CN109594333A - 一种防蚊抗菌纺织品织物及其制备方法 - Google Patents
一种防蚊抗菌纺织品织物及其制备方法 Download PDFInfo
- Publication number
- CN109594333A CN109594333A CN201811375425.5A CN201811375425A CN109594333A CN 109594333 A CN109594333 A CN 109594333A CN 201811375425 A CN201811375425 A CN 201811375425A CN 109594333 A CN109594333 A CN 109594333A
- Authority
- CN
- China
- Prior art keywords
- fiber
- added
- mosquito
- fabric
- essential oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 86
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 239000000835 fiber Substances 0.000 claims abstract description 115
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 71
- 239000000077 insect repellent Substances 0.000 claims abstract description 32
- 150000001450 anions Chemical group 0.000 claims abstract description 25
- 229920000297 Rayon Polymers 0.000 claims abstract description 21
- 239000004753 textile Substances 0.000 claims abstract description 19
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 17
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 17
- 244000068988 Glycine max Species 0.000 claims abstract description 17
- 235000010469 Glycine max Nutrition 0.000 claims abstract description 17
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 17
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011425 bamboo Substances 0.000 claims abstract description 17
- 210000002268 wool Anatomy 0.000 claims abstract description 17
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 16
- 229920002101 Chitin Polymers 0.000 claims abstract description 16
- 239000004917 carbon fiber Substances 0.000 claims abstract description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 81
- 239000003094 microcapsule Substances 0.000 claims description 70
- 239000000341 volatile oil Substances 0.000 claims description 53
- 238000003756 stirring Methods 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 38
- 230000008569 process Effects 0.000 claims description 31
- 108010010803 Gelatin Proteins 0.000 claims description 27
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 239000008273 gelatin Substances 0.000 claims description 27
- 229920000159 gelatin Polymers 0.000 claims description 27
- 235000019322 gelatine Nutrition 0.000 claims description 27
- 235000011852 gelatine desserts Nutrition 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 229920000858 Cyclodextrin Polymers 0.000 claims description 26
- 239000001116 FEMA 4028 Substances 0.000 claims description 26
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 26
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 26
- 229960004853 betadex Drugs 0.000 claims description 26
- 239000000843 powder Substances 0.000 claims description 23
