CN109517449A - It can washcoated crow wax crayon and preparation method thereof - Google Patents
It can washcoated crow wax crayon and preparation method thereof Download PDFInfo
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- CN109517449A CN109517449A CN201811571102.3A CN201811571102A CN109517449A CN 109517449 A CN109517449 A CN 109517449A CN 201811571102 A CN201811571102 A CN 201811571102A CN 109517449 A CN109517449 A CN 109517449A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D13/00—Pencil-leads; Crayon compositions; Chalk compositions
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Abstract
The present invention provide one kind can washcoated crow wax crayon and preparation method thereof, this can the component of washcoated crow wax crayon include: wax 5-15 parts by weight；Beeswax 0.5-2 parts by weight；Stearic acid 3-10 parts by weight；Fixed oil 30-40 parts by weight；Slab oil 1-4 parts by weight；Filler 15-30 parts by weight；Environmental-friendly pigment 1-15 parts by weight；Water-soluble water washing assistant and water 15-25 parts by weight；Antioxidant 0.01-1.5 parts by weight；Natural plant pefume 0.1-5 parts by weight；And food-grade bitters 0.001-0.3 parts by weight.It is of the invention can washcoated crow wax crayon have environment-protecting and non-poisonous, antibacterial safety, smell are pure and fresh, bright in colour, pen body it is smooth it is tack-free, scribble it is fine and smooth it is not scaling-off, can scribble on a variety of interfaces, and it can easily wash the outstanding advantages of removing, and after applying and being drawn on paper, the art effect of similar watercolor can produce with the writing brush dizzy dye that gets wet.
Description
Technical field
The present invention relates to a kind of draw tool material, in particular to one kind can washcoated crow wax crayon and preparation method thereof.
Background technique
Artistic oil painting stick, wax crayon have become one of the graphic products most common on the market at present, deep by from children to professional beauty
The various consumer groups' of patient likes.A kind of oleaginous system that traditional wax crayon is made of wax, filler, pigment, does not dissolve in
Water generally is not easy to paint, function and usage scenario are limited by adhesive force in scribbling on paper on more smooth surface.It uses
If contamination is to not easy cleaning on clothing and skin when wax crayon is painted, and there are the distinctive peculiar smell of wax.
With the raising of people's safety and environmental consciousness, the safety of wax crayon has also obtained consumer and has further paid close attention to,
It is concentrated mainly on content of beary metal in wax crayon, in toxic volatile organic content.Due to wax crayon various colors, children are used
When be easy to happen eat by mistake and bite phenomenon harm health, and arbitrarily scribble cause it is dirty cleaned for parent also become a disaster
Topic, therefore environment-protecting and non-poisonous, safe ready, the washable basic demand for having become parents to children art articles.
Summary of the invention
In order to overcome drawbacks described above, the present invention provides a kind of environment-protecting and non-poisonous, antibacterial safety, smell it is pure and fresh, it is bright in colour,
Pen body it is smooth it is tack-free, scribble it is fine and smooth it is not scaling-off, can scribble on a variety of interfaces, and can easily wash removings, and painting is drawn on
After on paper, with writing brush get wet dizzy dye can produce similar watercolor art effect can washcoated crow wax crayon and preparation method thereof.
The present invention provide one kind can washcoated crow wax crayon, including wax crayon substrate, environmental-friendly pigment and water-soluble water washing assistant and water；
Further, the content of the water-soluble water washing assistant and water is not more than the wax crayon substrate and the environmental-friendly pigment total weight
45%；
Further, the wax crayon substrate includes beeswax, wax, stearic acid, fixed oil, slab oil, filler, antioxygen
Agent, natural plant pefume and food-grade bitters；
Further, it is described can washcoated crow wax crayon, by weight, including the beeswax 0.5-2 parts by weight, the wax
5-15 parts by weight, the stearic acid 3-10 parts by weight, the fixed oil 30-40 parts by weight, the slab oil 1-4 weight
Part, the filler 15-30 parts by weight, the environmental-friendly pigment 1-15 parts by weight, the antioxidant 0.01-1.5 parts by weight, institute
Natural plant pefume 0.1-5 parts by weight, the food-grade bitters 0.001-0.3 parts by weight and the water-soluble washing is stated to help
Agent 15-25 parts by weight；
Further, the wax includes at least one selected from paraffin, microwax, synthetic wax；
The paraffin is semi-refined or fully refined paraffin wax of the fusing point at 54-62 DEG C；
The microwax is microwax of the fusing point at 80-95 DEG C；
The synthetic wax includes selected from Fischer-Tropsch wax, polyethylene wax, polypropylene wax, ethylene-vinyl acetate copolymer wax, oxidation
At least one of polyethylene wax；
The fixed oil is saturated fatty acid monoglyceride；
The slab oil is that 40 DEG C of kinematic viscosity are 30-70mm2The makeup grade white oil of/s；
The filler includes at least one selected from calcium carbonate, kaolin, talcum powder, white carbon black, barium sulfate；
The natural plant pefume includes being selected from least one of plants essential oil, plant extract；
The food-grade bitters is benzoic acid [2- [(2,6- 3,5-dimethylphenyl) amino]-N, N- diethylbenzyl ammonium；
The antioxidant includes being selected from 2,6 di tert butyl 4 methyl phenol, (1,1- dimethyl ethyl) -4- methoxyl group
At least one of phenol；
The environmental-friendly pigment includes the environmental-friendly pigment that harmful substance contents meet at least one color of European Union's EN71 standard；
Further, the water-soluble water washing assistant and water includes the composition of Monoolein and nonylphenol polyoxyethylene ether；
Further, the weight ratio of the Monoolein and the nonylphenol polyoxyethylene ether is 1:1-2；
Further, the nonylphenol polyoxyethylene ether includes
The combination of lipophilic nonylphenol polyoxyethylene ether and hydrophily nonylphenol polyoxyethylene ether, wherein the lipophilicity
Nonylphenol polyoxyethylene ether is molecular formula C15H24O.(C2H4O)nNonylphenol polyoxyethylene ether, wherein n be 4 or 5, one kind or
More than one；
The hydrophily nonylphenol polyoxyethylene ether is molecular formula C15H24O.(C2H4O)nNonylphenol polyoxyethylene ether,
Middle n be 9,10,11 or 12, one or more；
Further, the weight of the lipophilic nonylphenol polyoxyethylene ether and the hydrophily nonylphenol polyoxyethylene ether
Than for 1:2-3.
