CN109604296A - The processing method of living marine resources - Google Patents
The processing method of living marine resources Download PDFInfo
- Publication number
- CN109604296A CN109604296A CN201811067967.6A CN201811067967A CN109604296A CN 109604296 A CN109604296 A CN 109604296A CN 201811067967 A CN201811067967 A CN 201811067967A CN 109604296 A CN109604296 A CN 109604296A
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- China
- Prior art keywords
- marine resources
- living marine
- living
- processing method
- heavy metal
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- 238000003672 processing method Methods 0.000 title claims abstract description 38
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 60
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 43
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 40
- 241001474374 Blennius Species 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 238000010438 heat treatment Methods 0.000 claims abstract description 21
- 235000015170 shellfish Nutrition 0.000 claims abstract description 18
- 239000013535 sea water Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 238000004090 dissolution Methods 0.000 abstract description 33
- 230000002401 inhibitory effect Effects 0.000 abstract description 8
- 238000001035 drying Methods 0.000 description 12
- 239000002699 waste material Substances 0.000 description 11
- 229910052793 cadmium Inorganic materials 0.000 description 8
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 241000251468 Actinopterygii Species 0.000 description 6
- 241000195474 Sargassum Species 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 238000011010 flushing procedure Methods 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052711 selenium Inorganic materials 0.000 description 4
- 239000011669 selenium Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 210000004347 intestinal mucosa Anatomy 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 210000001835 viscera Anatomy 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000238586 Cirripedia Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241001147138 Mytilus galloprovincialis Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229940067573 brown iron oxide Drugs 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000013008 moisture curing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- -1 reduced iron powder Chemical compound 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The object of the present invention is to provide a kind of processing methods of living marine resources, can relatively easily generate the living marine resources for inhibiting the amount of dissolution of heavy metal.The present invention is the processing method of the living marine resources of mixed seaweeds or shellfish in water intaking containing seawater, wherein, the process of mixture after having the process of the mixture-metal insolubilizing agent in the above-mentioned living marine resources containing moisture, and dry above-mentioned mixed processes.The processing method of the living marine resources can be also equipped with the process for heating the above-mentioned living marine resources containing moisture before above-mentioned mixed processes.Above-mentioned living marine resources can contain arsenic.Above-mentioned heavy metal insolubilizing agent can be iron powder.
Description
Technical field
The present invention relates to the processing methods of living marine resources.
Background technique
Seawater for obtaining salt and alkali metal etc. raw material, domestic water, water ballast and in terms of use.
When obtaining seawater, according to water intaking period, water intaking place, the case where being mixed into various living marine resources.As sea
Water mixed living marine resources in water intaking, can enumerate seaweeds, shellfish.
Seawater these mixed living marine resources when fetching water, generally as trade waste processing.Living marine resources
When processed as trade waste, for the purpose of reducing volume and inhibit rancid, living marine resources can be implemented at dry
Reason.
Known seaweeds largely contains arsenic, includes arsenic, cadmium, Cr VI in the shellfish meat of shellfish, internal organ or mid intestinal gland (ウ ロ)
Deng.In addition, the arsenic the amount of dissolution of living marine resources has the tendency that increase if the arsenic content of living marine resources is more.Therefore, extra large
When foreign living resources largely contain arsenic, the arsenic the amount of dissolution of the living marine resources after drying can be more than that can be used as industrial waste
The discarded de jure standards value of object.
Arsenic in living marine resources dissolves out in water when living marine resources are impregnated in water.Therefore, if adopted
With for example by after the boiled water of living marine resources investment boiling, to the processing that the living marine resources are washed, then ocean is raw
The arsenic content in goods and materials source is reduced.But when using this processing, the huge energy is needed to prepare boiled water, in addition, also needing
Will for after the use containing arsenic boiled water and flushing water post-process.
On the other hand, the processing side for having fish and shellfish waste that mushroom is added in fish and shellfish waste is proposed
Method (patent document 1).Patent document 1 thinks, is added to vulcanization bacterium in fish and shellfish waste, Nitromonas, Nitrosomas,
The arsenic in fish and shellfish waste and cadmium decomposition will be remained in, and will be discharged into atmosphere by the arsenic and cadmium decomposed, thus
The heavy metal classes in fish and shellfish waste can be removed.But the processing method of patent document 1, it needs to carry out for making
The activity of mushroom keeps active temperature management, furthermore needs to spend the great time in processing.
[existing technical literature]
[patent document]
[patent document 1] Japanese Unexamined Patent Publication 10-114589 bulletin
Summary of the invention
It is done the present invention is based on above-mentioned such situation, it is intended that providing a kind of processing side of living marine resources
Method can relatively easily generate the living marine resources for inhibiting the amount of dissolution of heavy metal classes.