- 239000003921 oil Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 21
- 238000004945 emulsification Methods 0.000 claims description 20
- 238000005406 washing Methods 0.000 claims description 20
- 235000003826 Artemisia Nutrition 0.000 claims description 19
- 235000003261 Artemisia vulgaris Nutrition 0.000 claims description 19
- 229910021536 Zeolite Inorganic materials 0.000 claims description 19
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 19
- 244000030166 artemisia Species 0.000 claims description 19
- 235000009052 artemisia Nutrition 0.000 claims description 19
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 19
- 239000010457 zeolite Substances 0.000 claims description 19
- 229920000742 Cotton Polymers 0.000 claims description 18
- 239000004902 Softening Agent Substances 0.000 claims description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 18
- 239000002131 composite material Substances 0.000 claims description 17
- 235000011187 glycerol Nutrition 0.000 claims description 17
- 241001330002 Bambuseae Species 0.000 claims description 16
- 239000000725 suspension Substances 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 11
- 239000004793 Polystyrene Substances 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 9
- 239000003599 detergent Substances 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 9
- 239000012153 distilled water Substances 0.000 claims description 9
- 230000001804 emulsifying effect Effects 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 9
- 229920002223 polystyrene Polymers 0.000 claims description 9
- 239000008213 purified water Substances 0.000 claims description 9
- 238000010025 steaming Methods 0.000 claims description 9
- 238000004804 winding Methods 0.000 claims description 9
- -1 polyethylene Polymers 0.000 claims description 8
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 8
- 239000011118 polyvinyl acetate Substances 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- 229920000768 polyamine Polymers 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 230000001112 coagulating effect Effects 0.000 claims description 6
- 230000001376 precipitating effect Effects 0.000 claims description 6
- 239000003814 drug Substances 0.000 claims description 5
- 229940079593 drug Drugs 0.000 claims description 5
- 230000001442 anti-mosquito Effects 0.000 claims description 2
- 230000036541 health Effects 0.000 claims description 2
- 244000166124 Eucalyptus globulus Species 0.000 claims 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 238000004090 dissolution Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 241000255925 Diptera Species 0.000 abstract description 8
- 230000000172 allergic effect Effects 0.000 abstract description 3
