CN109793273A - For heating the preparation method and application of the mint aroma tow in not burning tobacco - Google Patents
For heating the preparation method and application of the mint aroma tow in not burning tobacco Download PDFInfo
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- CN109793273A CN109793273A CN201910092308.6A CN201910092308A CN109793273A CN 109793273 A CN109793273 A CN 109793273A CN 201910092308 A CN201910092308 A CN 201910092308A CN 109793273 A CN109793273 A CN 109793273A
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- 235000006679 Mentha X verticillata Nutrition 0.000 title claims abstract description 44
- 235000002899 Mentha suaveolens Nutrition 0.000 title claims abstract description 44
- 235000001636 Mentha x rotundifolia Nutrition 0.000 title claims abstract description 44
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 33
- 238000010438 heat treatment Methods 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 241000208125 Nicotiana Species 0.000 title claims description 33
- 239000000243 solution Substances 0.000 claims abstract description 60
- 239000000463 material Substances 0.000 claims abstract description 35
- 239000003094 microcapsule Substances 0.000 claims abstract description 32
- 239000003205 fragrance Substances 0.000 claims abstract description 31
- 235000019504 cigarettes Nutrition 0.000 claims abstract description 29
- 238000003756 stirring Methods 0.000 claims abstract description 26
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000003546 flue gas Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 16
- 108010010803 Gelatin Proteins 0.000 claims abstract description 9
- 238000001891 gel spinning Methods 0.000 claims abstract description 9
- 229920000159 gelatin Polymers 0.000 claims abstract description 9
- 239000008273 gelatin Substances 0.000 claims abstract description 9
- 235000019322 gelatine Nutrition 0.000 claims abstract description 9
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 9
- 239000011259 mixed solution Substances 0.000 claims abstract description 9
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- 238000002156 mixing Methods 0.000 claims abstract description 7
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- 238000007711 solidification Methods 0.000 claims abstract description 6
- 230000008023 solidification Effects 0.000 claims abstract description 6
- 238000004945 emulsification Methods 0.000 claims abstract description 5
- 150000004676 glycans Chemical class 0.000 claims abstract description 5
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- 239000005017 polysaccharide Substances 0.000 claims abstract description 5
- 238000010792 warming Methods 0.000 claims abstract description 5
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- 238000009987 spinning Methods 0.000 claims description 29
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- 235000013824 polyphenols Nutrition 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 6
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- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 claims description 4
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 4
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001525 mentha piperita l. herb oil Substances 0.000 claims description 4
- 235000019477 peppermint oil Nutrition 0.000 claims description 4
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 3
- 229940113088 dimethylacetamide Drugs 0.000 claims description 3
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- 239000000661 sodium alginate Substances 0.000 claims description 3
- 229940005550 sodium alginate Drugs 0.000 claims description 3
- 229920001661 Chitosan Polymers 0.000 claims description 2
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 claims description 2
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 2
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 claims description 2
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 239000004368 Modified starch Substances 0.000 claims description 2
- CWEZAWNPTYBADX-UHFFFAOYSA-N Procyanidin Natural products OC1C(OC2C(O)C(Oc3c2c(O)cc(O)c3C4C(O)C(Oc5cc(O)cc(O)c45)c6ccc(O)c(O)c6)c7ccc(O)c(O)c7)c8c(O)cc(O)cc8OC1c9ccc(O)c(O)c9 CWEZAWNPTYBADX-UHFFFAOYSA-N 0.000 claims description 2
- 108060008539 Transglutaminase Proteins 0.000 claims description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 2
- 238000013329 compounding Methods 0.000 claims description 2
- 229940015043 glyoxal Drugs 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- 229920002414 procyanidin Polymers 0.000 claims description 2
- 102000003601 transglutaminase Human genes 0.000 claims description 2
- 244000299461 Theobroma cacao Species 0.000 claims 1
- 235000009470 Theobroma cacao Nutrition 0.000 claims 1
- 238000013019 agitation Methods 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 claims 1
- 238000001723 curing Methods 0.000 abstract description 8