The present invention also provides it is a kind of can washcoated crow wax crayon preparation method, comprising:
Step (a) is by a part of slab oil and wax total amount, a part of stearic acid total amount and fixed oil total amount
A part carries out mixed melting, obtains mixing wax liquor later；
Environmental-friendly pigment is added in the mixing wax liquor that step (b) Xiang Suoshu step (a) obtains and carries out uniform stirring, in stirring
It is heated simultaneously, stirs to get homogeneous mixture；
The homogeneous mixture attrition process that step (c) obtains the step (b) is pre- at the pigment of fine granular semisolid
Processed material；
Step (d) by water-soluble water washing assistant and water, antioxidant and remaining wax, remaining stearic acid and remaining fixed oil into
Row mixed melting obtains aqueous wax liquor later；
The pigment pretreatment that the step (c) obtains is added in the aqueous wax liquor that step (e) Xiang Suoshu step (d) obtains
Object and beeswax, filler, natural plants essence, bitters, are heated to being completely melt it, and stir to get homogeneous liquid
Slurry；
The liquid slurry that the step (e) obtains is obtained the wax crayon by moulding process by step (f)；
Further, the fusion temperature in the step (a) is 80-110 DEG C, and fusing time is 60-120 minutes；
Heating temperature in the step (b) is 70-90 DEG C, and mixing time is 30-60 minutes；
Fusion temperature in the step (d) is 80-110 DEG C, and fusing time is 60-120 minutes；
Heating temperature in the step (e) is to be heated to 80-110 DEG C, and mixing time is 30-60 minutes；
The cooling temperature of the moulding process in the step (f) is 15-30 DEG C；
Further, in the step (a), by the half of the slab oil and the wax total amount, the stearic acid
The half of the half of total amount and the fixed oil total amount carries out mixed melting；
In the step (d), by the water-soluble water washing assistant and water, the antioxidant and the other half the wax, the other half
The stearic acid and the other half the fixed oil carry out mixed melting；
Further, in the step (c), including by the homogeneous mixture with three-roll grinder attrition process to described
The grain fineness of fine granular semisolid object is at 5-50 μm；
In the step (e), including stirring the grain fineness to the liquid slurry at 5-50 μm.
It is provided by the invention can washcoated crow wax crayon have the advantages that
1, it is of the invention can washcoated crow wax crayon it is beautiful in colour, painting coloring power is strong on paper, spreadability is good, is got wet with writing brush
Dizzy dye can produce the art effect of similar watercolor, and pen body it is smooth it is tack-free do not easily cause it is dirty, than watercolors using more
It is convenient；
2, it is of the invention can washcoated crow wax crayon scribble fine and smooth not scaling-off, and coloring, such as paper can be scribbled on a variety of media
The surfaces such as face, skin, cloth, plastics, glass, marble and metal, random graffiti or scribble mark after with clear water can be light
It removes, extends the function and usage scenario of wax crayon；
3, of the invention to have extremely strong antibacterial and antioxidation, while bee by beeswax used in washcoated crow wax crayon formula
The physical characteristics such as moulding, waterproof, disengaging, the film forming of wax make demoulding easy to form in wax crayon technique obtained, are functionally easy to
Film forming is scribbled at different interfaces；
It is 4, of the invention the original peculiar smell of wax not only to be masked using natural plant pefume in washcoated crow wax crayon formula,
Keep smell pure and fresh, and there is the health-care effects beneficial to body such as sterilization, calmness；
5, of the invention use in washcoated crow wax crayon formula food-grade bitters as aversive agent, effectively inhibition eat by mistake with
It bites, is more suitable for children's use；
6, of the invention to meet European Union by all kinds of harmful substance contents in environmental-friendly pigment used in washcoated crow wax crayon formula
71 standard of EN, the white oil and natural plant pefume used are cosmetics-stage, and antioxidant and bitters are food-grade, obtained
Wax crayon is authenticated by European Union CE, can be met to the requirement in terms of artistic drawing set safety and environmental protection；
7, it is of the invention can washcoated crow wax crayon formula be free of organic solvent, low VOC is environmentally friendly, safe and nontoxic, and produces
Material in journey can be recycled refuse and use, and recycle value is high, and economic effect is obvious.
8, the preparation method provided through the invention be prepared can washcoated crow wax crayon there is environment-protecting and non-poisonous, antibacterial to pacify
Entirely, smell is pure and fresh, bright in colour, pen body it is smooth it is tack-free, scribble it is fine and smooth it is not scaling-off, can scribble on a variety of interfaces, and can be with
Easily outstanding advantages that washing removes, and after applying and being drawn on paper can produce the art effect of similar watercolor with the writing brush dizzy dye that gets wet.
Specific embodiment
Below according to specific embodiment, technical scheme is described further.Protection scope of the present invention is unlimited
In following embodiment, these examples are enumerated merely for exemplary purpose without limiting the invention in any way.
It is of the invention can washcoated crow wax crayon include wax crayon substrate, environmental-friendly pigment and water-soluble water washing assistant and water.
It is of the invention can be in washcoated crow wax crayon, the content of the water-soluble water washing assistant and water is not more than the wax crayon substrate and described
The 45% of environmental-friendly pigment total weight.
In one embodiment of the invention, it is of the invention can washcoated crow wax crayon include the wax crayon substrate 54-108 weight
Part, the environmental-friendly pigment 1-15 parts by weight and the water-soluble water washing assistant and water 15-25 parts by weight.
In another embodiment of the present invention, including the wax crayon substrate 60-84 parts by weight, the environmental-friendly pigment 1-15
Parts by weight and the water-soluble water washing assistant and water 15-25 parts by weight.
Further, the wax crayon substrate includes beeswax, wax, stearic acid, fixed oil, slab oil, filler, antioxygen
Agent, natural plant pefume and food-grade bitters.
It is of the invention can washcoated crow wax crayon, by weight, including the beeswax 0.5-2 parts by weight, the wax 5-15 weight
Measure part, the stearic acid 3-10 parts by weight, the fixed oil 30-40 parts by weight, the slab oil 1-4 parts by weight, described
It is filler 15-30 parts by weight, the environmental-friendly pigment 1-15 parts by weight, the antioxidant 0.01-1.5 parts by weight, described natural
Plant perfume 0.1-5 parts by weight, the food-grade bitters 0.001-0.3 parts by weight and the water-soluble water washing assistant and water 15-25
Parts by weight.
It is of the invention can the wax in washcoated crow wax crayon include being selected from least one of paraffin, microwax, synthetic wax,
Wherein paraffin is semi-refined or fully refined paraffin wax of the fusing point at 54-62 DEG C；
Microwax is microwax of the fusing point at 80-95 DEG C；
Synthetic wax includes selected from Fischer-Tropsch wax, polyethylene wax, polypropylene wax, ethylene-vinyl acetate copolymer wax, the poly- second of oxidation
At least one of alkene wax；
Preferably paraffin and another combination to wax.
It is of the invention can the fixed oil main component in washcoated crow wax crayon be saturated fatty acid monoglyceride, have no it
He especially limits.
It is of the invention can the slab oil in washcoated crow wax crayon be preferably 40 DEG C of kinematic viscosity be 30-70mm2/s
Makeup grade white oil.
It is of the invention can the filler in washcoated crow wax crayon can be calcium carbonate, kaolin, talcum powder, white carbon black,
Barium sulfate etc. can be one or more, particularly preferably calcium carbonate and kaolin.
It is of the invention can the environmental-friendly pigment in washcoated crow wax crayon there is no particular restriction, as long as all kinds of harmful substance contents
Meet European Union's EN71 standard.Such as it can be titanium dioxide, zinc oxide etc. as white pigment；
Red pigment can be pigment scarlet powder, iron oxide red etc.；
Orange pigment can be forever solid orange, pigment orange 16 etc.；
Yellow uitramarine can be everbright fast yellow, iron oxide yellow etc.；
Viridine green can be phthalocyanine green etc.；
Blue pigment can be phthalocyanine blue, ultramarine etc.；
Violet pigment can be permanent violet, crystal violet etc.；
Black pigment can be carbon black, acetylene black, nigrosine etc.；
With paint can be one or more pigment combination, have no it is specifically limited, only need to be according to required color and face
Material color theory is deployed.
