CN109574164A - Environment-friendlywater water treatment agent and preparation method thereof for swimming pool water process - Google Patents
Environment-friendlywater water treatment agent and preparation method thereof for swimming pool water process Download PDFInfo
- Publication number
- CN109574164A CN109574164A CN201710904086.4A CN201710904086A CN109574164A CN 109574164 A CN109574164 A CN 109574164A CN 201710904086 A CN201710904086 A CN 201710904086A CN 109574164 A CN109574164 A CN 109574164A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- mixed liquor
- water
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 117
- 230000009182 swimming Effects 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 31
- 230000008569 process Effects 0.000 title claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 41
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 244000223014 Syzygium aromaticum Species 0.000 claims abstract description 13
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims abstract description 13
- 240000002234 Allium sativum Species 0.000 claims abstract description 12
- 241000205585 Aquilegia canadensis Species 0.000 claims abstract description 12
- 235000013717 Houttuynia Nutrition 0.000 claims abstract description 12
- 240000000691 Houttuynia cordata Species 0.000 claims abstract description 12
- 241000218682 Pseudolarix amabilis Species 0.000 claims abstract description 12
- 241000722921 Tulipa gesneriana Species 0.000 claims abstract description 12
- 235000004611 garlic Nutrition 0.000 claims abstract description 12
- 241001116389 Aloe Species 0.000 claims abstract description 11
- 244000020518 Carthamus tinctorius Species 0.000 claims abstract description 11
- 235000003255 Carthamus tinctorius Nutrition 0.000 claims abstract description 11
- 244000178870 Lavandula angustifolia Species 0.000 claims abstract description 11
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims abstract description 11
- 244000179560 Prunella vulgaris Species 0.000 claims abstract description 11
- 235000010674 Prunella vulgaris Nutrition 0.000 claims abstract description 11
- 235000011399 aloe vera Nutrition 0.000 claims abstract description 11
- 235000019441 ethanol Nutrition 0.000 claims abstract description 11
- 239000001102 lavandula vera Substances 0.000 claims abstract description 11
- 235000018219 lavender Nutrition 0.000 claims abstract description 11
- 229920002413 Polyhexanide Polymers 0.000 claims abstract description 9
- 229920001661 Chitosan Polymers 0.000 claims abstract description 8
- 229930006000 Sucrose Natural products 0.000 claims abstract description 8
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 8
- 239000005720 sucrose Substances 0.000 claims abstract description 8
- 108091003079 Bovine Serum Albumin Proteins 0.000 claims abstract description 7
- 108010010803 Gelatin Proteins 0.000 claims abstract description 7
- 229940098773 bovine serum albumin Drugs 0.000 claims abstract description 7
- 229920000159 gelatin Polymers 0.000 claims abstract description 7
- 239000008273 gelatin Substances 0.000 claims abstract description 7
- 235000019322 gelatine Nutrition 0.000 claims abstract description 7
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 7
- 239000000706 filtrate Substances 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 23
- 230000004913 activation Effects 0.000 claims description 22
- 238000004898 kneading Methods 0.000 claims description 21
- 239000000853 adhesive Substances 0.000 claims description 17
- 230000001070 adhesive effect Effects 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 15
- 229920002472 Starch Polymers 0.000 claims description 14
- 238000003763 carbonization Methods 0.000 claims description 12
- 239000010881 fly ash Substances 0.000 claims description 11
- 239000000047 product Substances 0.000 claims description 11
- 239000008107 starch Substances 0.000 claims description 10
- 235000019698 starch Nutrition 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 8
- 239000002893 slag Substances 0.000 claims description 8
- 229920002261 Corn starch Polymers 0.000 claims description 7
- 244000017020 Ipomoea batatas Species 0.000 claims description 7
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 7
- 239000008120 corn starch Substances 0.000 claims description 7
- 229940099112 cornstarch Drugs 0.000 claims description 7
- 229920001592 potato starch Polymers 0.000 claims description 7
- 239000012190 activator Substances 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- 235000019890 Amylum Nutrition 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract description 24
- 239000004202 carbamide Substances 0.000 abstract description 24
- 230000001954 sterilising effect Effects 0.000 abstract description 9
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 2
- 238000009835 boiling Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 18
- 238000004659 sterilization and disinfection Methods 0.000 description 18
- 241000894006 Bacteria Species 0.000 description 12
- 241000411851 herbal medicine Species 0.000 description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
- 239000000460 chlorine Substances 0.000 description 9
- 229910052801 chlorine Inorganic materials 0.000 description 9
- 239000000645 desinfectant Substances 0.000 description 9
- 238000013329 compounding Methods 0.000 description 8
- 108090000790 Enzymes Proteins 0.000 description 6
- 102000004190 Enzymes Human genes 0.000 description 6
- 241000233866 Fungi Species 0.000 description 6
- 244000005700 microbiome Species 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 239000005446 dissolved organic matter Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 235000008216 herbs Nutrition 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- 241000700605 Viruses Species 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 3
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 229960003260 chlorhexidine Drugs 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 230000002147 killing effect Effects 0.000 description 3
- 230000001404 mediated effect Effects 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 210000002700 urine Anatomy 0.000 description 3
- 206010043866 Tinea capitis Diseases 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004925 denaturation Methods 0.000 description 2
- 230000036425 denaturation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 210000003470 mitochondria Anatomy 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 210000003463 organelle Anatomy 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- -1 K-IAO Chemical compound 0.000 description 1
- 102000004895 Lipoproteins Human genes 0.000 description 1
- 108090001030 Lipoproteins Proteins 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 description 1
- 241001128140 Reseda Species 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- 230000001857 anti-mycotic effect Effects 0.000 description 1
- 239000002543 antimycotic Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229930006739 camphene Natural products 0.000 description 1
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 108010017796 epoxidase Proteins 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 238000002169 hydrotherapy Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 230000007853 structural degeneration Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 208000009189 tinea favosa Diseases 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/342—Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/42—Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
Abstract
The present invention is provided to Environment-friendlywater water treatment agents of swimming pool water process and preparation method thereof, comprising the following steps: mix cordate houttuynia, gingili leaf and garlic, ethyl alcohol grinding is added, filters to obtain the first mixed liquor；After cloves, tulip, honeysuckle, golden larch, radix scutellariae, lavender, aloe, safflower, rhizoma zingiberis, Prunella vulgaris and folium artemisiae argyi are mixed plus boiling boils, filters to obtain the second mixed liquor；Polyhexamethylene guanide, the first mixed liquor and the second mixed liquor are mixed into obtain third mixed liquor；Bovine serum albumin, K-IAO, sucrose, chitosan, gelatin and acetic acid are mixed, urase is then added and mixes to obtain the 4th mixed liquor；Column-shaped active carbon is immersed into drying after 20~40min in third mixed liquor, is then stirred 30~60min with the 4th mixed liquor of step 4, naturally dry obtains target product.Water treatment agent produced by the present invention can effectively decompose the organic matters such as the urea in water, safety and environmental protection, while have sterilizing effect.
