CN109626593A - A kind of aquaculture antidote and preparation method thereof - Google Patents
A kind of aquaculture antidote and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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Abstract
A kind of aquaculture antidote and preparation method thereof, belongs to aquatic products industry preparation technique field.The aquaculture antidote includes following components: active carbon, titanium dioxide, sodium acetate, sodium metasilicate, montmorillonite, aluminum oxide, deionized water, dehydrated alcohol, ethyl orthosilicate, photosynthetic bacteria, bacillus, active yeast and nitrobacteria.The absorption of Nano carbon is combined in removing toxic substances of the present invention using the beneficial microbe (microorganisms such as photosynthetic bacteria, bacillus, saccharomycete, nitrobacteria, denitrifying bacteria, sulfide-oxidizing enzyme) in aquatic ecological environment, pond can be made in the case where not interrupting breeding process, remove pond long-time Cultivated water bottom, it can be effectively improved water quality, and other is inhibited to endanger the breeding of the harmful bacteria of healthy fish.
Description
Technical field
The invention belongs to aquatic products industry preparation technique fields, and in particular to a kind of aquaculture antidote and preparation method thereof.
Background technique
As high density manual acquiculture is fast-developing, pond water quality constantly deteriorates, and directly or indirectly results in water body
Eutrophication, aquatic products disease it is frequent generation and aquatic products be intrinsic delicate flavour etc., this is caused to culture fishery
Massive losses have seriously affected the sustainable development of culture fishery.At the same time, any row of untreated breeding wastewater
It puts, not only brings secondary pollution, but also threaten the health and existence of mankind itself.
At present in aquaculture process, since the educational level of raiser is not generally high, heavy metal insecticide is often misapplied
The phenomenon that causing aquatic livestock to be poisoned, happens occasionally, and the pollution at pond water source also results in cultivated animals disease after breeding water body pollution
The generation of disease.In addition, the outburst and die by visitation of God of cyanobacteria and Euglena can all lead to the poisoning of Aquatic farming animals algae toxin, and
Cause one of the factor of the large quantities of death of aquatic livestock.
Currently, thimerosal is selected to carry out disinfection mostly during aquaculture.Although disinfectant can be killed effectively
Bacterium, but have huge side effect.Thimerosal is typically all to be made of chemical substance, and thimerosal, which is used for a long time, can make some diseases
Substance develops drug resistance, moreover it is possible to kill beneficial bacteria, and bring certain pollution to water quality.
The method of domestic and international aquaculture water purifying generally uses physical method, chemical method or bioanalysis.Physical method master
The suspended matter in water is separated using physical action or takes physical means to change using forms such as absorption, precipitating, filterings
Kind oxygen in water kills pathogenic microorganisms.But physical treatment is not thorough in the presence of purification, recycling rate of waterused is poor, input cost
The disadvantages of big.Chemical method mostly uses drug such as antibiotic, potassium permanganate.The form that heavy metal classes etc. carry out disinfection.Though chemical method
More apparent effect can so be played in a short time, and still there is also the halfway problems of purification, and in aquaculture
There is also antibiotic, and problem is excessively used.Research both at home and abroad shows that antibiotic and other chemicals, which is used for a long time, will lead to
Drug is enriched in aquatic livestock body.
Application No. is 201610868951X Chinese patent applications to disclose a kind of nano silver sterilization detoxification used for aquiculture
Agent belongs to aquaculture formulation art, a kind of nano silver sterilization detoxification agent used for aquiculture, the raw material including following parts by weight
Component: 12-18 parts of nano silver, 5-10 parts of Radix Astragali, 15-25 parts of rhizoma polygonati, 5-15 parts of Radix Isatidis, 20-30 parts of folium isatidis, medical stone 4-
6 parts, 6-8 parts of oldenlandia diffusa, 20-30 parts of sweet wormwood, 2-4 parts of viola mandshurica, 6-12 parts of wilsonii, 4-6 parts of pueraria lobata；Beneficial to effect
Fruit: a kind of nano silver sterilization detoxification agent used for aquiculture using nano silver, Radix Astragali, rhizoma polygonati, Radix Isatidis, folium isatidis, medical stone,
The pharmaceutical composition that oldenlandia diffusa, sweet wormwood, viola mandshurica, wilsonii, pueraria lobata are constituted effectively improves water quality, enhances fish
With the constitution of shrimps, immunity is improved, the variation of water body environment can be strained, promotes the growth and maturity of fish and shrimps.
