CN109504555A - A kind of natural feather sterilizing detergent for cleaning - Google Patents

A kind of natural feather sterilizing detergent for cleaning Download PDF

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Publication number
CN109504555A
CN109504555A CN201811430484.8A CN201811430484A CN109504555A CN 109504555 A CN109504555 A CN 109504555A CN 201811430484 A CN201811430484 A CN 201811430484A CN 109504555 A CN109504555 A CN 109504555A
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Prior art keywords
parts
cleaning
natural feather
aromatic
rare earth
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CN201811430484.8A
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Chinese (zh)
Inventor
占执灵
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Anhui Shangshang Home Textile Co Ltd
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Anhui Shangshang Home Textile Co Ltd
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Priority to CN201811430484.8A priority Critical patent/CN109504555A/en
Publication of CN109504555A publication Critical patent/CN109504555A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/349Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention discloses a kind of natural feather sterilizing detergent for cleaning, is made of the component of following parts by weight: two 1-4 parts of molybdic acid hydrate sodium, 10-15 parts of ethylenediamine base propanesulfonate, 2-5 parts of magnesium citrate, 0.6-0.9 parts of surfactant, 2-6 parts of gallic acid rare earth, 13-16 parts of aromatic, 18-24 parts of dehydrated alcohol, 85-90 parts of water.A kind of natural feather sterilizing detergent for cleaning provided by the invention, decontamination, bacteria-eliminating efficacy are significant, will not damaging laundry, while there is certain fragrant, the resting period is long, excellent quality.

