CN109602688A - One kind being used for the clean added material of cosmetics heavy metal - Google Patents
One kind being used for the clean added material of cosmetics heavy metal Download PDFInfo
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- CN109602688A CN109602688A CN201710924045.1A CN201710924045A CN109602688A CN 109602688 A CN109602688 A CN 109602688A CN 201710924045 A CN201710924045 A CN 201710924045A CN 109602688 A CN109602688 A CN 109602688A
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- cosmetics
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/99—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from microorganisms other than algae or fungi, e.g. protozoa or bacteria
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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Abstract
The present invention relates to one kind to be used for the clean added material of cosmetics heavy metal.The added material is made of following several raw materials: porous adsorbent, bean extract, amino acid, persimmon tannin and lactic acid bacteria.It is compounded using non-toxic, environmental friendly raw material, is acted on by physical absorption and chemical complexing, there is very strong adsorption capacity to micro heavy ion.90% or more is reached for the adsorption efficiency of common heavy metal in the cosmetics such as mercury, lead, cadmium, arsenic.The added material is non-stimulated to skin, and performance is stablized, and it is convenient to remove.And material itself is made it that can not diffuse into human body from skin pore, is reduced the harm of Heavy Metals in Cosmetics ion pair skin function and human health to greatest extent due to steric effect and surface group characteristic.There is good compatibility will not have a negative impact without changing the existing preparation process of cosmetics to the proper property of cosmetics for added material involved in the present invention and cosmetics.
Description
Technical field
The invention belongs to cosmetic fields, and in particular to one kind is used for the clean added material of cosmetics heavy metal.
Background technique
With the development of economy with the raising of living standards of the people, people are increasingly keen to each toward piling up on the face for oneself
Kind cosmetics, effort, which allows, oneself becomes coloured and dazzling.Reform and opening-up three during the last ten years China's Cosmetic Market sales volume it is average with
Annual 23.8% speed increases, and the highest time, growth rate was significantly larger than the average speed of growth of national economy up to 41%.So
And the huge sum of money such as chemical component, such as mercury, lead, cadmium, arsenic in cosmetics often containing damage skin normal function and human health
Belong to element.The result of study of health supervision office, Zhejiang Department of Public Health shows the crowd for smearing cosmetics daily, will absorb two within 1 year
Kilogram harmful substance.Due to the strong and stimulating of huge sum of money element, the skin care item containing heavy metal can cause the strong allergy of skin, need
Hormone to be added in cosmetics to inhibit the immune response of skin, so that skin is necessarily by heavy metal and hormone
Dual damage.
Currently, the predominating path for reducing Heavy Metals in Cosmetics pollution be by manufacturer to the control of raw material quality and
The supervision of government department.Manufacturer must not prohibitive materials in operating specification, reinforce to the source of raw material, transport, store, make
With the management of situation, guarantee the quality of product from source, avoid the pollution brought by raw material, eliminates hidden danger of quality.Government supervisor
Department carries out proactive regulation and supervision, supervision, subsequent supervision in thing, reinforces the audit and management to manufacturing enterprise, irregularly produces to it
Environment and semi-finished product are tested, and are strengthened market management, and are made a random inspection to cosmetics in the market, and fake and forged production is prevented
Product, ingredient and the formula product that there is any discrepancy come into the market.Nonetheless, due to the mechanism of action of cosmetics itself, so that some
Toxic heavy metal ion is still present in cosmetics.Even micro heavy-metal residual, to human body band after accumulating over a long period
The harm come should not be underestimated.Also there are document and patent to propose, can be used with the face cleaning product for absorbing heavy metal ion function
To reduce harm of the heavy metal to skin.But this post-processing thinking can only remove the heavy metal for being adsorbed on skin surface, it is right
It is unsatisfactory in the heavy metal contaminants eradicating efficacy that major part is absorbed by deep skin.
Summary of the invention
The present invention status difficult for Heavy Metals in Cosmetics removal, proposes a kind of thinking that front end is administered, develops
One kind being used for the clean added material of cosmetics heavy metal.Using the porous material to the non-stimulated nonhazardous of skin as adsorbent,
Biological bacteria, plant extraction liquid, natural polymer etc. are used as modifying agent, and height is prepared by blending, inverse suspension, the means of crosslinking
It imitates heavy metal and eliminates material, double route is absorbed by physical absorption and chemical complexing and is anchored heavy metal ion.Then existing
This material is directly added into cosmetics preparation process, while the cosmetics being prepared remain original performance, additionally it is possible to
Eliminate absorption of the skin to heavy metal ion.It is demonstrated experimentally that by this cleaning added material be respectively placed in 100 ug/L mercury, lead, cadmium,
In arsenic solution, 4 h heavy metal adsorption rates are up to 90% or more under room temperature.The added material is since size is greater than skin hair simultaneously
Bore dia (about 50 μm), and a large amount of hydrophilic radicals are contained on surface, make its human body that can hardly enter by skin pore.
