little consumption, to reach the de-sludging effect identical with commercially available product.
It is cited that content of the present invention is not limited to embodiment, and the conversion of any equivalence that those of ordinary skill in the art take technical solution of the present invention by reading specification sheets of the present invention, is claim of the present invention and contains.
Claims (2)
1. the lasting wall built-up type of an acidity water closet pan clean-out system, is characterized in that:
Component by following mass percent is made:
Aliphatic amine polyoxyethylene ether 10%;
Fatty alcohol-polyoxyethylene ether 1%;
Acid 10%;
Acrylic polymers 1%;
Inorganic salt 5%;
Hydroxyl ethylene-diphosphonic acid 1%;
Essence 0.5%;
Colorant 0.01%;
Water surplus;
Wherein:
Aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5;
Fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10;
Acid is selected from oxyacetic acid, lactic acid;
Acrylic polymers is chosen Mirapol SURF-S500;
Inorganic salt are chosen sodium sulfate;
Colorant is acid lake blue;
Water is softening water.
2. a preparation method for the lasting wall built-up type of acidity water closet pan clean-out system, is characterized in that:
Realized by following steps:
Step 1: by following mass percent raw material is got the raw materials ready:
Aliphatic amine polyoxyethylene ether 10%;
Fatty alcohol-polyoxyethylene ether 1%;
Acid 10%;
Acrylic polymers 1%;
Inorganic salt 5%;
Hydroxyl ethylene-diphosphonic acid 1%;
Essence 0.5%;
Colorant 0.01%;
Water surplus;
Step 2: add water, colorant and acrylic polymers in batch tank, and stir, then add acid, be stirred to completely and dissolve;
Step 3: in the situation that stirring, add aliphatic amine polyoxyethylene ether, until dissolve completely;
Step 4: in the situation that continuing to stir, add fatty alcohol-polyoxyethylene ether, inorganic salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and essence;
Step 5: work in-process carry out ripening;
Step 6: sampling Detection, finished product packing;
Wherein:
Aliphatic amine polyoxyethylene ether is the ethoxylate of straight or branched aliphatic amide, and the average adduct number of EO is 1-5;
Fatty alcohol-polyoxyethylene ether is the ethoxylate of straight or branched fatty alcohol, and the average adduct number of EO is 6-10;
Acid is selected from oxyacetic acid, lactic acid;
Acrylic polymers is chosen Mirapol SURF-S500;
Inorganic salt are chosen sodium sulfate;
Colorant is acid lake blue;
Water is softening water.
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| CN104017662A (en) * | 2014-06-03 | 2014-09-03 | 北京洛娃日化有限公司 | Deodorant-containing acidic toilet cleaning agent |
| CN105861171B (en) * | 2016-05-08 | 2018-10-23 | 浙江艾卡医学科技有限公司 | A kind of strength toilet cleaner of degerming smelly eliminating |
| CN106479702A (en) * | 2016-09-22 | 2017-03-08 | 长兴净安环保科技有限公司 | A kind of toilet cleaner and preparation method thereof |
| CN106479781A (en) * | 2016-09-22 | 2017-03-08 | 长兴净安环保科技有限公司 | A kind of efficient sterilizing decontamination toilet cleaner and preparation method thereof |
| WO2018058413A1 (en) * | 2016-09-29 | 2018-04-05 | 张振宾 | Toilet cleaner and preparation method therefor |
| CN106566676A (en) * | 2016-10-12 | 2017-04-19 | 重庆市五洁新材料有限公司 | Powerful decontaminating and toilet cleaning detergent and preparation method thereof |
| CN109536306A (en) * | 2018-12-29 | 2019-03-29 | 河南绿澳化工科技有限公司 | A kind of liquid toilet cleaner and preparation method thereof |
| CN112029593B (en) * | 2020-07-21 | 2022-08-30 | 名臣健康用品股份有限公司 | Low-viscosity foam type toilet cleaning liquid composition with foam spraying effect and preparation method thereof |
| CN113403627A (en) * | 2021-06-10 | 2021-09-17 | 上海佳船工程监理发展有限公司 | Ship pipeline cleaning process |
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| CN102618395A (en) * | 2012-03-02 | 2012-08-01 | 北京洛娃日化有限公司 | Water-proof ceramic tile cleaning agent |
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| CN102618395A (en) * | 2012-03-02 | 2012-08-01 | 北京洛娃日化有限公司 | Water-proof ceramic tile cleaning agent |
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