- 208000010668 atopic eczema Diseases 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 244000082204 Phyllostachys viridis Species 0.000 abstract 1
- 230000003115 biocidal effect Effects 0.000 abstract 1
- 241000219927 Eucalyptus Species 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 239000003292 glue Substances 0.000 description 6
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 4
- 102000002322 Egg Proteins Human genes 0.000 description 4
- 108010000912 Egg Proteins Proteins 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 235000014103 egg white Nutrition 0.000 description 4
- 210000000969 egg white Anatomy 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 150000004767 nitrides Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 4
- 241000256113 Culicidae Species 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 206010067482 No adverse event Diseases 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000004490 capsule suspension Substances 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229940023184 after bite Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/40—Fibres of carbon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明公开了一种防蚊抗菌纺织品织物及其制备方法，所述纺织品织物包括重量百分比为10‑15％黏胶负离子功能纤维、10‑15％大豆蛋白纤维、20‑30％麻纤维、5‑10％羊毛纤维、5‑10％纳米竹炭纤维、10‑15％甲壳素纤维、2‑5％纳米银离子纤维、4‑6％抗紫外整理剂和2‑4％驱蚊整理剂。所述防蚊虫抗菌织物对皮肤无刺激、无过敏现象，对人体安全、无毒，穿着舒适。
Description
技术领域
本发明涉及纺织品技术领域，尤其涉及一种防蚊抗菌纺织品织物及其制备方法。
背景技术
纺织品面料主要是用于制作家纺和服装或医用纺织品，其种类很多。随着市场需求的多样化，面料的功能性也越来越受到人们的重视。随着生活水平不断提高，人们对服装面料的功能要求越来越高，除了要求服装有正常的保暖功能外，还要要求能具有防止蚊虫叮咬的功效，随着是处于炎热的夏季，蚊虫叮咬现象已经让大人小孩措手不及。蚊虫叮咬后轻则皮肤红肿，重则传染疾病，严重影响日常生活。因而研制一种可防止蚊虫叮咬的纺织面料是一种极具市场和社会效益的工程。
据资料介绍，世界卫生组织提倡以杀虫剂浸泡蚊帐，可以使织物具有杀虫或驱虫之功能。经过多年的实践证明，一般都得到良好的效果。但是处理之后，驱蚊的持久性较弱，因此，研发一种防蚊效果好并且效力持久的防蚊并具有抑菌作用的纺织品已成为目前亟待解决的问题。
发明内容
为解决上述技术问题，本发明提供了一种防蚊抗菌纺织品织物及其制备方法。经本发明应用的防蚊抗菌纺织品织物，对蚊虫具有快速击倒灭杀作用，防蚊效果达到99％；对织物的外观、强力、吸湿性等物理指标无不良影响；水洗30次后仍具有良好的防蚊虫效果；防蚊虫整理织物对皮肤无刺激、无过敏现象，对人体安全、无毒，穿着舒适。
为达此目的，本发明采用了以下技术方案：
第一方面，本发明提供了一种防蚊抗菌纺织品织物，所述纺织品织物包括重量百分比为10-15％黏胶负离子功能纤维、10-15％大豆蛋白纤维、20-30％麻纤维、5-10％羊毛纤维、5-10％纳米竹炭纤维、10-15％甲壳素纤维、2-5％纳米银离子纤维、4-6％抗紫外整理剂和2-4％驱蚊整理剂；
所述防蚊整理剂的防蚊药物为大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1-5:3-10:1-5:3-7:8-12的质量比的混合物。
根据本发明，所述黏胶负离子功能纤维在纺织品织物中的含量为10-15％，例如可以是10％、11％、12％、13％、14％或15％；所述大豆蛋白纤维在纺织品织物中的含量为10-15％，例如可以是10％、11％、12％、13％、14％或15％；所述麻纤维在纺织品织物中的含量为20-30％，例如可以是20％、21％、22％、23％、24％、25％、26％、28％或30％；所述羊毛纤维在纺织品织物中的含量为5-10％，例如可以是5％、6％、7％、8％、9％或10％；所述纳米竹炭纤维在纺织品织物中的含量为5-10％，例如可以是5％、6％、7％、8％、9％或10％；所述甲壳素纤维在纺织品织物中的含量为10-15％，例如可以是10％、11％、12％、13％、14％或15％；所述纳米银离子纤维在纺织品织物中的含量为2-5％，例如可以是2％、3％、4％或5％；所述抗紫外整理剂在纺织品织物中的含量为4-6％，例如可以是4％、4.5％、5％或6％；所述驱蚊整理剂在纺织品织物中的含量为2-4％，例如可以是2％、2.5％、3％或4％。
