CN109505129A - 一种液态凝胶树脂和制备超高分子量聚乙烯钓线的方法 - Google Patents

一种液态凝胶树脂和制备超高分子量聚乙烯钓线的方法 Download PDF

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CN109505129A
CN109505129A CN201811318756.5A CN201811318756A CN109505129A CN 109505129 A CN109505129 A CN 109505129A CN 201811318756 A CN201811318756 A CN 201811318756A CN 109505129 A CN109505129 A CN 109505129A
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liquid gel
gel resin
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吕从慧
仲陈锐
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Lianyungang Lunyang Monofilament Technology Co ltd
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    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
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    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract

一种液态凝胶树脂和超高分子量聚乙烯钓线的制备方法,该树脂由以下重量配比的原料组成,FEVE氟碳涂料50‑100、固化剂1‑20、二月桂酸二丁基锡0.1‑4、有机溶剂50‑100、钨粉1‑15、硅酮粉1‑5、色粉0.1‑1,其步骤为,先将直接成束或采用大节距编织方法编织好的复丝芯线浸入到上述液态凝胶树脂中,完全浸没,浸入1‑5分钟后,液态凝胶树脂渗透到复丝芯线的空隙,再将液态凝胶树脂与复丝芯线形成的组合物通过模口挤压成型,常温固化,即可。本发明通过合理设置FEVE氟碳涂料与钨粉的比重,实现钓线良好的沉水性能,调节沉水速率,通过合理设置固化剂的比例来控制常温固化需要的时间,降低生产成本,有效地解决横向开叉和沉水这两个问题。