Description
Technical field
The present invention relates to water-treatment technology fields, the more particularly, to Environment-friendlywater water treatment agent and its system of swimming pool water process
Preparation Method.
Background technique
Swimming is the favorite movement of people, and swimming can not only enjoy the enjoyment with water phase touching, moreover it is possible to reach and keep fit and healthy
Effect.It especially scorching summer, swims freely in swimming pool, strictly a kind of very satisfied enjoyment.As people live
Horizontal raising, indoor swimming provide the Swimming pool not constrained by season for vast swimming fan.Swimming pool, hydrotherapy pool
Skin night, secretion, urine, sweat, the skin care item, makeup brought into Deng the organic pollutant in similar water environment mainly from human body
Product etc., wherein most are the dissolved organic matters such as urea, these dissolved organic matters are that conventional filtration technique can not filter out,
These dissolved organic matters not only increase the dosage of the oxidized forms disinfectant such as ozone and chlorine, increase reagent cost, can also disappear with chlorine
Toxic agent reacts, and generates the carcinogenic substance to human health.
Studies have shown that swimming pool is averaged, everyone urine volume is 50ml, and urea content is 1.8% in urine, commuter rush hour summer
When, a 2000m3Standard swimming pool, the volume of the flow of passengers is at 3000 person-times or so within one day, it is only necessary to 3 days, urea and other organic matters
Content can reach standard max, and the method that swimming pool reduces water organic matter both at home and abroad at present is to change water, this is resulted in largely
The waste of tap water, it is also very big with stylish benefit tap water heating energy consumption, heavy burden is brought to natatorium operation.Therefore, at present
Domestic natatorium is all not achieved quantity of exchanged water required by standard at runtime, when summer peak, 90% or more natatorium urea
And combined residual chlorine is exceeded, many natatorium urea contents reach 10mg/L or more, combined residual chlorine content be more than 1.0mg/L,
CODMn content is more than 10mg/L, causes water and air quality to be deteriorated, is detrimental to health.
Existing swimming pool water treatment technology mainly intercepts then oxidation sterilizing using filtering, but can not effectively remove water
Urea, ammonia nitrogen and the organic matter of middle dissolution.Even if being also only capable of absorbed portion molecular weight in 400- using active carbon absorption technology
2000 dissolved organic matter, and organic matter and urea, ammonia nitrogen etc. to other molecular weight, without suction-operated, simultaneously as swimming
Water cycle process in pond can also often add a small amount of fresh water, so microorganism problem can not be excluded completely.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of Environment-friendlywater water treatment agents and its system for swimming pool water process
Preparation Method, which can effectively decompose urea in water, ammonia nitrogen and other organic matters, safety and environmental protection, while having and killing
Bacterium disinfection can greatly improve water quality, and can effectively reduce later period disinfectant consumption and quantity of exchanged water.
To achieve the goals above, the technical solution adopted by the present invention one are as follows:
The preparation method of Environment-friendlywater water treatment agent for swimming pool water process, comprising the following steps:
Step 1: the garlic of the cordate houttuynia of 3~5 parts by weight, the gingili leaf of 5~6 parts by weight and 2~3 parts by weight being mixed, then
The ethyl alcohol that 10~15 parts by weight volumetric concentrations are 80~90% is added to grind, the first mixed liquor is obtained by filtration；
Step 2: by the cloves of 4~5 parts by weight, the tulip of 5~7 parts by weight, the honeysuckle of 3~5 parts by weight, 7~9 parts by weight
Golden larch, the radix scutellariae of 2~3 parts by weight, the lavender of 4~5 parts by weight, the aloe of 2~3 parts by weight, 2~3 parts by weight hiding
The folium artemisiae argyi mixing of safflower, the rhizoma zingiberis of 2~3 parts by weight, the Prunella vulgaris of 2~3 parts by weight and 1~2 parts by weight, then it is added 200~
The water of 300 parts by weight, boils 40~60min, and the second mixed liquor is obtained by filtration；
Step 3: by the polyhexamethylene guanide of 0.3~0.5 parts by weight, the second mixed liquor of the first mixed liquor of step 1 and step 2
Mixing, obtains third mixed liquor；
Step 4: by the bovine serum albumin of 0.05~0.08 parts by weight, the K-IAO of 0.5~1.0 parts by weight, 0.2~1.0
The sucrose of parts by weight, the chitosan of 0.5~1.0 parts by weight, the gelatin of 0.5~1.0 parts by weight and 20~30mL mass concentration are
Then 1% acetic acid mixing is added 0.1 ~ 0.2 parts by weight urase and mixes to obtain the 4th mixed liquor；
Step 5: the column-shaped active carbon of 50~100 parts by weight is immersed into drying after 20~40min in the third mixed liquor of step 3,
Then it is stirred 30~60min with the 4th mixed liquor of step 4, naturally dry obtains target product.
The key ideas of above-mentioned technical proposal one is: as compounding Chinese medicine sterilizing disinfectant and being divided using column-shaped active carbon
The carrier of the urase of urea is solved, so that the column-shaped active carbon puts into swimming pool in use, using the urase decomposing pool on activated carbon
The organic matters such as a large amount of urea in water, while sterilizing, pole are carried out using the compound sterilizing disinfectant carried on activated carbon
It is big to improve water quality, to reduce the dosage and quantity of exchanged water of later period chlorhexidine-containing disinfectant.
Further, the column-shaped active carbon is prepared by following methods:
Step a: stirring carries out 10~20min of kneading after water in kneader, is added after flyash and shell carbonization power are mixed,
Then adhesive is added and continues 10~15min of kneading, obtains kneading material；
Step b: the kneading material of step a is squeezed into the column billot that diameter is 3.0~6.0mm using press machine, is then set
30~60min is toasted in the environment of 200~250 DEG C；
Step c: it will be activated in step b treated column billot investment activation furnace, make activator, the temperature of activation with superheated water
At 950~1000 DEG C, 4~10h of activation time obtains the column-shaped active carbon for control.
