CN106580739A - Essence liquid for adsorbing heavy metals - Google Patents
Essence liquid for adsorbing heavy metals Download PDFInfo
- Publication number
- CN106580739A CN106580739A CN201710098037.6A CN201710098037A CN106580739A CN 106580739 A CN106580739 A CN 106580739A CN 201710098037 A CN201710098037 A CN 201710098037A CN 106580739 A CN106580739 A CN 106580739A
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- China
- Prior art keywords
- heavy metals
- essence
- skin
- fulvic acid
- essence liquid
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/005—Preparations for sensitive skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/008—Preparations for oily skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Medicines Containing Plant Substances (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention relates to an essence liquid for adsorbing heavy metals, and the essence liquid mainly includes the following components by mass: 1-4% of a Ag / graphene composite material, 5-10% of fulvic acid, 1-10% of persimmon tannin and 5-15% of a moisturizing agent. The essence liquid contains the Ag / graphene composite material, the fulvic acid and the persimmon tannin which all can adsorb heavy metal ions and skin surface dirt to promote the moisturizing agent to penetrate skin to purify and dredge pores, and by long-term use, the essence liquid can improve blackheads, moisturize the skin and relieve allergic skin, spots and other symptoms caused by heavy metal poisoning.
Description
Technical field
The present invention relates to cosmetic field, is specifically related to a kind of essence of Adsorption of Heavy Metals.
Background technology
China State of Air pollution is extremely serious.If the dust suspended material carried in air pollution does not note clearly
It is clean, pore may be slowly collected in, cause clogging of pores and acne to occur.
Media frequently report some because of the cosmetics of the whitening and speckle dispelling using mercury content severe overweight, and cause in hydrargyrum
Poison.After testing, exceeded 60,000 times unexpectedly of some Mercury In Cosmetics contents.Jing rough estimate, the mercury poisoning victim accepted for medical treatment in ward works as
In, can account for more than eighty per cant by ratio caused by cosmetics.
Nickel poisoning mainly sucks the dust of nickel and its esters, causes respiratory system irritation and skin lesion.It is chronic
Poisoning is that chronic skin contact has allergic dermatitises.
In chromium production of articles environment, workman is not in place due to safeguard procedures, easily causes the chronic poisoning of chromium, shows as
Skin ulcer, can cause to fester and formed chrome ulcer or nasal septum infringement and be difficult to cure when serious.
What T.S.Sreeprasad et al. was delivered《Reduced graphene oxide–metal/metal oxide
composites:Facile synthesis and application in waterpurification》Prepare in paper
Graphene-Ag composites are tested and show the Graphene-Ag composites in an absorption huge sum of money as the model of absorption pollutant Hg
Possesses excellent effect on category Hg.
What Li Yuqing et al. was delivered《The impact of absorption and fractions distribution of the fulvic acid heavy metal on deposit》Middle table
It is bright when the addition of fulvic acid is more than 5%, fulvic acid is the leading factor for affecting heavy metal ion adsorbed rate to decline.Addition is rich
In acid increased H in system+Concentration, H+Carbonate combine state metal can be replaced, carbonate combine state metal is made from deposit
Discharge, so as to the carbonate combine state for causing heavy metal is in significantly negatively correlated with fulvic acid addition.
Chinese patent application 105287248A, discloses a kind of graphene oxide facial film and preparation method thereof.The invention is first
It is secondary that Graphene is applied in facial film, and elaborate that Graphene kills acarid and deep layer removes the effect of acarid, but do not have
The derivative effect of further investigation graphene composite material.
The content of the invention
Present invention aim at a kind of essence of Adsorption of Heavy Metals is provided, from Ag/ graphene composite materials, fulvic acid
With persimmon tannin with the use of aging cutin and excess oil can be dispelled, unimpeded pore is purified, improve blackhead and comedo, made for a long time
With symptoms such as the skin allergy, long speckle that can also slow down because mercurialism causes.