- 230000002045 lasting effect Effects 0.000 abstract description 5
- 230000001953 sensory effect Effects 0.000 abstract description 2
- 244000061176 Nicotiana tabacum Species 0.000 abstract 1
- 238000013006 addition curing Methods 0.000 abstract 1
- 239000000686 essence Substances 0.000 description 19
- 239000000796 flavoring agent Substances 0.000 description 8
- 235000019634 flavors Nutrition 0.000 description 8
- 239000002304 perfume Substances 0.000 description 5
- 235000013599 spices Nutrition 0.000 description 4
- 235000019505 tobacco product Nutrition 0.000 description 4
- 235000019640 taste Nutrition 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
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- 238000009835 boiling Methods 0.000 description 2
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- 230000035479 physiological effects, processes and functions Effects 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
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- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
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- 238000010521 absorption reaction Methods 0.000 description 1
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- 230000000996 additive effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
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- 239000012530 fluid Substances 0.000 description 1
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- 235000012907 honey Nutrition 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
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- 229960002715 nicotine Drugs 0.000 description 1
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Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacture Of Tobacco Products (AREA)
- Fats And Perfumes (AREA)
Abstract
The present invention provides a kind of for heating the preparation method and application of the peppermint tow in not burning tobacco.The peppermint tow is the mixed solution that mixture quality score is 15~25% to be configured in solvent by being uniformly mixed to be added to cellulose diacetate containing fragrant microcapsules, and solidification obtains tow in the coagulating bath of solvent and water composition through dry wet spinning machine after standing and defoaming；Wherein the mint aroma is the wall material solution soluble in water for being prepared into mixture concentration and being 0.5%~2.0% after mixing gelatin and polysaccharide containing fragrant microcapsules, then addition curing agent is warming up to 35 ± 5 DEG C after the essence of addition mint aroma continuously stirs emulsification, solidify 1~4h, it stands, it filters, and micro-capsule curing agent remained on surface is washed away, it is dried at room temperature for obtaining.Tow prepared by the above method is added to heating not burn in cigarette filter rod, and the slow-release fragrance when high-temperature flue gas passes through, to make to heat the cigarette lasting fragrance that do not burn, reduces flue-gas temperature, consumer is made to obtain better sensory experience.
Description
Technical field
The present invention relates to a kind of preparation method and application of the mint aroma tow in heating not burning tobacco, belong to novel
Field of Tobacco.
Background technique
Burning tobacco is not to be heated by special heating source to pipe tobacco for heating, nicotine when heating in pipe tobacco and
Fragrance matter generates flue gas by volatilization to meet a kind of new tobacco products of smoker's demand.Compared with traditional cigarette, add
One of the great change of the hot cigarette that do not burn is in process of consumption that environment temperature locating for tobacco-containing material is lower.Traditional cigarette
Combustion cone temperature reaches as high as 950 DEG C, and cigarette shreds can be formed thousands of by the reaction path of the complexity such as distillation, cracking and burning
Kind product；It does not burn cigarette for heating, temperature locating for tobacco-containing material is generally below 500 DEG C when consumer's use, and main logical
The pyrolytic reaction for crossing tobacco-containing material generates flue gas.Therefore, consumer's physiology satisfaction is not strong, and it is current that fragrance is rich not enough
New tobacco products common problem for traditional cigarette.
The physiology satisfaction and fragrance heated when not burning tobacco product is aspirated by flavoring and casing skill upgrading consumer
It is rich, it is effective means.Traditional perfuming process be fragrance is uniformly sprayed onto pipe tobacco by a certain percentage, however
Due to heating the unique Smoking regime of cigarette that do not burn, in aspiration procedure, former one's intention as revealed in what one says tastes are sufficient, and then several mouthfuls of fragrance are non-
Often thin, the release of fragrance is not uneven, lasting.
