CN109553888A - 一种耐高温包装薄膜 - Google Patents

一种耐高温包装薄膜 Download PDF

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CN109553888A
CN109553888A CN201811448945.4A CN201811448945A CN109553888A CN 109553888 A CN109553888 A CN 109553888A CN 201811448945 A CN201811448945 A CN 201811448945A CN 109553888 A CN109553888 A CN 109553888A
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parts
high temperature
temperature resistant
packing film
resistant packing
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晁飞
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Xuzhou Jintaiyang Packing Material Co Ltd
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10—Homopolymers or copolymers of propene
    • C08J2423/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass

Abstract

本发明涉及包装薄膜技术领域，尤其是一种耐高温包装薄膜；其质量份组成如下：聚氯乙烯18～32份、聚丙烯16～24份、环氧改性有机硅树脂2.4～4.2份、全氟辛酸聚甘油酯6.4～8份、硼酸三甲酯2～3.6份、氧化聚乙烯蜡4.5～5.8份，聚对苯二甲酸丁二醇酯12～15份，玻璃纤维6～8份，聚1‑丁烯6～10份、聚三氟氯乙烯4～6份、二氧化钛0.3～0.5份，碳酸钙粉2.1～3.8份，偶联剂3～4份，阻燃剂4～8份，固化剂1～3份，酒石酸盐11～18份，相容剂1～3份，石油焦8～12份，氨基锂0.1～0.5份；本发明的耐高温包装薄膜，性能优异，稳定性好，具有良好的强度，老化速度慢，耐磨性高，使用效果好，应用范围广。

Description

一种耐高温包装薄膜
技术领域
本发明涉及包装薄膜技术领域，尤其是一种耐高温包装薄膜。
背景技术
目前，农药普遍存在浓度高、剧毒等特性，对人体危害极大。因而，农药包装的安全性十分重要。农药使用完后，其包装物所带来的残留农药污染环境问题也不容忽视。中国生产的农药三分之二为液态剂型。而长期以来，液剂农药一直采用玻璃瓶包装。可是，玻璃瓶存在破损率高、玻璃瓶内塞封口不严和计量不便等缺点，因此“以塑代玻”已成为农药包装不可逆转的发展潮流。
发明内容
本发明的目的是：提供一种使用安全性高的液体包装薄膜。
为解决上述技术问题，本发明采用的技术方案如下：
一种耐高温包装薄膜，其质量份组成如下：聚氯乙烯18～32份、聚丙烯16～24份、环氧改性有机硅树脂2.4～4.2份、全氟辛酸聚甘油酯6.4～8份、硼酸三甲酯2～3.6份、氧化聚乙烯蜡4.5～5.8份，聚对苯二甲酸丁二醇酯12～15份，玻璃纤维6～8份，聚1-丁烯6～10份、聚三氟氯乙烯4～6份、二氧化钛0.3～0.5份，碳酸钙粉2.1～3.8份，偶联剂3～4份，阻燃剂4～8份，固化剂1～3份，酒石酸盐11～18份，相容剂1～3份，石油焦8～12份，氨基锂0.1～0.5份。
进一步的，所述固化剂选用对羟基苯磺酸。
进一步的，所述阻燃剂选用氢氧化镁。
进一步的，所述相容剂选用PE-g-ST、ABS-g-MAH和PP-g-MAH的混合物，其质量比为1:1:1-3。
进一步的，所述相容剂选用PE-g-ST、ABS-g-MAH和PP-g-MAH的混合物，其质量比为1:1:2。
进一步的，所述偶联剂为硅烷偶联剂，选用KH550，KH560，KH570，KH792，DL602，DL171中的一种或几种。
进一步的，所述偶联剂选用KH550和DL602的混合物，其质量比为1:1-4。
进一步的，所述固化剂选用对羟基苯磺酸。
采用本发明的技术方案的有益效果是：
本发明的耐高温包装薄膜，性能优异，稳定性好，具有良好的强度，老化速度慢，耐磨性高，使用效果好，应用范围广。
具体实施方式
现在结合具体实施例对本发明作进一步详细的说明。
实施例1
一种耐高温包装薄膜，其质量份组成如下：聚氯乙烯18份、聚丙烯16份、环氧改性有机硅树脂2.4份、全氟辛酸聚甘油酯6.4份、硼酸三甲酯2份、氧化聚乙烯蜡4.5份，聚对苯二甲酸丁二醇酯12份，玻璃纤维6份，聚1-丁烯6份、聚三氟氯乙烯4份、二氧化钛0.3份，碳酸钙粉2.1份，偶联剂3份，阻燃剂4份，固化剂1份，酒石酸盐11份，相容剂1份，石油焦8份，氨基锂0.1份。
其中，固化剂选用对羟基苯磺酸。
其中，阻燃剂选用氢氧化镁。
其中，相容剂选用PE-g-ST、ABS-g-MAH和PP-g-MAH的混合物，其质量比为1:1:1。
其中，偶联剂选用KH550和DL602的混合物，其质量比为1:1。
其中，固化剂选用对羟基苯磺酸。
实施例2
一种耐高温包装薄膜，其质量份组成如下：聚氯乙烯20份、聚丙烯18份、环氧改性有机硅树脂3份、全氟辛酸聚甘油酯7份、硼酸三甲酯3份、氧化聚乙烯蜡5份，聚对苯二甲酸丁二醇酯13份，玻璃纤维7份，聚1-丁烯8份、聚三氟氯乙烯5份、二氧化钛0.4份，碳酸钙粉3份，偶联剂3.2份，阻燃剂6份，固化剂2份，酒石酸盐16份，相容剂2份，石油焦10份，氨基锂0.3份。
其中，固化剂选用对羟基苯磺酸。
其中，阻燃剂选用氢氧化镁。
其中，相容剂选用PE-g-ST、ABS-g-MAH和PP-g-MAH的混合物，其质量比为1:1:2。
其中，偶联剂选用KH550和DL602的混合物，其质量比为1:2。
其中，固化剂选用对羟基苯磺酸。
实施例3
一种耐高温包装薄膜，其质量份组成如下：聚氯乙烯32份、聚丙烯24份、环氧改性有机硅树脂4.2份、全氟辛酸聚甘油酯8份、硼酸三甲酯3.6份、氧化聚乙烯蜡5.8份，聚对苯二甲酸丁二醇酯15份，玻璃纤维8份，聚1-丁烯10份、聚三氟氯乙烯6份、二氧化钛0.5份，碳酸钙粉3.8份，偶联剂4份，阻燃剂8份，固化剂3份，酒石酸盐18份，相容剂3份，石油焦12份，氨基锂0.5份。
其中，固化剂选用对羟基苯磺酸。
其中，阻燃剂选用氢氧化镁。
其中，相容剂选用PE-g-ST、ABS-g-MAH和PP-g-MAH的混合物，其质量比为1:1:3。
其中，偶联剂选用KH550和DL602的混合物，其质量比为1:4。
其中，固化剂选用对羟基苯磺酸。
以上述依据本发明的理想实施例为启示，通过上述的说明内容，相关工作人员完全可以在不偏离本项发明技术思想的范围内，进行多样的变更以及修改。凡在本发明的精神和原则之内，所做的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。本项发明的技术性范围并不局限于说明书上的内容，必须要根据权利要求范围来确定其技术性范围。

