CN109628219A - For heating preparation method and application of the mint aroma in not burning tobacco containing fragrant microcapsules - Google Patents
For heating preparation method and application of the mint aroma in not burning tobacco containing fragrant microcapsules Download PDFInfo
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- CN109628219A CN109628219A CN201910091610.XA CN201910091610A CN109628219A CN 109628219 A CN109628219 A CN 109628219A CN 201910091610 A CN201910091610 A CN 201910091610A CN 109628219 A CN109628219 A CN 109628219A
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- 235000006679 Mentha X verticillata Nutrition 0.000 title claims abstract description 45
- 235000002899 Mentha suaveolens Nutrition 0.000 title claims abstract description 45
- 235000001636 Mentha x rotundifolia Nutrition 0.000 title claims abstract description 45
- 239000003094 microcapsule Substances 0.000 title claims abstract description 44
- 238000010438 heat treatment Methods 0.000 title claims abstract description 30
- 241000208125 Nicotiana Species 0.000 title claims abstract description 29
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 31
- 238000003756 stirring Methods 0.000 claims abstract description 24
- 235000019504 cigarettes Nutrition 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 14
- 108010010803 Gelatin Proteins 0.000 claims abstract description 9
- 229920000159 gelatin Polymers 0.000 claims abstract description 9
- 239000008273 gelatin Substances 0.000 claims abstract description 9
- 235000019322 gelatine Nutrition 0.000 claims abstract description 9
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 9
- 238000009987 spinning Methods 0.000 claims abstract description 9
- 239000002304 perfume Substances 0.000 claims abstract description 8
- 239000000758 substrate Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 6
- 150000004676 glycans Chemical class 0.000 claims abstract description 5
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 5
- 239000005017 polysaccharide Substances 0.000 claims abstract description 5
- 238000004945 emulsification Methods 0.000 claims abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 10
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 9
- 235000013824 polyphenols Nutrition 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 239000008236 heating water Substances 0.000 claims description 6
- 239000005457 ice water Substances 0.000 claims description 6
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 5
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 5
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 5
- 229930091371 Fructose Natural products 0.000 claims description 5
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 5
- 239000005715 Fructose Substances 0.000 claims description 5
- 244000269722 Thea sinensis Species 0.000 claims description 5
- 229930007050 cineol Natural products 0.000 claims description 5
- 229960005233 cineole Drugs 0.000 claims description 5
- 229930007744 linalool Natural products 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 229920000858 Cyclodextrin Polymers 0.000 claims description 4
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 claims description 4
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 4
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001525 mentha piperita l. herb oil Substances 0.000 claims description 4
- 235000019477 peppermint oil Nutrition 0.000 claims description 4
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 3
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 claims description 3
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 3
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 claims description 3
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 claims description 3
- 235000010413 sodium alginate Nutrition 0.000 claims description 3
- 239000000661 sodium alginate Substances 0.000 claims description 3
- 229940005550 sodium alginate Drugs 0.000 claims description 3
- 229920001661 Chitosan Polymers 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 239000004368 Modified starch Substances 0.000 claims description 2
- CWEZAWNPTYBADX-UHFFFAOYSA-N Procyanidin Natural products OC1C(OC2C(O)C(Oc3c2c(O)cc(O)c3C4C(O)C(Oc5cc(O)cc(O)c45)c6ccc(O)c(O)c6)c7ccc(O)c(O)c7)c8c(O)cc(O)cc8OC1c9ccc(O)c(O)c9 CWEZAWNPTYBADX-UHFFFAOYSA-N 0.000 claims description 2
- 244000299461 Theobroma cacao Species 0.000 claims description 2
- 235000009470 Theobroma cacao Nutrition 0.000 claims description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 2
- 229940015043 glyoxal Drugs 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- 229920002414 procyanidin Polymers 0.000 claims description 2
- 240000002853 Nelumbo nucifera Species 0.000 claims 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims 1
- 108060008539 Transglutaminase Proteins 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 claims 1
- 102000003601 transglutaminase Human genes 0.000 claims 1
- 239000003205 fragrance Substances 0.000 abstract description 21
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000686 essence Substances 0.000 description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 239000003546 flue gas Substances 0.000 description 5
- 235000019505 tobacco product Nutrition 0.000 description 5