Description

A kind of natural feather sterilizing detergent for cleaning
Technical field
The invention belongs to natural feather processing technology fields, and in particular to a kind of natural feather sterilizing detergent for cleaning.
Background technique
Natural feather is as a kind of porous, hydrophilic fabric, microorganism easy to breed in use process, and antimicrobial properties compared with Difference.And microorganism of the growth on down cloth passes through the metabolite that breeding generates and down cloth is easily made to change colour, is mouldy, even Nauseating bad odor is released, this can not only induce the various skin diseases of human skin, but also cause to environment certain Pollution.Natural feather sterilizing detergent for cleaning in the prior art, not only there is antibacterials to be not thorough, but also there is the injuries to natural feather Biggish technological deficiency, the dress for affecting natural feather use.
Summary of the invention
The object of the present invention is to provide a kind of natural feather sterilizing detergent for cleaning, the various diseases depended on natural feather can be effectively killed Bacteria microorganism, while the quality of natural feather will not be had adverse effect on.
The present invention is achieved by the following technical solutions.
A kind of natural feather sterilizing detergent for cleaning, is made of the component of following parts by weight: two 1-4 parts of molybdic acid hydrate sodium, ethylenediamine base 10-15 parts of propanesulfonate, 2-5 parts of magnesium citrate, 0.6-0.9 parts of surfactant, 2-6 parts of gallic acid rare earth, aromatic 13- 16 parts, 18-24 parts of dehydrated alcohol, 85-90 parts of water,
The gallic acid rare earth is made of following methods: by weight, by 13-16 parts of samarium trichlorides, 8-14 parts of chlorine Change ytterbium to be dissolved in 55-60 parts of ethyl alcohol, then proceedes to that 140-160 parts of n,N-Dimethylformamide and 25-30 parts are added thereto Gallic acid after reacting 20-24 hours in 115-120 DEG C of environment, after cleaning-drying, obtains gallic acid after mixing evenly Rare earth,
The aromatic is made of the component of following parts by weight: 10-16 parts of Fructus Aurantii, 8-12 parts of Chinese honey locust, 5-9 parts of lilac daphne, calabash 2-6 parts of reed tea, 8-12 parts of gardenia, 120-150 parts of water.
Specifically, in above-mentioned steps (1), surfactant is Cocoamidopropyl betaine, dodecyl polyoxyethylene Any one in ether sodium sulfate.
Specifically, above-mentioned to prepare reaction vessel used in gallic acid rare earth as polytetrafluoroethylene (PTFE) stainless steel reaction under high pressure Kettle, the step of cleaning-drying after reaction are as follows: the white product for obtaining reaction is impregnated 2 days with the ethyl alcohol that volume fraction is 75%, 12h is dried in vacuo at 55 DEG C later.
Specifically, the aromatic the preparation method is as follows: boiling is boiled after, then thereto be added Fructus Aurantii, Chinese honey locust, Yuan After being mixed evenly, after isothermal holding 2-3 hours, filtrate is obtained by filtration in flower, desmodium triquetrum, gardenia, then that filtrate is cooling To room temperature, aromatic is obtained.
From the above technical scheme, it can be seen that the beneficial effects of the present invention are:
A kind of natural feather sterilizing detergent for cleaning provided by the invention, decontamination, bacteria-eliminating efficacy are significant, will not damaging laundry, have simultaneously There is certain fragrant, the resting period is long, excellent quality.Two molybdic acid hydrate sodium, ethylenediamine base propanesulfonate, magnesium citrate, table After face activating agent synergistic effect, the various residual stains on natural feather can be effectively removed, and chemical property is mild, it will not be to plumage The quality of suede adversely affects;The compatibility of gallic acid rare earth and natural feather is good, can effectively kill growth and knit in natural feather Microorganism on object, gallic acid rare earth can be killed because of the presence of its organic group in the superficial residence longer time of natural feather Bacterium significant effect, while also making natural feather that there is certain anti-microbial property, samarium and ytterbium element have excellent bactericidal property, simultaneously The quality of natural feather will not be adversely affected;Aromatic provided by the invention, fragrant is strong, may make down products can Fragrant is effectively released for a long time, while aromatic itself can also play certain antibacterial action.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is The conventional products of commercially available acquisition can be passed through.
Embodiment 1
A kind of natural feather sterilizing detergent for cleaning, is made of the component of following parts by weight: two 1 part of molybdic acid hydrate sodium, ethylenediamine base third 10 parts of sodium sulfonate, 2 parts of magnesium citrate, 0.6 part of surfactant, 2 parts of gallic acid rare earth, 13 parts of aromatic, dehydrated alcohol 18 Part, 85 parts of water,
The gallic acid rare earth is made of following methods: by weight, 13 parts of samarium trichlorides, 8 parts of ytterbium chlorides are molten Solution then proceedes to that 140 parts of n,N-Dimethylformamide and 25 parts of gallic acids are added thereto, stirs evenly in 55 parts of ethyl alcohol Afterwards, after reacting 20 hours in 115 DEG C of environment, after cleaning-drying, gallic acid rare earth is obtained,
The aromatic is made of the component of following parts by weight: 10 parts of Fructus Aurantii, 8 parts of Chinese honey locust, 5 parts of lilac daphne, 2 parts of desmodium triquetrum, 8 parts of gardenia, 120 parts of water.
Specifically, in above-mentioned steps (1), surfactant is Cocoamidopropyl betaine.
Specifically, above-mentioned to prepare reaction vessel used in gallic acid rare earth as polytetrafluoroethylene (PTFE) stainless steel reaction under high pressure Kettle, the step of cleaning-drying after reaction are as follows: the white product for obtaining reaction is impregnated 2 days with the ethyl alcohol that volume fraction is 75%, 12h is dried in vacuo at 55 DEG C later.
Specifically, the aromatic the preparation method is as follows: boiling is boiled after, then thereto be added Fructus Aurantii, Chinese honey locust, Yuan Flower, desmodium triquetrum, gardenia after being mixed evenly, after isothermal holding 2 hours, are obtained by filtration filtrate, are then cooled to filtrate After room temperature, aromatic is obtained.
Embodiment 2