根据本发明，所述防蚊药物为大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1-5:3-10:1-5:3-7:8-12的质量比的混合物；所述大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇的质量比为1-5:3-10:1-5:3-7:8-12，例如可以是1:3:1:3:8、2:4:3:6:9、4:3:1:5:10、5:5:1:7:12、2:6:2:7:8、2:4:2:3:8、1:7:2:7:11、3:6:2:5:9、2:4:3:6:12、2:7:2:5:8、1:4:1:7:8、5:10:2:4:8、1:6:5:7:9或5:10:1:7:12，优选为1-3:5-8:1-4:5-7:10-12，进一步优选为1:3:1:3:8。
本发明通过采用由大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇组成的防蚊药物，其相比采用单独的各组分而言，该组合物各组分之间具有协同增效作用，其能够使纺织品织物具有更好的防蚊效果，并且持久性更强。
第二方面，本发明还提供了一种如第一方面所述防蚊抗菌纺织品织物的制备方法，所述方法包括如下步骤：
(1)将黏胶负离子功能纤维、羊毛纤维、纳米竹炭纤维、纳米银离子纤维混合均匀，加入分散剂、粘结剂、柔软剂，经过搅拌，晾干处理；
(2)将大豆蛋白纤维、麻纤维、甲壳素纤维各自经清棉、疏棉处理；
(3)将经过步骤(1)和(2)处理的纤维并条，再依次经粗纱、细纱、自动络筒、蒸纱、高速并线、倍捻处理得到精仿纱；
(4)采用平纹、二上一下斜纹或二上二下斜纹进行织造；
(5)加入3％的净洗剂和2％的柔软剂对衣服进行水洗处理，水温控制在40-45℃，水洗10-15min；
(6)加入抗紫外整理剂、驱蚊整理剂浸渍经过步骤(5)处理过的布匹30-70分钟，然后再在70-80℃下焙烤，最后定型处理；
(7)检查织物是否合格，合格则为成品。
根据本发明，所述驱蚊整理剂的制备方法为：
第一步：制备微胶囊：
将10.0g明胶、4.5g甘油和6gβ-环糊精，加入1000ml蒸馏水中，在50℃水浴锅中溶解完全，制备明胶、甘油、β-环糊精溶液；
取出100-250ml明胶、甘油、β-环糊精溶液，加入大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1-3:5-8:1-4:5-7:10-12的质量比的混合物，在高剪切力分散乳化机下乳化，转速为4000r/min，乳化时间为10min；乳化结束后滴加10％的醋酸溶液调节体系的pH值为4.5-5.0，转速为2500r/min条件下复凝15min，形成微胶囊悬浮液；复凝完成后，将微胶囊悬浮液置于-20℃的恒温低温反应浴中，边搅拌边降温，搅拌速度为2500r/min，待溶液温度降至5℃时，加入10％氢氧化钠溶液调节至pH为9.0，搅拌处理20min；加入5-9ml多乙烯多胺，搅拌处理20-25min，再移到45-48℃水浴锅中，搅拌处理2h，然后在转速为7000-7500r/min条件下离心5min，取沉淀，室温下晾干，得到复合精油微胶囊；
第二步：制备复合精油微胶囊整理剂：
将25-35g微胶囊溶于1L纯化水中，加入聚苯乙烯2-4g，使微胶囊均匀的分散在整理液中，再加入50-150g聚乙酸乙烯酯，混合均匀得到微胶囊整理剂。
具体的，本发明所述防蚊抗菌纺织品织物的制备方法包括以下步骤：
(1)将黏胶负离子功能纤维、羊毛纤维、纳米竹炭纤维、纳米银离子纤维混合均匀，加入分散剂、粘结剂、柔软剂，经过搅拌，晾干处理；
(2)将大豆蛋白纤维、麻纤维、甲壳素纤维各自经清棉、疏棉处理；
(3)将经过步骤(1)和(2)处理的纤维并条，再依次经粗纱、细纱、自动络筒、蒸纱、高速并线、倍捻处理得到精仿纱；
(4)采用平纹、二上一下斜纹或二上二下斜纹进行织造；
(5)加入3％的净洗剂和2％的柔软剂对衣服进行水洗处理，水温控制在40-45℃，水洗10-15min；
(6)加入抗紫外整理剂、驱蚊整理剂浸渍经过步骤(5)处理过的布匹30-70分钟，然后再在70-80℃下焙烤，最后定型处理；
其中所述驱蚊整理剂的制备方法为：
第一步：制备微胶囊：
将10.0g明胶、4.5g甘油和6gβ-环糊精，加入1000ml蒸馏水中，在50℃水浴锅中溶解完全，制备明胶、甘油、β-环糊精溶液；
取出100-250ml明胶、甘油、β-环糊精溶液，加入大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1-3:5-8:1-4:5-7:10-12的质量比的混合物，在高剪切力分散乳化机下乳化，转速为4000r/min，乳化时间为10min；乳化结束后滴加10％的醋酸溶液调节体系的pH值为4.5-5.0，转速为2500r/min条件下复凝15min，形成微胶囊悬浮液；复凝完成后，将微胶囊悬浮液置于-20℃的恒温低温反应浴中，边搅拌边降温，搅拌速度为2500r/min，待溶液温度降至5℃时，加入10％氢氧化钠溶液调节至pH为9.0，搅拌处理20min；加入5-9ml多乙烯多胺，搅拌处理20-25min，再移到45-48℃水浴锅中，搅拌处理2h，然后在转速为7000-7500r/min条件下离心5min，取沉淀，室温下晾干，得到复合精油微胶囊；
第二步：制备复合精油微胶囊整理剂：
将25-35g微胶囊溶于1L纯化水中，加入聚苯乙烯2-4g，使微胶囊均匀的分散在整理液中，再加入50-150g聚乙酸乙烯酯，混合均匀得到微胶囊整理剂。
(7)检查织物是否合格，合格则为成品。
示例性地，所述防蚊抗菌纺织品织物的制备方法为：
(1)将黏胶负离子功能纤维、羊毛纤维、纳米竹炭纤维、纳米银离子纤维混合均匀，加入分散剂、粘结剂、柔软剂，经过搅拌，晾干处理；
(2)将大豆蛋白纤维、麻纤维、甲壳素纤维各自经清棉、疏棉处理；
(3)将经过步骤(1)和(2)处理的纤维并条，再依次经粗纱、细纱、自动络筒、蒸纱、高速并线、倍捻处理得到精仿纱；
(4)采用平纹、二上一下斜纹或二上二下斜纹进行织造；
(5)加入3％的净洗剂和2％的柔软剂对衣服进行水洗处理，水温控制在40-45℃，水洗10-15min；
(6)加入抗紫外整理剂、驱蚊整理剂浸渍经过步骤(5)处理过的布匹70分钟，然后再在80℃下焙烤，最后定型处理；
其中所述驱蚊整理剂的制备方法为：
第一步：制备微胶囊：
将10.0g明胶、4.5g甘油和6gβ-环糊精，加入1000ml蒸馏水中，在50℃水浴锅中溶解完全，制备明胶、甘油、β-环糊精溶液；