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 230000035479 physiological effects, processes and functions Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002074 melt spinning Methods 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000050510 Cunninghamia lanceolata Species 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 238000005354 coacervation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 125000005909 ethyl alcohol group Chemical group 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0003—Compounds of unspecified constitution defined by the chemical reaction for their preparation
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0216—Applying additives to filter materials the additive being in the form of capsules, beads or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Manufacture Of Tobacco Products (AREA)
- Fats And Perfumes (AREA)
Abstract
The present invention provides a kind of for heating preparation method and application of the mint aroma in not burning tobacco containing fragrant microcapsules.The mint aroma is to mix gelatin and polysaccharide according to the ratio of mass ratio 1:1.0~1.5 containing fragrant microcapsules, then by the mixture wall material solution soluble in water for being prepared into mixture concentration and being 0.5%~2.0%, then the essence that mint aroma is added continuously stirs 10~15min of emulsification under the revolving speed of 500~800rpm, adjust pH to 3.5~4.2, and constant temperature stirs 15~30min, curing agent is added, and pH is adjusted to 6.0~7.0, system is heated to 35 ± 5 DEG C, solidify 1~4h, stop stirring, it stands, it filters, and wash away micro-capsule curing agent remained on surface, dry powdered samples at room temperature.The microcapsules containing perfume of above method preparation are subjected to co-blended spinning at silk substrate, additive amount is the 5%~15% of silk thread, and then silk thread is added and heats in the cigarette filter rod that do not burn, achievees the purpose that the release of fragrance controllable.
Description
Technical field
The present invention relates to a kind of for heating preparation method of the mint aroma in not burning tobacco containing fragrant microcapsules and answering
With belonging to novel tobacco field.
Background technique
New cigarette is also referred to as low temperature cigarette or heating is not burnt cigarette (heat not burn), it is mainly characterized by
The non-ignition tobacco using external heat source heating tobacco.Since heating temperature is far below ignition temperature, cigarette can be effectively reduced
The harmful components that careless high-temp combustion cracking generates, are greatly reduced main flume harmful components burst size.New tobacco products by
It does not burn in it, heating temperature is low, generally 200~500 DEG C, has very big difference with 900 DEG C of traditional cigarette.Therefore, it consumes
Person's physiology satisfaction is not strong, and it is that current new tobacco products is generally existing for traditional cigarette that fragrance is rich not enough
The problem of.Therefore, how effectively to be promoted consumer aspirate new tobacco products when physiology satisfaction and fragrance it is rich, be
New tobacco products needs the important technological problems solved.
Physiology satisfaction and fragrance when by flavoring and casing skill upgrading consumer suction new tobacco products is rich,
It is effective means.Part flavors and fragrances is added in new cigarette, with traditional tobacco high temperature burn release fragrance at
Point difference, different release rule and ingredient under the conditions of there is heating not burn, and be easy to scatter and disappear with characteristic perfume substance
Defect.
Patent CN107574016A discloses a kind of heating and does not burn dedicated mint flavored essence of cigarette and preparation method thereof, packet
Menthol 5%-10%, menthyl-glycoside 1%-5%, trehalose 1%-10%, 1 are included, 2-propylene glycol 30%-40% are remaining
Amount is ethyl alcohol；Patent CN105919152A discloses a kind of preparation method that tobacco-based bottom of not burning is heated containing microcapsules, including
A kind of microcapsules containing essential oil of tobaccos are prepared, and by microcapsules coating fluid on tobacco-based bottom.Due to heating not burning tobacco system
The tobacco material absorbability of product is poor, and the fragrance being added in tobacco material is easy to be lost because of mechanical presses, leads to perfume (or spice)
Taste content of material is low, and release is uneven, and more stable addition and release flavors and fragrances are that burning tobacco is not urgently for Novel heating
It solves the problems, such as.
Summary of the invention
The present invention according to prior art it is insufficient provide it is a kind of micro- containing perfume for heat the mint aroma in not burning tobacco
Boiling point can be wrapped in microcapsules by the preparation method and application of capsule, this method in 200~300 DEG C of Mint Essence,
Fragrance is not directly heated during heating the tobacco leaf production that do not burn, can inhibit fragrance in process and is thermally decomposed, reduces fragrance
Scatter and disappear, microgap when flue gas passes through on micro-capsule wall can slow-release fragrance, so that heating be made not burn cigarette lasting fragrance.