Fragrant wire material generally use allow in cotton fiber or cigarette using some synthetic fibers, fragrant line is immersed in essence
Physical absorption in spice solution by fibre bundle is fixed on fragrant line.It will using the high temperature of flue gas when flue gas passes through
Flavors and fragrances releases.Its burst size and release in flue gas is controlled by adjusting formula and the additive amount of flavors and fragrances
Speed.Patent CN107574016A discloses a kind of heating and does not burn dedicated mint flavored essence of cigarette and preparation method thereof, including
Menthol 5%-10%, menthyl-glycoside 1%-5%, trehalose 1%-10%, 1,2-propylene glycol 30%-40%, surplus
For ethyl alcohol, but heating do not burn tobacco product tobacco material absorbability it is poor, the fragrance being added in tobacco material holds very much
Easily it is lost because of mechanical presses.Patent CN105595415A discloses a kind of side that the fragrant cigarette perfume (or spice) line of honey is prepared using lichee nectar
Short fiber of plant is immersed in lichee nectar spice liquid by method, is air-dried and is obtained sweet fragrant cigarette perfume (or spice) line.The perfume as made from infusion method
Line, the flavors and fragrances early release that part is had in the forming process of filter tip, which comes out, to cause damages.In the storage and fortune of cigarette
During defeated, due to not shielding effectively, also have the evolution of flavors and fragrances part and suction taste is caused not reach requirement.It is more stable
Addition and release flavors and fragrances be fragrant line urgent problem to be solved.
Summary of the invention
The present invention is insufficient according to prior art to provide a kind of preparation side for heating the minty note tow in not burning tobacco
Method and application, this method are wrapped in microcapsules using essence of the complex coacervation by boiling point at 200~300 DEG C, containing fragrant micro- glue
Capsule be made in spinning coagulation bath through dry wet spinning machine at silk substrate containing fragrant tow again, and fragrance is not during the spinning process
It is directly heated, it can inhibit fragrance in process and thermally decomposed, reduce fragrance and scatter and disappear, microgap when flue gas passes through on micro-capsule wall can
Slow-release fragrance, to make to heat the cigarette lasting fragrance that do not burn.
Technical solution provided by the invention: described a kind of for heating the preparation of the mint aroma tow in not burning tobacco
Method, it is characterised in that specific step is as follows:
(1) preparation of the mint aroma containing fragrant microcapsules:
A. gelatin and polysaccharide are mixed and made into wall material raw material according to the ratio of mass ratio 1:1.0~1.5, then by wall material original
It is molten to expect that the stirring soluble in water under conditions of 50~65 DEG C of temperature is prepared into the wall material that wall material raw material concentration is 0.5%~2.0%
Liquid；
B. prepare Mint Essence according to following parts by weight: N- ethyl-is to 8~12 parts of menthyl -3- formamide, bergamot
Oily 4~7 parts, Peppermint Oil 50~70 part, 5~15 parts of cineol, 5~15 parts of linalool, 3~8 parts of ethyl alcohol；Above-mentioned substance is mixed
Uniformly it is configured to Mint Essence；
C. it takes according to the ratio of wall material material quality ratio 1:0.4~1.5 in Mint Essence and step a and to be prepared in step b
Mint Essence is added in step a in the wall material solution that configures, and continuously stir under the revolving speed of 500~800rpm emulsification 10~
15min after emulsification, is kept for 35 ± 5 DEG C of emulsified solution temperature, adjusts pH to 3.5~4.2, and permanent at 400~500rpm
15~30min of temperature stirring；
D. the solution after stirring in step c is cooled to 10 ± 3 DEG C, is then according to the mass ratio of curing agent and gelatin
Curing agent is added in the ratio of 0.01~0.2:1, adjusts pH to 6.0~7.0, system is then heated to 35 ± 5 DEG C, solidification
1~4h stops stirring, stands, and filters, and wash away micro-capsule curing agent remained on surface, dry that powdered samples are at room temperature
Contain fragrant microcapsules for mint aroma；
(2) ratio containing fragrant microcapsules and cellulose diacetate according to 0.1~0.2:1 of mass ratio will be prepared in step (1)
Example is uniformly mixed, and compounding substances are added in solvent in the condition that temperature is 50~70 DEG C, 400~600rpm of mixing speed
1~2h of lower heating stirring configures mixture quality score and is 15~25% mixed solution, and mixed solution standing and defoaming is obtained
To spinning solution；Wherein the solvent includes dimethylformamide (DMF), dimethyl acetamide (DMAC), dimethyl sulfoxide
One of (DSMO) or it is a variety of；
(3) solidification of the solvent and water composition by the spinning solution in step (2) through dry wet spinning machine in step (2)
Solidification obtains tow in bath；The concentration of the spinning coagulation bath be 30%~50%, 30~50 DEG C of coagulation bath temperature, spinning air gap
Highly 9~12cm, 50 hole of spinneret hole number, spinning aperture 0.08mm.
