CN109487550A - A kind of mould proof cotton of efficient cool feeling and preparation method thereof - Google Patents
A kind of mould proof cotton of efficient cool feeling and preparation method thereof Download PDFInfo
- Publication number
- CN109487550A CN109487550A CN201811252563.4A CN201811252563A CN109487550A CN 109487550 A CN109487550 A CN 109487550A CN 201811252563 A CN201811252563 A CN 201811252563A CN 109487550 A CN109487550 A CN 109487550A
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- Prior art keywords
- cotton fiber
- cotton
- cool feeling
- mould proof
- cation
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- 229920000742 Cotton Polymers 0.000 title claims abstract description 178
- 238000002360 preparation method Methods 0.000 title claims description 20
- 239000000284 extract Substances 0.000 claims abstract description 39
- 241000411851 herbal medicine Species 0.000 claims abstract description 6
- 238000004321 preservation Methods 0.000 claims description 41
- 241000196324 Embryophyta Species 0.000 claims description 33
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
- 230000004048 modification Effects 0.000 claims description 30
- 238000012986 modification Methods 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 239000000835 fiber Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 20
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 20
- 239000006260 foam Substances 0.000 claims description 18
- 238000010792 warming Methods 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000002203 pretreatment Methods 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 10
- 125000002091 cationic group Chemical group 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 9
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 8
- 150000001768 cations Chemical class 0.000 claims description 8
- 229940105902 mint extract Drugs 0.000 claims description 8
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 8
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 8
- 239000003607 modifier Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- QCCKPZOPTXCJPL-UHFFFAOYSA-N dodecyl(dimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[NH+](C)C QCCKPZOPTXCJPL-UHFFFAOYSA-N 0.000 claims description 6
- 241000334160 Isatis Species 0.000 claims description 5
- 240000002853 Nelumbo nucifera Species 0.000 claims description 5
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims description 5
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims description 5
- 229960000583 acetic acid Drugs 0.000 claims description 5
- 238000009960 carding Methods 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 239000012362 glacial acetic acid Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000011534 incubation Methods 0.000 claims description 5
- 229920001661 Chitosan Polymers 0.000 claims description 4
- 239000001522 artemisia absinthium l. herb extract Substances 0.000 claims description 4
- 239000008234 soft water Substances 0.000 claims description 4
- 229940119569 wormwood extract Drugs 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 claims description 2
- 244000303040 Glycyrrhiza glabra Species 0.000 claims description 2
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 claims description 2
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 claims description 2
- 229920000289 Polyquaternium Polymers 0.000 claims description 2
- 235000008081 Rheum officinale Nutrition 0.000 claims description 2
- 240000001745 Rheum palmatum Species 0.000 claims description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 2
- 229940010454 licorice Drugs 0.000 claims description 2
- 150000001875 compounds Chemical group 0.000 claims 1
- 229940092665 tea leaf extract Drugs 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 18
- 239000004753 textile Substances 0.000 abstract description 16
- 238000001514 detection method Methods 0.000 abstract description 11
- 238000011156 evaluation Methods 0.000 abstract description 5
- 230000000855 fungicidal effect Effects 0.000 abstract description 3
- 239000011521 glass Substances 0.000 abstract description 3
- 241001468872 Fumagospora capnodioides Species 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 35
- 235000013311 vegetables Nutrition 0.000 description 12
- 229910010271 silicon carbide Inorganic materials 0.000 description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000004043 dyeing Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 210000003296 saliva Anatomy 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000011160 research Methods 0.000 description 5
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- 230000000052 comparative effect Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000000696 magnetic material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 230000036559 skin health Effects 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000001046 anti-mould Effects 0.000 description 2
- 239000002546 antimould Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000994 depressogenic effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000000774 hypoallergenic effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000004900 laundering Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 244000171897 Acacia nilotica subsp nilotica Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 241000221079 Euphorbia <genus> Species 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- 101001018064 Homo sapiens Lysosomal-trafficking regulator Proteins 0.000 description 1
- 244000018716 Impatiens biflora Species 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 102100033472 Lysosomal-trafficking regulator Human genes 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- 244000038561 Modiola caroliniana Species 0.000 description 1
- 235000010703 Modiola caroliniana Nutrition 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 241000095444 Populus davidiana Species 0.000 description 1
- 206010040830 Skin discomfort Diseases 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 235000020737 peppermint extract Nutrition 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 238000009970 yarn dyeing Methods 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Coloring (AREA)
Abstract
The present invention relates to a kind of mould proof cotton of efficient cool feeling, Extracts from Plant Recourses is contained in the book on Chinese herbal medicine cotton fiber, the dry of the book on Chinese herbal medicine cotton fiber is 3.0-3.5cN/dtex by force.Using pure-cotton fabric made of mould proof cotton of efficient cool feeling prepared by the present invention, by " detection and evaluation of GB ∕ T 35263-2017 textile Contact cool feeling performance " standard detection, touching moment cool feeling coefficient is > 0.58J/cm2.s.Mould proof cotton of efficient cool feeling prepared by the present invention, by " evaluation of GBT 24346-2009 textile fungicidal properties " standard detection, mould proof grade is 0 grade, i.e., without obvious mildew under magnifying glass, mould proof grade is highest.
