CN103060116A - Domestic acid cleaning agent - Google Patents
Domestic acid cleaning agent Download PDFInfo
- Publication number
- CN103060116A CN103060116A CN2013100205223A CN201310020522A CN103060116A CN 103060116 A CN103060116 A CN 103060116A CN 2013100205223 A CN2013100205223 A CN 2013100205223A CN 201310020522 A CN201310020522 A CN 201310020522A CN 103060116 A CN103060116 A CN 103060116A
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- CN
- China
- Prior art keywords
- parts
- acid
- water
- cleaning agent
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 15
- 239000002253 acid Substances 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 6
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 16
- 230000002378 acidificating effect Effects 0.000 claims description 12
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 claims description 11
- QSWLZYUOSZOHCL-UHFFFAOYSA-N [Na].[Na].[Na].C(=O)(O)C(N(C)C(=O)O)(C)C(=O)O Chemical compound [Na].[Na].[Na].C(=O)(O)C(N(C)C(=O)O)(C)C(=O)O QSWLZYUOSZOHCL-UHFFFAOYSA-N 0.000 claims description 10
- OOIOHEBTXPTBBE-UHFFFAOYSA-N [Na].[Fe] Chemical compound [Na].[Fe] OOIOHEBTXPTBBE-UHFFFAOYSA-N 0.000 claims description 8
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 8
- 238000005406 washing Methods 0.000 abstract description 10
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 abstract description 3
- 239000011734 sodium Substances 0.000 abstract description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- CAQWNKXTMBFBGI-UHFFFAOYSA-N C.[Na] Chemical compound C.[Na] CAQWNKXTMBFBGI-UHFFFAOYSA-N 0.000 abstract 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 abstract 1
- 235000004279 alanine Nutrition 0.000 abstract 1
- 229940098779 methanesulfonic acid Drugs 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 229940104261 taurate Drugs 0.000 abstract 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 abstract 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000005303 weighing Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- -1 ethoxylated dodecyl alcohols Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000000271 synthetic detergent Substances 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 241000287828 Gallus gallus Species 0.000 description 1
- 241000190070 Sarracenia purpurea Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a domestic acid cleaning agent which is prepared from the following raw materials in parts by weight: 80 parts of water, 8-12 parts of methanesulfonic acid, 3-5 parts of laurinol polyoxyethylene ether, 2-4 parts of methyl sodium cocoyl taurate, 1-3 parts of glycolic acid, 0.1-0.3 part of divinyl penteticacid-sodium complex and 0.1-0.3 parts of dicarboxylic methyl alanine trisodium. The domestic acid cleaning agent has good derusting and descaling functions and is applicable to washing of water jugs, thermos bottles, water heaters, dish washers, water cups and hot water cups.
Description
Technical field:
The present invention relates to a kind of hard surface cleaner, particularly a kind of family expenses acidic cleaning agent.
Background technology:
The human washing composition that uses the earliest is soap.Along with succeeding in developing of organic synthesis tensio-active agent, synthetic detergent has progressively entered people's life.A large amount of productions of 20 world's tetrapropylenes fifties have promoted synthetic detergent at global high speed development.
As one of principal item of synthetic detergent, liquid washing agent appeared at for the 20 actual forties, to the nineties in 20th century, because liquid washing agent has had new variation on form, function, structure, became the important kind that is only second to powdery in the washing composition.
Compare with solid detergent, need not dissolving before liquid washing agent uses, have the advantages such as easy to use, that dissolving is rapid, the cold washing performance is good.
Liquid washing agent generally is divided into fabric washing composition, hard surface cleaner and Personal hygiene sanitising agent.Hard surface cleaner is a large class washing composition, comprises dish washing detergent, daily hard surface cleaner, metallic surface sanitising agent and vehicles sanitising agent.
Summary of the invention:
For the prior art above shortcomings, technical problem to be solved by this invention provides a kind of family expenses acidic cleaning agent.
Technical problem of the present invention is achieved by following technical proposals:
A kind of family expenses acidic cleaning agent; raw material by following weight part forms: 80 parts in water; methylsulphonic acid 8-12 part; ethoxylated dodecyl alcohol 3-5 part; sodium methyl cocoyl taurate 2-4 part; oxyacetic acid 1-3 part, diethylene triamine pentacetic acid (DTPA) iron-sodium complex 0.1-0.3 part, dicarboxyl methylalanine trisodium 0.1-0.3 part.