A kind of a kind of preferably technical solution provided by the invention: mint aroma for heating in not burning tobacco
The preparation method of tow, it is characterised in that specific step is as follows:
(1) preparation of the mint aroma containing fragrant microcapsules:
A. the cyclodextrin of the gelatin of 45 parts by weight, the fructose of 15 parts by weight and 40 parts by weight is dissolved in as wall material raw material
In 60 DEG C of hot water, it is configured to the wall material solution that concentration is 1.5%；
B. by the N- ethyl-of 10 parts of parts by weight to the bergamot oil of menthyl -3- formamide, 5 parts by weight, 60 parts by weight
Peppermint oil, the cineol of 10 parts by weight, the linalool of 10 parts by weight, 5 parts by weight ethyl alcohol be uniformly mixed be configured to Mint Essence
It is spare；
C. the Mint Essence prepared in 150 parts by weight step b is taken, is then added in the wall material solution prepared in step (1),
In the emulsified 10min that continuously stirs of 600rpm, kept for 40 DEG C of solution temperature, be added 10% citric acid solution slowly adjust pH to
4.0, and constant temperature stirs 30min at 400rpm；
D. the solution in step c is then reduced into temperature to 10 DEG C using ice-water bath, the tea polyphenols of 8 parts by weight is added, use
5%NaOH solution adjusts pH to 6.8, and then system heating water bath is warming up to 40 DEG C, solidifies 3h, stops stirring, stands, and filters,
Micro-capsule curing agent remained on surface is washed away, it is dry that powdered samples are that mint aroma contains fragrant microcapsules at room temperature.
(2) after mixing by the microcapsules containing perfume prepared in step (1) and cellulose diacetate 0.16:1 in mass ratio
It is added in DSMO, the mixed solution that configuration quality score is 22% stirs 70min under the conditions of 65 DEG C, 450rpm, stands de-
Bubble obtains spinning solution；
(3) spinning solution in step (2) is solidified in the DSMO solution of concentration 45% through dry wet spinning machine and is obtained
Tow；Wherein, 45 DEG C of the coagulation bath temperature, spinning air gap height 10cm, 50 hole of spinneret hole number, spinning aperture 0.08mm.
A kind of preferably technical solution provided by the invention: polysaccharide includes fructose, sandlwood in a step of the step (1)
One of sugar, carboxymethyl chitosan, sodium alginate, cyclodextrin, modified starch are any several.
A kind of preferably technical solution provided by the invention: 10% citric acid solution is added in the step c of the step (1)
Slow 3.5~4.2；Solution is cooled down using ice-water bath in Step d, is heated up using heating water bath；Using concentration 5% in Step d
NaOH solution adjusts pH to 6.0~7.0.