Description
Technical field
The present invention relates to a kind of cotton fiber and preparation method thereof, especially a kind of mould proof cotton of efficient cool feeling and its preparation
Method belongs to field of textiles.
Background technique
Since cotton fiber is natural fiber, the uni-material fabric for imparting cotton fiber has comfortable, moisture absorption of wearing nature
Warming characteristic, therefore, pure cotton fiber is used to be spun into thermal protection coat, underwear etc. mostly in the prior art, but with society
The development of meeting, the simple function of pure cotton fabric, it is clear that be not able to satisfy people to the diversified demand of fabric, in particular with complete
Increasingly hotter trend is presented in summer in ball climate warming, China's most area, and therefore, inventing a kind of cool fiber is that have must
It wants, and cool fiber in the prior art is largely chemical fibre, for example terylene is also known as " really cool ", such as existing also
Some substances etc. with cool feeling characteristic are added in cellulose fibre, although making the fiber of preparation with the characteristic of cool feeling,
Also it has lost the intensity of fiber or causes certain pressure to environment.Simultaneously because Summer Indoor is hot, interior is due to length
Phase turns on the aircondition, and air humidity is larger, causes a large amount of mould to breed, because the invention is a kind of using natural cotton fiber as the cool feeling of matrix
Mould proof cotton fiber is necessary.
In addition, in the prior art, the dyeability of pure cotton fiber is poor, for example is easy fade (jeans etc.), especially
Pure cotton fiber dye using natural plant dye and is easier to fade.In general, natural plant dye is from plant
It is extracted in flower, leaf, stem, root and fruit, being compatible with the environment property is good, and biodegradable.In dyeing course, vegetable colour
Drug, fragrance absorbed together with pigment composition by fabric, make dyeing after fabric have special medicinal health-care function to human body.
China's appliable plant dyestuff is with a history of thousands of years, and far away from Paleolithic Upper Cave Man's period, people are contaminated with plant
Material dyes on the stone pearl of ornament.Up to the Ming Dynasty and the Qing Dynasty, preparation process and printing and dyeing are extracted in the plantation of dye yielding herb, dyestuff
Technology etc. is mature.
Vegetable colour is the primary dye of textile dyeing before in the middle of the 19th century.But vegetable colour dyeing needs mostly
Metal salt treatment is carried out to textile, dyeing course is complicated, and color fastness is not also high, large labor intensity, in addition, vegetable colour is also
Have the defects that seasonal dependence is strong, Britain chemist Perkin has successfully synthesized mauve for the first time within 1856, has started conjunction
At new era of dyestuff.Synthetic dyestuffs are compared with vegetable colour, and with its chromatography, complete, simple process, favorable reproducibility, color fastness are high
And the advantages that low in cost, it is able to worldwide generally use.But people's gorgeous color and just is brought in synthetic dyestuffs
While sharp, serious pollution also is caused to environment, in addition some intermediates that synthetic dyestuffs use are carcinogens, gives people
Class health brings huge hidden danger.
With the development of economic civilization, people increasingly focus on the life of quality, and environmental protection, health and Green Consciousness are fade-in
The popular feeling.The advantages that this makes vegetable colour again environmentally friendly with it, healthy and nuisanceless is paid close attention to by people again.Japanese special establishment
" vegetation dye " research institute, develops euphorbia dyestuff using modern science and technology；Huang Li company batch develops brown, green
With the vegetable colour of blue three colour systems, the other colors of dye are spelled again with the combination of these three colour systems；Big and dyer company releases " careless clothing dye
Color "；Xing Ran company releases " indigo stamp ".India successively develops david poplar bark and balsamine dyestuff, and with Folium Pruni yarn dyeing
Line, Babool skin dye nylon and tealeaves dyeing wool.At home, it has also put into there are many research institution to vegetable colour in recent years
Research.Such as Dalian Chemiclophysics Inst., Chinese Academy of Sciences, Beijing Institute of Clothing Tech and University Of Suzhou's unit have researcher from
The research of thing vegetable colour dyeing aspect.