取出100-250ml明胶、甘油、β-环糊精溶液，加入大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1:3:1:3:8的质量比的混合物，在高剪切力分散乳化机下乳化，转速为4000r/min，乳化时间为10min；乳化结束后滴加10％的醋酸溶液调节体系的pH值为5.0，转速为2500r/min条件下复凝15min，形成微胶囊悬浮液；复凝完成后，将微胶囊悬浮液置于-20℃的恒温低温反应浴中，边搅拌边降温，搅拌速度为2500r/min，待溶液温度降至5℃时，加入10％氢氧化钠溶液调节至pH为9.0，搅拌处理20min；加入5-9ml多乙烯多胺，搅拌处理25min，再移到48℃水浴锅中，搅拌处理2h，然后在转速为7500r/min条件下离心5min，取沉淀，室温下晾干，得到复合精油微胶囊；
第二步：制备复合精油微胶囊整理剂：
将25g微胶囊溶于1L纯化水中，加入聚苯乙烯4g，使微胶囊均匀的分散在整理液中，再加入150g聚乙酸乙烯酯，混合均匀得到微胶囊整理剂。
(7)检查织物是否合格，合格则为成品。
与现有技术相比，本发明至少具有以下有益效果：
经本发明应用的防蚊抗菌纺织品织物，对蚊虫具有快速击倒灭杀作用，防蚊效果达到99％；对织物的外观、强力、吸湿性等物理指标无不良影响；水洗30次后仍具有良好的防蚊虫效果；防蚊虫整理织物对皮肤无刺激、无过敏现象，对人体安全、无毒，穿着舒适。
下面结合实施例对本发明作进一步说明。
具体实施方式
为便于理解本发明，本发明列举实施例如下。本领域技术人员应该明了，所述实施例仅仅是帮助理解本发明，不应视为对本发明的具体限制。
实施例1
一种防蚊抗菌纺织品织物，包括重量百分比为10％黏胶负离子功能纤维、10％大豆蛋白纤维、30％麻纤维、10％羊毛纤维、10％纳米竹炭纤维、10％甲壳素纤维、2％纳米银离子纤维、4％抗紫外整理剂、2％驱蚊整理剂；其中黏胶负离子功能纤维采用120旦的复丝，且黏胶负离子功能纤维中负离子粉添加量为5％；纳米二氮化钛的粒径为70nm；抗紫外整理剂是由40％氧化锌、40％二氧化钛、20％的聚酯母粒混合而成；驱蚊整理剂为大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1:3:1:3:8的质量比的混合物。
所述防蚊抗菌纺织品织物，包括以下步骤：
(1)将黏胶负离子功能纤维、羊毛纤维、纳米竹炭纤维、纳米银离子纤维混合均匀，加入分散剂、粘结剂、柔软剂，经过搅拌，晾干处理；
(2)将大豆蛋白纤维、麻纤维、甲壳素纤维各自经清棉、疏棉处理；
(3)将经过步骤(1)和(2)处理的纤维并条，再依次经粗纱、细纱、自动络筒、蒸纱、高速并线、倍捻处理得到精仿纱；
(4)采用平纹、二上一下斜纹或二上二下斜纹进行织造；
(5)加入3％的净洗剂和2％的柔软剂对衣服进行水洗处理，水温控制在40℃，水洗15min；
(6)加入抗紫外整理剂、驱蚊整理剂浸渍经过步骤(5)处理过的布匹30分钟，然后再在70℃下焙烤，最后定型处理；
所述驱蚊整理剂的制备方法为：
第一步：制备微胶囊：
将10.0g明胶、4.5g甘油和6gβ-环糊精，加入1000ml蒸馏水中，在50℃水浴锅中溶解完全，制备明胶、甘油、β-环糊精溶液；
取出100-250ml明胶、甘油、β-环糊精溶液，加入大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1:3:1:3:8的质量比的混合物，在高剪切力分散乳化机下乳化，转速为4000r/min，乳化时间为10min；乳化结束后滴加10％的醋酸溶液调节体系的pH值为4.5-5.0，转速为2500r/min条件下复凝15min，形成微胶囊悬浮液；复凝完成后，将微胶囊悬浮液置于-20℃的恒温低温反应浴中，边搅拌边降温，搅拌速度为2500r/min，待溶液温度降至5℃时，加入10％氢氧化钠溶液调节至pH为9.0，搅拌处理20min；加入5ml多乙烯多胺，搅拌处理20min，再移到45℃水浴锅中，搅拌处理2h，然后在转速为7500r/min条件下离心5min，取沉淀，室温下晾干，得到复合精油微胶囊；
第二步：制备复合精油微胶囊整理剂：
将25g微胶囊溶于1L纯化水中，加入聚苯乙烯4g，使微胶囊均匀的分散在整理液中，再加入150g聚乙酸乙烯酯，混合均匀得到微胶囊整理剂。
(7)检查织物是否合格，合格则为成品。
实施例2
一种防蚊抗菌纺织品织物，包括重量百分比为12％黏胶负离子功能纤维、12％大豆蛋白纤维、25％麻纤维、8％羊毛纤维、7％纳米竹炭纤维、12％甲壳素纤维、4％纳米银离子纤维、5％抗紫外整理剂和3％驱蚊整理剂；其中黏胶负离子功能纤维采用120旦的复丝，且黏胶负离子功能纤维中负离子粉添加量为5％；纳米二氮化钛的粒径为85nm；抗紫外整理剂是由40％氧化锌、40％二氧化钛、20％的聚酯母粒混合而成；驱蚊整理剂为大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按2:6:2:7:8的质量比的混合物。
所述防蚊抗菌纺织品织物，包括以下步骤：
(1)将黏胶负离子功能纤维、羊毛纤维、纳米竹炭纤维、纳米银离子纤维混合均匀，加入分散剂、粘结剂、柔软剂，经过搅拌，晾干处理；
(2)将大豆蛋白纤维、麻纤维、甲壳素纤维各自经清棉、疏棉处理；
(3)将经过步骤(1)和(2)处理的纤维并条，再依次经粗纱、细纱、自动络筒、蒸纱、高速并线、倍捻处理得到精仿纱；
(4)采用平纹、二上一下斜纹或二上二下斜纹进行织造；
(5)加入3％的净洗剂和2％的柔软剂对衣服进行水洗处理，水温控制在40℃，水洗15min；
(6)加入抗紫外整理剂、驱蚊整理剂浸渍经过步骤(5)处理过的布匹30分钟，然后再在70℃下焙烤，最后定型处理；
所述驱蚊整理剂的制备方法为：
第一步：制备微胶囊：
将10.0g明胶、4.5g甘油和6gβ-环糊精，加入1000ml蒸馏水中，在50℃水浴锅中溶解完全，制备明胶、甘油、β-环糊精溶液；
取出100-250ml明胶、甘油、β-环糊精溶液，加入大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按2:6:2:7:8的质量比的混合物，在高剪切力分散乳化机下乳化，转速为4000r/min，乳化时间为10min；乳化结束后滴加10％的醋酸溶液调节体系的pH值为5.0，转速为2500r/min条件下复凝15min，形成微胶囊悬浮液；复凝完成后，将微胶囊悬浮液置于-20℃的恒温低温反应浴中，边搅拌边降温，搅拌速度为2500r/min，待溶液温度降至5℃时，加入10％氢氧化钠溶液调节至pH为9.0，搅拌处理20min；加入5ml多乙烯多胺，搅拌处理20min，再移到45℃水浴锅中，搅拌处理2h，然后在转速为7500r/min条件下离心5min，取沉淀，室温下晾干，得到复合精油微胶囊；
