CN109609289A - A kind of calcined shell calcium powder fruits and vegetables cleaning powder and preparation method thereof - Google Patents

A kind of calcined shell calcium powder fruits and vegetables cleaning powder and preparation method thereof Download PDF

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Publication number
CN109609289A
CN109609289A CN201910070739.2A CN201910070739A CN109609289A CN 109609289 A CN109609289 A CN 109609289A CN 201910070739 A CN201910070739 A CN 201910070739A CN 109609289 A CN109609289 A CN 109609289A
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powder
shell calcium
fruits
shell
calcium powder
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李东
李东一
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/1233Carbonates, e.g. calcite or dolomite
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/384Animal products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Zoology (AREA)
  • Molecular Biology (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of calcined shell calcium powder fruits and vegetables cleaning powders, including following component (by mass percentage): shell calcium powder 35-60%, walnut powder 6-12%, almond powder 4-8%, potassium carbonate 3-7%, potassium sorbate 1.85-5.63%, auxiliary additive are surplus;The invention also discloses a kind of preparation methods of calcined shell calcium powder fruits and vegetables cleaning powder, comprising the following steps: prepares shell calcium powder, preparation mixing addition powder and obtained fruits and vegetables cleaning powder;Formula of the invention is more scientific and reasonable, the fruits and vegetables cleaning powder can play the role of good absorption, degrading pesticide, and product efficacy is strong, can achieve very high pesticide clearance rate, absolutely pathogen clearance rate, suitable for the cleaning of various gourd, fruit and vegetables, and organic chemical reagent is not contained in the cleaning powder, feedstock processing and preparation process are simple, it is easy to spread with it is universal, whole people's healthy diet safety is improved, it is without secondary pollution after washing, efficiently use waste resource.