By years of researches, the problem of China scientific and technical personnel have been resolved a part of vegetalitas color source.Meanwhile they are also
It was found that the plant that can be used for producing dyestuff is very universal.The vegetable colour production industry in China is in the starting stage at present, greatly
The scale of most enterprises is relatively small, and the market status that the enterprise of China's vegetable colour industry faces is as follows:
The market status of 1 China's vegetable colour industry of table
As seen in table 1, the main problem that the prior art faces is how to improve the color jail of plant dye fiber or fabric
Degree, especially color fastness to water, the color fastness of resistance to artificial light, color fastness to saliva, the technical problems such as wear no resistance.
In conclusion inventing a kind of by the mould proof herbal cotton fiber of the efficient cool feeling of matrix of natural cotton fiber is that the present invention wants
The technical issues of solution.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of mould proof cotton of efficient cool feeling and preparation method thereof, with reality
Existing following goal of the invention:
1, a kind of mould proof cotton of efficient cool feeling and preparation method thereof is invented, makes the cotton fiber of preparation that there is good cool feeling, anti-
Mould characteristic.
2, mould proof cotton color fastness of efficient cool feeling prepared by the present invention is higher.
3, mould proof cotton of efficient cool feeling prepared by the present invention, fungicidal properties are good.
4, find the cotton fiber production treatment process of suitable children's garment production, the compactness of the fiber of production and human skin compared with
It is good, after long-term dress, it is not easy to cause the feeling of skin discomfort, that is, produce it is a kind of with soft comfortable, antistatic, it is hypo-allergenic,
Good hygroscopicity is beneficial to human skin health and the superior fiber product of sanitation performance.
5, mould proof cotton wearability of efficient cool feeling prepared by the present invention is good.
6, mould proof cotton of efficient cool feeling prepared by the present invention has good hygroscopicity, does not generate scratchy feeling, resists
Bacterium performance is good, protects skin health.
In order to achieve the above-mentioned object of the invention, present invention provide the technical scheme that
A kind of mould proof cotton of efficient cool feeling contains Extracts from Plant Recourses in the book on Chinese herbal medicine cotton fiber, the book on Chinese herbal medicine cotton fiber
Dry be 3.0-3.5cN/dtex by force；The Extracts from Plant Recourses is mint extract and Lotus Leafextract, tea extract, smokes clothing
Careless extract, isatis root extract, wormwood extract, the one or more of Chinese rhubarb extract, licorice.
A kind of preparation method of mould proof cotton of efficient cool feeling, pre-treatment step, cotton fiber including cotton fiber sun from
Sub- modification procedure, the complex function modification procedure of cotton fiber.
The pre-treatment step of the cotton fiber includes:
1, the cotton fiber dress cage after cotton carding cleaning is put into dye vat, and sodium hydroxide solution is added and bath is made in natural agents
Liquid carries out isothermal holding；The bath foam bath raio is 1:15, is started the cycle over after then opening circulating pump, power of motor at least 20,000
Watt, the speed that bath foam is projected from cage core is in 20-22 meter per second；Bath temperature is to slowly warm up to according to 2-3 DEG C/min of speed
60-80 DEG C, heat preservation 30-50min is spare；The dry of cotton fiber after removal of impurities is 3.5-4.5 cN by force；
Further, the concentration of the sodium hydroxide solution is 4-6%；The natural agents are dodecyl dimethyl beet
Alkali；The additional amount of the dodecyldimethylammonium hydroxide inner salt is the 0.2-0.4% of the cotton fiber weight.
2, hydrogen peroxide is added after bath temperature being cooled to 20 ± 3 DEG C after step 1 heat preservation；The concentration of the hydrogen peroxide is
2-3g/L closes cylinder top cover, and turn on pump circulation is to slowly warm up to 95 ± 3 DEG C, increases pressure to 130-150kPa, keeps the temperature 90-120
After minute, the slow pressure release of relief valve is opened to standard atmospheric pressure.
3, cotton fiber is washed to neutrality after emptying bath foam.
In the pre-treatment step of above-mentioned cotton fiber, the addition of sodium hydroxide and surfactant makes the hemicellulose in cotton
The substances such as element, cotton wax, fructose remove, and the removing of impurity reduces the generation of phenomenon of photosensitivity, increases resistance to photochromic jail from side
Degree；More important is will appear microcosmic micron-sized gap after pretreatment in cotton fiber internal structure, hydrogen peroxide is in alkalinity
Under the conditions of handle cotton fiber, make the reduction degree of polymerization that cotton fiber is mild, reduce crystalline region, increase amorphous region, because of dyestuff or water
It can only enter the surface of amorphous region and crystalline region, such processing is next step Extracts from Plant Recourses dyestuff and nanometer silicon carbide
Into laying a good groundwork.