But although this antidote effect is relatively good, long-time service will lead to drug and be enriched in aquatic products animal and plant body.
Summary of the invention
Aiming at the shortcomings in the prior art, the present invention provides a kind of aquaculture antidote and preparation method thereof, has and changes
The advantages that being apt to water quality, other inhibited to endanger the breeding of the harmful bacteria of healthy fish.
In order to achieve the above-mentioned object of the invention, the invention adopts the following technical scheme:
A kind of aquaculture antidote, the aquaculture antidote are matched as follows by mass fraction: 15-25 parts of activity
Charcoal, 2-6 part titanium dioxide, 5-8 parts of sodium acetates, 6-9 parts of sodium metasilicate, 2-4 parts of montmorillonites, 1-3 parts of aluminum oxides, 30-40 parts
Deionized water, 16-25 part dehydrated alcohol, 4-6 parts of ethyl orthosilicates, 0.02-0.15 parts of photosynthetic bacterias, 0.05-0.08 parts of gemma
Bacillus, 0.01-0.03 part active yeast, 0.03-0.045 parts of nitrobacterias.
Preferably, the aquaculture antidote by mass fraction match it is as follows: 20 parts of active carbons, 4 parts of titanium dioxide,
6 parts of sodium acetates, 8 parts of sodium metasilicate, 3 parts of montmorillonites, 2 parts of aluminum oxides, 35 parts of deionized waters, 20 parts of dehydrated alcohols, 5 parts of positive silicon
Acetoacetic ester, 0.1 part of photosynthetic bacteria, 0.06 part of bacillus, 0.02 part of active yeast, 0.04 part of nitrobacteria.
Another technical solution of the invention is the preparation method of above-mentioned aquaculture antidote, and the preparation method includes
Following steps:
Dehydrated alcohol, deionized water are added in reactor and are stirred by step 1, mixing speed 300-450r/
Min, stir 10-20min, ethyl orthosilicate is then added, 40-50min is stirred under 1450-1600r/min revolving speed, then plus
Enter glacial acetic acid, stirs while adding to obtain mixed liquor A；
Step 2 mixes active carbon, titanium dioxide, montmorillonite and aluminum oxide, is then ground in the ball mill
Partial size is that 200-500nm obtains mixture B；
Sodium acetate, sodium metasilicate and mixture B are added into mixed liquor A by step 3, then in 1300-1500r/min revolving speed
Lower stirring 20-30min is then placed in 100 DEG C of dry 5-6h in thermostatic drying chamber, mixture after dehydration is put into Muffle furnace
450-500 DEG C of roasting temperature 3-5h, is cooled to room temperature to form Nanocrystal；
Step 4 dry, photosynthetic bacteria after incubation, gemma spare to weight after the Nanocrystal of preparation sterilizes
Sterile water is added in bacillus, active yeast and nitrobacteria, then at a temperature of 25-35 DEG C, under 200-300r/min revolving speed
2-4h is stood after water-bath concussion 30-50min, finally obtains the aquaculture antidote.
Preferably, dehydrated alcohol, deionized water are added in reactor and are stirred in the step 1, mixing speed
For 350r/min, 15min is stirred, ethyl orthosilicate is then added, 45min is stirred under 1500r/min revolving speed, ice is then added
Acetic acid stirs while adding to obtain mixed liquor A.
Preferably, mixing active carbon, titanium dioxide, montmorillonite and aluminum oxide in the step 2, then exist
It is that 300nm obtains mixture B that partial size is ground in ball mill.