Description

A kind of calcined shell calcium powder fruits and vegetables cleaning powder and preparation method thereof
Technical field
The present invention relates to fruits and vegetables cleaning technique field, specially a kind of calcined shell calcium powder fruits and vegetables cleaning powder and its preparation side Method.
Background technique
Existing fruits and vegetables cleaning agent, mostly chemical synthesis, although dirt-removing power is relatively strong, since chemically synthesized product is not easy Degradation, impacts environment, in addition its secondary cleaning is also difficult to thoroughly, is easy to cause harm to the human body if being used for a long time;For This, it is proposed that a kind of calcined shell calcium powder fruits and vegetables cleaning powder and preparation method thereof.
Summary of the invention
The purpose of the present invention is to provide a kind of calcined shell calcium powder fruits and vegetables cleaning powders and preparation method thereof, to solve background The problem of technology proposes.
To achieve the above object, the invention provides the following technical scheme: a kind of calcined shell calcium powder fruits and vegetables cleaning powder, including Following component (by mass percentage): shell calcium powder 35-60%, walnut powder 6-12%, almond powder 4-8%, potassium carbonate 3- 7%, natrium malicum 4.5-8.6%, methylhydroxypropylcellulose 2.1-6.7%, potassium sorbate 1.85-5.63%, auxiliary addition Agent is surplus.
Preferably, including following component (by mass percentage): shell calcium powder 60%, walnut powder 6%, almond powder 4%, Potassium carbonate 3%, natrium malicum 4.5%, methylhydroxypropylcellulose 2.1%, potassium sorbate 1.85%, auxiliary additive are remaining Amount.
Preferably, including following component (by mass percentage): shell calcium powder 50%, walnut powder 8%, almond powder 6%, Potassium carbonate 5%, natrium malicum 6.5%, methylhydroxypropylcellulose 4.8%, potassium sorbate 3.68%, auxiliary additive are remaining Amount.
Preferably, including following component (by mass percentage): shell calcium powder 40%, walnut powder 12%, almond powder 8%, potassium carbonate 7%, natrium malicum 8.6%, methylhydroxypropylcellulose 6.7%, potassium sorbate 5.63%, auxiliary additive are Surplus.
Preferably, the potassium carbonate is extracted in the plant ash being burnt by various plants shell, is separated using the method for filtering Be made out, the plant shell be cotton seed hulls, ribes shell, seeds of a tung oil tree shell, sunflower seed shell it is one or more.
Preferably, the auxiliary additive includes surfactant and synergist, and the ratio of the two is 1:2, described auxiliary Helping additive is one of lauryl sodium sulfate, neopelex, and the synergist is sodium bicarbonate, sodium carbonate One of.
A kind of preparation method of calcined shell calcium powder fruits and vegetables cleaning powder as described above, comprising the following steps:
Step 1: it prepares shell calcium powder: being added to after shell is cleaned up in dryer and dry 60-80 minutes, then Crushing, ball milling are taken out, 200-400 mesh is crossed and obtains conch meal, conch meal is calcined into 120-180 under conditions of 900-1500 DEG C Minute, obtain shell calcium powder;
Step 2: preparation mixing addition powder: prepare walnut, almond is added separately to dry in dryer after cleaning up 40-60 minutes, crushing, ball milling are then taken out, 200-400 mesh is crossed and obtains walnut powder and almond powder, by walnut powder and almond powder It is mixed and stirred for uniformly, obtaining mixing addition powder;
Step 3: shell calcium powder is mixed with addition powder is mixed, then sequentially adds potassium carbonate, malic acid in proportion Sodium, methylhydroxypropylcellulose, potassium sorbate and auxiliary additive, and be mixed evenly, the product obtained after mixing is micro- Powder can be obtained shell calcium powder fruits and vegetables cleaning powder.
Compared with prior art, the beneficial effects of the present invention are: formula of the invention is more scientific and reasonable, the fruit-vegetable clear Powder is washed, by the way that walnut powder using shell calcium powder as primary raw material, is added, almond powder is auxiliary material, can play good absorption, degradation The effect of pesticide, the addition of potassium carbonate, natrium malicum and methylhydroxypropylcellulose, reach very high at the effect of enhancing product Pesticide clearance rate, absolutely pathogen clearance rate, suitable for the cleaning of various gourd, fruit and vegetables, and in the cleaning powder not Containing organic chemical reagent, feedstock processing and preparation process are simple, it is easy to spread with it is universal, improve the whole people's healthy diet safety, It is without secondary pollution after washing, efficiently use waste resource.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described, Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of calcined shell calcium powder fruits and vegetables cleaning powder, including following component (by mass percentage): shell calcium powder 60%, Walnut powder 6%, almond powder 4%, potassium carbonate 3%, natrium malicum 4.5%, methylhydroxypropylcellulose 2.1%, potassium sorbate 1.85%, auxiliary additive is surplus.
Further, potassium carbonate is extracted in the plant ash being burnt by various plants shell, is isolated using the method for filtering It is made, plant shell is cotton seed hulls and two kinds of ribes shell.
Further, auxiliary additive includes surfactant and synergist, and the ratio of the two is 1:2, auxiliary addition Agent is lauryl sodium sulfate, and synergist is sodium bicarbonate.
A kind of preparation method of calcined shell calcium powder fruits and vegetables cleaning powder, comprising the following steps:
Step 1: it prepares shell calcium powder: being added in dryer and dry 60 minutes after shell is cleaned up, then take out It crushes, ball milling, crosses 200 meshes and obtain conch meal, conch meal is calcined 120 minutes under conditions of 1000 DEG C, obtains shell calcium Powder;
Step 2: preparation mixing addition powder: prepare walnut, almond is added separately to dry in dryer after cleaning up 40 minutes, crushing, ball milling are then taken out, 200 meshes is crossed and obtains walnut powder and almond powder, walnut powder and almond powder are mixed and stirred It mixes uniformly, obtains mixing addition powder;
Step 3: shell calcium powder is mixed with addition powder is mixed, then sequentially adds potassium carbonate, malic acid in proportion Sodium, methylhydroxypropylcellulose, potassium sorbate and auxiliary additive, and be mixed evenly, the product obtained after mixing is micro- Powder can be obtained shell calcium powder fruits and vegetables cleaning powder.
Embodiment two:
A kind of calcined shell calcium powder fruits and vegetables cleaning powder, including following component (by mass percentage): shell calcium powder 50%, Walnut powder 8%, almond powder 6%, potassium carbonate 5%, natrium malicum 6.5%, methylhydroxypropylcellulose 4.8%, potassium sorbate 3.68%, auxiliary additive is surplus.
Further, potassium carbonate is extracted in the plant ash being burnt by various plants shell, is isolated using the method for filtering It is made, plant shell is seeds of a tung oil tree shell and two kinds of sunflower seed shell.
Further, auxiliary additive includes surfactant and synergist, and the ratio of the two is 1:2, auxiliary addition Agent is neopelex, and synergist is sodium carbonate.
A kind of preparation method of calcined shell calcium powder fruits and vegetables cleaning powder, comprising the following steps:
Step 1: it prepares shell calcium powder: being added in dryer and dry 70 minutes after shell is cleaned up, then take out It crushes, ball milling, crosses 400 meshes and obtain conch meal, conch meal is calcined 140 minutes under conditions of 1200 DEG C, obtains shell calcium Powder;
Step 2: preparation mixing addition powder: prepare walnut, almond is added separately to dry in dryer after cleaning up 50 minutes, crushing, ball milling are then taken out, 400 meshes is crossed and obtains walnut powder and almond powder, walnut powder and almond powder are mixed and stirred It mixes uniformly, obtains mixing addition powder;
Step 3: shell calcium powder is mixed with addition powder is mixed, then sequentially adds potassium carbonate, malic acid in proportion Sodium, methylhydroxypropylcellulose, potassium sorbate and auxiliary additive, and be mixed evenly, the product obtained after mixing is micro- Powder can be obtained shell calcium powder fruits and vegetables cleaning powder.
Embodiment three:
A kind of calcined shell calcium powder fruits and vegetables cleaning powder, including following component (by mass percentage): shell calcium powder 40%, Walnut powder 12%, almond powder 8%, potassium carbonate 7%, natrium malicum 8.6%, methylhydroxypropylcellulose 6.7%, potassium sorbate 5.63%, auxiliary additive is surplus.
Further, potassium carbonate is extracted in the plant ash being burnt by various plants shell, is isolated using the method for filtering It is made, plant shell is cotton seed hulls, ribes shell and three kinds of seeds of a tung oil tree shell.
Further, auxiliary additive includes surfactant and synergist, and the ratio of the two is 1:2, auxiliary addition Agent is neopelex, and synergist is sodium bicarbonate.
A kind of preparation method of calcined shell calcium powder fruits and vegetables cleaning powder, comprising the following steps:
Step 1: it prepares shell calcium powder: being added in dryer and dry 80 minutes after shell is cleaned up, then take out It crushes, ball milling, crosses 400 meshes and obtain conch meal, conch meal is calcined 180 minutes under conditions of 1400 DEG C, obtains shell calcium Powder;
Step 2: preparation mixing addition powder: prepare walnut, almond is added separately to dry in dryer after cleaning up 60 minutes, crushing, ball milling are then taken out, 400 meshes is crossed and obtains walnut powder and almond powder, walnut powder and almond powder are mixed and stirred It mixes uniformly, obtains mixing addition powder;
Step 3: shell calcium powder is mixed with addition powder is mixed, then sequentially adds potassium carbonate, malic acid in proportion Sodium, methylhydroxypropylcellulose, potassium sorbate and auxiliary additive, and be mixed evenly, the product obtained after mixing is micro- Powder can be obtained shell calcium powder fruits and vegetables cleaning powder.
Shell calcium powder fruits and vegetables cleaning powder can be made in above three groups of embodiments, and formula of the invention more science is closed Reason, the fruits and vegetables cleaning powder can be played good by the way that walnut powder, almond powder using shell calcium powder as primary raw material, is added as auxiliary material Absorption, degrading pesticide effect, the addition of potassium carbonate, natrium malicum and methylhydroxypropylcellulose enhances the function of product Effect, reaches very high pesticide clearance rate, absolutely pathogen clearance rate, suitable for the cleaning of various gourd, fruit and vegetables, and In the cleaning powder do not contain organic chemical reagent, feedstock processing and preparation process are simple, it is easy to spread with it is universal, improve the whole people drink Eat healthy and safe, without secondary pollution after washing, effective use waste resource.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (7)