Further, described adhesive is the amylum adhesive or carboxylic that cornstarch, sweet potato starch and other starch are prepared
Methylcellulose.
Further, the concrete operations of step 1 are as follows: by the gingili leaf of the cordate houttuynia of 3~5 parts by weight and 5~6 parts by weight point
It does not shred, then the garlic mixing smashed to pieces with 2~3 parts by weight, the second that 10~15 parts by weight volumetric concentrations are 80~90% is then added
Alcohol grinds 20~40min, is removed slag using 150 mesh filtered through gauze, obtains the first mixed liquor.
Further, the concrete operations of step 2 are as follows: by the cloves of 4~5 parts by weight, the tulip of 5~7 parts by weight, 3~5
The honeysuckle of parts by weight, the golden larch of 7~9 parts by weight, the radix scutellariae of 2~3 parts by weight, the lavender of 4~5 parts by weight, 2~3 weights
Measure the aloe of part, the safflower of 2~3 parts by weight, the rhizoma zingiberis of 2~3 parts by weight, the Prunella vulgaris of 2~3 parts by weight and 1~2 parts by weight
Folium artemisiae argyi mixing, then be added 100~150 parts by weight water, boil 20~30min, the dregs of a decoction and the first filtrate filtered to obtain, to medicine
The water of 100~150 parts by weight is added in slag, boils 20~30min, filter and remove residue obtains the second filtrate, merges the first filtrate and the
Two filtrates obtain the second mixed liquor.
Further, the concrete operations of step 5 are as follows: the column-shaped active carbon of 50~100 parts by weight is immersed to the third of step 3
Stir 20~40min in mixed liquor, then dried under 28~35 DEG C of environment, then be placed under 45~50 DEG C of environment drying 20~
30min, before use, being stirred 30~60min with the 4th mixed liquor of step 4 again, naturally dry obtains target product.
The beneficial effect of above-mentioned technical proposal one is: (1) preparation method of the invention is using column-shaped active carbon as urase
Carrier so that obtained water treatment agent had both maintained the absorption property of active carbon script, can remove in swimming pool suspended matter and point
Dissolved organic matter of the molecular weight 400~2000, at the same the urase on activated carbon can to the organic matters such as urea in swimming-pool water into
Row decomposes, and to significantly improve water quality, effectively reduces quantity of exchanged water, can increase the number of water recycling, saves water resource；
(2) preparation method of the invention is simultaneously using column-shaped active carbon as the Chinese herbal medicine disinfection sanitizer (third mixed liquor) of compounding
Carrier, so that the middle medicinal herbs disinfection sanitizer compounded in the water treatment agent is in the case where injuring human skin, it can be effective
The microorganisms such as most bacterium, fungi or the virus in water are killed, reduces the usage amount of later period chlorhexidine-containing disinfectant, effectively avoids chemical combination
Property chlorine residue it is exceeded, meanwhile, the Chinese herbal medicine disinfection sanitizer of compounding can be effectively relieved in water rich in a variety of dulcet flowers of tool
Existing pungent smell；(3) for water treatment agent prepared by the present invention not using the chemical reagent that will appear secondary pollution, majority is natural
Environment-friendly materials, more safety and environmental protection；(4) preparation method of the invention can make the effective component in Chinese herbal medicine sufficiently be dissolved into solvent
In to keep subsequent sterilization effect, while can effectively keep the enzyme activity of urase by adding stabilizer, and then ensure to make
Decomposition efficiency of the used time urase to organic matters such as urea；(5) using column-shaped active carbon as carrier, on the one hand, it has preferable
Porous structure, adsorptivity is more preferable, on the other hand, recycling can be facilitated.
To achieve the goals above, the technical solution adopted by the present invention two are as follows:
The Environment-friendlywater water treatment agent of swimming pool water process is used for according to made from above-mentioned preparation method.
The key ideas of above-mentioned technical proposal two is: by and meanwhile carry compound Chinese medicine disinfection sanitizer and urea and decompose
The column-shaped active carbon of enzyme is as swimming pool water treatment agent.
Specific embodiment
It is as follows that the present invention is described further combined with specific embodiments below:
Provided by the present invention for the preparation method of the Environment-friendlywater water treatment agent of swimming pool water process, comprising the following steps:
Step 1: the garlic of the cordate houttuynia of 3~5 parts by weight, the gingili leaf of 5~6 parts by weight and 2~3 parts by weight being mixed, then
The ethyl alcohol that 10~15 parts by weight volumetric concentrations are 80~90% is added to grind, the first mixed liquor is obtained by filtration；
Step 2: by the cloves of 4~5 parts by weight, the tulip of 5~7 parts by weight, the honeysuckle of 3~5 parts by weight, 7~9 parts by weight
Golden larch, the radix scutellariae of 2~3 parts by weight, the lavender of 4~5 parts by weight, the aloe of 2~3 parts by weight, 2~3 parts by weight hiding
The folium artemisiae argyi mixing of safflower, the rhizoma zingiberis of 2~3 parts by weight, the Prunella vulgaris of 2~3 parts by weight and 1~2 parts by weight, then it is added 200~
The water of 300 parts by weight, boils 40~60min, and the second mixed liquor is obtained by filtration；
Step 3: by the polyhexamethylene guanide of 0.3~0.5 parts by weight, the second mixed liquor of the first mixed liquor of step 1 and step 2
Mixing, obtains third mixed liquor；
Step 4: by the bovine serum albumin of 0.05~0.08 parts by weight, the K-IAO of 0.5~1.0 parts by weight, 0.2~1.0
The sucrose of parts by weight, the chitosan of 0.5~1.0 parts by weight, the gelatin of 0.5~1.0 parts by weight and 20~30mL mass concentration are
Then 1% acetic acid mixing is added 0.1 ~ 0.2 parts by weight urase and mixes to obtain the 4th mixed liquor；
Step 5: the column-shaped active carbon of 50~100 parts by weight is immersed into drying after 20~40min in the third mixed liquor of step 3,
Then it is stirred 30~60min with the 4th mixed liquor of step 4, naturally dry obtains target product.