Technical solution provided by the invention: described a kind of for heating the mint aroma in not burning tobacco containing fragrant microcapsules
Preparation method, it is characterised in that specific preparation process is as follows:
(1) prepare Mint Essence according to following parts by weight: N- ethyl-is to 8~12 parts of menthyl -3- formamide, fragrant lemon
4~7 parts of lemon oil, Peppermint Oil 50~70 part, 5~15 parts of cineol, 5~15 parts of linalool, 3~8 parts of ethyl alcohol；Above-mentioned substance is mixed
It closes and is uniformly configured to Mint Essence；
(2) gelatin and polysaccharide are hybridly prepared into wall material raw material according to the ratio of mass ratio 1:1.0~1.5, then by wall
Material raw material is soluble in water, and the wall that wall material raw material concentration is 0.5%~2.0% is prepared under 50~65 DEG C of temperature of stirring condition
Material solution；
(3) take the Mint Essence prepared in step (1) according to the wall material raw material mass ratio 1 in Mint Essence and step (2):
0.4~1.5 ratio is added in the wall material solution prepared in step (2), and continuously stirs cream under the revolving speed of 500~800rpm
Change 10~15min；
(4) 35 ± 5 DEG C of emulsified solution temperature are kept, 10% citric acid solution is added and slowly adjusts pH to 3.5~4.2, and
Constant temperature stirs 15~30min at 400~500rpm；
(5) solution after stirring in step (4) is cooled to 10 ± 3 DEG C, then according to the mass ratio of curing agent and gelatin
Curing agent is added for the ratio of 0.01~0.2:1, and adjusts pH to 6.0~7.0, system is then heated to 35 ± 5 DEG C,
Solidify 1~4h, stop stirring, stand, filter, and wash away micro-capsule curing agent remained on surface, at room temperature dry powdered sample
Product are that mint aroma contains fragrant microcapsules.
Preferably technical solution provided by the invention are as follows: described a kind of to contain for heating the mint aroma in not burning tobacco
The preparation method of fragrant microcapsules, it is characterised in that specific step is as follows:
(1) bergamot oil by the N- ethyl-of 10 parts of parts by weight to menthyl -3- formamide, 5 parts by weight, 60 parts by weight
Peppermint oil, the cineol of 10 parts by weight, the linalool of 10 parts by weight, 5 parts by weight ethyl alcohol be uniformly mixed be configured to minty note
Essence is spare；
(2) using the cyclodextrin of the gelatin of 45 parts by weight, the fructose of 15 parts by weight and 40 parts by weight as wall material raw material, dissolution
In 60 DEG C of hot water, it is configured to the wall material solution that concentration is 1.5%；
(3) Mint Essence prepared in 150 parts by weight steps (1) is taken, the wall material solution prepared in step (2) is then added
In, it in the emulsified 10min that continuously stirs of 600rpm, is kept for 40 DEG C of solution temperature, 10% citric acid solution is added and slowly adjusts
PH to 4.0, and constant temperature stirs 30min at 400rpm；
(4) solution in step (3) is then reduced into temperature to 10 DEG C using ice-water bath, the tea polyphenols of 8 parts by weight is added,
PH to 6.8 is adjusted with 5%NaOH solution, then system heating water bath is warming up to 40 DEG C, solidifies 3h, stops stirring, stands, and takes out
Filter, washes away micro-capsule curing agent remained on surface, dry that powdered samples are that mint aroma contains fragrant microcapsules at room temperature.
The present invention preferably technical solution: the polysaccharide in the step (1) include fructose, rhamnose, carboxymethyl chitosan,
One of sodium alginate, cyclodextrin, modified starch are any several.
The present invention preferably technical solution: solution is cooled down using ice-water bath in the step (4)；Using heating water bath liter
Temperature；PH to 6.0~7.0 is adjusted using the NaOH solution of concentration 5%.