Methylsulphonic acid, ethoxylated dodecyl alcohol, sodium methyl cocoyl taurate, oxyacetic acid, diethylene triamine pentacetic acid (DTPA) iron-sodium complex and dicarboxyl methylalanine trisodium are added to the water; be heated to 40-60 ℃; mix, can make this family expenses acidic cleaning agent.
Family expenses acidic cleaning agent of the present invention has good rust removing and contaminant releasing function, is applicable to the cleaning of kettle, thermos flask, water-heater, dishwasher and water tumbler, hot water cup.
Embodiment:
Following embodiment further specifies of the present invention, rather than limits the scope of the invention.In the present invention, if no special instructions, each raw material is all take working substance content as 100%.
In following examples and the Comparative Examples, the raw material introduction:
| Material name | CAS number |
| Methylsulphonic acid | 75-75-2 |
| Ethoxylated dodecyl alcohol | 9002-92-0 |
| Sodium methyl cocoyl taurate | 12765-39-8 |
| Oxyacetic acid | 79-14-1 |
| Diethylene triamine pentacetic acid (DTPA) iron-sodium complex | 12389-75-2 |
| Dicarboxyl methylalanine trisodium | 164462-16-2 |
Embodiment 1
Take by weighing: 80 kilograms in water, 10 kilograms of methylsulphonic acids, 4 kilograms of ethoxylated dodecyl alcohols, 3 kilograms of sodium methyl cocoyl taurate, 2 kilograms of oxyacetic acids, 0.2 kilogram of diethylene triamine pentacetic acid (DTPA) iron-sodium complex, 0.2 kilogram of dicarboxyl methylalanine trisodium.
Methylsulphonic acid, ethoxylated dodecyl alcohol, sodium methyl cocoyl taurate, oxyacetic acid, diethylene triamine pentacetic acid (DTPA) iron-sodium complex and dicarboxyl methylalanine trisodium are added to the water; be heated to 50 ℃; mix, can make this family expenses acidic cleaning agent.
Comparative Examples 1
Take by weighing: 80 kilograms in water, 10 kilograms of methylsulphonic acids, 4 kilograms of ethoxylated dodecyl alcohols, 3 kilograms of sodium methyl cocoyl taurate, 2 kilograms of oxyacetic acids, 0.4 kilogram in EDTA four sodium.
Methylsulphonic acid, ethoxylated dodecyl alcohol, sodium methyl cocoyl taurate, oxyacetic acid and EDTA four sodium are added to the water, are heated to 50 ℃, mix, can make this family expenses acidic cleaning agent.
Comparative Examples 2
Take by weighing: 80 kilograms in water, 10 kilograms of methylsulphonic acids, 4 kilograms of ethoxylated dodecyl alcohols, 3 kilograms of sodium methyl cocoyl taurate, 2 kilograms of oxyacetic acids, 0.4 kilogram of dicarboxyl methylalanine trisodium.
Methylsulphonic acid, ethoxylated dodecyl alcohol, sodium methyl cocoyl taurate, oxyacetic acid and dicarboxyl methylalanine trisodium are added to the water, are heated to 50 ℃, mix, can make this family expenses acidic cleaning agent.
Test case
15cm * 15cm stainless steel metal plate, check weighing W1, apply the dirt of about 25 grams of one deck on the stainless steel metal plate, in 120 ℃ of lower roastings 1 hour, check weighing W2 evenly sprayed 5 gram family expenses acidic cleaning agents and to shine on the stainless steel metal plate, placed 2 hours under the room temperature, then under 60 ℃ of hot water flow, use the sponge rinsing, oven for drying, check weighing W3.By weighting method, draw soil removal efficiency.
Above-mentioned dirt is comprised of 50wt% chicken fat, 20wt% vegetables oil, 20wt% stearic acid, 5wt% tomato-sauce, 5wt% particulate sugar.