Specifically, working principle of the present invention is as follows: since existing swimming pool water process is usually filtered using active carbon, institute
On the one hand to keep the original suction of activated carbon using active carbon as the carrier of medicinal herbs disinfection sanitizer and the carrier of urase in compounding
Attached effect (removal swimming pool in the dissolved organic matter of suspended matter and fractionated molecule amount 400~2000), another side can discharge or not
The disinfection sanitizer on activated carbon is discharged to kill the microorganism in water, decomposes the urea in water using the urase on activated carbon
Equal organic matters, it is ensured that urea and combined residual chlorine in swimming pool meet national standard.The cloves bud carbolic oil of cloves containing volatility has
Strong antibacterial action can be such that bacterium cell structure is denaturalized, and organelle disappears, the obvious shrinkage of cell membrane, structure of mitochondria denaturation
Even disappear, it can 100% killing when bacterium sufficiently exposes；Tulip bud camphene containing volatility oil can be to the skin for causing favus of the scalp
Tinea bacterium has very strong antibacterial action；The honeysuckle vegetable oil of reseda containing the volatility confrontation stronger Candida albicans of bacterium power has extremely strong
Bactericidal effect；Golden larch has very strong antimycotic effect, can make fungal cell's structural degeneration, and organelle disappears, cell membrane
Obvious shrinkage, structure of mitochondria denaturation even disappear, and 100% killing in the case where fungi exposure；Polyhexamethylene guanide has
Very high activity has very strong compatibility to microorganism, it is easy to is usually in electronegative all kinds of bacteriums, fungi and virus
Equal Institute of Micro-biology attract, and quickly comprehensively penetrate into microbial cell, and intracellular protein coagulating is made to be denaturalized to inhibit
Their schizogamy function.By above-mentioned various components (cordate houttuynia, gingili leaf, garlic, cloves, tulip, honeysuckle,
Golden larch, radix scutellariae, lavender, aloe, safflower, rhizoma zingiberis, Prunella vulgaris, folium artemisiae argyi and polyhexamethylene guanide) synergistic effect can be fast
Speed crack all kinds of bacteriums, fungi, virocyte wall main component --- peptide glycan and lipoprotein, and the oxidation of bacterium can be inhibited
The activity of enzyme and epoxidase makes bacterial growth breeding, metabolism obtain required energy by biological oxidation and be destroyed, carefully
The basic vital movement of bacterium stops, and reaches bactericidal effect, while said components have good skin care effect, using more pacifying
Entirely.Since urase is easy interference by external environment, causes unstable and cause to inactivate, by by urase and cow's serum egg
White, K-IAO, sucrose, chitosan, gelatin and the mixing of suitable acetic acid, can improve the Activity and stabill of urase, it is ensured that
The removal rate of urea.
As can be seen from the above description, the invention has the following advantages: (1) preparation method of the invention utilizes column activity
Carrier of the charcoal as urase can remove in swimming pool so that obtained water treatment agent had both maintained the absorption property of active carbon script
The dissolved organic matter of suspended matter and fractionated molecule amount 400~2000, while the urase on activated carbon can be to the urea in swimming-pool water
Equal organic matters are decomposed, and to significantly improve water quality, effectively reduce quantity of exchanged water, can increase the number of water recycling, section
About water resource；(2) preparation method of the invention is simultaneously using column-shaped active carbon as the Chinese herbal medicine disinfection sanitizer (third of compounding
Mixed liquor) carrier so that the middle medicinal herbs disinfection sanitizer compounded in the water treatment agent is in the case where injuring human skin,
The microorganisms such as most bacterium, fungi or the virus in water can be effectively killed, reduce the usage amount of later period chlorhexidine-containing disinfectant, effectively
Avoid combined residual chlorine exceeded, meanwhile, the Chinese herbal medicine disinfection sanitizer of compounding can be effectively relieved rich in a variety of dulcet flowers of tool
Occurs pungent smell in water；(3) water treatment agent prepared by the present invention is more not using the chemical reagent that will appear secondary pollution
Number is natural environmental-protective material, more safety and environmental protection；(4) preparation method of the invention can make the effective component in Chinese herbal medicine sufficiently molten
Solution keeps subsequent sterilization effect to being dissolved into solvent, while can effectively keep the enzyme of urase by adding stabilizer
It is living, so ensure using when urase to the decomposition efficiencies of the organic matters such as urea；(5) using column-shaped active carbon as carrier, a side
Face, with preferable porous structure, adsorptivity is more preferable, on the other hand, can facilitate recycling.
Further, the column-shaped active carbon is prepared by following methods:
Step a: stirring carries out 10~20min of kneading after water in kneader, is added after flyash and shell carbonization power are mixed,
Then adhesive is added and continues 10~15min of kneading, obtains kneading material；
Step b: the kneading material of step a is squeezed into the column billot that diameter is 3.0~6.0mm using press machine, is then set
30~60min is toasted in the environment of 200~250 DEG C；
Step c: it will be activated in step b treated column billot investment activation furnace, make activator, the temperature of activation with superheated water
At 950~1000 DEG C, 4~10h of activation time obtains the column-shaped active carbon for control.
The intensity of active carbon obtained by the above method is good, minimum floating dust, has good adsorption capacity, dry process
Direct activation simplifies process without carbonization process；It can be realized using flyash and shell carbonization power as activated carbon raw material useless
Gurry recycles, more environmentally-friendly and reduce cost.
Further, described adhesive is the amylum adhesive or carboxylic that cornstarch, sweet potato starch and other starch are prepared
Methylcellulose.
The amylum adhesive or carboxymethyl cellulose prepared in the above method using cornstarch, sweet potato starch and other starch
Element is adhesive, is avoided using coal tar, more environmentally-friendly, expensive due to coal tar, can also reduce production cost.
Further, the concrete operations of step 1 are as follows: by the gingili leaf of the cordate houttuynia of 3~5 parts by weight and 5~6 parts by weight point
It does not shred, then the garlic mixing smashed to pieces with 2~3 parts by weight, the second that 10~15 parts by weight volumetric concentrations are 80~90% is then added
Alcohol grinds 20~40min, is removed slag using 150 mesh filtered through gauze, obtains the first mixed liquor.
The above method enables to the effective component in cordate houttuynia, gingili leaf and garlic to be more fully dissolved into ethyl alcohol,
Meanwhile individually dissolving these types of substance, and not with other ingredient heating extractions, preferably protect having for its sterilization component
Effect property, further enhances bactericidal effect.