It is of the invention can the water-soluble water washing assistant and water in washcoated crow wax crayon include nonionic surfactant glycerol list oil
The combination of acid esters and nonylphenol polyoxyethylene ether；
It is of the invention can the water-soluble water washing assistant and water in washcoated crow wax crayon be Monoolein that weight ratio is 1:1-2
With the combination of nonylphenol polyoxyethylene ether；The weight ratio of the Monoolein and nonylphenol polyoxyethylene ether can be 1:
1.19；Or the weight ratio of the Monoolein and nonylphenol polyoxyethylene ether can be 1:1.18.
It is of the invention can the nonylphenol polyoxyethylene ether in washcoated crow wax crayon include lipophilic Nonyl pheno
The combination of ether and hydrophily nonylphenol polyoxyethylene ether.
Wherein, it is C that the lipophilic nonylphenol polyoxyethylene ether, which is molecular formula,15H24O.(C2H4O)nPolyoxyethylene nonyl phenyl second
Alkene ether, wherein n be 4 or 5, one or more.
Molecular formula is C15H24O.(C2H4O)n, wherein n be 4 or 5, nonylphenol polyoxyethylene ether have Nonyl pheno
Ether (n 4), nonylphenol polyoxyethylene ether (n 5).
It is C that the hydrophily nonylphenol polyoxyethylene ether, which is molecular formula,15H24O.(C2H4O)nNonylphenol polyoxyethylene ether,
Wherein n be 9,10,11 or 12, one or more.
Molecular formula is C15H24O.(C2H4O)n, wherein n be 9,10,11 or 12, nonylphenol polyoxyethylene ether have nonyl phenol
Polyoxyethylene ether (n 9), nonylphenol polyoxyethylene ether (n 10), nonylphenol polyoxyethylene ether (n 11) or polyoxyethylene nonyl phenyl
Vinethene (n 12).
Preferably, the group of the lipophilic nonylphenol polyoxyethylene ether and hydrophily nonylphenol polyoxyethylene ether is combined into nonyl
The combination of phenol polyethenoxy ether (n 4) and nonylphenol polyoxyethylene ether (n 10)；
Or to be combined into nonyl phenol poly- for the group of the lipophilic nonylphenol polyoxyethylene ether and hydrophily nonylphenol polyoxyethylene ether
The combination of ethylene oxide ether (n 4) and nonylphenol polyoxyethylene ether (n 12)；
Or to be combined into nonyl phenol poly- for the group of the lipophilic nonylphenol polyoxyethylene ether and hydrophily nonylphenol polyoxyethylene ether
The combination of ethylene oxide ether (n 4) and nonylphenol polyoxyethylene ether (n 9)；
Or to be combined into nonyl phenol poly- for the group of the lipophilic nonylphenol polyoxyethylene ether and hydrophily nonylphenol polyoxyethylene ether
The combination of ethylene oxide ether (n 5) and nonylphenol polyoxyethylene ether (n 12).
Further, the weight of the lipophilic nonylphenol polyoxyethylene ether and the hydrophily nonylphenol polyoxyethylene ether
Than for 1:2-3.
It is of the invention can be in an embodiment of washcoated crow wax crayon, the nonylphenol polyoxyethylene ether molecular formula is
C15H24O.(C2H4O)n, it is the lipophilic nonylphenol polyoxyethylene ether (n is 4 or 5) and hydrophily nonyl phenol that weight ratio is 1:2-3
The combination of two kinds of nonylphenol polyoxyethylene ether of polyoxyethylene ether (n is 9,10,11 or 12).
In one embodiment, the lipophilic nonylphenol polyoxyethylene ether and the hydrophily Nonyl pheno
The weight ratio of ether is 1:2.17；In another embodiment, the lipophilic nonylphenol polyoxyethylene ether and the hydrophily nonyl
The weight ratio of base phenol polyethenoxy ether is 1:2.28.
It is of the invention can the antioxidant in washcoated crow wax crayon be 2,6 di tert butyl 4 methyl phenol, (1,1- bis-
One of Methylethyl) -4- metoxyphenol.
It is of the invention can the natural plant pefume in washcoated crow wax crayon be plants essential oil, at least one in plant extract
Kind, as long as the plant perfume of this two kinds of forms, has no other and especially limits.Such as plants essential oil can be rhodamine toner
Oil, Lavender, Rosemary Oil etc., plant extract can be jasmine flower concrete etc..
It is of the invention can the food-grade bitters in washcoated crow wax crayon be benzoic acid [2- [(2,6- 3,5-dimethylphenyl)
Amino]-N, N- diethylbenzyl ammonium.
It is of the invention can washcoated crow wax crayon preparation method, need first pre-process pigment so that granularity reaches wants
It asks, tints finer and smoother, and prepare a kind of aqueous wax liquor as base-material, the washability of guarantee system specifically comprises the following steps:
Step (a) is by half, the half of the half of stearic acid total amount and fixed oil total amount of slab oil and wax total amount
Mixed melting is carried out, fusion temperature is 80-110 DEG C, and fusing time is 60-120 minutes, obtains mixing wax liquor later；
Environmental-friendly pigment is added in the mixing wax liquor that step (b) Xiang Suoshu step (a) obtains and carries out uniform stirring, in stirring
It is heated simultaneously, heating temperature is 70-90 DEG C, and stirring obtains a homogeneous mixture for 30-60 minutes；
The homogeneous mixture that step (c) obtains the step (b) is with three-roll grinder attrition process at fine granular half
Solid pigment pre-processes object；
Step (d) by water-soluble water washing assistant and water, antioxidant and wax total amount the other half, stearic acid total amount the other half and it is hard
The other half of carburetion total amount carries out mixed melting, and fusion temperature is 80-110 DEG C, and fusing time is 60-120 minutes, obtains later
Aqueous wax liquor；
Step (e) be added into the aqueous wax liquor that step (d) obtains the pigment pretreatment object that step (c) obtain and beeswax,
Filler, natural plants essence, bitters, being heated to 80-110 DEG C is completely melt it, and stirs and obtain within 30-60 minutes uniformly
Liquid slurry；
The liquid slurry that step (e) obtains is obtained the wax crayon, the moulding process by moulding process by step (f)
Cooling temperature be 15-30 DEG C.
Further, in above-mentioned steps (c), by the grinding of three-roll grinder so that pigment pre-processes in step (c)
The grain fineness of object is at 5-50 μm；In above-mentioned steps (e), the grain fineness to the liquid slurry is stirred at 5-50 μm.
The addition of the above components is carried out according to scheduled weight.
By the above method be prepared can washcoated crow wax crayon have that environment-protecting and non-poisonous, antibacterial safety, smell be pure and fresh, color
Bright-coloured, pen body it is smooth it is tack-free, scribble it is fine and smooth it is not scaling-off, can scribble on a variety of interfaces, and can easily wash the prominent of removing
Advantage out, and after applying and being drawn on paper can produce the art effect of similar watercolor with the writing brush dizzy dye that gets wet.