For achieving the above object, the present invention is adopted the following technical scheme that：
In a preferred embodiment of the invention, a kind of essence of described Adsorption of Heavy Metals, including following quality
Percent composition：Ag/ graphene composite materials：1-4%, fulvic acid：1-10%, persimmon tannin：1-10%, wetting agent：5-15%.
Preferably, in a preferred embodiment of the invention, a kind of essence of described Adsorption of Heavy Metals, including with
Lower mass percent component：Ag/ graphene composite materials：2-3%, fulvic acid：3-8%, persimmon tannin：3-8%, wetting agent：8-
12%.
Preferably, in a preferred embodiment of the invention, a kind of essence of described Adsorption of Heavy Metals, including with
Lower mass percent component：Ag/ graphene composite materials：2.5%th, fulvic acid：5%th, persimmon tannin：6.5%th, wetting agent：10%.
Preferably, in a preferred embodiment of the invention, the wetting agent is glycerol, Propylene Glycol, butanediol, poly- second
The mixing of one or more in glycol and Sorbitol.
The principal element for affecting adsorbent absorption property is its specific surface area and structure, and Graphene has the ratio table of super large
Area (the close 2630m of monolayer specific surface area2/ g, multilamellar is 270～1550m2/ g) and abundant pore structure, this point becomes
The basis of its good adsorption properties.Therefore, we are it is believed that Graphene is a kind of preferable adsorbent or separation material.
Graphene oxide structure is substantially the same with Graphene, and substantial amounts of-COOH ,-OH are simply connected with two-dimentional basal plane
Deng oxygen-containing functional group.These oxy radicals not only can obviously improve its water solublity, can also become an activated adoption site absorption huge sum of money
Category, and then efficiently separate the heavy metal ion in waste water.What is more important, the introducing of a large amount of oxygen-containing functional groups causes to aoxidize stone
Black alkene can be stable in the presence of in various conventional organic solvents, become the presoma for preparing graphene-based composite.
Graphene-based composite is that, with Graphene and other compositions material prepared after compound, this material not only may be used
To keep the superiority of Graphene and institute's composite simultaneously, and new cooperative effect can be produced.Graphene-based composite
Preparation be mostly first to be combined graphene oxide with metal, metal-oxide and polymer, then will it is compound after material also
What original was obtained.
Fulvic acid is the rotten elite element for planting (growing) acid, less than 1%<Contain rate.Jing science proves that fulvic acid is known
Most powerful antioxidant and free radical scavenger.It is unique, can produce reaction with negative, positive electronics simultaneously, is allowed to become
Into harmless free radical.Fulvic acid has significantly work to healthy, heavy metal (radiation element) fusion excretion, cell regeneration etc.
With.
Persimmon tannin is a kind of natural polymer of abundance, because the B rings in its molecular structure contain abundant ortho position
Phenolic hydroxyl group, has very strong price reduction absorbability to metal ion.Metal absorbent with persimmon tannin as effective ingredient has into
This advantage such as low, environmentally friendly and efficient.Generally make the clarifier of rice wine using persimmon tannin in Japan, with persimmon tannin as effective ingredient
Adsorbent can remove the Low Concentration Iron ion in rice wine brew water.In addition, persimmon tannin also has conjugated protein, antioxidation, resists
Bacterium is used for numerous functions such as health care with antimicrobial, suppression snake venom activity and as medicinal ingredient.
A kind of essence of Adsorption of Heavy Metals of the present invention is used cooperatively with electro-ionic therapy, can promote nutritional activities
Material permeance sweat pore, the deep for penetrating to the skin.Current iontophoresis method, is the principle repelled each other using galvanic positive and negative electricity,
By identical polar medicine (or nutrient substance) by sweat pore, the deep for penetrating to the skin, or made using unidirectional current polarity
With infiltration of the medicine (or nutrient substance) to skin is strengthened, to reach the effect of beautifying skin.Medicine ion enters internal
Afterwards, can be done directly on local, or into blood, lymph fluid and be brought to whole body, or rest on skin top layer formed ion
Heap, progresses in vivo.The advantage of this therapy can be that medicine is introduced directly into the focus shallow compared with table, and local keep compared with
High drug level, and due to the effect of ion heap, the long action time of medicine has comprehensive function of unidirectional current and medicine etc. concurrently.