A kind of natural feather sterilizing detergent for cleaning, is made of the component of following parts by weight: two 3 parts of molybdic acid hydrate sodium, ethylenediamine base third 13 parts of sodium sulfonate, 3 parts of magnesium citrate, 0.8 part of surfactant, 4 parts of gallic acid rare earth, 15 parts of aromatic, dehydrated alcohol 22 Part, 88 parts of water,
The gallic acid rare earth is made of following methods: by weight, 15 parts of samarium trichlorides, 12 parts of ytterbium chlorides are molten Solution then proceedes to that 150 parts of n,N-Dimethylformamide and 28 parts of gallic acids are added thereto, stirs evenly in 58 parts of ethyl alcohol Afterwards, after reacting 22 hours in 118 DEG C of environment, after cleaning-drying, gallic acid rare earth is obtained,
The aromatic is made of the component of following parts by weight: 14 parts of Fructus Aurantii, 10 parts of Chinese honey locust, 7 parts of lilac daphne, 4 parts of desmodium triquetrum, 10 parts of gardenia, 130 parts of water.
Specifically, in above-mentioned steps (1), surfactant is Cocoamidopropyl betaine, dodecyl polyoxyethylene Any one in ether sodium sulfate.
Specifically, above-mentioned to prepare reaction vessel used in gallic acid rare earth as polytetrafluoroethylene (PTFE) stainless steel reaction under high pressure Kettle, the step of cleaning-drying after reaction are as follows: the white product for obtaining reaction is impregnated 2 days with the ethyl alcohol that volume fraction is 75%, 12h is dried in vacuo at 55 DEG C later.
Specifically, the aromatic the preparation method is as follows: boiling is boiled after, then thereto be added Fructus Aurantii, Chinese honey locust, Yuan After being mixed evenly, after isothermal holding 2.5 hours, filtrate is obtained by filtration in flower, desmodium triquetrum, gardenia, then that filtrate is cooling To room temperature, aromatic is obtained.
Embodiment 3
A kind of natural feather sterilizing detergent for cleaning, is made of the component of following parts by weight: two 4 parts of molybdic acid hydrate sodium, ethylenediamine base third 14 parts of sodium sulfonate, 4 parts of magnesium citrate, 0.8 part of surfactant, 5 parts of gallic acid rare earth, 15 parts of aromatic, dehydrated alcohol 22 Part, 89 parts of water,
The gallic acid rare earth is made of following methods: by weight, 15 parts of samarium trichlorides, 13 parts of ytterbium chlorides are molten Solution then proceedes to that 155 parts of n,N-Dimethylformamide and 28 parts of gallic acids are added thereto, stirs evenly in 59 parts of ethyl alcohol Afterwards, after reacting 23 hours in 119 DEG C of environment, after cleaning-drying, gallic acid rare earth is obtained,
The aromatic is made of the component of following parts by weight: 15 parts of Fructus Aurantii, 11 parts of Chinese honey locust, 8 parts of lilac daphne, 5 parts of desmodium triquetrum, 11 parts of gardenia, 140 parts of water.
Specifically, in above-mentioned steps (1), surfactant is dodecyl polyoxyethylene ether sodium sulphate.
Specifically, above-mentioned to prepare reaction vessel used in gallic acid rare earth as polytetrafluoroethylene (PTFE) stainless steel reaction under high pressure Kettle, the step of cleaning-drying after reaction are as follows: the white product for obtaining reaction is impregnated 2 days with the ethyl alcohol that volume fraction is 75%, 12h is dried in vacuo at 55 DEG C later.
Specifically, the aromatic the preparation method is as follows: boiling is boiled after, then thereto be added Fructus Aurantii, Chinese honey locust, Yuan Flower, desmodium triquetrum, gardenia after being mixed evenly, after isothermal holding 3 hours, are obtained by filtration filtrate, are then cooled to filtrate After room temperature, aromatic is obtained.
Embodiment 4
A kind of natural feather sterilizing detergent for cleaning, is made of the component of following parts by weight: two 4 parts of molybdic acid hydrate sodium, ethylenediamine base third 15 parts of sodium sulfonate, 5 parts of magnesium citrate, 0.9 part of surfactant, 6 parts of gallic acid rare earth, 16 parts of aromatic, dehydrated alcohol 24 Part, 90 parts of water,
The gallic acid rare earth is made of following methods: by weight, 16 parts of samarium trichlorides, 14 parts of ytterbium chlorides are molten Solution then proceedes to that 160 parts of n,N-Dimethylformamide and 30 parts of gallic acids are added thereto, stirs evenly in 60 parts of ethyl alcohol Afterwards, after reacting 24 hours in 120 DEG C of environment, after cleaning-drying, gallic acid rare earth is obtained,
The aromatic is made of the component of following parts by weight: 16 parts of Fructus Aurantii, 12 parts of Chinese honey locust, 9 parts of lilac daphne, 6 parts of desmodium triquetrum, 12 parts of gardenia, 150 parts of water.
Specifically, in above-mentioned steps (1), surfactant is dodecyl polyoxyethylene ether sodium sulphate.
Specifically, above-mentioned to prepare reaction vessel used in gallic acid rare earth as polytetrafluoroethylene (PTFE) stainless steel reaction under high pressure Kettle, the step of cleaning-drying after reaction are as follows: the white product for obtaining reaction is impregnated 2 days with the ethyl alcohol that volume fraction is 75%, 12h is dried in vacuo at 55 DEG C later.
Specifically, the aromatic the preparation method is as follows: boiling is boiled after, then thereto be added Fructus Aurantii, Chinese honey locust, Yuan Flower, desmodium triquetrum, gardenia after being mixed evenly, after isothermal holding 3 hours, are obtained by filtration filtrate, are then cooled to filtrate After room temperature, aromatic is obtained.
Comparative example 1
By gallic acid rare earth be substituted for equivalent to chloroxylenol, remaining operating procedure is identical with embodiment 1.
Measurement 1g natural feather total plate count before and after the processing respectively, then calculate each embodiment and comparative example method it is antibacterial Rate, test result are as shown in table 1:
A kind of bacteriostasis rate of the natural feather sterilizing detergent for cleaning of table 1
Project Bacteriostasis rate, %
Embodiment 1 73.8
Comparative example 1 52.1
Embodiment 2 74.9
Embodiment 3 75.2
Embodiment 4 75.8
As shown in Table 1, a kind of natural feather sterilizing detergent for cleaning produced by the present invention, bacteria-eliminating efficacy is significant, and will not damage clothing Object, excellent quality.
Certainly, the above description is not a limitation of the present invention, and the present invention is also not limited to the example above, the art Those of ordinary skill, within the essential scope of the present invention, variation, change, addition or the replacement made all should belong to the present invention Protection scope.