Unless otherwise defined, term used herein is the normally understood meaning of those skilled in the art.
The present invention is described in further detail by the following examples.
Embodiment
Embodiment 1: it is orange can washcoated crow wax crayon
It is formulated as follows: 0.8 parts by weight of beeswax；10 parts by weight of paraffin；2 parts by weight of microwax；8 parts by weight of stearic acid；Hardening
Oily 34 parts by weight；2 parts by weight of slab oil；15.1 parts by weight of calcium carbonate；5 parts by weight of kaolin；16 2 parts by weight of pigment orange；
9 parts by weight of Monoolein；3 parts by weight of nonylphenol polyoxyethylene ether (n 4)；6 weight of nonylphenol polyoxyethylene ether (n 10)
Measure part；0.25 parts by weight of 2,6 di tert butyl 4 methyl phenol；2.8 parts by weight of Rosa Damascana；Benzoic acid [2- [(2,6- diformazan
Base phenyl) amino]-N, 0.05 parts by weight of N- diethylbenzyl ammonium.
The preparation method is as follows: by the slab oil of 2 parts by weight and 5 parts by weight paraffin, 1 parts by weight microwax, 4 parts by weight
Stearic acid and 17 parts by weight fixed oils carry out mixed melting, and fusion temperature is 80-110 DEG C, and fusing time is 60-120 minutes, it
After obtain mixing wax liquor；
2 parts by weight pigment oranges 16 are added into above-mentioned blended wax liquid and carry out uniform stirring, are heated while agitating,
Heating temperature is 70-90 DEG C, and stirring obtains a homogeneous mixture for 30-60 minutes；
It is processed into fine granular orange pigment with three-roll grinder again and pre-processes object；
By 9 parts by weight of glycerin monoleates, 3 parts by weight nonylphenol polyoxyethylene ether (n 4), 6 parts by weight polyoxyethylene nonyl phenyls
Vinethene (n 10), 0.25 parts by weight 2,6- di-tert-butyl-4-methy phenol, with remaining 5 parts by weight paraffin, 1 parts by weight crystallite
Wax, 4 parts by weight stearic acid and 17 parts by weight fixed oils carry out mixed melting, and fusion temperature is 80-110 DEG C, fusing time 60-
120 minutes, aqueous wax liquor was obtained later；
Orange pigment pretreatment object and 0.8 parts by weight beeswax, 15.1 weights obtained are added into above-mentioned water-borne wax liquid
Measure part calcium carbonate, 5 parts by weight kaolin clay, 2.8 parts by weight Rosa Damascanas, 0.05 parts by weight [2- [(2,6- dimethyl benzene
Base) amino]-N, N- diethylbenzyl ammonium, being heated to 80-110 DEG C is completely melt it, and stirs and obtain within 30-60 minutes uniformly
Liquid slurry；
Again by obtained liquid slurry by moulding process obtain it is described it is orange can washcoated crow wax crayon, what when molding, used
Cooling temperature is 15-30 DEG C.
By the above method be prepared it is orange can washcoated crow wax crayon is environment-protecting and non-poisonous, antibacterial is safe, it is clear with rose
It is fragrant；With bitter taste, children can be effectively suppressed and eat by mistake and bite；Pen body is smooth tack-free when use, in contamination to clothing and skin
Can easily be cleaned with water, can a variety of surfaces such as glass, metal, plastics, marble carry out scribble and with clear water it is i.e. erasable；It applies
It is drawn on paper fine and smooth easily colouring, is got wet dizzy dye with writing brush, can dissolve the art effect for generating similar watercolor.
Embodiment 2: green can washcoated crow wax crayon
It is formulated as follows: 0.7 parts by weight of beeswax；14 parts by weight of paraffin；6 parts by weight of stearic acid；32 parts by weight of fixed oil；White
3 parts by weight of mineral oil；13.7 parts by weight of calcium carbonate；4 parts by weight of kaolin；1.4 parts by weight of Phthalocyanine Green G；Fast Yellow 10G 3.8
Parts by weight；0.7 parts by weight of titanium dioxide；8.4 parts by weight of Monoolein；2.1 parts by weight of nonylphenol polyoxyethylene ether (n 4)；
6.3 parts by weight of nonylphenol polyoxyethylene ether (n 9)；0.3 parts by weight of 2,6 di tert butyl 4 methyl phenol；Jasmine flower concrete
3.55 parts by weight；Benzoic acid [2- [(2,6- 3,5-dimethylphenyl) amino]-N, 0.05 parts by weight of N- diethylbenzyl ammonium.
The preparation method is as follows: by the slab oil of 3 parts by weight and 7 parts by weight paraffin, 3 parts by weight stearic acid and 16 weight
Part fixed oil carries out mixed melting, and fusion temperature is 80-110 DEG C, and fusing time is 60-120 minutes, obtains blended wax later
Liquid；
1.4 parts by weight Phthalocyanine Green Gs, 3.8 parts by weight Fast Yellow 10Gs, 0.7 parts by weight titanium white are added into above-mentioned blended wax liquid
Powder carries out uniform stirring, is heated while agitating, and heating temperature is 70-90 DEG C, and stirring is uniformly mixed for 30-60 minutes
Close object；
It is processed into fine granular viridine green with three-roll grinder again and pre-processes object；
By 8.4 parts by weight of glycerin monoleates, 2.1 parts by weight nonylphenol polyoxyethylene ether (n 4), 6.3 parts by weight nonyls
Phenol polyethenoxy ether (n 9), 0.3 parts by weight 2,6- di-tert-butyl-4-methy phenol, with remaining 7 parts by weight paraffin, 3 parts by weight
Stearic acid and 16 parts by weight fixed oils carry out mixed melting, and fusion temperature is 80-110 DEG C, and fusing time is 60-120 minutes, it
After obtain aqueous wax liquor；
Viridine green pretreatment object and 0.7 parts by weight beeswax, 13.7 weights obtained are added into above-mentioned water-borne wax liquid
Measure part calcium carbonate, 4 parts by weight kaolin clay, 3.55 parts by weight jasmine flower concretes, 0.05 parts by weight [2- [(2,6- dimethyl
Phenyl) amino]-N, N- diethylbenzyl ammonium, being heated to 80-110 DEG C is completely melt it, and stirs and obtain within 30-60 minutes
Even liquid slurry；
Again by obtained liquid slurry by moulding process obtain the green can washcoated crow wax crayon, what when molding, used
Cooling temperature is 15-30 DEG C.
The green being prepared by the above method can washcoated crow wax crayon be environment-protecting and non-poisonous, antibacterial is safe, with Jasmine
Faint scent；With bitter taste, children can be effectively suppressed and eat by mistake and bite；Pen body is smooth tack-free when use, and clothing and skin are arrived in contamination
On can easily be cleaned with water, can a variety of surfaces such as glass, metal, plastics, marble carry out scribble and with clear water it is i.e. erasable；
Painting is drawn on paper fine and smooth easily colouring, is got wet dizzy dye with writing brush, can dissolve the art effect for generating similar watercolor.