General drug level is 2%～10%, and treatment time, current intensity was according to different tissues, position and patient at 20 minutes or so
Tolerance degree depending on.
Beneficial effects of the present invention：Compared with prior art, the invention has the advantages that：By the way that Ag/ Graphenes are answered
Condensation material, fulvic acid and persimmon tannin mutually cooperate with compounding, reach the work of more preferable Adsorption of Heavy Metal Ions and skin surface dirt
With, to promote wetting agent to permeate into skin, unimpeded pore being purified, life-time service can improve blackhead and keep moisture of skin sufficient,
Slow down the symptoms such as skin allergy, long speckle because heavy metal poisoning causes.
Description of the drawings
Fig. 1 is the comparison diagram of embodiment 1 and essence sample adsorption Hg (II) of comparative example 1,2,3,4.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1～5
A kind of 5 specific embodiments of the essence of Adsorption of Heavy Metals of the present invention are listed in table 1.
Table 1
4 concrete comparative examples of the essence that a kind of Adsorption of Heavy Metals of the present invention is listed in table 2.
Table 2
By detecting Hg (II) sample for adding embodiment 1 and comparative example 1,2,3,4 with conventional method (concentration is 1mg/L)
Content, as a result as shown in figure.
From figure 1 it appears that embodiment 1 has the characteristic of significantly absorption Hg (II) compared with comparative example 1,2,3,4,
And with the effect of significant Synergistic.Show that Ag/ graphene composite materials, fulvic acid and persimmon tannin are respectively provided with certain suction
The effect of attached Hg (II), three's compounding effect is more preferable, i.e. the effect with Synergistic.
Evaluation test on probation
Preferably to prove that a kind of essence of Adsorption of Heavy Metals provided by the present invention has excellent effect, choose real
Applying example 1,2,3,4,5 and comparative example 1,2,3,4 carries out further investigation on probation and evaluation test.Embodiment is as follows：Choose
50 special volunteers, the wherein people of male 20, the people of women 30.Evaluation test is carried out to embodiment and comparative example, each sample examination
It it is one month with the phase, object on probation is using cosmetics mercurialism rear face allergy, long speckle crowd.Table 3 is test index and knot
Really.
Table 3
As a result show：
For using cosmetics poisoning rear face allergy, long speckle crowd, a kind of life-time service absorption of the present invention is heavy
The essence of metal, the effect for improving significantly and alleviating.And embodiment 1 has the best effect for being obviously improved and alleviating
Really.Show that Ag/ graphene composite materials, fulvic acid and persimmon tannin are respectively provided with the effect of certain absorption Hg (II), three's compounding
Effect is more preferable, i.e. the effect with Synergistic.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope of present disclosure, the change or replacement that can be readily occurred in,
All should be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection of claims
Scope is defined.
Claims (4)
1. a kind of essence of Adsorption of Heavy Metals, it is characterised in that including following mass percent component：Ag/ Graphenes are combined
Material：1-4%, fulvic acid：1-10%, persimmon tannin：1-10%, wetting agent：5-15%.
2. the essence of a kind of Adsorption of Heavy Metals according to claim 1, it is characterised in that including following mass percent
Component：Ag/ graphene composite materials：2-3%, fulvic acid：3-8%, persimmon tannin：3-8%, wetting agent：8-12%.
3. the essence of a kind of Adsorption of Heavy Metals according to claim 1, it is characterised in that including following mass percent
Component：Ag/ graphene composite materials：2.5%th, fulvic acid：5%th, persimmon tannin：6.5%th, wetting agent：10%.