Preferably, sodium acetate, sodium metasilicate and mixture B is added in the step 3 into mixed liquor A, then exist
25min is stirred under 1400r/min revolving speed, 100 DEG C of dry 5h in thermostatic drying chamber is then placed in, mixture after dehydration is put into horse
Not 480 DEG C of roasting temperature 4h in furnace, are cooled to room temperature to form Nanocrystal.
Preferably, drying is spare to weight after the Nanocrystal of preparation sterilizes in the step 4, after incubation
Photosynthetic bacteria, bacillus, sterile water is added in active yeast and nitrobacteria, then at a temperature of 30 DEG C, 250r/
3h is stood after water-bath concussion 45min under min revolving speed, finally obtains the aquaculture antidote.
Bacillus have have no toxic side effect, noresidue, the advantage not developed drug resistance, and cultivation ring can be improved
Border, can be with large-scale application in aquaculture.In addition to this, also there are the spies such as the good resistance of degree of stability is strong, activation rate is high
Point.Photosynthetic bacteria is the beneficial microbe in breeding water body, can significantly improve the immunocompetence of cultured product, and it is immune to enhance it
Function improves disease resistance.Photosynthetic bacteria can effectively treat red appendages disease of prawn, gill rot, fish yctalopia etc., and inhibit it
He endangers the breeding of the harmful bacteria of healthy fish.Active carbon, titanium dioxide, montmorillonite and aluminum oxide are sorptive material,
Especially up to its surface area greatly increases after nanoscale, adsorption capacity enhancing, and beneficial microbe is inhaled in aquatic ecological environment
The mixture of active carbon nanoparticles, titanium dioxide, montmorillonite and aluminum oxide is invested, can have the function that synergy, add
The decomposition of discharged waste, harmful object in fast aquaculture system.
(photosynthetic bacteria, bacillus, saccharomycete, nitrobacteria, denitrification are thin for beneficial microbe in aquatic ecological environment
The microorganisms such as bacterium, sulfide-oxidizing enzyme) in conjunction with the absorption of Nano carbon, pond can be made in the case where not interrupting breeding process, removed
Pond long-time Cultivated water bottom, the abundant residues bait of especially old pond bottom accumulation, discharged waste, plant and animal residues
And pernicious gas (ammonia, sulfide etc.), it is allowed to first be decomposed into small molecule (polypeptide, higher fatty acids etc.), is afterwards more small molecule
Organic matter (amino acid, lower fatty acid, monosaccharide, cyclic hydrocarbon etc.), is finally decomposed to carbon dioxide, nitrate, sulfate etc., effectively
Ground reduces COD, BOD in water, makes the ammonia nitrogen (NH in water body4 +- N) and nitrite nitrogen (NO2-- N), sulfide, ammonia it is dense
Degree reduces, to effectively improve water quality, and can provide nutriment for the breeding of the phytoplankton based on unicellular alga,
Promote the breeding of the phytoplankton based on algae.
Compared with prior art, the invention has the following advantages:
Using beneficial microbe (photosynthetic bacteria, bacillus, the yeast in aquatic ecological environment in removing toxic substances of the present invention
The microorganisms such as bacterium, nitrobacteria, denitrifying bacteria, sulfide-oxidizing enzyme) combine Nano carbon absorption, can make pond do not interrupt it is feeding
In the case where growing process, pond long-time Cultivated water bottom is removed, water quality can be effectively improved, and other is inhibited to endanger fish
The breeding of the harmful bacteria of class health.
Specific embodiment
Below by specific embodiment, invention is further described in detail.But those skilled in the art will manage
Solution, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.Specific skill is not specified in embodiment
Art or condition person, described technology or conditions carry out to specifications according to the literature in the art.Agents useful for same or instrument
Production firm person is not specified, being can be with conventional products that are commercially available.