Description

一种液态凝胶树脂和制备超高分子量聚乙烯钓线的方法
技术领域
本发明涉及一种钓线的生产方法,特别涉及一种液态凝胶树脂和制备超高分子量聚乙烯钓线的方法。
背景技术
目前,采用超高分子量聚乙烯(简称:HUMEPE)原料生产的钓线有多种,具有代表性的是两类:一是美国公司采用“热”加工的方式生产的钓线(俗称“火线”);另一类是编织线加表面涂层处理。这两类钓线的共同特性是,使用后,容易产生横向的“分叉开裂”状况和表面“起毛”。并且,这种钓线比重较轻,不容易沉水。虽然,国内外厂家大多采用金属丝和高比重纤维的混合来改变沉水性能,但同时造成强力下降和线硬的弊病。
发明内容
本发明所要解决的技术问题是针对现有技术的不足,提供一种设计合理,制备超高分子量聚乙烯钓线的液态凝胶树脂。
本发明所要解决的另一技术问题是针对现有技术的不足,提供一种设计合理,能有效解决横向开叉和沉水这两个问题的超高分子量聚乙烯钓线的制备方法。
本发明所要解决的技术问题是通过以下的技术方案来实现的,本发明是一种制备超高分子量聚乙烯钓线的液态凝胶树脂,一种制备超高分子量聚乙烯钓线的液态凝胶树脂,其特点是,该树脂由以下重量配比的原料组成,FEVE氟碳涂料 50-100、固化剂1-20、催化剂0.1-4、有机溶剂50-100、钨粉1-15、硅酮粉1-5、色粉0.1-1。
本发明所要解决的技术问题还可以通过以下的技术方案来实现的,各原料的重量配比为,FEVE氟碳涂料 80、固化剂10、催化剂2.5、有机溶剂80、钨粉10、硅酮粉2.5、色粉0.5。
本发明所要解决的技术问题还可以通过以下的技术方案来实现的,所述的固化剂为聚氨基甲酸酯或二乙烯三胺,所述的有机溶剂为二甲苯、丙酮或甲酰二甲胺,所述催化剂为二月桂酸二丁基锡或二醋酸二丁基锡。
本发明所要解决的另一技术问题是通过以下的技术方案来实现的,本发明是一种超高分子量聚乙烯钓线的制备方法,其特点是,先将直接成束或采用大节距编织方法编织好的复丝芯线浸入到上述液态凝胶树脂中,完全浸没,浸入1-5分钟后,液态凝胶树脂渗透到复丝芯线的空隙,再将液态凝胶树脂与复丝芯线形成的组合物通过模口挤压成型,常温固化,制得超高分子量聚乙烯钓线。
本发明所要解决的技术问题还可以通过以下的技术方案来实现的,挤压成型过程中所使用的液态凝胶树脂占钓线总质量的10%-50%。
与现有技术相比,本发明通过采用浸入和挤压成型工艺,很好地解决了钓线横向开叉的问题,通过合理设置FEVE氟碳涂料与钨粉的比重,实现钓线良好的沉水性能,调节沉水速率;通过合理设置固化剂的比例来控制常温固化需要的时间,降低生产成本;设计简单、合理,成本低,有效地解决横向开叉和沉水这两个问题。
具体实施方式
进一步描述本发明的具体技术方案,以便于本领域的技术人员进一步地理解本发明,而不构成对其权利的限制。
实施例1,一种制备超高分子量聚乙烯钓线的液态凝胶树脂,该树脂由以下重量配比的原料组成,FEVE氟碳涂料 50、聚氨基甲酸酯1、二月桂酸二丁基锡0.1、二甲苯50、钨粉1、硅酮粉1、色粉0.1,将上述原料混合均匀即制得液态凝胶树脂。
实施例2,一种制备超高分子量聚乙烯钓线的液态凝胶树脂,该树脂由以下重量配比的原料组成,FEVE氟碳涂料 100、聚氨基甲酸酯20、二醋酸二丁基锡4、丙酮100、钨粉15、硅酮粉5、色粉1,将上述原料混合均匀即制得液态凝胶树脂。
实施例3,一种制备超高分子量聚乙烯钓线的液态凝胶树脂,该树脂由以下重量配比的原料组成,FEVE氟碳涂料 80、聚氨基甲酸酯10、二月桂酸二丁基锡2.5、二甲苯80、钨粉10、硅酮粉2.5、色粉0.5,将上述原料混合均匀即制得液态凝胶树脂。
实施例4,一种制备超高分子量聚乙烯钓线的液态凝胶树脂,该树脂由以下重量配比的原料组成,FEVE氟碳涂料 90、聚氨基甲酸酯6、二月桂酸二丁基锡0.2、甲酰二甲胺70、钨粉5、硅酮粉2、色粉0.6,将上述原料混合均匀即制得液态凝胶树脂。
实施例5,一种超高分子量聚乙烯钓线的制备方法,其步骤为,先将直接成束或采用大节距编织方法编织好的复丝芯线浸入到实施例1-4所述的液态凝胶树脂中,完全浸没,浸入1-5分钟后,液态凝胶树脂渗透到复丝芯线的空隙,再将液态凝胶树脂与复丝芯线形成的组合物通过模口挤压成型,常温固化,制得超高分子量聚乙烯钓线。本发明通过浸没和挤压成型,使液态凝胶树脂完全充满HUMEPE复丝芯线之间的空隙,很好地提高了复丝芯线与液态凝胶树脂的组合,通过采用常温固化,不同于加热固化工艺,工艺成本低;本发明中所述的硅酮粉可采用有机硅硅酮粉。
实施例6,实施例5所述的超高分子量聚乙烯钓线的制备方法,挤压成型过程中所使用的液态凝胶树脂占钓线总质量的10%。
实施例7,实施例5所述的超高分子量聚乙烯钓线的制备方法,挤压成型过程中所使用的液态凝胶树脂占钓线总质量的50%。
实施例8,实施例5所述的超高分子量聚乙烯钓线的制备方法,挤压成型过程中所使用的液态凝胶树脂占钓线总质量的25%。
本发明制定适中的钓线强度标准,选取20G/D--30G/D为本发明钓线的强力标准,所述复丝芯线为HUMEPE复丝芯线,是在尼龙强度10G/D和HUMEPE 强度40G/D的中间位置,选用直接成束或采用大节距编织方法编织得到的复丝芯线,以最大限度的保留复丝芯线的直线强力;本发明通过合理设置原料和辅料的比重,来实现沉水性能,重点采使用钨粉(密度13G/CM3)辅料的混入,混入量取1%到15%之间,实现钓线的沉水性能,调节沉水速率; 通过调整固化剂的比例来控制常温固化需要的时间,固化剂的加入量占原料总质量的1%-20%,以提高生产效率,降低生产成本;通过调整固化剂和催化剂的比例,来实现不同的柔软度;通过调整硅酮粉的加入量,来提高爽滑性,增加耐磨性能,另外,本发明中所述的FEVE氟碳涂料可采用现有市售的FEVE氟碳涂料产品。