Embodiment 3: black can washcoated crow wax crayon
It is formulated as follows: 1.5 parts by weight of beeswax；9 parts by weight of paraffin；2 parts by weight of Fischer-Tropsch wax；9 parts by weight of stearic acid；Fixed oil
36 parts by weight；3 parts by weight of slab oil；11.44 parts by weight of calcium carbonate；4.5 parts by weight of kaolin；2.4 parts by weight of carbon black；It is sweet
Oily 6.3 parts by weight of monoleate；4.2 parts by weight of nonylphenol polyoxyethylene ether (n 5)；Nonylphenol polyoxyethylene ether (n 12)
8.4 parts by weight；0.2 parts by weight of 2,6 di tert butyl 4 methyl phenol；2 parts by weight of Lavender；Benzoic acid [2- [(2,6-
3,5-dimethylphenyl) amino]-N, 0.06 parts by weight of N- diethylbenzyl ammonium.
The preparation method is as follows: by the slab oil of 3 parts by weight and 4.5 parts by weight paraffin, 1 parts by weight Fischer-Tropsch wax, 4.5 weights
It measures part stearic acid and 18 parts by weight fixed oils carries out mixed melting, fusion temperature is 80-110 DEG C, and fusing time is 60-120 points
Clock obtains mixing wax liquor later；
2.4 parts by weight of carbon black per are added into above-mentioned blended wax liquid and carry out uniform stirring, is heated, is added while agitating
Hot temperature is 70-90 DEG C, and stirring obtains a homogeneous mixture for 30-60 minutes；
It is processed into fine black particle pigment with three-roll grinder again and pre-processes object；
By 6.3 parts by weight of glycerin monoleates, 4.2 parts by weight nonylphenol polyoxyethylene ether (n 5), 8.4 parts by weight nonyls
Phenol polyethenoxy ether (n 12), 0.2 parts by weight 2,6- di-tert-butyl-4-methy phenol, with remaining 4.5 parts by weight paraffin, 1 weight
It measures part Fischer-Tropsch wax, 4.5 parts by weight stearic acid and 18 parts by weight fixed oils and carries out mixed melting, fusion temperature is 80-110 DEG C, is melted
Changing the time is 60-120 minutes, obtains aqueous wax liquor later；
Black pigment pretreatment object and 1.5 parts by weight beeswaxs, 11.44 obtained are added into above-mentioned water-borne wax liquid
Weight parts of calcium carbonate, 4.5 parts by weight kaolin clay, 2 parts by weight Lavenders, 0.06 parts by weight [2- [(2,6- diformazan
Base phenyl) amino]-N, N- diethylbenzyl ammonium, being heated to 80-110 DEG C is completely melt it, and stirs 30-60 minutes and obtain
Homogeneous liquid slurry；
Again by obtained liquid slurry by moulding process obtain the black can washcoated crow wax crayon, what when molding, used
Cooling temperature is 15-30 DEG C.
The black being prepared by the above method can washcoated crow wax crayon be environment-protecting and non-poisonous, antibacterial is safe, with lavender
Fragrance；With bitter taste, children can be effectively suppressed and eat by mistake and bite；Pen body is smooth tack-free when use, and clothing and skin are arrived in contamination
On can easily be cleaned with water, can a variety of surfaces such as glass, metal, plastics, marble carry out scribble and with clear water it is i.e. erasable；
Painting is drawn on paper fine and smooth easily colouring, is got wet dizzy dye with writing brush, can dissolve the art effect for generating similar watercolor.
Embodiment 4: pink colour can washcoated crow wax crayon
It is formulated as follows: 1 parts by weight of beeswax；12 parts by weight of paraffin；1 parts by weight of microwax；7 parts by weight of stearic acid；Fixed oil
32 parts by weight；2.4 parts by weight of slab oil；15.6 parts by weight of calcium carbonate；3.9 parts by weight of kaolin；The yellow phase 0.5 of pigment violet 19
Parts by weight；7.4 parts by weight of titanium dioxide；5 parts by weight of Monoolein；2.5 parts by weight of nonylphenol polyoxyethylene ether (n 4)；Nonyl
7.5 parts by weight of base phenol polyethenoxy ether (n 12)；0.3 parts by weight of 2,6 di tert butyl 4 methyl phenol；Rose medicinal extract 1.83
Parts by weight；Benzoic acid [2- [(2,6- 3,5-dimethylphenyl) amino]-N, 0.07 parts by weight of N- diethylbenzyl ammonium.
The preparation method is as follows: by the slab oil of 2.4 parts by weight and 6 parts by weight paraffin, 0.5 parts by weight microwax, 3.5
Parts by weight stearic acid and 16 parts by weight fixed oils carry out mixed melting, and fusion temperature is 80-110 DEG C, fusing time 60-120
Minute, mixing wax liquor is obtained later；
The yellow phase of 0.5 parts by weight pigment violet 19 is added into above-mentioned blended wax liquid, 7.4 parts by weight titanium dioxides are uniformly stirred
It mixes, is heated while agitating, heating temperature is 70-90 DEG C, and stirring obtains a homogeneous mixture for 30-60 minutes；
It is processed into fine granular pink colour pigment with three-roll grinder again and pre-processes object；
By 5 parts by weight of glycerin monoleates, 2.5 parts by weight nonylphenol polyoxyethylene ether (n 4), 7.5 parts by weight nonyl phenols
Polyoxyethylene ether (n 12), 0.3 parts by weight 2,6- di-tert-butyl-4-methy phenol, with remaining 6 parts by weight paraffin, residue 0.5
Parts by weight microwax, 3.5 parts by weight stearic acid and 16 parts by weight fixed oils carry out mixed melting, and fusion temperature is 80-110 DEG C,
Fusing time is 60-120 minutes, obtains aqueous wax liquor later；
Pink colour pigment pretreatment object and 1 parts by weight beeswax, 15.6 weight obtained are added into above-mentioned water-borne wax liquid
Part calcium carbonate, 3.9 parts by weight kaolin clay, 1.83 parts by weight rose medicinal extract, 0.07 parts by weight [2- [(2,6- dimethyl benzene
Base) amino]-N, N- diethylbenzyl ammonium, being heated to 80-110 DEG C is completely melt it, and stirs and obtain within 30-60 minutes uniformly
Liquid slurry；
Again by obtained liquid slurry by moulding process obtain the pink colour can washcoated crow wax crayon, what when molding, used
Cooling temperature is 15-30 DEG C.
The pink colour being prepared by the above method can washcoated crow wax crayon be environment-protecting and non-poisonous, antibacterial is safe, the perfume (or spice) with rose
Gas；With bitter taste, children can be effectively suppressed and eat by mistake and bite；Pen body is smooth tack-free when use, in contamination to clothing and skin
Can easily be cleaned with water, can a variety of surfaces such as glass, metal, plastics, marble carry out scribble and with clear water it is i.e. erasable；It applies
It is drawn on paper fine and smooth easily colouring, is got wet dizzy dye with writing brush, can dissolve the art effect for generating similar watercolor.