Embodiment 1
A kind of aquaculture antidote, the aquaculture antidote are matched as follows by mass fraction: 15 parts of active carbons, 2
Part titanium dioxide, 5 parts of sodium acetates, 6 parts of sodium metasilicate, 2 parts of montmorillonites, 1 part of aluminum oxide, 30 parts of deionized waters, 16 parts it is anhydrous
Ethyl alcohol, 4 parts of ethyl orthosilicates, 0.02 part of photosynthetic bacteria, 0.05 part of bacillus, 0.01 part of active yeast, 0.03 part of nitrification
Bacterium.
The preparation method of above-mentioned aquaculture antidote, the preparation method comprises the following steps:
Dehydrated alcohol, deionized water are added in reactor and are stirred by step 1, and mixing speed 300r/min is stirred
10min is mixed, ethyl orthosilicate is then added, 40min is stirred under 1450r/min revolving speed, glacial acetic acid is then added, when being added
Stir to get mixed liquor A；
Step 2 mixes active carbon, titanium dioxide, montmorillonite and aluminum oxide, is then ground in the ball mill
Partial size is that 200nm obtains mixture B；
Sodium acetate, sodium metasilicate and mixture B are added into mixed liquor A by step 3, then stir under 1300r/min revolving speed
20min is mixed, 100 DEG C of dry 5h in thermostatic drying chamber is then placed in, mixture after dehydration is put into Muffle furnace at a temperature of 450 DEG C
3h is roasted, is cooled to room temperature to form Nanocrystal；
Drying is spare to weight after step 4 sterilizes the Nanocrystal of preparation, (uses Rhodospirillaceae bacterium in culture
Isolation medium (Qian Cunrou Huang Yixiu, 1999)) after photosynthetic bacteria, bacillus, in active yeast and nitrobacteria plus
Enter sterile water, then stands 2h after water-bath concussion 30min at a temperature of 25 DEG C, under 200r/min revolving speed, finally obtain the water
Produce cultivation antidote.
Embodiment 2
A kind of aquaculture antidote, the aquaculture antidote are matched as follows by mass fraction: 25 parts of active carbons, 6
Part titanium dioxide, 8 parts of sodium acetates, 9 parts of sodium metasilicate, 4 parts of montmorillonites, 3 parts of aluminum oxides, 40 parts of deionized waters, 25 parts it is anhydrous
Ethyl alcohol, 6 parts of ethyl orthosilicates, 0.15 part of photosynthetic bacteria, 0.08 part of bacillus, 0.03 part of active yeast, 0.045 part of nitrification
Bacterium.
The preparation method of above-mentioned aquaculture antidote, the preparation method comprises the following steps:
Dehydrated alcohol, deionized water are added in reactor and are stirred by step 1, and mixing speed 450r/min is stirred
20min is mixed, ethyl orthosilicate is then added, 50min is stirred under 1600r/min revolving speed, glacial acetic acid is then added, when being added
Stir to get mixed liquor A；
Step 2 mixes active carbon, titanium dioxide, montmorillonite and aluminum oxide, is then ground in the ball mill
Partial size is that 500nm obtains mixture B；
Sodium acetate, sodium metasilicate and mixture B are added into mixed liquor A by step 3, then stir under 1500r/min revolving speed
30min is mixed, 100 DEG C of dry 6h in thermostatic drying chamber is then placed in, mixture after dehydration is put into Muffle furnace at a temperature of 500 DEG C
5h is roasted, is cooled to room temperature to form Nanocrystal；
Drying is spare to weight after step 4 sterilizes the Nanocrystal of preparation, (uses Rhodospirillaceae bacterium in culture
Isolation medium (Qian Cunrou Huang Yixiu, 1999)) after photosynthetic bacteria, bacillus, in active yeast and nitrobacteria plus
Enter sterile water, then stands 4h after water-bath concussion 50min at a temperature of 35 DEG C, under 300r/min revolving speed, finally obtain the water
Produce cultivation antidote.