1. a kind of calcined shell calcium powder fruits and vegetables cleaning powder, which is characterized in that including following component (by mass percentage): shell Calcium powder 35-60%, walnut powder 6-12%, almond powder 4-8%, potassium carbonate 3-7%, natrium malicum 4.5-8.6%, methylhydroxypropyl Cellulose 2.1-6.7%, potassium sorbate 1.85-5.63%, auxiliary additive are surplus.
2. a kind of calcined shell calcium powder fruits and vegetables cleaning powder according to claim 1, which is characterized in that including following component (by mass percentage): shell calcium powder 60%, walnut powder 6%, almond powder 4%, potassium carbonate 3%, natrium malicum 4.5%, first Base hydroxypropyl cellulose 2.1%, potassium sorbate 1.85%, auxiliary additive are surplus.
3. a kind of calcined shell calcium powder fruits and vegetables cleaning powder according to claim 1, which is characterized in that including following component (by mass percentage): shell calcium powder 50%, walnut powder 8%, almond powder 6%, potassium carbonate 5%, natrium malicum 6.5%, first Base hydroxypropyl cellulose 4.8%, potassium sorbate 3.68%, auxiliary additive are surplus.
4. a kind of calcined shell calcium powder fruits and vegetables cleaning powder according to claim 1, which is characterized in that including following component (by mass percentage): shell calcium powder 40%, walnut powder 12%, almond powder 8%, potassium carbonate 7%, natrium malicum 8.6%, first Base hydroxypropyl cellulose 6.7%, potassium sorbate 5.63%, auxiliary additive are surplus.
5. a kind of calcined shell calcium powder fruits and vegetables cleaning powder according to any one of claims 1-4, it is characterised in that: described Potassium carbonate is extracted in the plant ash being burnt by various plants shell, is isolated using the method for filtering obtained, and the plant shell is Cotton seed hulls, ribes shell, seeds of a tung oil tree shell, sunflower seed shell it is one or more.
6. a kind of calcined shell calcium powder fruits and vegetables cleaning powder according to any one of claims 1-4, it is characterised in that: described Auxiliary additive includes surfactant and synergist, and the ratio of the two is 1:2, and the auxiliary additive is dodecyl sulphur One of sour sodium, neopelex, the synergist are one of sodium bicarbonate, sodium carbonate.
7. a kind of preparation method of calcined shell calcium powder fruits and vegetables cleaning powder as claimed in any one of claims 1 to 6, feature It is, comprising the following steps:
Step 1: it prepares shell calcium powder: being added in dryer and dry 60-80 minutes after shell is cleaned up, then take out It crushes, ball milling, crosses 200-400 mesh and obtain conch meal, conch meal is calcined to 120-180 points under conditions of 900-1500 DEG C Clock obtains shell calcium powder;
Step 2: preparation mixing addition powder: prepare walnut, almond is added separately to dry 40- in dryer after cleaning up 60 minutes, crushing, ball milling are then taken out, 200-400 mesh is crossed and obtains walnut powder and almond powder, walnut powder and almond powder are mixed And stir evenly, obtain mixing addition powder;
Step 3: shell calcium powder is mixed with addition powder is mixed, then sequentially adds potassium carbonate, natrium malicum, first in proportion Base hydroxypropyl cellulose, potassium sorbate and auxiliary additive, and be mixed evenly, the product micro mist that will be obtained after mixing, i.e., It can get shell calcium powder fruits and vegetables cleaning powder.
CN201910070739.2A 2019-01-25 2019-01-25 A kind of calcined shell calcium powder fruits and vegetables cleaning powder and preparation method thereof Pending CN109609289A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110951554A (en) * 2019-11-06 2020-04-03 高万东 Deoiling plant laundry detergent and preparation method thereof
CN115404132A (en) * 2022-09-06 2022-11-29 洁美来(山东)生态科技有限公司 Ecological detergent powder production method and ecological detergent powder

