CN101372647A - Thickened non-phosphate acidic detergent - Google Patents
Thickened non-phosphate acidic detergent Download PDFInfo
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- CN101372647A CN101372647A CNA2008102228820A CN200810222882A CN101372647A CN 101372647 A CN101372647 A CN 101372647A CN A2008102228820 A CNA2008102228820 A CN A2008102228820A CN 200810222882 A CN200810222882 A CN 200810222882A CN 101372647 A CN101372647 A CN 101372647A
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Abstract
The invention relates to cleaning and washing products for sanitary facilities and discloses a thickened phosphoric acid-free detergent; the main active ingredients and the parts by weight thereof are as follows: 1-3 part(s) of straight chain dodecyl benzene sulfonic acid, 8-15 parts of non-ionic surface active agent, 0.2-1 part of corrosion inhibitor and 3-10 parts of hydrochloric acid, the non-ionic surface active agent is selected from or is the combination of any agents from nonyl phenol polyoxyethylene (4) ether, nonyl phenol polyoxyethylene (10) ether, fatty alcohol polyoxyethylene (3) ether and fatty alcohol polyoxyethylene (7) ether. The detergent disclosed by the invention has excellent wall cling property, can effectively remove human excrement, urine alkali and urine scale on the surfaces of enamel lavatory facilities as well as the rust and scale, and the like, in tap water and has the functions of stain removal, cleaning, sterilization and odor removal.
Description
Technical field
The present invention relates to sanitary facility cleaning washing series products, design a kind of thickening acidic cleaning agent especially.
Background technology
How phosphorous the sanitising agent of existing market production and sales is, the auxiliary agent of aluminium etc., and phosphides such as tripoly phosphate sodium STPP are discharged into the sewage after washing and go in the rivers,lakes and seas, make the organism in water growth rapidly, cause anoxic in the water, serious environment pollution, the part countries and regions are forbidden in the washing composition phosphorous with legal means.
Commercially available acidic cleaning agent multiselect strong acid system can only effectively be removed urine alkalinuria dirt, and is relatively poor to organic dirt removal effect of human secretory, and wall built-up is relatively poor, makes sanitising agent have little time effect and just flows into water drain, utilization ratio less than 10%; Or select the more composite acid thickening materials of strong acid system for use, though reached the effect of removing urine alkalinuria dirt, also have certain wall built-up simultaneously, selected acid thickening material can only be to the system thickening, the decontamination cleaning action is not good enough to other organic dirt removal effect of human secretory.
Summary of the invention
In view of this, main purpose of the present invention is to overcome the deficiencies in the prior art, and a kind of not phosphorated is provided, and with low cost, soil removability is strong and have an acidic cleaning agent of the thickening of good wall built-up.
Sanitising agent provided by the invention, its main active component and mass fraction thereof are:
Straight chain Witco 1298 Soft Acid 1-3 part,
Nonionogenic tenside 8-15 part,
Inhibiter 0.2-1 part,
Hydrochloric acid 3-10 part.
Sanitising agent provided by the invention, its main active component and mass fraction thereof are preferably:
Straight chain Witco 1298 Soft Acid 1-2.5 part,
Nonionogenic tenside 10-15 part,
Inhibiter 0.2-1 part,
Hydrochloric acid 4-9 part,
Above-mentioned nonionogenic tenside is selected in Nonyl pheno (4) ether, Nonyl pheno (10) ether, aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether or arbitrarily several combination.Above-mentioned straight chain Witco 1298 Soft Acid content is preferably 1.5-2.5 part
Above-mentioned inhibiter is preferably thiocarbamide or vulkacit H.
Also can contain optional ingredients such as 1-5 part oxalic acid, 0.05-0.2 part food flavour.
Above-mentioned sanitising agent also contains deionized water 69-87 part.
The raw material that sanitising agent of the present invention adopts is easy to get, and easy and simple to handle, without phosphorus prescription can not cause body eutrophication, helps protecting environment, is furnished with inhibiter simultaneously, has reduced acidic substance to Corrosion of Pipeline.Both helped urinating the removing of alkalinuria dirt, to because the formed obstinate rust of pipeline water clock steeps good scavenging(action) being arranged, it is former glossy to recover sanitary equipment simultaneously.
Sanitising agent of the present invention is selected for use surfactant thickened, has both reached good wall built-up, has brought into play the advantage of tensio-active agent again, cost is saved in effects such as performance infiltration, wetting, emulsification, decontamination, only needs a small amount of, good cleaning and thickening power are just arranged, effectively water-saving and emission-reducing.Described straight chain Witco 1298 Soft Acid content is 1-3 part, and content does not have thickening power less, and how content easily causes muddiness.