The invention done in order to solve the above problems is the sea containing seaweeds mixed in the water intaking of seawater or shellfish
The processing method of foreign living resources, wherein have following process: a huge sum of money is mixed in the above-mentioned living marine resources containing moisture
Belong to the process of class insolubilizing agent；With the process of the mixture after the above-mentioned mixed processes of drying.
About the heavy metal classes for including in living marine resources, since living marine resources contain moisture, so in the water
Dissolution in point.In the processing method of the living marine resources, mixed in the living marine resources of the state of moisture content because having
The process for closing heavy metal classes insolubilizing agent dissolves out so heavy metal classes are dissolved out from living marine resources into moisture into moisture
The heavy metal classes it is insoluble.Moreover, the processing method of the living marine resources, because making the thawless state of heavy metal classes
Under, dry mixed has the living marine resources of heavy metal classes insolubilizing agent, so the too many energy and flushing water are not needed, it can
Relatively easily generate the living marine resources for inhibiting the amount of dissolution of heavy metal classes.
The processing method of the living marine resources can be also equipped with the above-mentioned of heating aqueous point before above-mentioned mixed processes
The process of living marine resources.The processing method of the living marine resources as a result, by the weight that living marine resources are greatly decreased
The content of metal class keeps the heavy metal classes dissolved out to moisture insoluble, sufficiently inhibits the molten of heavy metal classes so as to generate
The living marine resources of output.
Above-mentioned living marine resources can contain arsenic.The processing method of the living marine resources as a result, can generate inhibition
The living marine resources of the amount of dissolution of arsenic.
Above-mentioned heavy metal classes insolubilizing agent can be iron powder.Other than arsenic, iron can also be made by absorption lead, cadmium,
Cr VI, selenium etc. are insoluble, therefore the processing method of the living marine resources can generate and inhibit the molten of these heavy metal classes
The living marine resources of output.
The processing method of living marine resources of the invention can relatively easily generate the dissolution for inhibiting heavy metal classes
The living marine resources of amount.
Detailed description of the invention
Fig. 1 is the flow chart for illustrating the processing method of living marine resources of an embodiment of the invention.
Specific embodiment
Hereinafter, the embodiment of the processing method of living marine resources of the invention is described in detail.
The processing method of the living marine resources is the ocean containing seaweeds mixed in the water intaking of seawater or shellfish
The processing method of living resources, as shown in Figure 1, having following process: the heating process of the living marine resources of heating aqueous point
S1；The mixed processes S2 of mixture-metal class insolubilizing agent in the living marine resources of moisture content；With dry mixed process S2
The drying process S3 of mixture afterwards.Here, the living marine resources of so-called moisture content, indicate unseasoned, be attached with seawater or
The living marine resources of the state of flushing water.
< heating process >
Heating process S1 is the process of the living marine resources of the state of heating aqueous point, in order to promote marine organisms to provide
The heavy metal classes for including in source are implemented to the dissolution of moisture.The heating of the living marine resources of moisture content is not particularly limited,
Such as can be used the absorption bring heat release of sunlight, the combustion heat of fossil fuel, factory from power plant etc. heat extraction,
Heat etc..
(living marine resources)
The living marine resources as process object of the processing method of the living marine resources, are mixed into when being extracting seawater
The living marine resources containing seaweeds or shellfish, such as can enumerate marine floating seaweeds, be attached to water fetching device
Shellfish in water route, hole pond or piping.These living marine resources are taken out from seawater in water intaking or after water intaking, but are deposited
Largely include the heavy metal classes of arsenic, lead, cadmium, sexivalent chromium, selenium etc. as harmful substance the case where.For example, knowing sargassum fusifome
With largely contain arsenic in the seaweeds of Sargassum etc., it is big in the shellfish meat of the shellfish of barnacle and Mytilus galloprovincialis etc., internal organ or mid intestinal gland
Amount contains arsenic, cadmium, Cr VI etc..The processing method of the living marine resources, as process object, if these is selected largely to contain
The living marine resources of heavy metal classes, then particularly preferably.In addition, living marine resources, containing in seaweeds or shellfish at least
One, but also may include the marine organisms such as fish in addition to this.