Embodiment 5: white can washcoated crow wax crayon
It is formulated as follows: 1 parts by weight of beeswax, 10 parts by weight of paraffin；1.4 parts by weight of microwax；7 parts by weight of stearic acid；Hardening
Oily 32 parts by weight；2 parts by weight of slab oil；9.3 parts by weight of calcium carbonate；4 parts by weight of kaolin；13 parts by weight of titanium dioxide；It is sweet
Oily 8 parts by weight of monoleate；3 parts by weight of nonylphenol polyoxyethylene ether (n 4)；6.5 weight of nonylphenol polyoxyethylene ether (n 10)
Measure part；0.25 parts by weight of 2,6 di tert butyl 4 methyl phenol；2.5 parts by weight of Rosa Damascana；Benzoic acid [2- [(2,6- diformazan
Base phenyl) amino]-N, 0.05 parts by weight of N- diethylbenzyl ammonium.
The preparation method is as follows: by the slab oil of 2 parts by weight and 5 parts by weight paraffin, 0.7 parts by weight microwax, 3.5 weights
It measures part stearic acid and 16 parts by weight fixed oils carries out mixed melting, fusion temperature is 80-110 DEG C, and fusing time is 60-120 points
Clock obtains mixing wax liquor later；
13 parts by weight titanium dioxides are added into above-mentioned blended wax liquid and carry out uniform stirring, are heated while agitating,
Heating temperature is 70-90 DEG C, and stirring obtains a homogeneous mixture for 30-60 minutes；
It is processed into fine granular white pigment with three-roll grinder again and pre-processes object；
8 parts by weight of glycerin monoleates, 3 parts by weight nonylphenol polyoxyethylene ether (n 4), 6.5 parts by weight nonyl phenols are poly-
Ethylene oxide ether (n 10), 0.25 parts by weight 2,6- di-tert-butyl-4-methy phenol, with remaining 5 parts by weight paraffin, 0.7 parts by weight
Microwax, 3.5 parts by weight stearic acid and 16 parts by weight fixed oils carry out mixed melting, and fusion temperature is 80-110 DEG C, when fusing
Between be 60-120 minutes, obtain aqueous wax liquor later；
White pigment pretreatment object and 1 parts by weight beeswax, 9.3 weight obtained are added into above-mentioned water-borne wax liquid
Part calcium carbonate, 4 parts by weight kaolin clay, 2.5 parts by weight Rosa Damascanas, 0.05 parts by weight [2- [(2,6- 3,5-dimethylphenyl)
Amino]-N, N- diethylbenzyl ammonium, being heated to 80-110 DEG C is completely melt it, and stirs 30-60 minutes and obtain uniform liquid
State slurry；
Again by obtained liquid slurry by moulding process obtain the white can washcoated crow wax crayon, what when molding, used
Cooling temperature is 15-30 DEG C.
The white being prepared by the above method can washcoated crow wax crayon be environment-protecting and non-poisonous, antibacterial is safe, the perfume (or spice) with rose
Gas；With bitter taste, children can be effectively suppressed and eat by mistake and bite；Pen body is smooth tack-free when use, in contamination to clothing and skin
Can easily be cleaned with water, can a variety of surfaces such as glass, metal, plastics, marble carry out scribble and with clear water it is i.e. erasable；It applies
It is drawn on paper fine and smooth easily colouring, is got wet dizzy dye with writing brush, can dissolve the art effect for generating similar watercolor.
Embodiment 6: lemon yellow can washcoated crow wax crayon
It is formulated as follows: 0.8 parts by weight of beeswax, 14 parts by weight of paraffin；6 parts by weight of stearic acid；32 parts by weight of fixed oil；White
3 parts by weight of mineral oil；13.85 parts by weight of calcium carbonate；5 parts by weight of kaolin；5 parts by weight of Fast Yellow 10G；Monoolein
7.8 parts by weight；2.8 parts by weight of nonylphenol polyoxyethylene ether (n 4)；6.4 parts by weight of nonylphenol polyoxyethylene ether (n 10)；2,
0.3 parts by weight of 6- di-tert-butyl-4-methy phenol；3 parts by weight of jasmine flower concrete；Benzoic acid [2- [(2,6- 3,5-dimethylphenyl) ammonia
Base]-N, 0.05 parts by weight of N- diethylbenzyl ammonium.
The preparation method is as follows: by the slab oil of 3 parts by weight and 7 parts by weight paraffin, 3 parts by weight stearic acid and 16 weight
Part fixed oil carries out mixed melting, and fusion temperature is 80-110 DEG C, and fusing time is 60-120 minutes, obtains blended wax later
Liquid；
5 parts by weight Fast Yellow 10Gs are added into above-mentioned blended wax liquid and carry out uniform stirring, are added while agitating
Heat, heating temperature are 70-90 DEG C, and stirring obtains a homogeneous mixture for 30-60 minutes；
It is processed into fine granular lemon yellow pigment with three-roll grinder again and pre-processes object；
By 7.8 parts by weight of glycerin monoleates, 2.8 parts by weight nonylphenol polyoxyethylene ether (n 4), 6.4 parts by weight nonyls
Phenol polyethenoxy ether (n 10), 0.3 parts by weight 2,6- di-tert-butyl-4-methy phenol, with remaining 7 parts by weight paraffin, 3 weight
Part stearic acid and 16 parts by weight fixed oils carry out mixed melting, and fusion temperature is 80-110 DEG C, and fusing time is 60-120 minutes,
Aqueous wax liquor is obtained later；
Be added into above-mentioned water-borne wax liquid obtained lemon yellow pigment pretreatment object and 0.8 parts by weight beeswax,
13.85 weight parts of calcium carbonate, 5 parts by weight kaolin clay, 3 parts by weight jasmine flower concretes, 0.05 parts by weight [2- [(2,6- bis-
Aminomethyl phenyl) amino]-N, N- diethylbenzyl ammonium, being heated to 80-110 DEG C is completely melt it, and stirs 30-60 minutes
To homogeneous liquid slurry；
Again by obtained liquid slurry by moulding process obtain the lemon yellow can washcoated crow wax crayon, when molding makes
Cooling temperature is 15-30 DEG C.
The lemon yellow being prepared by the above method can washcoated crow wax crayon be environment-protecting and non-poisonous, antibacterial is safe, has jasmine
Colored fragrance；With bitter taste, children can be effectively suppressed and eat by mistake and bite；Pen body is smooth tack-free when use, contamination to clothing and
It can easily be cleaned on skin with water, on a variety of surfaces such as glass, metal, plastics, marble can carry out scribble and with clear water
Erasing；Painting is drawn on paper fine and smooth easily colouring, is got wet dizzy dye with writing brush, can dissolve the art effect for generating similar watercolor.
In order to better illustrate the present invention the advantages of, in addition to the implementation, the present invention also provides implement as a comparison
The wax crayon of example:
Comparative example 1a
Orange wax crayon formula is as follows: 0.8 parts by weight of beeswax；10 parts by weight of paraffin；2 parts by weight of microwax；8 weight of stearic acid
Part；34 parts by weight of fixed oil；2 parts by weight of slab oil；15.1 parts by weight of calcium carbonate；5 parts by weight of kaolin；Pigment orange 16 2
Parts by weight；6 parts by weight of nonylphenol polyoxyethylene ether (n 4)；12 parts by weight of nonylphenol polyoxyethylene ether (n 10)；Bis- uncle of 2,6-
0.25 parts by weight of butyl -4- methylphenol；2.8 parts by weight of Rosa Damascana；Benzoic acid [2- [(2,6- 3,5-dimethylphenyl) amino]-
0.05 parts by weight of N, N- diethylbenzyl ammonium.