Sanitising agent of the present invention can be removed the lavatory tool rapidly, and multiple common dirts such as the iron rust on sanitary equipment surface, incrustation scale, organic dirt, urine dirt, dust and dirt, soap scum have certain viscosity, and wall built-up is good.Sanitising agent stops the long time in the vertical surface that dirt is arranged, and good sterilization, cleaning function are arranged, and be 100% to intestinal bacteria and staphylococcus killing rate, and color and luster is limpid, gives the sense of cleaning, and fragrance is pleasant, can effectively remove peculiar smell.
Embodiment
1. 1 kinds of sanitising agents of embodiment, its component and mass fraction thereof are:
1 part of straight chain Witco 1298 Soft Acid,
6 parts in Nonyl pheno (10) ether,
2 parts in Nonyl pheno (4) ether,
3 parts of hydrochloric acid,
0.199 part of oxalic acid
0.5 part of vulkacit H
0.2 part of thiocarbamide,
0.1 part of food flavour,
0.001 part of pigment,
87 parts of deionized waters.
Nonyl pheno (10) ether, Nonyl pheno (4) ether are nonionogenic tenside, and vulkacit H, thiocarbamide are inhibiter.
The preparation method:
1, adds 2 parts in 1 part of 0.5 part of 0.199 part of 0.2 part of 87 parts of deionized waters, thiocarbamide, oxalic acid, vulkacit H, straight chain Witco 1298 Soft Acid, 6 parts in Nonyl pheno (10) ether, Nonyl pheno (4) ether measure successively, 3 parts of technical hydrochloric acids, 0.1 part of food flavour, 0.001 part of pigment, stirring at normal temperature is dissolved fully until material.
2, filter with 300 mesh filter screens.
2. 1 kinds of sanitising agents of embodiment, the mass fraction of its component is:
3 parts of straight chain Witco 1298 Soft Acids,
13 parts in aliphatic alcohol polyethenoxy (7) ether,
2 parts in aliphatic alcohol polyethenoxy (3) ether,
1 part of oxalic acid,
10 parts of technical hydrochloric acids,
1 part of thiocarbamide,
0.1 part of food flavour,
0.001 part of pigment,
69.899 parts of deionized waters.
Aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (3) ether are nonionogenic tenside, and thiocarbamide is an inhibiter.
The preparation method:
1, adds 13 parts in 3 parts of 1 part of 1 part of 69.899 parts of deionized waters, thiocarbamide, oxalic acid, straight chain Witco 1298 Soft Acids, 2 parts in aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether measure successively, 10 parts of technical hydrochloric acids, 0.1 part of food flavour, 0.001 part of pigment, stirring at normal temperature is dissolved fully until material.
2, filter with 300 mesh filter screens.
3. 1 kinds of sanitising agents of embodiment, the mass fraction of its component is:
The straight chain Witco 1298 Soft Acid: 2.5 parts,
10 parts in Nonyl pheno (10) ether,
5 parts of oxalic acid,
4 parts of hydrochloric acid,
0.5 part of vulkacit H,
0.1 part of food flavour,
0.001 part of pigment,
77.899 parts of deionized waters.
Nonyl pheno (10) ether is nonionogenic tenside, and vulkacit H is an inhibiter.
The preparation method:
1, adds 77.899 parts of deionized waters, 0.5 part of vulkacit H (urotropine), 5 parts of oxalic acid, 2.5 parts of straight chain Witco 1298 Soft Acids, 10 parts in Nonyl pheno (10) ether, 4 parts of technical hydrochloric acids, 0.1 part of food flavour, 0.001 part of the pigment that measures successively, stirring at normal temperature is dissolved fully until material.
2, filter with 300 mesh filter screens.
The result of use experiment (is example with embodiment 1,2,3) of embodiment 4. sanitising agents of the present invention
1. wall built-up relatively: with the smooth white ceramic tiles of identical 20cm * 20cm, from the like product and the sanitising agent of the present invention contrast of the commercially available different manufacturers of top dropping same amount (1g), the time of 20cm distance under the calculating vertical current.The result is as shown in table 1.
Table 1. sanitising agent of the present invention and commercial like product wall built-up time ratio are
| Product category | Embodiment 1 | Embodiment 2 | Embodiment 3 | Product 1 | Product 2 | Product 3 | Product 4 | Product 5 | Product 6 |
| Time (second) | 59 | 51 | 57 | 23 | 15 | 31 | 10 | 36 | 41 |
As seen, the wall built-up effect of sanitising agent of the present invention is better than the commercial like product.
2. soil release characteristics relatively
Get the sanitising agent of the present invention (is example with embodiment 1,2,3) of same amount 5g and the like product of commercially available different manufacturers, the smooth sanitary ware of identical 20cm * 20cm are cleaned, contrast the removal effect of organic dirt and urine dirt.
Table 2. sanitising agent of the present invention and commercial like product clean effect are relatively
This evaluation method adopts the sense organ contrast, being divided into is five ranks, is followed successively by from getting well to differing from: fine〉better〉general relatively poor very poor, recruit 10 people and assess, think that the ratio that qualified assessment number accounts for the overall evaluation number is a percent of pass, percent of pass 〉=90% is " fine "; 90%〉percent of pass 〉=70% is " better "; 70%〉percent of pass 〉=60% is " generally "; 60%〉percent of pass〉20% be " relatively poor "; Percent of pass≤20% is " very poor ".