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102296007A (en) * 2011-07-25 2011-12-28 彭旗 Fruit and vegetable cleaning powder and its preparation method
CN105132208A (en) * 2015-09-11 2015-12-09 舟山赛莱特海洋科技有限公司 Ocean micro-nano fruit and vegetable washing detergent and preparation method thereof
CN106318691A (en) * 2016-08-08 2017-01-11 吴敬华 Ultrafine calcium powder-containing bacteriostasis liquid detergent and preparation method thereof
CN106434028A (en) * 2016-09-23 2017-02-22 王泽铭 Fruit and vegetable washing salt for removing pesticide residues and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102296007A (en) * 2011-07-25 2011-12-28 彭旗 Fruit and vegetable cleaning powder and its preparation method
CN105132208A (en) * 2015-09-11 2015-12-09 舟山赛莱特海洋科技有限公司 Ocean micro-nano fruit and vegetable washing detergent and preparation method thereof
CN106318691A (en) * 2016-08-08 2017-01-11 吴敬华 Ultrafine calcium powder-containing bacteriostasis liquid detergent and preparation method thereof
CN106434028A (en) * 2016-09-23 2017-02-22 王泽铭 Fruit and vegetable washing salt for removing pesticide residues and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110951554A (en) * 2019-11-06 2020-04-03 高万东 Deoiling plant laundry detergent and preparation method thereof
CN115404132A (en) * 2022-09-06 2022-11-29 洁美来(山东)生态科技有限公司 Ecological detergent powder production method and ecological detergent powder
CN115404132B (en) * 2022-09-06 2023-07-21 洁美来(山东)生态科技有限公司 Ecological cleaning powder raw material crushing device

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