Further, the concrete operations of step 2 are as follows: by the cloves of 4~5 parts by weight, the tulip of 5~7 parts by weight, 3~5
The honeysuckle of parts by weight, the golden larch of 7~9 parts by weight, the radix scutellariae of 2~3 parts by weight, the lavender of 4~5 parts by weight, 2~3 weights
Measure the aloe of part, the safflower of 2~3 parts by weight, the rhizoma zingiberis of 2~3 parts by weight, the Prunella vulgaris of 2~3 parts by weight and 1~2 parts by weight
Folium artemisiae argyi mixing, then be added 100~150 parts by weight water, boil 20~30min, the dregs of a decoction and the first filtrate filtered to obtain, to medicine
The water of 100~150 parts by weight is added in slag, boils 20~30min, filter and remove residue obtains the second filtrate, merges the first filtrate and the
Two filtrates obtain the second mixed liquor.
The above method can be such that the effective component of each component is more fully extracted, and be obtained the active principle in each component
It more fully utilizes, with save the cost.
Meanwhile the effective use in order to further promote each component, the dregs of a decoction of medicinal herbs among the above can be dried and be crushed,
One of initial raw material as above-mentioned column-shaped active carbon (is used in mixed way) with flyash and shell carbonization power, not only saved cost but also
Utilize Chinese herbal medicine more fully.
Further, the concrete operations of step 5 are as follows: the column-shaped active carbon of 50~100 parts by weight is immersed to the third of step 3
Stir 20~40min in mixed liquor, then dried under 28~35 DEG C of environment, then be placed under 45~50 DEG C of environment drying 20~
30min, before use, being stirred 30~60min with the 4th mixed liquor of step 4 again, naturally dry obtains target product.
The column-shaped active carbon for carrying Chinese herbal medicine disinfection sanitizer is being immersed into urase mixing again using preceding by the above method
In liquid, the enzyme activity before on the one hand farthest active carbon being kept to be lauched ensures the urea decomposition efficiency in later period, another side of convenience
Just the preservation of active carbon.
Several preferred embodiments or Application Example are enumerated, again below to help those skilled in the art to better understand
The technical contribution that technology contents and the present invention of the invention are made compared with the existing technology:
Embodiment 1
The preparation method of Environment-friendlywater water treatment agent for swimming pool water process, comprising the following steps:
The preparation of column-shaped active carbon: preparation early period in kneader after flyash and shell carbonization power are mixed, is stirred after water is added
It mixes and carries out 10~20min of kneading, the adhesive (starch adhesion that cornstarch, sweet potato starch and other starch are prepared then is added
Agent or carboxymethyl cellulose) continue 10~15min of kneading, obtain kneading material；Material will be mediated and be squeezed into diameter using press machine
For the column billot of 3.0~6.0mm, 30~60min is toasted in the environment of being subsequently placed in 200~250 DEG C, then puts into activation furnace
Interior activation makees activator with superheated water, and the temperature of activation is controlled at 950~1000 DEG C, 4~10h of activation time, obtains column activity
Charcoal, wherein the mass ratio of the gross mass and adhesive of flyash and shell carbonization power is 10: 1~3；
Step 1: the gingili leaf of the cordate houttuynia of 300g and 500g are shredded respectively, then the garlic mixing smashed to pieces with 200g, then plus
Enter the ethyl alcohol that 1000g volumetric concentration is 80% and grind 20min, is removed slag using 150 mesh filtered through gauze, obtain the first mixed liquor；
Step 2: by the cloves of 400g, the tulip of 500g, the honeysuckle of 300g, the golden larch of 700g, the radix scutellariae of 200g, 400g
Lavender, the aloe of 200g, the safflower of 200g, the rhizoma zingiberis of 200g, the Prunella vulgaris of 200g and 100g folium artemisiae argyi mixing, then
The water of 10000g is added, boils 20min, filters to obtain the dregs of a decoction and the first filtrate, the water of 10000g is added into the dregs of a decoction, boils
20min, filter and remove residue obtain the second filtrate, merge the first filtrate and the second filtrate obtains the second mixed liquor；
Step 3: the second mixed liquor of the polyhexamethylene guanide of 30g, the first mixed liquor of step 1 and step 2 being mixed, obtains the
Three mixed liquors；
Step 4: by the bovine serum albumin of 5g, the K-IAO of 50g, the sucrose of 20g, the chitosan of 50g, 50g gelatin and
The acetic acid that 2000mL mass concentration is 1% mixes, and 10 g urases are then added and mix to obtain the 4th mixed liquor；
Step 5: the column-shaped active carbon of 5000g being immersed in the third mixed liquor of step 3 and stir 20min, then in 28~35 DEG C
It is dried under environment, then is placed under 45 DEG C of environment and dries 20min, before use, in the 4th mixed liquor for being immersed into step 4 again
30min, naturally dry (are dried) under 28~35 DEG C of environment, obtain target product.
Application method: the target product comes into operation during swimming pool is filtered, and can be directly loaded into filter
Canister in use.