To achieve the above object, the present invention adopts the following technical scheme:
The cleaning added material includes following mass percent component: porous adsorbent 83-90 wt%, persimmon tannin 1-3 wt%,
Bean extract 0.5-1.5 wt%, lactic acid bacteria 0.5-1 wt%, 2 ~ 5 wt% of amino acid are formed.
Porous adsorbent by one of diatomite, montmorillonite, middle pore titanium oxide, molecular sieve, white bamboo charcoal or it is a variety of form,
Its content is 83-90 wt%.
Modifying agent is by persimmon list (1-3 wt%), bean extract (0.5-1.5 wt%), lactic acid bacteria (0.5-1 wt%), amino
Sour (2 ~ 5 wt%) is formed
Added material during the preparation process used wetting dispersing agent by polyethylene glycol 400, Tween-80, sodium lauryl sulfate, rouge
One of fat acid sodium, alpha-sulfo Methyl fatty acid esters or a variety of compositions.
Added material during the preparation process used pH adjusting agent by citric acid, edible L MALIC ACID, potassium carbonate, lemon
One of lemon acid potassium or a variety of compositions.
White bamboo charcoal is made under 800 DEG C~1000 DEG C of high temperature drying carbonization technique using the Meng Zongzhu of Japan's growth as raw material
Make the bamboo charcoal formed.White bamboo charcoal is fine and closely woven porous, and absorption power is strong, and surface has oxygen-containing functional group abundant, with heavy metal ion
Interaction force is stronger.
Middle pore titanium oxide, using metatitanic acid and potassium carbonate as raw material, by kneading, the hydration of solid phase high temperature sintering, room temperature, from
Middle pore titanium oxide is obtained after son exchange, drying roasting, equivalent diameter is about 200-500 microns.Titanium oxide is commonly used in cosmetics
Pigments and fillers, the Large ratio surface that middle pore titanium oxide has becomes good adsorbent material.
Diatomite, montmorillonite, molecular sieve are the business porous material with bigger serface.
Persimmon tannin is a kind of soluble phenolic compounds.It is widely distributed in plant kingdom, it is a kind of important cometabolism
Product, and the most a kind of plant phenolics of content in addition to lignin.β ring phenol rich in its molecular structure
Hydroxyl has very strong price reduction adsorption capacity to metal ion.In addition to this, persimmon tannin also has anti-oxidant and antibiotic effect.
The protein on lactobacillus cell surface possesses a large amount of negatively charged functional groups, can have by electrostatic adsorption
The effect ground positively charged heavy metal ion of mating surface.And the netted physical structure in cell wall is conducive to stick together and adsorb a huge sum of money
Belong to.
Bean extract, phytate rich in are the most potential natural mixture of heavy metal chela.And have long-acting
Antibacterial and antioxidant effect.
One kind is as follows for its advantage of the clean added material of cosmetics heavy metal:
(1) it is put forward for the first time and harm of the heavy metal to skin and human body is eliminated using front end Treatment process；
(2) the cleaning added material is at low cost, environmentally protective, abundance, preparation process are simple；
(3) the cleaning added material does not influence the performance of cosmetics itself, and the preparation process without adjusting cosmetics；
(4) using the cosmetics containing cleaning added material, skin allergy caused by heavy metal poisoning and long spot be can obviously reduce
Long acne；(5) by this cleaning added material be respectively placed in 5mg/L mercury, lead, cadmium, in arsenic solution, 2 h heavy metal adsorption rate under room temperature
It is up to 98% or more.
Detailed description of the invention
Fig. 1 is the performance map that added material absorption heavy metal is cleaned in the present invention；
Fig. 2 be before modified after in lipstick heavy metal ion concentration map (dotted line indicates state's scale value).