A kind of preferably technical solution provided by the invention: the curing agent in the Step d of the step (1) includes penta 2
Aldehyde, glyoxal, any one or more or curing agent in transglutaminase be tea polyphenols, grape procyanidins, apple polyphenol, can
It can any one or more in polyphenol.
Flavor of raw material in the present invention is the product directly bought.
It is provided by the invention a kind of for heating the application of the mint aroma tow in not burning tobacco, it is characterised in that:
The mint aroma tow of above method preparation being used to heat in not burning tobacco is added to and heats the cigarette filter rod that do not burn
Pipe tobacco end hollow stick or temperature descending section hollow part are placed in pipe tobacco end hollow stick or temperature descending section hollow part simultaneously simultaneously, and in height
Slow-release fragrance when warm flue gas passes through.
The present invention is wrapped in microcapsules using essence of the complex coacervation by boiling point at 200~300 DEG C, containing fragrant microcapsules
Be made in spinning coagulation bath through dry wet spinning machine containing fragrant tow at silk substrate again, fragrance is not straight during the spinning process
Receive heat, can inhibit fragrance in process and thermally decomposed, reduces fragrance and scatter and disappear, microgap when flue gas passes through on micro-capsule wall can delay
Fragrance is released, to make to heat the cigarette lasting fragrance that do not burn.The present invention by spining technology one-pass molding or to institute's spinning threadling into
Row post-processing makes the ability containing fragrant tow with stable addition and release flavors and fragrances of preparation, and with the process for crossing spinning
The release of flavors and fragrances is achieved the purpose that controllable.And to be added to heating cigarette filter rod pipe tobacco end of not burning hollow for the tow of preparation
The hollow part of stick and hollow temperature descending section, when high-temperature flue gas passes through tow can slow-release fragrance, thus make heating do not burn cigarette perfume
Taste is lasting, while reducing flue-gas temperature, and consumer is made to obtain better sensory experience.
Specific embodiment
In order to better explain the present invention, below in conjunction with specific embodiment, the present invention is described in further detail, but
Limiting the invention for they.
Mint Essence in following embodiment is made of the substance of following parts by weight: N- ethyl-is to menthyl -3- first
10 parts of amide (peppermint), 5 parts of bergamot oil, 60 parts of peppermint oil, 10 parts of cineol, 10 parts of linalool, 5 parts of ethyl alcohol, by above-mentioned object
Matter is uniformly mixed and is configured to Mint Essence.
All substance numbers in following embodiment are parts by weight.
Embodiment 1 provides a kind of for heating the mint aroma in not burning tobacco containing fragrant microcapsules, preparation method
It is as follows: 45 parts of gelatin, 15 parts of fructose, 40 parts of cyclodextrin being dissolved in 60 DEG C of hot water as wall material raw material, are configured to wall material original
Expect that concentration is 1.5% wall material solution；Then 150 parts of above-mentioned Mint Essences are added, it is emulsified in continuously stirring for 600rpm
10min is kept for 40 DEG C of solution temperature, and 10% citric acid solution is added and slowly adjusts pH to 4.0, and constant temperature stirs at 400rpm
30min；Solution is reduced into solution temperature to 10 DEG C using ice-water bath later, 8 parts of tea polyphenols are added, with 5%NaOH solution tune
Save pH to 6.8；System heating water bath is warming up to 40 DEG C, solidifies 3h, stops stirring, stands, and filters, it is remained on surface to wash away micro-capsule
Curing agent, at room temperature dry powdered samples, that is, mint aroma microcapsules.
Fragrant microcapsules and cellulose diacetate 0.16:1 in mass ratio will be contained to be added in DSMO after mixing, configure matter
The mixed solution that score is 22% is measured, stirs 70min under the conditions of 65 DEG C, 450rpm, standing and defoaming obtains spinning solution；It will spin
Silk solution solidifies in 45%DSMO solution through dry wet spinning machine obtains tow.45 DEG C of coagulation bath temperature, spinning air gap height
Minty note tow A is prepared in 10cm, 50 hole of spinneret hole number, spinning aperture 0.08mm.