Embodiment 3
A kind of aquaculture antidote, the aquaculture antidote are matched as follows by mass fraction: 20 parts of active carbons, 4
Part titanium dioxide, 6 parts of sodium acetates, 8 parts of sodium metasilicate, 3 parts of montmorillonites, 2 parts of aluminum oxides, 35 parts of deionized waters, 20 parts it is anhydrous
Ethyl alcohol, 5 parts of ethyl orthosilicates, 0.1 part of photosynthetic bacteria, 0.06 part of bacillus, 0.02 part of active yeast, 0.04 part of nitrification are thin
Bacterium.
The preparation method of above-mentioned aquaculture antidote, the preparation method comprises the following steps:
Dehydrated alcohol, deionized water are added in reactor and are stirred by step 1, and mixing speed 350r/min is stirred
15min is mixed, ethyl orthosilicate is then added, 45min is stirred under 1500r/min revolving speed, glacial acetic acid is then added, when being added
Stir to get mixed liquor A；
Step 2 mixes active carbon, titanium dioxide, montmorillonite and aluminum oxide, is then ground in the ball mill
Partial size is that 300nm obtains mixture B；
Sodium acetate, sodium metasilicate and mixture B are added into mixed liquor A by step 3, then stir under 1400r/min revolving speed
25min is mixed, 100 DEG C of dry 5h in thermostatic drying chamber is then placed in, mixture after dehydration is put into Muffle furnace at a temperature of 480 DEG C
4h is roasted, is cooled to room temperature to form Nanocrystal；
Drying is spare to weight after step 4 sterilizes the Nanocrystal of preparation, (uses Rhodospirillaceae bacterium in culture
Isolation medium (Qian Cunrou Huang Yixiu, 1999)) after photosynthetic bacteria, bacillus, in active yeast and nitrobacteria plus
Enter sterile water, then stands 3h after water-bath concussion 45min at a temperature of 30 DEG C, under 250r/min revolving speed, finally obtain the water
Produce cultivation antidote.
Comparative example 1
With embodiment 3, difference is not add the specific preparation process of titanium dioxide as follows:
Dehydrated alcohol, deionized water are added in reactor and are stirred by step 1, and mixing speed 350r/min is stirred
15min is mixed, ethyl orthosilicate is then added, 45min is stirred under 1500r/min revolving speed, glacial acetic acid is then added, when being added
Stir to get mixed liquor A；
Step 2 mixes active carbon, montmorillonite and aluminum oxide, and being then ground to partial size in the ball mill is
300nm obtains mixture B；
Sodium acetate, sodium metasilicate and mixture B are added into mixed liquor A by step 3, then stir under 1400r/min revolving speed
25min is mixed, 100 DEG C of dry 5h in thermostatic drying chamber is then placed in, mixture after dehydration is put into Muffle furnace at a temperature of 480 DEG C
4h is roasted, is cooled to room temperature to form Nanocrystal；
Drying is spare to weight after step 4 sterilizes the Nanocrystal of preparation, (uses Rhodospirillaceae bacterium in culture
Isolation medium (Qian Cunrou Huang Yixiu, 1999)) after photosynthetic bacteria, bacillus, in active yeast and nitrobacteria plus
Enter sterile water, then stands 3h after water-bath concussion 45min at a temperature of 30 DEG C, under 250r/min revolving speed, finally obtain the water
Produce cultivation antidote.
Comparative example 2
With embodiment 3, difference is not add sodium metasilicate, and specific preparation process is as follows:
Dehydrated alcohol, deionized water are added in reactor and are stirred by step 1, and mixing speed 350r/min is stirred
15min is mixed, ethyl orthosilicate is then added, 45min is stirred under 1500r/min revolving speed, glacial acetic acid is then added, when being added
Stir to get mixed liquor A；
Step 2 mixes active carbon, titanium dioxide, montmorillonite and aluminum oxide, is then ground in the ball mill
Partial size is that 300nm obtains mixture B；
Sodium acetate and mixture B are added into mixed liquor A by step 3, then stir 25min under 1400r/min revolving speed,
100 DEG C of dry 5h in thermostatic drying chamber are then placed in, mixture after dehydration is put into 480 DEG C of roasting temperature 4h in Muffle furnace,
It is cooled to room temperature to form Nanocrystal；
Drying is spare to weight after step 4 sterilizes the Nanocrystal of preparation, (uses Rhodospirillaceae bacterium in culture
Isolation medium (Qian Cunrou Huang Yixiu, 1999)) after photosynthetic bacteria, bacillus, in active yeast and nitrobacteria plus
Enter sterile water, then stands 3h after water-bath concussion 45min at a temperature of 30 DEG C, under 250r/min revolving speed, finally obtain the water
Produce cultivation antidote.