The lower limit of holding temperature when living marine resources as heating aqueous in heating process S1 point, preferably 30
DEG C, more preferably 35 DEG C, further preferably 40 DEG C.On the other hand, preferably 100 DEG C, more excellent as the upper limit for keeping temperature
It is selected as 80 DEG C, further preferably 70 DEG C.If temperature is kept to be lower than above-mentioned lower limit, heavy metal classes contained by living marine resources
Dissolution to moisture is possible to not to be promoted.Conversely, if temperature is kept to be higher than the above-mentioned upper limit, it is likely that need excessively high add
Thermal energy.
Heating process S1, the type of the heavy metal classes according to contained by living marine resources, the amount of heavy metal classes and be suitable for real
It applies, the huge sum of money when solubility of heavy metal classes contained in living marine resources to water is high or contained in living marine resources
When belonging to the amount of class less, it can not also implement.
< mixed processes >
Mixed processes S2 is the process of the mixture-metal class insolubilizing agent in the living marine resources of moisture content, in order to
Keep the heavy metal classes dissolved out from living marine resources into moisture insoluble and implements.For moisture content living marine resources with
The mixing of heavy metal classes insolubilizing agent is not particularly limited, such as can take the method with batch mixing machine, or to transport dress
In the living marine resources for setting the moisture content into conveying, the method for heavy metal classes insolubilizing agent is continuously supplied by feed hopper.
(heavy metal classes insolubilizing agent)
Heavy metal classes insolubilizing agent is to possess the additive for making to dissolve out the insoluble this function of the heavy metal classes in moisture.
As heavy metal classes insolubilizing agent, such as iron powder, curing agent, ferric trichloride, aluminium polychloride can be used etc..As above-mentioned solidification
Agent has the curing agent of lime, magnesia system, cement system etc..But it when using curing agent, needs before with moisture-curing
It dissolves out heavy metal classes from living marine resources, when using ferric trichloride and more conjunction aluminium chloride, needs to hold them in liquid
The state of body, until it is co-precipitated with heavy metal classes.On the other hand, iron powder is not needing particularly to operate, and can
It will be adsorbed together with the heavy metal classes such as arsenic and lead, cadmium, sexivalent chromium, selenium and be allowed to insoluble.Therefore, if being used for the living marine resources
The heavy metal classes insolubilizing agent of processing method be iron powder, then particularly preferably.
When using iron powder as heavy metal classes insolubilizing agent, as the iron powder, such as reduced iron powder, atomization iron can be used
Powder, powdered alloy steel, brown iron oxide or pulverized slag.Metal but from the viewpoint of the adsorption capacity of heavy metal classes, in iron powder
The content of iron, preferably 80 mass % or more, more preferably 90 mass % or more.Here, so-called metallic iron, indicates that valence mumber is 0
State iron.
The average grain diameter of iron powder as heavy metal classes insolubilizing agent to the adsorption capacity of heavy metal classes and is mixed based on iron powder
The considerations of ease for operation of conjunction, selects.The lower limit of average grain diameter as iron powder, preferably 0.02mm, more preferably
0.07mm, further preferably 0.10mm.On the other hand, the upper limit as the average grain diameter of iron powder, preferably 1mm, more preferably
For 0.8mm, further preferably 0.5mm.If the average grain diameter of iron powder is lower than above-mentioned lower limit, in the marine organisms containing moisture
Processing when mixing iron powder in resource is possible to become difficult.Conversely, if the average grain diameter of iron powder is higher than the above-mentioned upper limit, iron powder
Specific surface area become smaller, the ability for adsorbing heavy metal classes is likely to decrease.In addition, the average grain diameter of iron powder, e.g. according to by
Size distribution that the particle size distribution measurement device of laser diffraction formula is measured and the volume average particle size (D50) acquired.
The additive amount of iron powder as heavy metal classes insolubilizing agent, based on iron powder to the adsorption capacity and economy of heavy metal classes
The considerations of property and select.As the lower limit of iron powder and the mixing ratio of living marine resources, in terms of quality standard, preferably 1:50,
More preferably 1:30, further preferably 1:20.On the other hand, the upper limit as above-mentioned mixing ratio, preferably 2:1, more preferably
For 1.5:1, further preferably 1:1.If above-mentioned mixing ratio is lower than above-mentioned lower limit, iron powder to the adsorption capacities of heavy metal classes not
Foot, it is possible to heavy metal classes can not be inhibited after drying process S3 from the dissolution of living marine resources.Conversely, if above-mentioned mixing ratio is high
In the above-mentioned upper limit, then increase for the amount of mixed iron powder, cost is possible to excessive.