4. a kind of essence of the Adsorption of Heavy Metals according to any one of claim 1-3, it is characterised in that the wetting agent
For the mixing of one or more in glycerol, Propylene Glycol, butanediol, Polyethylene Glycol and Sorbitol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710098037.6A CN106580739A (en) | 2017-02-22 | 2017-02-22 | Essence liquid for adsorbing heavy metals |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710098037.6A CN106580739A (en) | 2017-02-22 | 2017-02-22 | Essence liquid for adsorbing heavy metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106580739A true CN106580739A (en) | 2017-04-26 |
Family
ID=58587719
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710098037.6A Pending CN106580739A (en) | 2017-02-22 | 2017-02-22 | Essence liquid for adsorbing heavy metals |
Country Status (1)
| Country | Link |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107334689A (en) * | 2017-08-24 | 2017-11-10 | 广州聚注通用技术研究院有限公司 | A kind of heavy metal adsorption film |
| CN107412075A (en) * | 2017-09-04 | 2017-12-01 | 广州聚注通用技术研究院有限公司 | A kind of deep layer cleaning mildy wash |
| CN107496217A (en) * | 2017-09-04 | 2017-12-22 | 广州聚注通用技术研究院有限公司 | A kind of mildy wash |
| CN109602688A (en) * | 2017-09-30 | 2019-04-12 | 江苏瑞丰科技实业有限公司 | One kind being used for the clean added material of cosmetics heavy metal |
| CN114601753A (en) * | 2022-05-13 | 2022-06-10 | 汕头市特丝多丽化妆品有限公司 | Cosmetic containing graphene for adsorbing heavy metals and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140062425A (en) * | 2011-03-03 | 2014-05-23 | 위시스 테크놀로지 파운데이션, 인크. | Thermodynamic solutions of metal oxides and metal chalcogenides and mixed metal oxides and chalcogenides |
| CN106109294A (en) * | 2016-06-29 | 2016-11-16 | 广州市巧美化妆品有限公司 | A kind of moisturizing essence and preparation method thereof |
-
2017
- 2017-02-22 CN CN201710098037.6A patent/CN106580739A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140062425A (en) * | 2011-03-03 | 2014-05-23 | 위시스 테크놀로지 파운데이션, 인크. | Thermodynamic solutions of metal oxides and metal chalcogenides and mixed metal oxides and chalcogenides |
| CN106109294A (en) * | 2016-06-29 | 2016-11-16 | 广州市巧美化妆品有限公司 | A kind of moisturizing essence and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| T.S. SREEPRASAD等: "Reduced graphene oxide–metal/metal oxide composites: Facile synthesis and application in water purification", 《JOURNAL OF HAZARDOUS MATERIALS》 * |
| 佚名: "秀丽韩 完美奇蹟逆龄精华液", 《获取网址：HTTP://WWW.COSDNA.COM/CHS/COSMETIC_9919236582.HTML》 * |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107334689A (en) * | 2017-08-24 | 2017-11-10 | 广州聚注通用技术研究院有限公司 | A kind of heavy metal adsorption film |
| CN107412075A (en) * | 2017-09-04 | 2017-12-01 | 广州聚注通用技术研究院有限公司 | A kind of deep layer cleaning mildy wash |
| CN107496217A (en) * | 2017-09-04 | 2017-12-22 | 广州聚注通用技术研究院有限公司 | A kind of mildy wash |
| CN109602688A (en) * | 2017-09-30 | 2019-04-12 | 江苏瑞丰科技实业有限公司 | One kind being used for the clean added material of cosmetics heavy metal |
| CN114601753A (en) * | 2022-05-13 | 2022-06-10 | 汕头市特丝多丽化妆品有限公司 | Cosmetic containing graphene for adsorbing heavy metals and preparation method thereof |
| CN114601753B (en) * | 2022-05-13 | 2022-07-22 | 汕头市特丝多丽化妆品有限公司 | Cosmetic containing graphene for adsorbing heavy metals and preparation method thereof |
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