Comparative example 2a
Green wax crayon formula is as follows: 0.7 parts by weight of beeswax；14 parts by weight of paraffin；6 parts by weight of stearic acid；32 weight of fixed oil
Measure part；3 parts by weight of slab oil；13.7 parts by weight of calcium carbonate；4 parts by weight of kaolin；1.4 parts by weight of Phthalocyanine Green G；It is sun-proof
Yellow 3.8 parts by weight of 10G；0.7 parts by weight of titanium dioxide；8.4 parts by weight of Monoolein；Nonylphenol polyoxyethylene ether (n 9)
8.4 parts by weight；0.3 parts by weight of 2,6 di tert butyl 4 methyl phenol；3.55 parts by weight of jasmine flower concrete；Benzoic acid [2- [(2,
6- 3,5-dimethylphenyl) amino]-N, 0.05 parts by weight of N- diethylbenzyl ammonium.
Comparative example 3a
Black crayon formula is as follows: 1.5 parts by weight of beeswax；9 parts by weight of paraffin；2 parts by weight of Fischer-Tropsch wax；9 weight of stearic acid
Part；36 parts by weight of fixed oil；3 parts by weight of slab oil；11.44 parts by weight of calcium carbonate；4.5 parts by weight of kaolin；Carbon black 2.4
Parts by weight；6.3 parts by weight of Monoolein；12.6 parts by weight of nonylphenol polyoxyethylene ether (n 5)；2,6- di-t-butyl -4-
0.2 parts by weight of methylphenol；2 parts by weight of Lavender；Benzoic acid [2- [(2,6- 3,5-dimethylphenyl) amino]-N, N- diethyl
0.06 parts by weight of base hexadecyldimethyl benzyl ammonium.
Comparative example 4a
Pink colour wax crayon formula is as follows: 1 parts by weight of beeswax；12 parts by weight of paraffin；1 parts by weight of microwax；7 weight of stearic acid
Part；32 parts by weight of fixed oil；2.4 parts by weight of slab oil；15.6 parts by weight of calcium carbonate；3.9 parts by weight of kaolin；Pigment violet
19 0.5 parts by weight of yellow phase；7.4 parts by weight of titanium dioxide；5 parts by weight of Monoolein；Nonylphenol polyoxyethylene ether (n 7) 2.5
Parts by weight；7.5 parts by weight of nonylphenol polyoxyethylene ether (n 12)；0.3 parts by weight of 2,6 di tert butyl 4 methyl phenol；Rose
1.83 parts by weight of medicinal extract；Benzoic acid [2- [(2,6- 3,5-dimethylphenyl) amino]-N, 0.07 parts by weight of N- diethylbenzyl ammonium.
Comparative example 1a, 2a, 3a, the wax crayon of 4a are obtained by preparation method identical with above-described embodiment 1-4.
Properties of product test:
According to following methods evaluate embodiment 1-6 can scribble obtained in washcoated crow wax crayon and comparative example 1a-4a
Wax crayon carries out fracture resistence force, tinting strength, tinting power, illustrative, watercolor solute effect and the test of washing property.
Fracture resistence force measuring method is referring to QB/T 1336-2000 wax crayon professional standard, it is desirable that fracture resistence force > 4N.
Tinting strength, tinting power test is to be applied with sample on a variety of surfaces such as paper, skin, cloth, plastics, glass, marble and metal
It draws, and gives a mark to tinting strength, tinting power:
A: colouring can be scribbled in various dielectric surfaces, tinting strength, tinting power is good；
B: it easily paints in rough surfaces such as paper, clothes, but is not easy to paint in smooth surface, face can just be showed by scribbling repeatedly
Color；
C: can only scribble coloring on paper, cloth, can not paint in other smooth surfaces.
Illustrative test be with sample on lead drawing paper uniform full coat 50mm*50mm area painting sample, and to illustrative
It gives a mark:
A: it is fluent to describe, and it is uniform to apply sample color；
B: it is fluent to describe, but applies sample irregular colour；
C: it is unfluent to describe, and applies sample irregular colour.
After the test of watercolor solute effect refers to and scribbled on lead drawing paper with sample, is got wet stitching drawn by dizzy dye, seen with writing brush
The water-soluble situation of stitching is examined, and is given a mark to watercolor solute effect:
A: stitching is soluble easily in water, and pigment generates watercolor effect in diffusion on paper；
B: stitching is slightly soluble in water, there is micro pigment in water, but can not be in spreading on paper；
C: stitching is not soluble in water, adds stitching before and after water to change without diffusion, pigment and the separated state of water.
The test of washing property refers to sample in scribbling 50mm*50mm respectively on the different mediums such as skin, desktop, cloth surface
It after the color lump of area, is washed by rubbing with the hands with clear water, observes cleaning effect；If do not clean, then plus cleaning agent wash by rubbing with the hands, observation cleaning effect
Fruit, and give a mark to washing property:
A: can be cleaned with clear water, without obvious remaining trace；
B: can not be cleaned with clear water, detergent need to be added to clean, without obvious remaining trace；
C: adding detergent to clean, and still has obvious remaining trace.
Test result is shown in Table 1.
Table 1
The result shown in the table 1 can be seen that compared with comparative example, it is of the invention can washcoated crow wax crayon, with regard to it
For color power, there is tinting strength, tinting power more stronger than comparative example, it can be in paper, skin, cloth, plastics, glass, marble and gold
Scribble colouring in a variety of surfaces such as category；Watercolor solute effect is good, can produce the effect of watercolor with water dizzy dye；It is easier to clean, not
It can be cleaned after being scribbled with surface with clear water, noresidue trace；For illustrative, there is more preferable smoothness, color sophistication
And homogeneity；In addition, their fracture resistence force meets industry requirement.
Wax crayon in comparative example is not easy to paint in smooth surface, with the anhydrous color effect of water dizzy dye, also, after scribbling not
It is easily cleaned.Wax crayon in comparative example, tinting strength, tinting power, illustrative, watercolor solute effect and washing property are inferior to of the invention
It can washcoated crow wax crayon.
Shown according to above-mentioned test result, compared with conventional wax crayon, it is of the invention can washcoated crow wax crayon just include fracture resistence force,
Tinting strength, tinting power, illustrative, watercolor solute effect, and washing property including performance for, as can washcoated crow wax crayon function it is excellent.
And it is environment-protecting and non-poisonous, antibacterial is safe, with natural plants fragrance；There is bitter taste when eating by mistake and biting, children's mistake can be effectively suppressed
It eats and bites, be more suitable for children's use.
Those skilled in the art should be noted that embodiment described in the invention is only exemplary, can be
Various other replacements, changes and improvements are made in the scope of the present invention.Thus, the present invention is not limited to the above embodiments, and only
It is defined by the claims.
Claims (13)
1. one kind can washcoated crow wax crayon, including wax crayon substrate, environmental-friendly pigment and water-soluble water washing assistant and water.
2. as described in claim 1 can washcoated crow wax crayon, which is characterized in that the content of the water-soluble water washing assistant and water is not more than institute
State the 45% of wax crayon substrate and the environmental-friendly pigment total weight.