第二步：制备复合精油微胶囊整理剂：
将28g微胶囊溶于1L纯化水中，加入聚苯乙烯4g，使微胶囊均匀的分散在整理液中，再加入100g聚乙酸乙烯酯，混合均匀得到微胶囊整理剂。
(7)检查织物是否合格，合格则为成品。
实施例3
一种防蚊抗菌纺织品织物，包括重量百分比为15％黏胶负离子功能纤维、15％大豆蛋白纤维、20％麻纤维、5％羊毛纤维、5％纳米竹炭纤维、15％甲壳素纤维、5％纳米银离子纤维、6％抗紫外整理剂和4％驱蚊整理剂；其中黏胶负离子功能纤维采用120旦的复丝，且黏胶负离子功能纤维中负离子粉添加量为5％；纳米二氮化钛的粒径为105nm；抗紫外整理剂是由40％氧化锌、40％二氧化钛、20％的聚酯母粒混合而成；驱蚊整理剂为大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1:4:1:7:8的质量比的混合物。
所述防蚊抗菌纺织品织物，包括以下步骤：
(1)将黏胶负离子功能纤维、羊毛纤维、纳米竹炭纤维、纳米银离子纤维混合均匀，加入分散剂、粘结剂、柔软剂，经过搅拌，晾干处理；
(2)将大豆蛋白纤维、麻纤维、甲壳素纤维各自经清棉、疏棉处理；
(3)将经过步骤(1)和(2)处理的纤维并条，再依次经粗纱、细纱、自动络筒、蒸纱、高速并线、倍捻处理得到精仿纱；
(4)采用平纹、二上一下斜纹或二上二下斜纹进行织造；
(5)加入3％的净洗剂和2％的柔软剂对衣服进行水洗处理，水温控制在40℃，水洗15min；
(6)加入抗紫外整理剂、驱蚊整理剂浸渍经过步骤(5)处理过的布匹30分钟，然后再在70℃下焙烤，最后定型处理；
所述驱蚊整理剂的制备方法为：
第一步：制备微胶囊：
将10.0g明胶、4.5g甘油和6gβ-环糊精，加入1000ml蒸馏水中，在50℃水浴锅中溶解完全，制备明胶、甘油、β-环糊精溶液；
取出100-250ml明胶、甘油、β-环糊精溶液，加入大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1:4:1:7:8的质量比的混合物，在高剪切力分散乳化机下乳化，转速为4000r/min，乳化时间为10min；乳化结束后滴加10％的醋酸溶液调节体系的pH值为4.5-5.0，转速为2500r/min条件下复凝15min，形成微胶囊悬浮液；复凝完成后，将微胶囊悬浮液置于-20℃的恒温低温反应浴中，边搅拌边降温，搅拌速度为2500r/min，待溶液温度降至5℃时，加入10％氢氧化钠溶液调节至pH为9.0，搅拌处理20min；加入5ml多乙烯多胺，搅拌处理20min，再移到45℃水浴锅中，搅拌处理2h，然后在转速为7500r/min条件下离心5min，取沉淀，室温下晾干，得到复合精油微胶囊；
第二步：制备复合精油微胶囊整理剂：
将25g微胶囊溶于1L纯化水中，加入聚苯乙烯4g，使微胶囊均匀的分散在整理液中，再加入100g聚乙酸乙烯酯，混合均匀得到微胶囊整理剂。
(7)检查织物是否合格，合格则为成品。
实施例4
一种防蚊抗菌纺织品织物，包括重量百分比为15％黏胶负离子功能纤维、15％大豆蛋白纤维、20％麻纤维、10％羊毛纤维、10％纳米竹炭纤维、10％甲壳素纤维、2％纳米银离子纤维、4％抗紫外整理剂、2％驱蚊整理剂；其中黏胶负离子功能纤维采用120旦的复丝，且黏胶负离子功能纤维中负离子粉添加量为5％；纳米二氮化钛的粒径为90nm；抗紫外整理剂是由40％氧化锌、40％二氧化钛、20％的聚酯母粒混合而成；驱蚊整理剂为大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1:7:2:7:11的质量比的混合物。
所述防蚊抗菌纺织品织物，包括以下步骤：
(1)将黏胶负离子功能纤维、羊毛纤维、纳米竹炭纤维、纳米银离子纤维混合均匀，加入分散剂、粘结剂、柔软剂，经过搅拌，晾干处理；
(2)将大豆蛋白纤维、麻纤维、甲壳素纤维各自经清棉、疏棉处理；
(3)将经过步骤(1)和(2)处理的纤维并条，再依次经粗纱、细纱、自动络筒、蒸纱、高速并线、倍捻处理得到精仿纱；
(4)采用平纹、二上一下斜纹或二上二下斜纹进行织造；
(5)加入3％的净洗剂和2％的柔软剂对衣服进行水洗处理，水温控制在40℃，水洗15min；
(6)加入抗紫外整理剂、驱蚊整理剂浸渍经过步骤(5)处理过的布匹30分钟，然后再在70℃下焙烤，最后定型处理；
所述驱蚊整理剂的制备方法为：
第一步：制备微胶囊：
将10.0g明胶、4.5g甘油和6gβ-环糊精，加入1000ml蒸馏水中，在50℃水浴锅中溶解完全，制备明胶、甘油、β-环糊精溶液；
取出100-250ml明胶、甘油、β-环糊精溶液，加入大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1:7:2:7:11的质量比的混合物，在高剪切力分散乳化机下乳化，转速为4000r/min，乳化时间为10min；乳化结束后滴加10％的醋酸溶液调节体系的pH值为4.5，转速为2500r/min条件下复凝15min，形成微胶囊悬浮液；复凝完成后，将微胶囊悬浮液置于-20℃的恒温低温反应浴中，边搅拌边降温，搅拌速度为2500r/min，待溶液温度降至5℃时，加入10％氢氧化钠溶液调节至pH为9.0，搅拌处理20min；加入5ml多乙烯多胺，搅拌处理20min，再移到45℃水浴锅中，搅拌处理2h，然后在转速为7500r/min条件下离心5min，取沉淀，室温下晾干，得到复合精油微胶囊；
第二步：制备复合精油微胶囊整理剂：
将35g微胶囊溶于1L纯化水中，加入聚苯乙烯3g，使微胶囊均匀的分散在整理液中，再加入50g聚乙酸乙烯酯，混合均匀得到微胶囊整理剂。
(7)检查织物是否合格，合格则为成品。
申请人声明，本发明通过上述实施例来说明本发明的详细工艺设备和工艺流程，但本发明并不局限于上述详细工艺设备和工艺流程，即不意味着本发明必须依赖上述详细工艺设备和工艺流程才能实施。所属技术领域的技术人员应该明了，对本发明的任何改进，对本发明产品各原料的等效替换及辅助成分的添加、具体方式的选择等，均落在本发明的保护范围和公开范围之内。
Claims (6)