Embodiment 1-3 and comparative example 1 and comparative example 2 antidote prepared are tested for the property.To Yancheng City aquatic products
Farm is tested, and Example 1-3 and comparative example 1 and comparative example 2 and commercially available aquaculture antidote are respectively with 50g/L
It is put into breeding water body, stirs evenly, after impregnating one end time, then with the water in breeding water body be diluted to 50 kilograms or more,
Even is spread across in 1 mu of water body, then the relevant parameter of periodic detection water body, and concrete outcome is referring to following table.
As can be seen from the above table, after using antidote provided by the invention, water quality has more significant improvement.
The above is only preferred embodiments of the present invention, is not intended to limit the scope of the present invention,
Therefore any trickle amendment, equivalent variations and modification made to the above embodiment according to the technical essence of the invention, belong to
In the range of technical solution of the present invention.
Claims (7)
1. a kind of aquaculture antidote, which is characterized in that the aquaculture antidote is matched as follows by mass fraction: 15-
25 parts of active carbons, 2-6 parts of titanium dioxide, 5-8 parts of sodium acetates, 6-9 parts of sodium metasilicate, 2-4 parts of montmorillonites, 1-3 parts of aluminum oxides,
30-40 parts of deionized waters, 16-25 parts of dehydrated alcohols, 4-6 parts of ethyl orthosilicates, 0.02-0.15 parts of photosynthetic bacterias, 0.05-0.08
Part bacillus, 0.01-0.03 parts of active yeasts, 0.03-0.045 parts of nitrobacterias.
2. a kind of aquaculture antidote according to claim 1, which is characterized in that the aquaculture antidote presses matter
It is as follows to measure number proportion: 20 parts of active carbons, 4 parts of titanium dioxide, 6 parts of sodium acetates, 8 parts of sodium metasilicate, 3 parts of montmorillonites, 2 part of three oxidation
Two aluminium, 35 parts of deionized waters, 20 parts of dehydrated alcohols, 5 parts of ethyl orthosilicates, 0.1 part of photosynthetic bacteria, 0.06 part of bacillus,
0.02 part of active yeast, 0.04 part of nitrobacteria.
3. based on a kind of preparation method of aquaculture antidote described in claim 1, which is characterized in that the preparation method
The following steps are included:
Dehydrated alcohol, deionized water are added in reactor and are stirred by step 1, and mixing speed is 300-450 r/min, are stirred
10-20 min is mixed, ethyl orthosilicate is then added, 40-50 min is stirred under 1450-1600 r/min revolving speed, is then added
Glacial acetic acid stirs while adding to obtain mixed liquor A；
Step 2 mixes active carbon, titanium dioxide, montmorillonite and aluminum oxide, is then ground to partial size in the ball mill
Mixture B is obtained for 200-500 nm；
Sodium acetate, sodium metasilicate and mixture B are added into mixed liquor A by step 3, then stir under 1300-1500r/min revolving speed
20-30 min is mixed, 100 DEG C of dry 5-6 h in thermostatic drying chamber is then placed in, mixture after dehydration is put into 450- in Muffle furnace
500 DEG C of roasting temperature 3-5 h, are cooled to room temperature to form Nanocrystal；
Step 4 dry, photosynthetic bacteria after incubation, gemma bar spare to weight after the Nanocrystal of preparation sterilizes
Sterile water is added in bacterium, active yeast and nitrobacteria, then at a temperature of 25-35 DEG C, 200-300r/min revolving speed is lauched
2-4 h is stood after bath concussion 30-50 min, finally obtains the aquaculture antidote.