The minty note tow A prepared in embodiment 1 is added to and is heated in the cigarette filter rod that do not burn in hollow temperature descending section
In cavity body, rolls to obtain and heat the cigarette sample A that do not burn.
Embodiment 2 provides a kind of for heating the mint aroma in not burning tobacco containing fragrant microcapsules, preparation method
It is as follows: 20 parts of gelatin, 13 parts of rhamnose, 45 parts of sodium alginate being dissolved in 50 DEG C of hot water as wall material raw material, are configured to wall material
Then 120 parts of above-mentioned Mint Essences are added, in the company of 650rpm in the wall material solution that material concentration is 1.3% into wall material solution
The continuous emulsified 15min of stirring, is kept for 38 DEG C of solution temperature, and 10% citric acid solution is added and slowly adjusts pH to 3.8, in 400rpm
Lower constant temperature stirs 30min；Ice-water bath reduce solution temperature to 10 DEG C, be added 2 parts of glutaraldehyde, with 5%NaOH solution adjust pH to
6.8；System heating water bath is warming up to 40 DEG C, solidifies 1h, stops stirring, stands, and filters, washes away micro-capsule solidification remained on surface
Agent, at room temperature dry powdered samples, that is, mint aroma microcapsules.
Fragrant microcapsules and cellulose diacetate 0.2:1 in mass ratio will be contained to be added in DMAc after mixing, configure matter
The mixed solution that score is 20% is measured, stirs 90min under the conditions of 60 DEG C, 550rpm, standing and defoaming obtains spinning solution；It will spin
Silk solution solidifies in 40%DMAc solution through dry wet spinning machine obtains tow.50 DEG C of coagulation bath temperature, spinning air gap height
Minty note tow B is prepared in 12cm, 50 hole of spinneret hole number, spinning aperture 0.08mm.
The minty note tow B prepared in embodiment 2 is added to and is heated in the cigarette filter rod that do not burn in hollow temperature descending section
In cavity body, rolls to obtain and heat the cigarette sample B that do not burn.
Reference examples 1: common cotton thread is immersed in 30min in above-mentioned Mint Essence, room temperature air-dries and obtains fragrant line sample C, so
Afterwards fragrant line is added in filter stick to roll to obtain and heats the cigarette sample C that do not burn.
Reference examples 2: above-mentioned essence is added in novel tobacco tobacco slice coating fluid by mass fraction 18%, heating is made
Do not burn cigarette sample D.
For in embodiment 1,2 tow and comparative example 1 in the fragrant line heat stability testing for preparing: fragrant line sample is distinguished
30 DEG C, 50 DEG C, 80 DEG C, 100 DEG C four kinds it is different at a temperature of, when heating 8h, test the volatilization quality (unit: milli of its essence
Gram), see Table 1 for details:
Table 1 is fragrant line essence volatile quantity at different temperatures in tow and comparative example 1 in embodiment 1,2
Cigarette is not burnt by essence content measuring in mouth flue gas for the heating prepared in four embodiments: not using heating
Combustion products heat utensil and aspirate by mouth flue gas to the cigarette for adding fragrant line on 10 duct linear type smoking machines, specific to take out
Inhale parameter: pumping volume 50mL, puff duration 2s, puff interval 30s, test main flume in essence content (unit:
Microgram), see Table 2 for details:
Cigarette is not burnt by essence content in mouth flue gas in heating in 2 four embodiments of table
As can be known from the results, using the technical program preparation tow in better heat stability, fragrance scatter and disappear it is less, while
Fragrance is discharged more evenly, persistently when suction.