Embodiment 2
The preparation of column-shaped active carbon: preparation early period in kneader after flyash and shell carbonization power are mixed, is stirred after water is added
It mixes and carries out 10~20min of kneading, the adhesive (starch adhesion that cornstarch, sweet potato starch and other starch are prepared then is added
Agent or carboxymethyl cellulose) continue 10~15min of kneading, obtain kneading material；Material will be mediated and be squeezed into diameter using press machine
For the column billot of 3.0~6.0mm, 30~60min is toasted in the environment of being subsequently placed in 200~250 DEG C, then puts into activation furnace
Interior activation makees activator with superheated water, and the temperature of activation is controlled at 950~1000 DEG C, 4~10h of activation time, obtains column activity
Charcoal, wherein the mass ratio of the gross mass and adhesive of flyash and shell carbonization power is 10: 1~3；
Step 1: the gingili leaf of the cordate houttuynia of 500g and 600g are shredded respectively, then the garlic mixing smashed to pieces with 300g, then plus
Enter the ethyl alcohol that 1500g volumetric concentration is 90% and grind 40min, is removed slag using 150 mesh filtered through gauze, obtain the first mixed liquor；
Step 2: by the cloves of 500g, the tulip of 700g, the honeysuckle of 500g, the golden larch of 900g, the radix scutellariae of 300g, 500g
Lavender, the aloe of 300g, the safflower of 300g, the rhizoma zingiberis of 300g, the Prunella vulgaris of 300g and 200g folium artemisiae argyi mixing, then
The water of 15000g is added, boils 30min, filters to obtain the dregs of a decoction and the first filtrate, the water of 15000g is added into the dregs of a decoction, boils
30min, filter and remove residue obtain the second filtrate, merge the first filtrate and the second filtrate obtains the second mixed liquor；
Step 3: the second mixed liquor of the polyhexamethylene guanide of 50g, the first mixed liquor of step 1 and step 2 being mixed, obtains the
Three mixed liquors；
Step 4: by the bovine serum albumin of 8g, the K-IAO of 100g, the sucrose of 100g, the chitosan of 100g, 100g it is bright
The acetic acid that glue and 3000mL mass concentration are 1% mixes, and 20g urase is then added and mixes to obtain the 4th mixed liquor；
Step 5: the column-shaped active carbon of 10000g being immersed in the third mixed liquor of step 3 and stir 40min, then in 28~35 DEG C
It is dried under environment, then is placed under 50 DEG C of environment and dries 30min, before use, being stirred again with the 4th mixed liquor of step 4
60min, naturally dry (are dried) under 28~35 DEG C of environment, obtain target product.
Application method is the same as embodiment 1.
Embodiment 3
The preparation of column-shaped active carbon: preparation early period in kneader after flyash and shell carbonization power are mixed, is stirred after water is added
It mixes and carries out 10~20min of kneading, the adhesive (starch adhesion that cornstarch, sweet potato starch and other starch are prepared then is added
Agent or carboxymethyl cellulose) continue 10~15min of kneading, obtain kneading material；Material will be mediated and be squeezed into diameter using press machine
For the column billot of 3.0~6.0mm, 30~60min is toasted in the environment of being subsequently placed in 200~250 DEG C, then puts into activation furnace
Interior activation makees activator with superheated water, and the temperature of activation is controlled at 950~1000 DEG C, 4~10h of activation time, obtains column activity
Charcoal, wherein the mass ratio of the gross mass and adhesive of flyash and shell carbonization power is 10: 1~3；
Step 1: the gingili leaf of the cordate houttuynia of 400g and 550g are shredded respectively, then the garlic mixing smashed to pieces with 250g, then plus
Enter the ethyl alcohol that 1250g volumetric concentration is 85% and grind 30min, is removed slag using 150 mesh filtered through gauze, obtain the first mixed liquor；
Step 2: by the cloves of 450g, the tulip of 600g, the honeysuckle of 400g, the golden larch of 800g, the radix scutellariae of 250g, 450g
Lavender, the aloe of 250g, the safflower of 250g, the rhizoma zingiberis of 250g, the Prunella vulgaris of 250g and 150g folium artemisiae argyi mixing, then
The water of 12500g is added, boils 25min, filters to obtain the dregs of a decoction and the first filtrate, the water of 12500g is added into the dregs of a decoction, boils
25min, filter and remove residue obtain the second filtrate, merge the first filtrate and the second filtrate obtains the second mixed liquor；
Step 3: the second mixed liquor of the polyhexamethylene guanide of 40g, the first mixed liquor of step 1 and step 2 being mixed, obtains the
Three mixed liquors；
Step 4: by the bovine serum albumin of 6.5g, the K-IAO of 75g, the sucrose of 60g, the chitosan of 75g, 75g gelatin
The acetic acid for being 1% with 2500mL mass concentration mixes, and 15g urase is then added and mixes to obtain the 4th mixed liquor；
Step 5: the column-shaped active carbon of 7500g being immersed in the third mixed liquor of step 3 and stir 30min, then in 28~35 DEG C
It is dried under environment, then is placed under 48 DEG C of environment and dries 25min, before use, being stirred again with the 4th mixed liquor of step 4
45min, naturally dry (are dried) under 28~35 DEG C of environment, obtain target product.
Application method is the same as embodiment 1.
Experiment proves that embodiment 1 to 3 can effectively decompose the substances such as the urea in water, with existing only by general
Logical activated carbon adsorption uses the processing mode of chlorination to compare, it can be achieved that reducing the 50% of quantity of exchanged water again；Meanwhile water is every physical and chemical
Index be better than original sub-block technique, wherein content of organics be reduced to 3mg/L hereinafter, urea content be reduced to 0.4mg/L with
Under, combined residual chlorine be reduced to 0.2mg/L hereinafter, disinfectant consumption reduce 70% or more, the present invention can not only energy-saving and water-saving,
Operating cost is reduced, and for the improvement of swimming pool water, guarantee swimmer health, energy-saving and emission-reduction important in inhibiting.
In conclusion provided by the present invention for the Environment-friendlywater water treatment agent and preparation method thereof of swimming pool water process, this hair
Bright preparation method is using column-shaped active carbon as the carrier of urase, so that obtained water treatment agent had both maintained active carbon originally
Absorption property, the dissolved organic matter of suspended matter and fractionated molecule amount 400~2000 in swimming pool can be removed, while on activated carbon
Urase can decompose the organic matters such as urea in swimming-pool water, to significantly improve water quality, effectively reduce quantity of exchanged water, can increase
The number that water is recycled saves water resource；Preparation method of the invention is simultaneously using column-shaped active carbon as in compounding
The carrier of herbal medicine disinfection sanitizer (third mixed liquor), so that the middle medicinal herbs disinfection sanitizer compounded in the water treatment agent is not being hurt
In the case where evil human skin, the microorganisms such as most bacterium, fungi or the virus in water can be effectively killed, reduce later period chlorine
The usage amount of disinfectant effectively avoids combined residual chlorine exceeded, meanwhile, the Chinese herbal medicine disinfection sanitizer of compounding has rich in a variety of
The flower of fragrance can be effectively relieved in water and pungent smell occurs；Water treatment agent prepared by the present invention is not secondary using will appear
The chemical reagent of pollution, majority are natural environmental-protective material, more safety and environmental protection；Preparation method of the invention can make in Chinese herbal medicine
Effective component is sufficiently dissolved into solvent to keep subsequent sterilization effect, while can have by adding stabilizer
Effect keeps the enzyme activity of urase, so ensure using when urase to the decomposition efficiencies of the organic matters such as urea；Made using column-shaped active carbon
For carrier, on the one hand, with preferable porous structure, adsorptivity is more preferable for it, on the other hand, can facilitate recycling.