Specific embodiment
It elaborates below by way of specific embodiment to the present invention:
Embodiment 1
A kind of test being used for heavy metal ion adsorbed performance for the clean added material of cosmetics heavy metal, the added material
The raw material and specific proportion used is (by weight) as follows: porous adsorbent 90wt%, persimmon tannin 2.5wt%, bean extract
1.5wt%, lactic acid bacteria 1wt%, glycine 5wt%.Described method includes following steps:
(1) a certain amount of white bamboo charcoal is placed in tube furnace, is taken out after activating 3 hours in 543 K air atmospheres stand-by；
(2) a certain amount of middle pore titanium oxide and the white bamboo charcoal of activation are immersed in 30 mL, 10 wt% hydrogen peroxide solution, are stirred at room temperature
It mixes 6 hours, it is stand-by with being dried after a large amount of deionized water filtering and washings；
(3) by above-mentioned drying sample dispersion in 100 mL aqueous solutions, persimmon tannin, bean extract are added under intense agitation
And amino acid, adjusting pH value to 9.5 are warming up to 343 K, strong stirring 8 hours is placed in Rotary Evaporators and is evaporated moisture,
Obtain dry powdered sample；
(4) above-mentioned sample is added in the aqueous solution containing lactic acid bacteria, is stirred 4 hours at room temperature, filtering and washing is placed on very
One kind involved in the present invention can be obtained for the clean added material of cosmetics heavy metal in 40 DEG C of empty drying box drying；
(5) the above-mentioned cleaning added material of 200 mg is taken to be separately added into mercurous (or the lead or cadmium or arsenic) solution (5 mg/Kg) of 30 ml
In, after stirring 4 h, centrifugation obtains supernatant liquor at 4000 rpm, takes in right amount for icp analysis, can be with molten after Absorption quantity
The content of heavy metal element in liquid, as a result as shown in Figure 1, it can be seen that under room temperature after 4 h, added material to heavy metal Hg,
Lead, cadmium, arsenic adsorption rate be respectively 91%, 95%, 93% and 93%.
Embodiment 2
One kind being used for lipstick product for the clean added material of cosmetics heavy metal.The mass ratio of added material and lipstick is 3:
97.Raw material that added material uses and specific proportion are (by weight) as follows: 90 wt% of porous adsorbent, 2.5 wt% of persimmon tannin,
1.5 wt% of bean extract, 1 wt% of lactic acid bacteria, 5 wt% of glycine.Evaluating the performance that modified lipstick adsorbs heavy metal includes
Following steps:
(1) lipstick by domestic certain producer production is dissolved in carbon tetrachloride solution, is persistently stirred 6 hours, is placed in high speed centrifugation
Supernatant liquor is taken after machine centrifugation, the concentration of heavy metal ion in clear liquid (mercury, lead, cadmium, arsenic) is gone out using ICP quantitative detection；
(2) 3wt% one kind of the present invention is mixed after melting lipstick is used for the clean added material of cosmetics heavy metal,
3000 rpm high speed emulsification 3-5 min, sample a part are used for heavy metal ion adsorbed performance test, and another part pours into mold
Re-solidify into column lipstick；
(3) the modification lipstick after above-mentioned emulsification is dissolved in carbon tetrachloride solution, persistently stirs 6 hours, is placed in high speed centrifugation
Supernatant liquor is taken after machine centrifugation, the concentration of heavy metal ion in clear liquid (mercury, lead, cadmium, arsenic) is gone out using ICP quantitative detection；
(4) before modified after in lipstick heavy metal ion concentration variation as shown in Fig. 2, mercury, lead and arsenic contain in lipstick before modified
Amount has exceeded the threshold value standard of 2015 editions cosmetics health specifications, and the heavy metal concentration that can dissociate out in modified lipstick subtracts
Lack 90% or more, has reached the threshold value standard of national regulation.Illustrate the ability that the material of our exploitations not only adsorbs heavy metal
By force, and adsorption strength is big, it is not easy to be desorbed.
Above embodiments are only the preferable example for absolutely proving the present invention and enumerating, and protection scope of the present invention is not limited to
This, addition, the transformation of preparation method of auxiliary element on the basis of the present invention are within the scope of the present invention.
Claims (5)
1. one kind is used for the clean added material of cosmetics heavy metal, it is characterised in that: the cleaning added material includes following
Mass percent component: porous adsorbent 83-95wt%, persimmon tannin 1-3 wt%, bean extract 0.5-1.5 wt%, lactic acid bacteria
0.5-1 wt%, 2 ~ 5wt% of amino acid are formed.
2. as described in claim 1 a kind of for the clean added material of cosmetics heavy metal, it is characterised in that: described is more
Hole adsorbent by one of diatomite, montmorillonite, middle pore titanium oxide, molecular sieve, white bamboo charcoal or it is a variety of form, content is
83-90 wt%。
3. as described in claim 1 a kind of for the clean added material of cosmetics heavy metal, it is characterised in that: described changes
Property agent is by persimmon tannin (1-3 wt%), bean extract (0.5-1.5 wt%), lactic acid bacteria (0.5-1 wt%), amino acid (2 ~ 5
Wt% it) is formed
It is as described in claim 1 a kind of for the clean added material of cosmetics heavy metal, it is characterised in that: in preparation process
Wetting dispersing agent used is by polyethylene glycol 400, Tween-80, sodium lauryl sulfate, sodium soap, alpha-sulfo methylfatty acid
One of ester or a variety of compositions.