< drying process >
Drying process S3 is the process of the mixture after dry mixed process S2, and it is insoluble to be mixed with heavy metal classes with reduction
The volume of the living marine resources of agent and inhibition are rancid to be implemented for mesh.The drying of mixture is not particularly limited, such as
The batch drying machine of oven etc. or the continuous drier of rotary furnace etc. can be used.Mixture is to eliminate water by dry
The dry product divided.
Dry product after drying process S3 can be filled into container bag or charging basket or directly put into the railway carriage of truck,
Disposal site is transported to when being dropped as trade waste, when being recycled as the extraction former material of effective component, fertilizer or feed,
It is transported to recovery plant.
(advantage)
The processing method of the living marine resources mixes a huge sum of money because having in the living marine resources of aqueous isloation state
Belong to the mixed processes S2 of class insolubilizing agent, so making in the state of dissolving out heavy metal classes from living marine resources to moisture
The heavy metal classes dissolved out in moisture are insoluble.Moreover, because of the processing method of the living marine resources, in drying process S,
Dry mixed has the living marine resources of heavy metal classes insolubilizing agent in the state of keeping heavy metal classes insoluble, so not needing
The too many energy and flushing water can relatively easily generate the living marine resources for inhibiting the amount of dissolution of heavy metal classes.
In addition, the processing method of the living marine resources, because having before mixed processes S2 by the ocean of moisture content
The heating process S1 that living resources are heated passes through so the content of the heavy metal classes of living marine resources is greatly decreased
The heavy metal classes for making to dissolve out in moisture are insoluble, so as to generate the ocean life for the amount of dissolution for sufficiently inhibiting heavy metal classes
Goods and materials source.
The especially processing method of the living marine resources, as heavy metal classes insolubilizing agent use iron powder, in addition to arsenic with
Outside, additionally it is possible to keep lead, cadmium, sexivalent chromium, selenium etc. insoluble using the suction-operated of iron.Therefore, the processing of the living marine resources
Method can generate the living marine resources that the amount of dissolution of the various heavy metal classes including arsenic is inhibited.
It is generated by the processing method of the living marine resources, it is suppressed that the living marine resources of the amount of dissolution of heavy metal classes,
It acts not only as trade waste to discard, and if meeting the condition needed, is also used as vitamin, minerals, food
The extraction former material of the effective component of fibres etc., the fertilizer in field or the feed of animal are recycled.Therefore, the marine organisms
The processing method of resource also has and can aid in a possibility that reducing carrying capacity of environment.
< others embodiment >
The processing method of living marine resources of the invention, is not limited to above embodiment.
In the above-described embodiment, the marine organisms for being divided before mixed processes S2 with heating process S1 heating aqueous
The mode of resource is illustrated, still, the heating time of the living marine resources of moisture content, can also be in mixed processes S2
It afterwards, can also be before drying process S3, after having heating mixed processes S2 for example, in the processing method of living marine resources
The process of mixture.But heavy metal classes make again from the dissolution of living marine resources and by heavy metal classes insolubilizing agent when heating
The insoluble of metal class needs the regular hour, therefore from the viewpoint of time efficiency, preferably such as above embodiment in this way,
The living marine resources of heating aqueous point before mixed processes S2.
[embodiment]
Hereinafter, the present invention is described in more detail by embodiment, but the present invention is not limited by these embodiments.
[heat run]
Firstly, the method for inspection (Showa Environmental Agency's bulletin in 48 years the 13rd examination based on metal contained by trade waste etc.
Test), measure the arsenic the amount of dissolution of the seaweed of Sargassum.The arsenic the amount of dissolution of seaweed is 1.2mg/L.
Secondly, putting into the seaweed of the Sargassum of aqueous isloation state in the boiled water 5000g for making pure water boil to 100 DEG C
100g is kept for 120 minutes with 100 DEG C of state.Later, it by from the flushing water that the seaweed taken out in boiled water puts into 25 DEG C, protects
It holds 3 minutes.Seaweed after washing is inserted into 180 DEG C of constant temperature oven, it is 30 minutes dry.If the arsenic for measuring boiled water and flushing water is dense
It spends, then respectively 0.72mg/L and 0.008mg/L.In addition, the quality of the seaweed after dry is 43g.In addition, being based on Showa 48 years
Environmental Agency's bulletin the 13rd test, the arsenic the amount of dissolution of the seaweed after measurement is dry as a result, arsenic the amount of dissolution is 0.06mg/L.
[test of No.1~No.4]
By the seaweed 100g of the Sargassum of aqueous isloation state and the iron powder of various amounts on square flat chassis (バ ッ ト: vat)
After evenly mixing, which is inserted into 105 DEG C of constant temperature oven, it is 6 hours dry.Later, it is based on Showa Environmental Agency's bulletin in 48 years
No. 13 test, measures the arsenic the amount of dissolution of dried object.The weight and drying of seaweed state, the iron powder mixed with seaweed before processing
The arsenic the amount of dissolution of object is shown in table 1.In addition, No.4 is the test of unmixed iron powder.