The present invention is described by above-mentioned related embodiment, however above-described embodiment is only to implement example of the invention.
It must be noted that the embodiment disclosed is not limiting as the scope of the present invention.On the contrary, be included in claim spirit and
The modification of range and impartial setting are included in the scope of the present invention.
Claims (7)
1. the preparation method of the Environment-friendlywater water treatment agent for swimming pool water process, which comprises the following steps:
Step 1: the garlic of the cordate houttuynia of 3~5 parts by weight, the gingili leaf of 5~6 parts by weight and 2~3 parts by weight being mixed, then
The ethyl alcohol that 10~15 parts by weight volumetric concentrations are 80~90% is added to grind, the first mixed liquor is obtained by filtration；
Step 2: by the cloves of 4~5 parts by weight, the tulip of 5~7 parts by weight, the honeysuckle of 3~5 parts by weight, 7~9 parts by weight
Golden larch, the radix scutellariae of 2~3 parts by weight, the lavender of 4~5 parts by weight, the aloe of 2~3 parts by weight, 2~3 parts by weight hiding
The folium artemisiae argyi mixing of safflower, the rhizoma zingiberis of 2~3 parts by weight, the Prunella vulgaris of 2~3 parts by weight and 1~2 parts by weight, then it is added 200~
The water of 300 parts by weight, boils 40~60min, and the second mixed liquor is obtained by filtration；
Step 3: by the polyhexamethylene guanide of 0.3~0.5 parts by weight, the second mixed liquor of the first mixed liquor of step 1 and step 2
Mixing, obtains third mixed liquor；
Step 4: by the bovine serum albumin of 0.05~0.08 parts by weight, the K-IAO of 0.5~1.0 parts by weight, 0.2~1.0
The sucrose of parts by weight, the chitosan of 0.5~1.0 parts by weight, the gelatin of 0.5~1.0 parts by weight and 20~30mL mass concentration are
Then 1% acetic acid mixing is added 0.1 ~ 0.2 parts by weight urase and mixes to obtain the 4th mixed liquor；
Step 5: the column-shaped active carbon of 50~100 parts by weight is immersed into drying after 20~40min in the third mixed liquor of step 3,
Then it is stirred 30~60min with the 4th mixed liquor of step 4, naturally dry obtains target product.
2. the preparation method of the Environment-friendlywater water treatment agent according to claim 1 for swimming pool water process, which is characterized in that
The column-shaped active carbon is prepared by following methods:
Step a: stirring carries out 10~20min of kneading after water in kneader, is added after flyash and shell carbonization power are mixed,
Then adhesive is added and continues 10~15min of kneading, obtains kneading material；
Step b: the kneading material of step a is squeezed into the column billot that diameter is 3.0~6.0mm using press machine, is then set
30~60min is toasted in the environment of 200~250 DEG C；
Step c: it will be activated in step b treated column billot investment activation furnace, make activator, the temperature of activation with superheated water
At 950~1000 DEG C, 4~10h of activation time obtains the column-shaped active carbon for control.
3. the preparation method of the Environment-friendlywater water treatment agent according to claim 2 for swimming pool water process, which is characterized in that
Described adhesive is the amylum adhesive or carboxymethyl cellulose that cornstarch, sweet potato starch and other starch are prepared.
4. the preparation method of the Environment-friendlywater water treatment agent according to claim 1 for swimming pool water process, which is characterized in that
The concrete operations of step 1 are as follows: the gingili leaf of the cordate houttuynia of 3~5 parts by weight and 5~6 parts by weight is shredded respectively, then with 2~3 weights
Then the garlic mixing that amount part is smashed to pieces is added the ethyl alcohol that 10~15 parts by weight volumetric concentrations are 80~90% and grinds 20~40min,
It is removed slag using 150 mesh filtered through gauze, obtains the first mixed liquor.
5. the preparation method of the Environment-friendlywater water treatment agent according to claim 1 for swimming pool water process, which is characterized in that
The concrete operations of step 2 are as follows: by the cloves of 4~5 parts by weight, the tulip of 5~7 parts by weight, the honeysuckle of 3~5 parts by weight, 7
The golden larch of~9 parts by weight, the radix scutellariae of 2~3 parts by weight, the lavender of 4~5 parts by weight, the aloe of 2~3 parts by weight, 2~3 weights
Measure the folium artemisiae argyi mixing of the safflower of part, the rhizoma zingiberis of 2~3 parts by weight, the Prunella vulgaris of 2~3 parts by weight and 1~2 parts by weight, then plus
The water for entering 100~150 parts by weight, boils 20~30min, filters to obtain the dregs of a decoction and the first filtrate, and 100~150 are added into the dregs of a decoction
The water of parts by weight boils 20~30min, and filter and remove residue obtains the second filtrate, merges the first filtrate and the second filtrate obtains second and mixes
Close liquid.
6. the preparation method of the Environment-friendlywater water treatment agent according to claim 1 for swimming pool water process, which is characterized in that
The concrete operations of step 5 are as follows: will 50~100 parts by weight column-shaped active carbon immerse step 3 third mixed liquor in stirring 20~
Then 40min dries under 28~35 DEG C of environment, then be placed in 20~30min of drying under 45~50 DEG C of environment, before use, again
It is stirred 30~60min with the 4th mixed liquor of step 4, naturally dry obtains target product.