4. as described in claim 1 a kind of for the clean added material of cosmetics heavy metal, it is characterised in that: preparation process
Used in pH adjusting agent by one of citric acid, edible L MALIC ACID, potassium carbonate, potassium citrate or a variety of form.
5. the preparation method of the modified absorbing material as described in claim 1-4 is any, which is characterized in that by following steps group
At:
(1) a certain amount of white bamboo charcoal is placed in tube furnace, is taken out after activating 3 hours in 543 K air atmospheres stand-by；
(2) a certain amount of middle pore titanium oxide and the white bamboo charcoal of activation are immersed in respectively in 5 wt% hydrogen peroxide solutions, stir 6 at room temperature
Hour, it is stand-by with being dried after a large amount of deionized water filtering and washings；
(3) by above-mentioned drying sample dispersion in 100 mL aqueous solutions, persimmon tannin, bean extract are added under intense agitation
And amino acid, adjusting pH value to 9.5 are warming up to 343 K, strong stirring 8 hours is placed in Rotary Evaporators and is evaporated moisture,
Obtain dry powdered sample；
(4) above-mentioned sample is added in the aqueous solution containing lactic acid bacteria, is stirred 4 hours at room temperature, filtering and washing is placed on very
One kind involved in the present invention can be obtained for the clean added material of cosmetics heavy metal in 40 DEG C of empty drying box drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710924045.1A CN109602688A (en) | 2017-09-30 | 2017-09-30 | One kind being used for the clean added material of cosmetics heavy metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710924045.1A CN109602688A (en) | 2017-09-30 | 2017-09-30 | One kind being used for the clean added material of cosmetics heavy metal |
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| Publication Number | Publication Date |
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| CN109602688A true CN109602688A (en) | 2019-04-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710924045.1A Pending CN109602688A (en) | 2017-09-30 | 2017-09-30 | One kind being used for the clean added material of cosmetics heavy metal |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111829918A (en) * | 2019-04-22 | 2020-10-27 | 新特能源股份有限公司 | Test device for adsorbing chlorosilane and test method for adsorbing chlorosilane |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104490719A (en) * | 2015-01-14 | 2015-04-08 | 广州孕肤宝日用品有限公司 | External application preparation with function of removing skin heavy metals |
| CN204910155U (en) * | 2015-07-16 | 2015-12-30 | 山东蒙山旅游集团地质矿产资源开发有限公司 | Medical stone facial mask |
| CN106390941A (en) * | 2016-11-04 | 2017-02-15 | 金福兴 | Environment-friendly heavy metal ion adsorbing material and preparation method thereof |
| CN106580739A (en) * | 2017-02-22 | 2017-04-26 | 广州市聚吉科绿色化学共性技术研究院有限公司 | Essence liquid for adsorbing heavy metals |
| CN106580719A (en) * | 2017-02-22 | 2017-04-26 | 广州市聚吉科绿色化学共性技术研究院有限公司 | Jelly facial mask capable of adsorbing heavy metals |
-
2017
- 2017-09-30 CN CN201710924045.1A patent/CN109602688A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104490719A (en) * | 2015-01-14 | 2015-04-08 | 广州孕肤宝日用品有限公司 | External application preparation with function of removing skin heavy metals |
| CN204910155U (en) * | 2015-07-16 | 2015-12-30 | 山东蒙山旅游集团地质矿产资源开发有限公司 | Medical stone facial mask |
| CN106390941A (en) * | 2016-11-04 | 2017-02-15 | 金福兴 | Environment-friendly heavy metal ion adsorbing material and preparation method thereof |
| CN106580739A (en) * | 2017-02-22 | 2017-04-26 | 广州市聚吉科绿色化学共性技术研究院有限公司 | Essence liquid for adsorbing heavy metals |
| CN106580719A (en) * | 2017-02-22 | 2017-04-26 | 广州市聚吉科绿色化学共性技术研究院有限公司 | Jelly facial mask capable of adsorbing heavy metals |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111829918A (en) * | 2019-04-22 | 2020-10-27 | 新特能源股份有限公司 | Test device for adsorbing chlorosilane and test method for adsorbing chlorosilane |
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Application publication date: 20190412 |