Claims (6)
1. a kind of for heating the preparation method of the mint aroma tow in not burning tobacco, it is characterised in that specific steps are such as
Under:
(1) preparation of the mint aroma containing fragrant microcapsules:
A. gelatin and polysaccharide are mixed and made into wall material raw material according to the ratio of mass ratio 1:1.0~1.5, it is then that wall material raw material is molten
Yu Shuizhong is stirred under conditions of 50~65 DEG C of temperature is prepared into the wall material solution that wall material raw material concentration is 0.5%~2.0%；
B. prepare Mint Essence according to following parts by weight: N- ethyl-is to 8~12 parts of menthyl -3- formamide, bergamot oil 4
~7 parts, Peppermint Oil 50~70 part, 5~15 parts of cineol, 5~15 parts of linalool, 3~8 parts of ethyl alcohol；Above-mentioned substance is mixed equal
It is even to be configured to Mint Essence；
C. the peppermint prepared in step b is taken according to the ratio of wall material material quality ratio 1:0.4~1.5 in Mint Essence and step a
Essence is added in the wall material solution configured in step a, and 10~15min of emulsification is continuously stirred under the revolving speed of 500~800rpm,
It after emulsification, is kept for 35 ± 5 DEG C of emulsified solution temperature, adjusts pH to 3.5~4.2, and constant temperature stirs at 400~500rpm
15~30min；
D. by step c stir after solution be cooled to 10 ± 3 DEG C, then according to the mass ratio of curing agent and gelatin be 0.01~
Curing agent is added in the ratio of 0.2:1, adjusts pH to 6.0~7.0, and system is then heated to 35 ± 5 DEG C, solidifies 1~4h,
Stop stirring, stand, filters, and wash away micro-capsule curing agent remained on surface, it is dry that powdered samples are peppermint at room temperature
Odor type contains fragrant microcapsules；
(2) mixed according to the ratio of 0.1~0.2:1 of mass ratio containing fragrant microcapsules and cellulose diacetate by what is prepared in step (1)
It closes uniformly, and compounding substances is added in solvent and are added under conditions of temperature is 50~70 DEG C, 400~600rpm of mixing speed
1~2h of thermal agitation configures mixture quality score and is 15~25% mixed solution, and mixed solution standing and defoaming is spun
Silk solution；Wherein the solvent includes one of dimethylformamide, dimethyl acetamide, dimethyl sulfoxide or a variety of；
(3) by the spinning solution in step (2) through dry wet spinning machine in step (2) solvent and water composition coagulating bath in
Solidification obtains tow；The concentration of the spinning coagulation bath be 30%~50%, 30~50 DEG C of coagulation bath temperature, spinning air gap height
9~12cm, 50 hole of spinneret hole number, spinning aperture 0.08mm.
2. it is according to claim 1 a kind of for heating the preparation method of the mint aroma tow in not burning tobacco,
It is characterized in that specific step is as follows:
(1) preparation of the mint aroma containing fragrant microcapsules:
A. 60 DEG C are dissolved in using the cyclodextrin of the gelatin of 45 parts by weight, the fructose of 15 parts by weight and 40 parts by weight as wall material raw material
Hot water in, be configured to concentration be 1.5% wall material solution；
B. by the N- ethyl-of 10 parts of parts by weight to the bergamot oil of menthyl -3- formamide, 5 parts by weight, the peppermint of 60 parts by weight
Oil, the cineol of 10 parts by weight, the linalool of 10 parts by weight, 5 parts by weight ethyl alcohol be uniformly mixed that be configured to Mint Essence spare；
C. the Mint Essence prepared in 150 parts by weight step b is taken, is then added in the wall material solution prepared in step (1),
600rpm's continuously stirs emulsified 10min, is kept for 40 DEG C of solution temperature, be added 10% citric acid solution slowly adjust pH to
4.0, and constant temperature stirs 30min at 400rpm；
D. the solution in step c is then reduced into temperature to 10 DEG C using ice-water bath, the tea polyphenols of 8 parts by weight is added, with 5%
NaOH solution adjusts pH to 6.8, and then system heating water bath is warming up to 40 DEG C, solidifies 3h, stops stirring, stands, and filters, washes away
Micro-capsule curing agent remained on surface, it is dry that powdered samples are that mint aroma contains fragrant microcapsules at room temperature.