4. a kind of aquaculture antidote according to claim 3 and preparation method thereof, which is characterized in that the step 1
Middle that dehydrated alcohol, deionized water are added in reactor and are stirred, mixing speed is 350 r/min, stirs 15 min, then
Ethyl orthosilicate is added, stirs 45 min under 1500 r/min revolving speeds, glacial acetic acid is then added, stirs while adding and is mixed
Close liquid A.
5. a kind of aquaculture antidote according to claim 3 and preparation method thereof, which is characterized in that the step 2
Middle to mix active carbon, titanium dioxide, montmorillonite and aluminum oxide, being then ground to partial size in the ball mill is that 300 nm are obtained
To mixture B.
6. a kind of aquaculture antidote according to claim 3 and preparation method thereof, which is characterized in that the step 3
It is middle that sodium acetate, sodium metasilicate and mixture B are added into mixed liquor A, 25 min then are stirred under 1400 r/min revolving speeds, then
100 DEG C of 5 h of drying in thermostatic drying chamber are put into, mixture after dehydration is put into Muffle furnace 480 DEG C of roasting temperature 4 h, it is cold
But Nanocrystal is formed to room temperature.
7. a kind of aquaculture antidote according to claim 3 and preparation method thereof, which is characterized in that the step 4
The middle Nanocrystal by preparation dry, photosynthetic bacteria, bacillus, active dry yeasr after incubation spare to weight after sterilizing
Sterile water is added in bacterium and nitrobacteria, then water-bath is stood after shaking 45 min at a temperature of 30 DEG C, under 250 r/min revolving speeds
3 h finally obtain the aquaculture antidote.
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| CN117814267A (en) * | 2024-02-29 | 2024-04-05 | 山东夙沙高科生物有限公司 | Botanical fungicide, preparation method and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6227036A (en) * | 1985-07-23 | 1987-02-05 | バイエル・アクチエンゲゼルシヤフト | Aqueous suspension of lumpy substance and its production anduse |
| CN104961242A (en) * | 2015-06-18 | 2015-10-07 | 成都八八五生物科技发展有限公司 | Water quality improver |
| CN105540874A (en) * | 2016-02-29 | 2016-05-04 | 苏州市相城区阳澄湖镇剑成水产生态养殖专业合作社 | Water quality modifying agent for aquaculture |
| CN107138129A (en) * | 2017-04-19 | 2017-09-08 | 句容市百诚活性炭有限公司 | Bacteriostatic activated carbon composition and preparation method thereof |
| CN107162218A (en) * | 2017-06-30 | 2017-09-15 | 合肥卓畅农业科技有限公司 | It is a kind of for water quality cleansing agent of fishery cultivating and preparation method thereof |
-
2018
- 2018-12-29 CN CN201811653111.7A patent/CN109626593A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6227036A (en) * | 1985-07-23 | 1987-02-05 | バイエル・アクチエンゲゼルシヤフト | Aqueous suspension of lumpy substance and its production anduse |
| CN104961242A (en) * | 2015-06-18 | 2015-10-07 | 成都八八五生物科技发展有限公司 | Water quality improver |
| CN105540874A (en) * | 2016-02-29 | 2016-05-04 | 苏州市相城区阳澄湖镇剑成水产生态养殖专业合作社 | Water quality modifying agent for aquaculture |
| CN107138129A (en) * | 2017-04-19 | 2017-09-08 | 句容市百诚活性炭有限公司 | Bacteriostatic activated carbon composition and preparation method thereof |
| CN107162218A (en) * | 2017-06-30 | 2017-09-15 | 合肥卓畅农业科技有限公司 | It is a kind of for water quality cleansing agent of fishery cultivating and preparation method thereof |
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| CN117814267A (en) * | 2024-02-29 | 2024-04-05 | 山东夙沙高科生物有限公司 | Botanical fungicide, preparation method and application |
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Application publication date: 20190416 |