The present invention preferably technical solution: the curing agent in the step (5) includes glutaraldehyde, glyoxal, turns glutamy
Any one or more or curing agent in amine enzyme (TG enzyme) are tea polyphenols, grape procyanidins, apple polyphenol, appointing in cocoa polyphenol
It anticipates one or more.
Flavor of raw material in the present invention is the product directly bought.
By above method preparation containing fragrant microcapsules at silk substrate carry out co-blended spinning and be prepared into be used to be added heating not
The silk thread containing perfume or tow or tow felt in burning cigarette filter rod, containing 5%~15% that fragrant microcapsules additive amount is silk thread.
The present invention is wrapped in microcapsules using essence of the complex coacervation by boiling point at 200~300 DEG C, is not burnt in heating
Fragrance is not directly heated during tobacco leaf production, can inhibit fragrance in process and is thermally decomposed, and reduces fragrance and scatters and disappears, flue gas is logical
Microgap on out-of-date micro-capsule wall can slow-release fragrance, so that heating be made not burn cigarette lasting fragrance；Minty note prepared by the present invention
Co-blended spinning can be carried out at silk substrate containing fragrant microcapsules, additive amount is the 5%~15% of silk thread, and then silk thread is added and adds
Heat is not burnt in cigarette filter rod, is achieved the purpose that the release of fragrance controllable.
Specific embodiment
In order to better explain the present invention, below in conjunction with specific embodiment, the present invention is described in further detail, but
Limiting the invention for they.
Mint Essence in following embodiment is made of the substance of following parts by weight: N- ethyl-is to menthyl -3- first
10 parts of amide (peppermint), 5 parts of bergamot oil, 60 parts of peppermint oil, 10 parts of cineol, 10 parts of linalool, 5 parts of ethyl alcohol, by above-mentioned object
Matter is uniformly mixed and is configured to Mint Essence.
All substance numbers in following embodiment are parts by weight.
Embodiment 1 provides a kind of for heating the mint aroma in not burning tobacco containing fragrant microcapsules, preparation method
It is as follows: 45 parts of gelatin, 15 parts of fructose, 40 parts of cyclodextrin being dissolved in 60 DEG C of hot water as wall material raw material, are configured to wall material original
Expect that concentration is 1.5% wall material solution；Then 150 parts of above-mentioned Mint Essences are added, it is emulsified in continuously stirring for 600rpm
10min is kept for 40 DEG C of solution temperature, and 10% citric acid solution is added and slowly adjusts pH to 4.0, and constant temperature stirs at 400rpm
30min；Solution is reduced into solution temperature to 10 DEG C using ice-water bath later, 8 parts of tea polyphenols are added, with 5%NaOH solution tune
Save pH to 6.8；System heating water bath is warming up to 40 DEG C, solidifies 3h, stops stirring, stands, and filters, it is remained on surface to wash away micro-capsule
Curing agent, at room temperature dry powdered samples, that is, mint aroma microcapsules.
The mint aroma microcapsules of above method preparation with Cheng Sicheng substrates be blended be placed in melt spinning machine into
Mint type perfume (or spice) line A is made in row spinning, is by polylactic acid, intermingling material, 1:0.1~0.15:0.02~0.08 at silk substrate
Ratio prepare and, the additive amounts of mint aroma microcapsules is the 10% of silk thread total raw material, melt spinning Screw Extrusion temperature, case
Body component, spinneret temperature are respectively 170~190 DEG C, 160~180 DEG C, 150~160 DEG C, and spinning rate is 1000~
2000m/min, heating temperature are 60~70 DEG C, 200~300m/min of draft speed, drafting multiple 2.8~3.2, spinning diameter
For 0.8~1.5mm.And fragrant line A is added in filter stick to roll to obtain and heats the cigarette sample A that do not burn.