Claims (4)

1. a kind of natural feather sterilizing detergent for cleaning, which is characterized in that be made of the component of following parts by weight: two 1-4 parts of molybdic acid hydrate sodium, 10-15 parts of ethylenediamine base propanesulfonate, 2-5 parts of magnesium citrate, 0.6-0.9 parts of surfactant, 2-6 parts of gallic acid rare earth, 13-16 parts of aromatic, 18-24 parts of dehydrated alcohol, 85-90 parts of water,
The gallic acid rare earth is made of following methods: by weight, by 13-16 parts of samarium trichlorides, 8-14 parts of ytterbium chlorides It is dissolved in 55-60 parts of ethyl alcohol, then proceedes to that 140-160 parts of n,N-Dimethylformamide are added thereto and 25-30 parts are not eaten Sub- acid, after mixing evenly, after reacting 20-24 hours in 115-120 DEG C of environment, after cleaning-drying, obtains gallic acid rare earth,
The aromatic is made of the component of following parts by weight: 10-16 parts of Fructus Aurantii, 8-12 parts of Chinese honey locust, 5-9 parts of lilac daphne, desmodium triquetrum 2-6 parts, 8-12 parts of gardenia, 120-150 parts of water.
2. a kind of natural feather sterilizing detergent for cleaning according to claim 1, which is characterized in that in above-mentioned steps (1), surface-active Agent is Cocoamidopropyl betaine, any one in dodecyl polyoxyethylene ether sodium sulphate.
3. a kind of natural feather sterilizing detergent for cleaning according to claim 1, which is characterized in that above-mentioned to prepare gallic acid rare earth institute Reaction vessel is polytetrafluoroethylene (PTFE) stainless steel autoclave, the step of cleaning-drying after reaction are as follows: obtains reaction White product is impregnated 2 days with the ethyl alcohol that volume fraction is 75%, is dried in vacuo 12h at 55 DEG C later.
4. a kind of natural feather sterilizing detergent for cleaning according to claim 1, which is characterized in that the preparation method of the aromatic is such as Under: after boiling is boiled, Fructus Aurantii, Chinese honey locust, lilac daphne, desmodium triquetrum, gardenia are then added thereto, after being mixed evenly, heat preservation After processing 2-3 hours, filtrate is obtained by filtration, after being then cooled to room temperature filtrate, obtains aromatic.
CN201811430484.8A 2018-11-28 2018-11-28 A kind of natural feather sterilizing detergent for cleaning Pending CN109504555A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102051276A (en) * 2011-01-24 2011-05-11 北京洛娃日化有限公司 Down jacket cleaning agent
CN104744024A (en) * 2015-03-31 2015-07-01 苏州维泰生物技术有限公司 Rare-earth-doped tricalcium phosphate bioceramic and preparation method thereof
CN106010235A (en) * 2016-05-06 2016-10-12 哈尔滨宇瀚科技有限公司 Silver ion and ytterbium ion compound titanium dioxide nanoparticle modified organic silicon resin interior wall antibacterial coating and preparation method thereof
CN106497684A (en) * 2016-11-01 2017-03-15 青岛海澄知识产权事务有限公司 A kind of cleaning agent
CN106833953A (en) * 2017-01-05 2017-06-13 安徽隆羽绒有限公司 A kind of high-efficiency antimicrobial deodorization eider down cleaning agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102051276A (en) * 2011-01-24 2011-05-11 北京洛娃日化有限公司 Down jacket cleaning agent
CN104744024A (en) * 2015-03-31 2015-07-01 苏州维泰生物技术有限公司 Rare-earth-doped tricalcium phosphate bioceramic and preparation method thereof
CN106010235A (en) * 2016-05-06 2016-10-12 哈尔滨宇瀚科技有限公司 Silver ion and ytterbium ion compound titanium dioxide nanoparticle modified organic silicon resin interior wall antibacterial coating and preparation method thereof
CN106497684A (en) * 2016-11-01 2017-03-15 青岛海澄知识产权事务有限公司 A kind of cleaning agent
CN106833953A (en) * 2017-01-05 2017-06-13 安徽隆羽绒有限公司 A kind of high-efficiency antimicrobial deodorization eider down cleaning agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
颜世铭等主编: "《实用元素医学》", 31 October 1999 *

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