Soil removal efficiency=[(W2-W3)/(W2-W1)] * 100%
| ? | Soil removal efficiency, % |
| Embodiment 1 | 94 |
| Comparative Examples 1 | 81 |
| Comparative Examples 2 | 71 |
Among the present invention, adopt diethylene triamine pentacetic acid (DTPA) iron-sodium complex and these the two kinds of composite uses of complexing agent of dicarboxyl methylalanine trisodium, obviously improved the soil removability of product.
Claims (2)
1. a family expenses acidic cleaning agent is characterized in that, is comprised of following raw material: water, methylsulphonic acid, ethoxylated dodecyl alcohol, sodium methyl cocoyl taurate, oxyacetic acid, diethylene triamine pentacetic acid (DTPA) iron-sodium complex, dicarboxyl methylalanine trisodium.
2. family expenses acidic cleaning agent; it is characterized in that; raw material by following weight part forms: 80 parts in water; methylsulphonic acid 8-12 part; ethoxylated dodecyl alcohol 3-5 part, sodium methyl cocoyl taurate 2-4 part, oxyacetic acid 1-3 part; diethylene triamine pentacetic acid (DTPA) iron-sodium complex 0.1-0.3 part, dicarboxyl methylalanine trisodium 0.1-0.3 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310020522.3A CN103060116B (en) | 2013-01-21 | 2013-01-21 | Domestic acid cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310020522.3A CN103060116B (en) | 2013-01-21 | 2013-01-21 | Domestic acid cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103060116A true CN103060116A (en) | 2013-04-24 |
| CN103060116B CN103060116B (en) | 2014-08-06 |
Family
ID=48103019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310020522.3A Active CN103060116B (en) | 2013-01-21 | 2013-01-21 | Domestic acid cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103060116B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1102432A (en) * | 1994-09-10 | 1995-05-10 | 王林权 | Acidic cleaning agent |
| CN101372647A (en) * | 2008-09-24 | 2009-02-25 | 北京洛娃日化有限公司 | Thickened non-phosphate acidic detergent |
| CN101568570A (en) * | 2006-12-21 | 2009-10-28 | 约翰逊迪瓦西公司 | Method for washing polycarbonate article |
| CN102618400A (en) * | 2012-03-02 | 2012-08-01 | 北京洛娃日化有限公司 | Hard surface cleaning agent with sterilizing effect |
-
2013
- 2013-01-21 CN CN201310020522.3A patent/CN103060116B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1102432A (en) * | 1994-09-10 | 1995-05-10 | 王林权 | Acidic cleaning agent |
| CN101568570A (en) * | 2006-12-21 | 2009-10-28 | 约翰逊迪瓦西公司 | Method for washing polycarbonate article |
| CN101372647A (en) * | 2008-09-24 | 2009-02-25 | 北京洛娃日化有限公司 | Thickened non-phosphate acidic detergent |
| CN102618400A (en) * | 2012-03-02 | 2012-08-01 | 北京洛娃日化有限公司 | Hard surface cleaning agent with sterilizing effect |
Non-Patent Citations (1)
| Title |
|---|
| 王慎敏等: "《洗涤剂配方与设计、制备工艺与配方实例》", 30 April 2003, 化学工业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103060116B (en) | 2014-08-06 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190923 Address after: 233010 Incubation Workshop, 414 Changle Road, Yuhui District, Bengbu City, Anhui Province Patentee after: Bengbu Xingshi Intellectual Property Operations Co.,Ltd. Address before: 201111 Shanghai city Minhang District Yuanjiang Road No. 5500 building first room E2128 Patentee before: SHANGHAI YANZI CHEMICAL TECHNOLOGY Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240411 Address after: 528000, Chaodong Village Committee, Zumiao Street, Chancheng District, Foshan City, Guangdong Province, China, Datangyong New Village (2) - Building 122, 5th Floor, Self designated No. 2-1 (Residence Declaration) Patentee after: Foshan Shihuasha New Materials Co.,Ltd. Country or region after: China Address before: 233010 1st floor, incubation workshop, Industrial Automation Research Institute, 414 Changle Road, Yuhui District, Bengbu City, Anhui Province Patentee before: Bengbu Xingshi Intellectual Property Operations Co.,Ltd. Country or region before: China |
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| TR01 | Transfer of patent right |