Embodiment 2 provides a kind of for heating the mint aroma in not burning tobacco containing fragrant microcapsules, preparation method
It is as follows: 20 parts of gelatin, 13 parts of rhamnose, 45 parts of sodium alginate being dissolved in 50 DEG C of hot water as wall material raw material, are configured to wall material
Then 120 parts of above-mentioned Mint Essences are added, in the company of 650rpm in the wall material solution that material concentration is 1.3% into wall material solution
The continuous emulsified 15min of stirring, is kept for 38 DEG C of solution temperature, and 10% citric acid solution is added and slowly adjusts pH to 3.8, in 400rpm
Lower constant temperature stirs 30min；Ice-water bath reduce solution temperature to 10 DEG C, be added 2 parts of glutaraldehyde, with 5%NaOH solution adjust pH to
6.8；System heating water bath is warming up to 40 DEG C, solidifies 1h, stops stirring, stands, and filters, washes away micro-capsule solidification remained on surface
Agent, at room temperature dry powdered samples, that is, mint aroma microcapsules.
Above method preparation is subjected to co-blended spinning according to the spinning process of fragrant line A at silk substrate containing fragrant microcapsules,
Its additive amount is the 12% of silk thread, obtains fragrant line sample B, and fragrant line B is added in filter stick to roll to obtain and heats the cigarette sample that do not burn
Product B.
Reference examples 1: common cotton thread is immersed in 30min in above-mentioned Mint Essence, room temperature air-dries and obtains minty note line sample
Then minty note line sample C is added in filter stick to roll to obtain and heats the cigarette sample C that do not burn by C.
Reference examples 2: above-mentioned Mint Essence is added in novel tobacco tobacco slice coating fluid by mass fraction 15%, is made
Heat the cigarette sample D that do not burn.
For the fragrant line heat stability testing prepared in embodiment 1,2 and comparative example 1: by fragrant line sample respectively 30 DEG C,
50 DEG C, 80 DEG C, 100 DEG C four kinds it is different at a temperature of, heat 8h when, test the volatilization quality (unit: milligram) of its essence, be detailed in
Table 1:
Table 1 is three kinds of fragrant lines essence volatile quantity at different temperatures
Cigarette is not burnt by essence content measuring in mouth flue gas for the heating prepared in four embodiments: not using heating
Combustion products heat utensil and aspirate by mouth flue gas to the cigarette for adding fragrant line on 10 duct linear type smoking machines, specific to take out
Inhale parameter: pumping volume 50mL, puff duration 2s, puff interval 30s, test main flume in essence content (unit:
Microgram), see Table 2 for details:
Cigarette is not burnt by essence content in mouth flue gas in heating in 2 four embodiments of table
From Chinese fir result it is found that fragrance dissipates using the fragrant line (fragrant line A, B) of the technical program preparation in better heat stability
Lose it is less, while suction when release fragrance more evenly, persistently.
Claims (6)
1. a kind of for heating preparation method of the mint aroma in not burning tobacco containing fragrant microcapsules, it is characterised in that specific system
It is standby that steps are as follows:
(1) prepare Mint Essence according to following parts by weight: N- ethyl-is to 8~12 parts of menthyl -3- formamide, bergamot oil 4
~7 parts, Peppermint Oil 50~70 part, 5~15 parts of cineol, 5~15 parts of linalool, 3~8 parts of ethyl alcohol；Above-mentioned substance is mixed equal
It is even to be configured to Mint Essence；
(2) gelatin and polysaccharide are hybridly prepared into wall material raw material according to the ratio of mass ratio 1:1.0~1.5, then by wall material original
Expect it is soluble in water, be prepared under 50~65 DEG C of temperature of stirring condition wall material raw material concentration be 0.5%~2.0% wall material it is molten
Liquid；
(3) take the Mint Essence prepared in step (1) according to the wall material raw material mass ratio 1:0.4 in Mint Essence and step (2)
~1.5 ratio is added in the wall material solution prepared in step (2), and emulsification is continuously stirred under the revolving speed of 500~800rpm
10~15min；
(4) 35 ± 5 DEG C of emulsified solution temperature are kept, 10% citric acid solution is added and slowly adjusts pH to 3.5~4.2, and 400
Constant temperature stirs 15~30min under~500rpm；
(5) solution after stirring in step (4) is cooled to 10 ± 3 DEG C, is then according to the mass ratio of curing agent and gelatin
Curing agent is added in the ratio of 0.01~0.2:1, and adjusts pH to 6.0~7.0, and system is then heated to 35 ± 5 DEG C, Gu
Change 1~4h, stop stirring, stand, filter, and wash away micro-capsule curing agent remained on surface, at room temperature dry powdered samples
As mint aroma contains fragrant microcapsules.