7. according to claim 1~6 at the environment-friendly type water obtained for swimming pool water process of preparation method described in any one
Manage agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710904086.4A CN109574164B (en) | 2017-09-29 | 2017-09-29 | Environment-friendly water treatment agent for swimming pool water treatment and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710904086.4A CN109574164B (en) | 2017-09-29 | 2017-09-29 | Environment-friendly water treatment agent for swimming pool water treatment and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109574164A true CN109574164A (en) | 2019-04-05 |
| CN109574164B CN109574164B (en) | 2022-01-11 |
Family
ID=65914084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710904086.4A Active CN109574164B (en) | 2017-09-29 | 2017-09-29 | Environment-friendly water treatment agent for swimming pool water treatment and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109574164B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110921842A (en) * | 2019-12-09 | 2020-03-27 | 苏州禾川化学技术服务有限公司 | Urea degradation agent |
| CN111517435A (en) * | 2020-05-09 | 2020-08-11 | 曹凤英 | Coagulant and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54143588A (en) * | 1978-04-25 | 1979-11-08 | Unitika Ltd | Preparation of sterilized, immobilized enzyme |
| CN85104238A (en) * | 1985-04-10 | 1986-10-08 | 华南师范大学 | Handle the preparation of immobilized urease that urea waste water is used |
| CN101028010A (en) * | 2006-02-27 | 2007-09-05 | 权力敏 | Chinese-herb disinfectant |
| CN101642582A (en) * | 2009-08-27 | 2010-02-10 | 浙江富来森炭材料有限公司 | Material with multi-functional long-acting slow-release effective components |
| CN103723725A (en) * | 2013-12-31 | 2014-04-16 | 海南大学 | Preparation method of silanized active carbon and preparation method of immobilized enzyme |
| CN105776659A (en) * | 2016-03-30 | 2016-07-20 | 安徽兴安电气设备股份有限公司 | Method for treating sewage |
| CN107185391A (en) * | 2017-04-27 | 2017-09-22 | 舒尔环保科技（合肥）有限公司 | A kind of filler and preparation method for air purifier |
-
2017
- 2017-09-29 CN CN201710904086.4A patent/CN109574164B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54143588A (en) * | 1978-04-25 | 1979-11-08 | Unitika Ltd | Preparation of sterilized, immobilized enzyme |
| CN85104238A (en) * | 1985-04-10 | 1986-10-08 | 华南师范大学 | Handle the preparation of immobilized urease that urea waste water is used |
| CN101028010A (en) * | 2006-02-27 | 2007-09-05 | 权力敏 | Chinese-herb disinfectant |
| CN101642582A (en) * | 2009-08-27 | 2010-02-10 | 浙江富来森炭材料有限公司 | Material with multi-functional long-acting slow-release effective components |
| CN103723725A (en) * | 2013-12-31 | 2014-04-16 | 海南大学 | Preparation method of silanized active carbon and preparation method of immobilized enzyme |
| CN105776659A (en) * | 2016-03-30 | 2016-07-20 | 安徽兴安电气设备股份有限公司 | Method for treating sewage |
| CN107185391A (en) * | 2017-04-27 | 2017-09-22 | 舒尔环保科技（合肥）有限公司 | A kind of filler and preparation method for air purifier |
Non-Patent Citations (1)
| Title |
|---|
| 汪沙: "《椰壳活性炭共价固载脲酶及尿素废水处理的研究》", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110921842A (en) * | 2019-12-09 | 2020-03-27 | 苏州禾川化学技术服务有限公司 | Urea degradation agent |
| CN111517435A (en) * | 2020-05-09 | 2020-08-11 | 曹凤英 | Coagulant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109574164B (en) | 2022-01-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102743782B (en) | Natural herb air purifying material and preparation method and use method thereof | |
| CN105594765A (en) | Environment-friendly pesticide | |
| CN105396163A (en) | Air smell removing liquid containing bamboo vinegar and preparing method of air smell removing liquid | |
| KR101407051B1 (en) | A producing method for natural antimicrobial using chives | |
| CN105435276A (en) | Air deodorant liquid containing wood vinegar and producing method of air deodorant liquid | |
| CN109574164A (en) | Environment-friendlywater water treatment agent and preparation method thereof for swimming pool water process | |
| CN103893803A (en) | Preparation raw materials and method of Chinese herbal deodorant | |
| CN104013878A (en) | Foot-bathing medicinal vinegar for quickly treating dermatophytosis and preparation method thereof | |
| CN102327343B (en) | External essential oil formula for preventing and treating beriberi | |
| CN105381485A (en) | Herb vinegar-containing air deodorizing liquid and manufacturing method thereof | |
| CN107439897A (en) | A kind of plant-based bacteriostat | |
| CN106492255A (en) | A kind of preparation method of composite type natural plant deodorizer | |
| CN105123783B (en) | A kind of Crazing in grassland culicifuge | |
| CN107519464A (en) | A kind of Chinese ephedra schizonepeta dipping for preventing and treating treating baby's cold cough and preparation method thereof | |
| CN107788229A (en) | A kind of purposes of plant-based bacteriostat | |
| KR102148800B1 (en) | Methods for manufacturing sulfur shampoo to prevent hair loss | |
| CN1228271A (en) | Method for preparing instant sea-tangle powder | |
| CN112957442A (en) | Traditional Chinese medicine formula spray for treating canine and feline skin diseases and preparation method thereof | |
| KR100344003B1 (en) | Manufacturing method of antibiotic detergent by silver and charcoal | |
| CN101085173A (en) | Liquid medicine for rapidly curing beriberi | |
| CN111249373A (en) | A disinfectant liquid containing lignum Aquilariae Resinatum component and its preparation method | |
| CN109645035A (en) | A kind of Extracts from Plant Recourses bactericidal deodorant and preparation method and application | |
| CN110526326A (en) | A kind of multipurpose waste water treating agent | |
| CN106667841B (en) | Tea seed footbath powder and preparation method and application thereof | |
| CN109527001A (en) | A kind of disinfectant and preparation method thereof for ward bedding |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: Office 02, 14th Floor, Building 1, Blue Wave Bay, No. 68-1 Jiangbin East Avenue, Mawei Town, Mawei District, Fuzhou City, Fujian Province, 350000 (within the Free Trade Zone) Patentee after: Fuzhou Mawei District Guomin Environmental Protection Technology Co.,Ltd. Address before: Shop 02, 1st Floor, Building 5, Junzhu Mingju, No. 56 Jianxing Road, Mawei District, Fuzhou City, Fujian Province, 350000 (within the Free Trade Zone) Patentee before: FUJIAN GUOMIN ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. |
|
| CP03 | Change of name, title or address | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231012 Address after: Floor 2-10, Building 4, Beixingyuan, No. 37 Jinbiao Road, Taijiang District, Fuzhou City, Fujian Province, 350000 Patentee after: FUJIAN YUANKE MACHINERY Co.,Ltd. Address before: Office 02, 14th Floor, Building 1, Blue Wave Bay, No. 68-1 Jiangbin East Avenue, Mawei Town, Mawei District, Fuzhou City, Fujian Province, 350000 (within the Free Trade Zone) Patentee before: Fuzhou Mawei District Guomin Environmental Protection Technology Co.,Ltd. |
|
| TR01 | Transfer of patent right |