Therefore, as can be seen, the net effect of this product is better than the commercial like product.
3. bactericidal properties detects
Sanitising agent of the present invention (is example with embodiment 1,2,3) detects (detecting according to QB/T 2738-2005) through Pu Ni test center, and intestinal bacteria and streptococcus aureus killing rate are all reached 100%.
Claims (6)
1. sanitising agent, its main active component and mass fraction thereof are:
Straight chain Witco 1298 Soft Acid 1-3 part,
Nonionogenic tenside 8-15 part,
Inhibiter 0.2-1 part,
Hydrochloric acid 3-10 part,
Described nonionogenic tenside is selected from Nonyl pheno (4) ether, Nonyl pheno (10) ether, aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether or several combination arbitrarily.
2. according to the described sanitising agent of claim 1, its main active component and mass fraction thereof are preferably:
Straight chain Witco 1298 Soft Acid 1-2.5 part,
Nonionogenic tenside 10-15 part,
Inhibiter 0.2-1 part,
Hydrochloric acid 4-9 part.
3. sanitising agent according to claim 1 and 2 is characterized in that, described inhibiter is thiocarbamide or vulkacit H.
4. sanitising agent according to claim 1 and 2 is characterized in that, also can add 1-5 part oxalic acid.
5. sanitising agent according to claim 1 and 2 is characterized in that, also can add 0.05-0.2 part food flavour.
6. sanitising agent according to claim 1 and 2 is characterized in that, also has deionized water 69-87 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102228820A CN101372647B (en) | 2008-09-24 | 2008-09-24 | Thickened non-phosphate acidic detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102228820A CN101372647B (en) | 2008-09-24 | 2008-09-24 | Thickened non-phosphate acidic detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101372647A true CN101372647A (en) | 2009-02-25 |
| CN101372647B CN101372647B (en) | 2011-03-16 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008102228820A Active CN101372647B (en) | 2008-09-24 | 2008-09-24 | Thickened non-phosphate acidic detergent |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051627A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Metal cleaner |
| CN103060116A (en) * | 2013-01-21 | 2013-04-24 | 上海艳紫化工科技有限公司 | Domestic acid cleaning agent |
| CN103789101A (en) * | 2014-01-27 | 2014-05-14 | 何丽萍 | Acid harsh detergent |
| CN107904040A (en) * | 2017-12-07 | 2018-04-13 | 巨浪(苏州)热水器有限公司 | A kind of preparation method of water heater liner detergent |
| CN107987985A (en) * | 2017-12-07 | 2018-05-04 | 巨浪(苏州)热水器有限公司 | A kind of water heater liner detergent |
| CN108019947A (en) * | 2017-12-07 | 2018-05-11 | 巨浪(苏州)热水器有限公司 | A kind of method of incrustation scale in cleaning water heater liner |
| CN108251223A (en) * | 2018-03-09 | 2018-07-06 | 王连队 | It is a kind of to contain enzymatic detergent and preparation method thereof suitable for low temperature washing |
-
2008
- 2008-09-24 CN CN2008102228820A patent/CN101372647B/en active Active
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051627A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Metal cleaner |
| CN103060116A (en) * | 2013-01-21 | 2013-04-24 | 上海艳紫化工科技有限公司 | Domestic acid cleaning agent |
| CN103060116B (en) * | 2013-01-21 | 2014-08-06 | 上海艳紫化工科技有限公司 | Domestic acid cleaning agent |
| CN103789101A (en) * | 2014-01-27 | 2014-05-14 | 何丽萍 | Acid harsh detergent |
| CN107904040A (en) * | 2017-12-07 | 2018-04-13 | 巨浪(苏州)热水器有限公司 | A kind of preparation method of water heater liner detergent |
| CN107987985A (en) * | 2017-12-07 | 2018-05-04 | 巨浪(苏州)热水器有限公司 | A kind of water heater liner detergent |
| CN108019947A (en) * | 2017-12-07 | 2018-05-11 | 巨浪(苏州)热水器有限公司 | A kind of method of incrustation scale in cleaning water heater liner |
| CN108251223A (en) * | 2018-03-09 | 2018-07-06 | 王连队 | It is a kind of to contain enzymatic detergent and preparation method thereof suitable for low temperature washing |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101372647B (en) | 2011-03-16 |
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Assignee: Lip river baby science and technology Industry Group Co.,Ltd Assignor: Beijing Luowa Daily Chemical Co., Ltd. Contract record no.: 2011990000620 Denomination of invention: Thickened non-phosphate acidic detergent Granted publication date: 20110316 License type: Exclusive License Open date: 20090225 Record date: 20110713 |