2. according to claim 1 a kind of for heating preparation side of the mint aroma in not burning tobacco containing fragrant microcapsules
Method, it is characterised in that specific step is as follows:
(1) by the N- ethyl-of 10 parts of parts by weight to the bergamot oil of menthyl -3- formamide, 5 parts by weight, 60 parts by weight it is thin
Lotus oil, the cineol of 10 parts by weight, the linalool of 10 parts by weight, 5 parts by weight ethyl alcohol be uniformly mixed that be configured to Mint Essence standby
With；
(2) using the cyclodextrin of the gelatin of 45 parts by weight, the fructose of 15 parts by weight and 40 parts by weight as wall material raw material, 60 are dissolved in
DEG C hot water in, be configured to concentration be 1.5% wall material solution；
(3) Mint Essence prepared in 150 parts by weight steps (1) is taken, is then added in the wall material solution prepared in step (2),
In the emulsified 10min that continuously stirs of 600rpm, kept for 40 DEG C of solution temperature, be added 10% citric acid solution slowly adjust pH to
4.0, and constant temperature stirs 30min at 400rpm；
(4) solution in step (3) is then reduced into temperature to 10 DEG C using ice-water bath, the tea polyphenols of 8 parts by weight is added, use
5%NaOH solution adjusts pH to 6.8, and then system heating water bath is warming up to 40 DEG C, solidifies 3h, stops stirring, stands, and filters,
Micro-capsule curing agent remained on surface is washed away, it is dry that powdered samples are that mint aroma contains fragrant microcapsules at room temperature.
3. according to claim 1 a kind of for heating preparation side of the mint aroma in not burning tobacco containing fragrant microcapsules
Method, it is characterised in that: the polysaccharide in the step (1) includes fructose, rhamnose, carboxymethyl chitosan, sodium alginate, ring paste
One of essence, modified starch are any several.
4. according to claim 1 a kind of for heating preparation side of the mint aroma in not burning tobacco containing fragrant microcapsules
Method, it is characterised in that: solution is cooled down using ice-water bath in the step (4)；It is heated up using heating water bath；Using concentration 5%
NaOH solution adjusts pH to 6.0~7.0.
5. according to claim 1 a kind of for heating preparation side of the mint aroma in not burning tobacco containing fragrant microcapsules
Method, it is characterised in that: the curing agent in the step (5) includes glutaraldehyde, glyoxal, appointing in transglutaminase (TG enzyme)
One or more or curing agent of anticipating is tea polyphenols, grape procyanidins, apple polyphenol, any one or more in cocoa polyphenol.
6. a kind of preparation of any one of claim 1 to 5 method contains perfume for heating the mint aroma in not burning tobacco
The application of microcapsules, it is characterised in that: above method preparation is subjected to co-blended spinning preparation at silk substrate containing fragrant microcapsules
It is containing fragrant silk thread or tow or tow felt, the microcapsules additive amount containing perfume at for being added to heat in the cigarette filter rod that do not burn
The 5%~15% of silk thread.
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| CN110720472A (en) * | 2019-09-18 | 2020-01-24 | 仲恺农业工程学院 | Preparation method of gelatin/CMC insect virus microcapsule |
| CN112227110A (en) * | 2020-10-29 | 2021-01-15 | 江西中烟工业有限责任公司 | Cigarette paper capable of adjusting pH value of smoke and preparation method thereof |
| CN112516113A (en) * | 2019-09-02 | 2021-03-19 | 江苏省农业科学院 | Preparation method of pleurotus eryngii triterpenoid nano microcapsule |
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| CN113693266A (en) * | 2021-08-31 | 2021-11-26 | 深圳市真味生物科技有限公司 | Combined type cigarette bullet and production process thereof |
| CN115350658A (en) * | 2022-10-24 | 2022-11-18 | 江西天佳生物工程股份有限公司 | Optimization method of thymol essential oil coating granulation process |
| CN116236983A (en) * | 2023-03-14 | 2023-06-09 | 福建中烟工业有限责任公司 | Fat-soluble essence slow-release double-layer microcapsule for cigarettes and preparation method thereof |
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