[test of No.5~No.8]
The seaweed 100g of pre-dry Sargassum is uniformly mixed in vinyl bag with the iron powder of various amounts.Thereafter,
It is tested based on Showa Environmental Agency's bulletin in 48 years the 13rd, measures the arsenic the amount of dissolution of mixture.Seaweed state and seaweed before processing
The weight of mixed iron powder and the arsenic the amount of dissolution of mixture are shown in table 1.In addition, No.8 is the test of unmixed iron powder.
[table 1]
| No. | Seaweed state | Iron powder weight (g) | Arsenic the amount of dissolution (mg/L) |
| 1 | It is aqueous | 100 | 0.11 |
| 2 | It is aqueous | 10 | 0.21 |
| 3 | It is aqueous | 1 | 0.35 |
| 4 | It is aqueous | 0 | 2.0 |
| 5 | It is dry | 100 | 0.30 |
| 6 | It is dry | 10 | 0.51 |
| 7 | It is dry | 1 | 2.0 |
| 8 | It is dry | 0 | 2.4 |
As shown in table 1, if confirming increases the amount for the iron powder being added in seaweed, the arsenic the amount of dissolution of seaweed is reduced.
In addition, the test for having No.1~No.3 of iron powder is added in the seaweed of aqueous isloation state, add in pre-dry seaweed
The test for having entered No.5~No.7 of iron powder is compared, then confirming the former is greatly decreased the arsenic the amount of dissolution of seaweed.
In addition, in the test of No.3~No.8, the arsenic the amount of dissolution of dried object or mixture shows the discarded of Japan
The value of the standard max value 0.3mg/L or more of the arsenic the amount of dissolution of object facture defined can be true in the test of No.1 and No.2
Recognize the arsenic the amount of dissolution of dried object, the value shown is lower than the standard max value.
According to the above results, it may be said that when the iron powder more than a certain amount of being added in the seaweed of the state of moisture content, energy
Enough effectively inhibit the amount of dissolution of the arsenic from seaweed.In addition, according to heat run, it may be said that by heating seaweed, in seaweed
Contained arsenic is effectively dissolved out to moisture, therefore, when adding iron powder after the seaweed of the state of heating aqueous point, it can be expected that more
The inhibitory effect of high arsenic the amount of dissolution.
[industrial availability]
The processing method of living marine resources of the invention, can be by containing seawater mixed seaweeds or shellfish in water intaking
The living marine resources of class relatively easily generate the living marine resources for inhibiting the amount of dissolution of heavy metal classes.Therefore, the sea
The processing method of foreign living resources, even can also largely carry out containing the living marine resources of heavy metal classes as industry
The processing of waste and recycling as resource.
Claims (5)
1. a kind of processing method of living marine resources is the sea containing seaweeds mixed in the water intaking of seawater or shellfish
The processing method of foreign living resources, wherein have
The process of mixture-metal class insolubilizing agent in the above-mentioned living marine resources containing moisture, and
The process of mixture after dry above-mentioned mixed processes.
2. the processing method of living marine resources according to claim 1, wherein before above-mentioned mixed processes, be also equipped with
The process for heating the above-mentioned living marine resources containing moisture.
3. the processing method of living marine resources according to claim 1, wherein above-mentioned living marine resources contain arsenic.
4. the processing method of living marine resources according to claim 2, wherein above-mentioned living marine resources contain arsenic.
5. according to claim 1 to the processing method of the living marine resources described in any one of claim 4, wherein above-mentioned
Heavy metal classes insolubilizing agent is iron powder.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017194676A JP6875973B2 (en) | 2017-10-04 | 2017-10-04 | How to treat marine biological resources |
| JP2017-194676 | 2017-10-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109604296A true CN109604296A (en) | 2019-04-12 |
| CN109604296B CN109604296B (en) | 2021-10-19 |
Family
ID=66002788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811067967.6A Active CN109604296B (en) | 2017-10-04 | 2018-09-13 | Method for treating marine biological resources |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP6875973B2 (en) |
| CN (1) | CN109604296B (en) |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0899001A (en) * | 1994-09-29 | 1996-04-16 | Yoichi Sakuta | Method for removing heavy metal included in living body and its device |
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| JP6875973B2 (en) | 2021-05-26 |
| CN109604296B (en) | 2021-10-19 |
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