(2) it is added what is prepared in step (1) after mixing containing fragrant microcapsules and cellulose diacetate 0.16:1 in mass ratio
Into DSMO, the mixed solution that configuration quality score is 22% stirs 70min under the conditions of 65 DEG C, 450rpm, standing and defoaming obtains
To spinning solution；
(3) spinning solution in step (2) is solidified in the DSMO solution of concentration 45% through dry wet spinning machine and obtains tow；
Wherein, 45 DEG C of the coagulation bath temperature, spinning air gap height 10cm, 50 hole of spinneret hole number, spinning aperture 0.08mm.
3. it is according to claim 1 a kind of for heating the preparation method of the mint aroma tow in not burning tobacco,
Be characterized in that: polysaccharide includes fructose, rhamnose, carboxymethyl chitosan, sodium alginate, ring paste in a step of the step (1)
One of essence, modified starch are any several.
4. it is according to claim 1 a kind of for heating the preparation method of the mint aroma tow in not burning tobacco,
It is characterized in that: 10% citric acid solution slow 3.5~4.2 is added in the step c of the step (1)；Solution uses ice in Step d
Water-bath cooling, is heated up using heating water bath；PH to 6.0~7.0 is adjusted using the NaOH solution of concentration 5% in Step d.
5. it is according to claim 1 a kind of for heating the preparation method of the mint aroma tow in not burning tobacco,
Be characterized in that: the curing agent in the Step d of the step (1) includes glutaraldehyde, glyoxal, any one in transglutaminase
Kind or a variety of or curing agent be tea polyphenols, grape procyanidins, apple polyphenol, any one or more in cocoa polyphenol.
6. according to claim 1 to any one of 5 preparations for heating answering for the mint aroma tow in not burning tobacco
With, it is characterised in that: the mint aroma tow of above method preparation being used to heat in not burning tobacco is added to heating not
Burn cigarette filter rod pipe tobacco end hollow stick or temperature descending section hollow part or be placed in pipe tobacco end hollow stick simultaneously or temperature descending section is hollow
In position simultaneously, the slow-release fragrance and when high-temperature flue gas passes through.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110652029A (en) * | 2019-09-25 | 2020-01-07 | 湖北中烟工业有限责任公司 | Preparation method and method of lemon mint flavor type blasting bead for cigarettes |
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| CN1067276A (en) * | 1992-04-29 | 1992-12-23 | 营口化学纤维厂 | Perfume synthetic fibre and manufacture method thereof |
| CN101144202A (en) * | 2007-10-18 | 2008-03-19 | 江苏盛虹化纤有限公司 | Production process of permanently aromatized polypropylene fiber cigarette tow |
| CN105062674A (en) * | 2015-07-23 | 2015-11-18 | 湖北中烟工业有限责任公司 | Preparation method of tobacco microcapsule spearmint oil |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1067276A (en) * | 1992-04-29 | 1992-12-23 | 营口化学纤维厂 | Perfume synthetic fibre and manufacture method thereof |
| CN101144202A (en) * | 2007-10-18 | 2008-03-19 | 江苏盛虹化纤有限公司 | Production process of permanently aromatized polypropylene fiber cigarette tow |
| CN105062674A (en) * | 2015-07-23 | 2015-11-18 | 湖北中烟工业有限责任公司 | Preparation method of tobacco microcapsule spearmint oil |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110652029A (en) * | 2019-09-25 | 2020-01-07 | 湖北中烟工业有限责任公司 | Preparation method and method of lemon mint flavor type blasting bead for cigarettes |
| CN110652029B (en) * | 2019-09-25 | 2022-03-04 | 湖北中烟工业有限责任公司 | Preparation method and method of lemon mint flavor type blasting bead for cigarettes |
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