Claims (7)

1.一种制备超高分子量聚乙烯钓线的液态凝胶树脂,其特征在于:该树脂由以下重量配比的原料组成,FEVE氟碳涂料 50-100、固化剂1-20、催化剂0.1-4、有机溶剂50-100、钨粉1-15、硅酮粉1-5、色粉0.1-1。
2.根据权利要求1所述的制备超高分子量聚乙烯钓线的液态凝胶树脂,其特征在于:各原料的重量配比为,FEVE氟碳涂料 80、固化剂10、催化剂2.5、有机溶剂80、钨粉10、硅酮粉2.5、色粉0.5。
3.根据权利要求1或2所述的制备超高分子量聚乙烯钓线的液态凝胶树脂,其特征在于:所述的固化剂为聚氨基甲酸酯或二乙烯三胺。
4.根据权利要求1或2所述的制备超高分子量聚乙烯钓线的液态凝胶树脂,其特征在于:所述的有机溶剂为二甲苯、丙酮或甲酰二甲胺。
5.根据权利要求1或2所述的制备超高分子量聚乙烯钓线的液态凝胶树脂,其特征在于:所述催化剂为二月桂酸二丁基锡或二醋酸二丁基锡。
6.一种超高分子量聚乙烯钓线的制备方法,其特征在于:先将直接成束或采用大节距编织方法编织好的复丝芯线浸入到权利要求1-5任一项所述的液态凝胶树脂中,完全浸没,浸入1-5分钟后,液态凝胶树脂渗透到复丝芯线的空隙,再将液态凝胶树脂与复丝芯线形成的组合物通过模口挤压成型,常温固化,制得超高分子量聚乙烯钓线。
7.根据权利要求6所述的制备超高分子量聚乙烯钓线的液态凝胶树脂,其特征在于:挤压成型过程中所使用的液态凝胶树脂占钓线总质量的10%-50%。
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08134394A (ja) * 1994-11-11 1996-05-28 Toshiba Silicone Co Ltd ゴムコーティング布用コーティング組成物
CN1417395A (zh) * 2001-10-29 2003-05-14 优知亚米有限公司 具有低伸长率和优异的耐磨性的比重可调的纱线
CN1712470A (zh) * 2004-06-23 2005-12-28 宁波艾利特科技发展有限公司 常温固化的含氟碳树脂纳米建筑涂料及其制备方法
CN102002289A (zh) * 2010-12-15 2011-04-06 广东电网公司电力科学研究院 一种常温固化氟碳树脂涂料及其制备方法
CN105505183A (zh) * 2015-12-26 2016-04-20 杭州福斯特光伏材料股份有限公司 一种高性能氟碳涂料的制备方法
CN108589352A (zh) * 2018-06-29 2018-09-28 湖北鼎中新材料有限公司 一种超高分子量聚乙烯纤维涂覆线绳及其光固化制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08134394A (ja) * 1994-11-11 1996-05-28 Toshiba Silicone Co Ltd ゴムコーティング布用コーティング組成物
CN1417395A (zh) * 2001-10-29 2003-05-14 优知亚米有限公司 具有低伸长率和优异的耐磨性的比重可调的纱线
CN1712470A (zh) * 2004-06-23 2005-12-28 宁波艾利特科技发展有限公司 常温固化的含氟碳树脂纳米建筑涂料及其制备方法
CN102002289A (zh) * 2010-12-15 2011-04-06 广东电网公司电力科学研究院 一种常温固化氟碳树脂涂料及其制备方法
CN105505183A (zh) * 2015-12-26 2016-04-20 杭州福斯特光伏材料股份有限公司 一种高性能氟碳涂料的制备方法
CN108589352A (zh) * 2018-06-29 2018-09-28 湖北鼎中新材料有限公司 一种超高分子量聚乙烯纤维涂覆线绳及其光固化制备方法

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