1. 一种防蚊抗菌纺织品织物，其特征在于，所述纺织品织物包括重量百分比为10-15％黏胶负离子功能纤维、10-15％大豆蛋白纤维、20-30％麻纤维、5-10％羊毛纤维、5-10％纳米竹炭纤维、10-15％甲壳素纤维、2-5％纳米银离子纤维、4-6％抗紫外整理剂和2-4％驱蚊整理剂；所述防蚊整理剂的防蚊药物为大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1-5:3-10:1-5:3-7:8-12的质量比的混合物。
2.如权利要求1所述的防蚊抗菌纺织品织物，其特征在于，所述防蚊药物为大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1-3:5-8:1-4:5-7:10-12的质量比的混合物。
3.如权利要求1或2所述的防蚊抗菌纺织品织物的制备方法，其特征在于，所述方法包括如下步骤：
(1)将黏胶负离子功能纤维、羊毛纤维、纳米竹炭纤维、纳米银离子纤维混合均匀，加入分散剂、粘结剂、柔软剂，经过搅拌，晾干处理；
(2)将大豆蛋白纤维、麻纤维、甲壳素纤维各自经清棉、疏棉处理；
(3)将经过步骤(1)和(2)处理的纤维并条，再依次经粗纱、细纱、自动络筒、蒸纱、高速并线、倍捻处理得到精仿纱；
(4)采用平纹、二上一下斜纹或二上二下斜纹进行织造；
(5)加入3％的净洗剂和2％的柔软剂对衣服进行水洗处理，水温控制在40-45℃，水洗10-15min；
(6)加入抗紫外整理剂、驱蚊整理剂浸渍经过步骤(5)处理过的布匹30-70分钟，然后再在70-80℃下焙烤，最后定型处理；
(7)检查织物是否合格，合格则为成品。
4. 如权利要求3所述的方法，其特征在于，所述驱蚊整理剂的制备方法为：第一步：制备微胶囊： 将10.0g明胶、4.5g甘油和6gβ-环糊精，加入1000ml蒸馏水中，在50℃水浴锅中溶解完全，制备明胶、甘油、β-环糊精溶液；取出100-250ml明胶、甘油、β-环糊精溶液，加入大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1-3:5-8:1-4:5-7:10-12的质量比的混合物，在高剪切力分散乳化机下乳化，转速为4000r/min，乳化时间为10min；乳化结束后滴加10％的醋酸溶液调节体系的pH值为4.5-5.0，转速为2500r/min条件下复凝15min，形成微胶囊悬浮液；复凝完成后，将微胶囊悬浮液置于-20℃的恒温低温反应浴中，边搅拌边降温，搅拌速度为2500r/min，待溶液温度降至5℃时，加入10％氢氧化钠溶液调节至pH为9.0，搅拌处理20min；加入5-9ml多乙烯多胺，搅拌处理20-25min，再移到45-48℃水浴锅中，搅拌处理2h，然后在转速为7000-7500r/min条件下离心5min，取沉淀，室温下晾干，得到复合精油微胶囊；第二步：制备复合精油微胶囊整理剂：将25-35g微胶囊溶于1L纯化水中，加入聚苯乙烯2-4g，使微胶囊均匀的分散在整理液中，再加入50-150g聚乙酸乙烯酯，混合均匀得到微胶囊整理剂。
5.根据权利要求3或4所述的方法，其特征在于，所述方法包括以下步骤：
(1)将黏胶负离子功能纤维、羊毛纤维、纳米竹炭纤维、纳米银离子纤维混合均匀，加入分散剂、粘结剂、柔软剂，经过搅拌，晾干处理；
(2)将大豆蛋白纤维、麻纤维、甲壳素纤维各自经清棉、疏棉处理；
(3)将经过步骤(1)和(2)处理的纤维并条，再依次经粗纱、细纱、自动络筒、蒸纱、高速并线、倍捻处理得到精仿纱；
(4)采用平纹、二上一下斜纹或二上二下斜纹进行织造；
(5)加入3％的净洗剂和2％的柔软剂对衣服进行水洗处理，水温控制在40-45℃，水洗10-15min；
(6)加入抗紫外整理剂、驱蚊整理剂浸渍经过步骤(5)处理过的布匹30-70分钟，然后再在70-80℃下焙烤，最后定型处理；其中所述驱蚊整理剂的制备方法为：
第一步：制备微胶囊： 将10.0g明胶、4.5g甘油和6gβ-环糊精，加入1000ml蒸馏水中，在50℃水浴锅中溶解完全，制备明胶、甘油、β-环糊精溶液；取出100-250ml明胶、甘油、β-环糊精溶液，加入大蒜精油、桉叶精油、青蒿油、沸石粉和对孟烷-3,8-二醇按1-3:5-8:1-4:5-7:10-12的质量比的混合物，在高剪切力分散乳化机下乳化，转速为4000r/min，乳化时间为10min；乳化结束后滴加10％的醋酸溶液调节体系的pH值为4.5-5.0，转速为2500r/min条件下复凝15min，形成微胶囊悬浮液；复凝完成后，将微胶囊悬浮液置于-20℃的恒温低温反应浴中，边搅拌边降温，搅拌速度为2500r/min，待溶液温度降至5℃时，加入10％氢氧化钠溶液调节至pH为9.0，搅拌处理20min；加入5-9ml多乙烯多胺，搅拌处理20-25min，再移到45-48℃水浴锅中，搅拌处理2h，然后在转速为7000-7500r/min条件下离心5min，取沉淀，室温下晾干，得到复合精油微胶囊；第二步：制备复合精油微胶囊整理剂： 将25-35g微胶囊溶于1L纯化水中，加入聚苯乙烯2-4g，使微胶囊均匀的分散在整理液中，再加入50-150g聚乙酸乙烯酯，混合均匀得到微胶囊整理剂；
(7)检查织物是否合格，合格则为成品。
6.根据权利要求1或2所述的防蚊驱蚊纺织品织物在家纺用品、卫生用品、体育用品或医疗保健上的应用。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811375425.5A CN109594333A (zh) | 2018-11-19 | 2018-11-19 | 一种防蚊抗菌纺织品织物及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811375425.5A CN109594333A (zh) | 2018-11-19 | 2018-11-19 | 一种防蚊抗菌纺织品织物及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109594333A true CN109594333A (zh) | 2019-04-09 |
Family