3. as described in claim 1 can washcoated crow wax crayon, which is characterized in that the wax crayon substrate includes beeswax, wax, tristearin
Acid, fixed oil, slab oil, filler, antioxidant, natural plant pefume and food-grade bitters.
4. as claimed in claim 3 can washcoated crow wax crayon, which is characterized in that by weight, it is described can washcoated crow wax crayon packet
Include the beeswax 0.5-2 parts by weight, the wax 5-15 parts by weight, the stearic acid 3-10 parts by weight, fixed oil 30-40 weight
Measure part, the slab oil 1-4 parts by weight, the filler 15-30 parts by weight, the environmental-friendly pigment 1-15 parts by weight, institute
State antioxidant 0.01-1.5 parts by weight, the natural plant pefume 0.1-5 parts by weight, the food-grade bitters 0.001-
0.3 parts by weight and the water-soluble water washing assistant and water 15-25 parts by weight.
5. as claimed in claim 4 can washcoated crow wax crayon, which is characterized in that
The wax includes at least one selected from paraffin, microwax, synthetic wax；
The paraffin is semi-refined or fully refined paraffin wax of the fusing point at 54-62 DEG C；
The microwax is microwax of the fusing point at 80-95 DEG C；
The synthetic wax includes selected from Fischer-Tropsch wax, polyethylene wax, polypropylene wax, ethylene-vinyl acetate copolymer wax, the poly- second of oxidation
At least one of alkene wax；
The fixed oil is saturated fatty acid monoglyceride；
The slab oil is that 40 DEG C of kinematic viscosity are 30-70mm2The makeup grade white oil of/s；
The filler includes at least one selected from calcium carbonate, kaolin, talcum powder, white carbon black, barium sulfate；
The natural plant pefume includes being selected from least one of plants essential oil, plant extract；
The food-grade bitters is benzoic acid [2- [(2,6- 3,5-dimethylphenyl) amino]-N, N- diethylbenzyl ammonium；
The antioxidant includes being selected from 2,6 di tert butyl 4 methyl phenol, (1,1- dimethyl ethyl) -4- metoxyphenol
At least one；
The environmental-friendly pigment includes the environmental-friendly pigment that harmful substance contents meet at least one color of European Union's EN71 standard.
6. as claimed in claim 2 can washcoated crow wax crayon, which is characterized in that the water-soluble water washing assistant and water includes glycerol list oleic acid
The composition of ester and nonylphenol polyoxyethylene ether.
7. as claimed in claim 6 can washcoated crow wax crayon, which is characterized in that the Monoolein and the nonyl phenol are poly-
The weight ratio of ethylene oxide ether is 1:1-2.
8. as claimed in claim 7 can washcoated crow wax crayon, which is characterized in that the nonylphenol polyoxyethylene ether includes
The combination of lipophilic nonylphenol polyoxyethylene ether and hydrophily nonylphenol polyoxyethylene ether, wherein the lipophilicity nonyl
Phenol polyethenoxy ether is molecular formula C15H24O.(C2H4O)nNonylphenol polyoxyethylene ether, wherein n be 4 or 5, one kind or one kind
More than；The hydrophily nonylphenol polyoxyethylene ether is molecular formula C15H24O.(C2H4O)nNonylphenol polyoxyethylene ether, wherein n
Be 9,10,11 or 12, one or more.
9. as claimed in claim 8 can washcoated crow wax crayon, which is characterized in that the lipophilicity nonylphenol polyoxyethylene ether and institute
The weight ratio for stating hydrophily nonylphenol polyoxyethylene ether is 1:2-3.
10. one kind can washcoated crow wax crayon preparation method, comprising:
Step (a) is by one of a part of slab oil and wax total amount, a part of stearic acid total amount and fixed oil total amount
Divide and carry out mixed melting, obtains mixing wax liquor later；
Environmental-friendly pigment is added in the mixing wax liquor that step (b) Xiang Suoshu step (a) obtains and carries out uniform stirring, while agitating
It is heated, stirs to get homogeneous mixture；
The homogeneous mixture attrition process that step (c) obtains the step (b) is pre-processed at the pigment of fine granular semisolid
Object；
Step (d) mixes water-soluble water washing assistant and water, antioxidant and remaining wax, remaining stearic acid and remaining fixed oil
Fusing is closed, obtains aqueous wax liquor later；
The pigment pretreatment object that the step (c) obtains is added in the aqueous wax liquor that step (e) Xiang Suoshu step (d) obtains, and
Beeswax, filler, natural plants essence, bitters, are heated to being completely melt it, and stir to get homogeneous liquid pulpous state
Object；
The liquid slurry that the step (e) obtains is obtained the wax crayon by moulding process by step (f).
11. preparation method as claimed in claim 10, which is characterized in that
Fusion temperature in the step (a) is 80-110 DEG C, and fusing time is 60-120 minutes；
Heating temperature in the step (b) is 70-90 DEG C, and mixing time is 30-60 minutes；
Fusion temperature in the step (d) is 80-110 DEG C, and fusing time is 60-120 minutes；
Heating temperature in the step (e) is to be heated to 80-110 DEG C, and mixing time is 30-60 minutes；
The cooling temperature of the moulding process in the step (f) is 15-30 DEG C.
12. preparation method as claimed in claim 10, which is characterized in that
In the step (a), by half, the half of the stearic acid total amount and the institute of the slab oil and the wax total amount
The half for stating fixed oil total amount carries out mixed melting；
In the step (d), by the water-soluble water washing assistant and water, the antioxidant and the other half the wax, the other half institute
It states stearic acid and the other half the fixed oil carries out mixed melting.
13. preparation method as claimed in claim 10, which is characterized in that
In the step (c), including by the homogeneous mixture with three-roll grinder attrition process to described fine granular half solid
The grain fineness of state object is at 5-50 μm；
In the step (e), including stirring the grain fineness to the liquid slurry at 5-50 μm.
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| CN114149712A (en) * | 2021-09-30 | 2022-03-08 | 深圳市兰亭科技股份有限公司 | Bathroom crayon and preparation method thereof |
| TWI761272B (en) * | 2021-08-03 | 2022-04-11 | 邱鈺芸 | Environment-friendly composite wax paint preparation method |
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| WO2021202829A1 (en) * | 2020-04-02 | 2021-10-07 | Sasol (Usa) Corporation | Water-soluble coloring compositions comprising alcohol alkoxylates with 40 to 160 ethoxy units derived from primary alcohols having a chain length between 20 and 30 carbon atoms |
| TWI761272B (en) * | 2021-08-03 | 2022-04-11 | 邱鈺芸 | Environment-friendly composite wax paint preparation method |
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| CN115029034A (en) * | 2022-07-04 | 2022-09-09 | 赤壁吉利隆文化用品有限公司 | Environment-friendly clean delicate fragrance type crayon |
| CN116855133A (en) * | 2023-05-17 | 2023-10-10 | 广州美术学院 | Pure natural soybean crayon and preparation method thereof |
| CN116855133B (en) * | 2023-05-17 | 2024-04-16 | 广州美术学院 | Pure natural soybean crayon and preparation method thereof |
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