Claims (8)

1.一种耐高温包装薄膜，其特征在于：其质量份组成如下：聚氯乙烯18～32份、聚丙烯16～24份、环氧改性有机硅树脂2.4～4.2份、全氟辛酸聚甘油酯6.4～8份、硼酸三甲酯2～3.6份、氧化聚乙烯蜡4.5～5.8份，聚对苯二甲酸丁二醇酯12～15份，玻璃纤维6～8份，聚1-丁烯6～10份、聚三氟氯乙烯4～6份、二氧化钛0.3～0.5份，碳酸钙粉2.1～3.8份，偶联剂3～4份，阻燃剂4～8份，固化剂1～3份，酒石酸盐11～18份，相容剂1～3份，石油焦8～12份，氨基锂0.1～0.5份。
2.根据权利要求1所述的一种耐高温包装薄膜，其特征在于：所述固化剂选用对羟基苯磺酸。
3.根据权利要求1所述的一种耐高温包装薄膜，其特征在于：所述阻燃剂选用氢氧化镁。
4.根据权利要求1所述的一种耐高温包装薄膜，其特征在于：所述相容剂选用PE-g-ST、ABS-g-MAH和PP-g-MAH的混合物，其质量比为1:1:1-3。
5.根据权利要求1所述的一种耐高温包装薄膜，其特征在于：所述相容剂选用PE-g-ST、ABS-g-MAH和PP-g-MAH的混合物，其质量比为1:1:2。
6.根据权利要求1所述的一种耐高温包装薄膜，其特征在于：所述偶联剂为硅烷偶联剂，选用KH550，KH560，KH570，KH792，DL602，DL171中的一种或几种。
7.根据权利要求6所述的一种耐高温包装薄膜，其特征在于：所述偶联剂选用KH550和DL602的混合物，其质量比为1:1-4。
8.根据权利要求1所述的一种耐高温包装薄膜，其特征在于：所述固化剂选用对羟基苯磺酸。
CN201811448945.4A 2018-11-28 2018-11-28 一种耐高温包装薄膜 Pending CN109553888A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111471253A (zh) * 2020-05-25 2020-07-31 江苏大海塑料股份有限公司 一种耐高温抗粘压花薄膜及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111471253A (zh) * 2020-05-25 2020-07-31 江苏大海塑料股份有限公司 一种耐高温抗粘压花薄膜及其制备方法

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Application publication date: 20190402