ID=65958733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811375425.5A Withdrawn CN109594333A (zh) | 2018-11-19 | 2018-11-19 | 一种防蚊抗菌纺织品织物及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109594333A (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110258000A (zh) * | 2019-07-09 | 2019-09-20 | 苏州经贸职业技术学院 | 一种抗菌防臭吸汗面料及其制备方法 |
| CN112252041A (zh) * | 2019-07-22 | 2021-01-22 | 新乡市护神特种织物有限公司 | 一种防蚊虫针织物及其制造方法 |
| CN112663334A (zh) * | 2020-12-23 | 2021-04-16 | 杭州宏达装饰布织造有限公司 | 一种驱蚊助眠面料及其加工方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103255538A (zh) * | 2013-04-19 | 2013-08-21 | 晋江市闽高纺织科技有限公司 | 一种防紫外抗菌面料及其制备工艺 |
| CN106480740A (zh) * | 2016-09-30 | 2017-03-08 | 无锡市长安曙光手套厂 | 一种防蚊抗菌纺织品织物及其制备方法 |
| CN108691033A (zh) * | 2018-06-25 | 2018-10-23 | 南通汇达服饰有限公司 | 一种防蚊抗菌面料 |
-
2018
- 2018-11-19 CN CN201811375425.5A patent/CN109594333A/zh not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103255538A (zh) * | 2013-04-19 | 2013-08-21 | 晋江市闽高纺织科技有限公司 | 一种防紫外抗菌面料及其制备工艺 |
| CN106480740A (zh) * | 2016-09-30 | 2017-03-08 | 无锡市长安曙光手套厂 | 一种防蚊抗菌纺织品织物及其制备方法 |
| CN108691033A (zh) * | 2018-06-25 | 2018-10-23 | 南通汇达服饰有限公司 | 一种防蚊抗菌面料 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110258000A (zh) * | 2019-07-09 | 2019-09-20 | 苏州经贸职业技术学院 | 一种抗菌防臭吸汗面料及其制备方法 |
| CN112252041A (zh) * | 2019-07-22 | 2021-01-22 | 新乡市护神特种织物有限公司 | 一种防蚊虫针织物及其制造方法 |
| CN112663334A (zh) * | 2020-12-23 | 2021-04-16 | 杭州宏达装饰布织造有限公司 | 一种驱蚊助眠面料及其加工方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106480740A (zh) | 一种防蚊抗菌纺织品织物及其制备方法 | |
| EP3819410A2 (en) | Plant-based functional polyester filament and preparation method thereof | |
| CN109594333A (zh) | 一种防蚊抗菌纺织品织物及其制备方法 | |
| CN108754867A (zh) | 一种抗菌无纺布及其制备方法 | |
| CN101215726A (zh) | 阻燃粘胶纤维制造方法 | |
| CN113638069B (zh) | 一种面膜基布用备长炭复合改性纳米铂金竹浆纤维及其制备方法 | |
| CN112779644B (zh) | 一种调温抗菌防蚊纱线、织物及其制备方法 | |
| CN112921449A (zh) | 壳聚糖季铵盐/海藻复合抗菌纤维及其制备方法和在儿童用家纺制品中的用途 | |
| CN106757466A (zh) | 植物纤维混纺亲肤面料及其加工方法 | |
| CN107142542B (zh) | 一种蚕丝蛋白再生纤维素纤维及其制备方法 | |
| CN107955995B (zh) | 一种多功能蛋白纤维 | |
| CN113981555A (zh) | 一种芳香型再生纤维素纤维、面料及制备方法 | |
| CN113089321A (zh) | 乙烯基单体接枝改性的抗菌纤维及其制备方法和在抗菌袜中的用途 | |
| CN106400520A (zh) | 一种驱蚊帐篷及其制备方法 | |
| CN113152082A (zh) | 一种含田菁纤维的抗菌家纺面料及其制备方法 | |
| CN106702572A (zh) | 含负离子且抗菌除臭的竹炭纤维被及其制备方法 | |
| CN110172741A (zh) | 一种功能性纤维素类纤维的制备方法 | |
| CN102146592A (zh) | 再生纤维素燃脂纤维及其生产方法 | |
| CN109338494A (zh) | 一种驱蚊粘胶纤维及其制备方法 | |
| CN113151925A (zh) | 一种聚季铵盐/芦荟抗菌纤维及其制备方法和在抗菌毛巾中的用途 | |
| CN106480739A (zh) | 一种防蚊虫纺织品织物及其制备方法 | |
| CN107956036B (zh) | 支撑气垫鞋底的3d网布 | |
| JP3096037B1 (ja) | トルマリン含有絹繊維製品とその製造方法 | |
| JP4933003B2 (ja) | 炭素粉を繊維内部に含有する単繊維及びこの単繊維からなる加工体並びに綿体及び炭素粉を繊維表面又は繊維間に含有する加工体並びに綿体 | |
| CN115976736A (zh) | 一种含茶多酚的抗菌无纺布及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190409 |
|
| WW01 | Invention patent application withdrawn after publication |