The cation-modified step of the cotton fiber includes:
1, cation-modified agent solution is configured
Cation modifier powder is dissolved in deionized water, and cationic solution is made；
The concentration of the cationic solution is 3.5%, is warming up to 80-95 DEG C of temperature, then adjusts pH with 0.5%-1% glacial acetic acid
Value 5-8, is stirred continuously, keep the temperature 60-80min, after cation-modified liquid is obtained by filtration；
Preferably, the cation modifier powder be water soluble chitosan, quaternary ammonium salt, polyquaternium it is one or more.
2, cation-modified
Manufactured cation-modified liquid and cotton fiber to be modified are added in dye vat, are first warming up to 35 ± 3 DEG C, keeps the temperature 20-
25 minutes；It then proceedes to be warming up to 95 ± 3 DEG C, takes out washing after heat preservation 25-30 minutes；
The dosage of the modification liquid is 0.4-0.6 times of cotton fiber weight, the bath of cotton fiber and cation-modified liquid in the dye vat
Compare 1:20；
By the cation-modified technological operation to cotton fiber, make cotton fiber with positive charge, it is negatively charged to adsorb in next step
Sodium carboxymethylcellulose, plant extracts slurries and nanometer silicon carbide precondition is provided.
The complex function modification procedure of the cotton fiber, specifically includes as follows:
1, complex function modifying agent configures
Extracts from Plant Recourses is added in 45-50 DEG C of softened water according to the 3-8% of cotton fiber weight, it is rear that carboxymethyl fibre is added
Plain sodium and nano silicon carbide powder are tieed up, stirring is filtered spare after 30-40 minutes；
The additional amount of the sodium carboxymethylcellulose is the 1.2-1.5% of cotton fiber weight；
The additional amount of the nano silicon carbide powder is the 2-4% of cotton fiber weight.
2, heat preservation is modified
By the complex function modifying agent of above-mentioned configuration, it is cation-modified after cotton fiber be added in dye vat, bath raio 1:12-15,
Turn on pump circulation, carries out heat preservation modification；The speed control that bath foam is projected from cage core is in 30-40 meter per second；
Preferably, the heat preservation modification procedure includes the heating of three phases, incubation step；
The first stage is to slowly warm up to 50 ± 3 DEG C, keeps the temperature 20 minutes；The second stage is to slowly warm up to 80 ± 3 DEG C, protects
Temperature 30 minutes；The phase III is to slowly warm up to 99 ± 3 DEG C, after covering cylinder cap, boosts to 150-170kPa, and heat preservation 2-4 is small
When；After the completion of heat preservation is modified, after being first slowly depressurized to standard atmospheric pressure, with the rapid washing cooling of 20 ± 3 DEG C of soft water.
3, it soaps
Fiber after heat preservation modification is placed in the 50-60 DEG C of liquid of soaping of 3-5g/L and is washed 10-15 minutes, is taken out, washing,
It is dry.
Preferably, the partial size of the nanometer silicon carbide is 100-200 nanometers, and dioxide-containing silica >=98.5%, iron oxide contains
Amount≤0.5%, magnetic material content≤0.1%, density 3.3-3.5g/cm3。
The thermal coefficient of silicon carbide is up to 400, similar with metallic copper, be added to it is thermally conductive fast after cotton fiber, silicon carbide plus
The wearability and colour fastness to rubbing for entering to increase cotton fiber improve the contact cool feeling performance of fiber.
Basic principle of the invention is:
Silicon carbide and Extracts from Plant Recourses are especially passed through any one of mint extract and other plant source extract
Technique of the invention is embedded into the cavity of the interior skin of cotton fiber, and is more than and is infected on the surface of fiber, uses in this way
Contact cool feeling, the functional persistence of technical solution treated cotton fiber be all significantly improved.
When cotton fiber passes through pre-treatment step, more small spaces in the microstructure of cotton fiber；By cation-modified
After had positive charge；Then modified by the complex function of cotton fiber, negative electrical charge is had, the excellent of technical solution is then passed through
Change, nanometer silicon carbide and Extracts from Plant Recourses are fixed, the spilling of functional components is avoided.By above process, make
The color fastness of cotton fiber, wearability have large increase, also improve cool feeling, the mould proof characteristic of fiber to greatest extent.In addition,
The content of functional component is successively reduced from outside to inside, will not influence the physical indexs such as the strength of fiber.
By adopting the above-described technical solution, having the technical effect that of reaching of the present invention
1, using pure-cotton fabric made of mould proof cotton of efficient cool feeling prepared by the present invention, pass through " GB ∕ T 35263-2017
The detection and evaluation of textile Contact cool feeling performance " standard detection, touching moment cool feeling coefficient is > 0.58J/cm2.s。
2, mould proof cotton of efficient cool feeling prepared by the present invention, belongs to cellulose Ⅱ type, Thermodynamically stable, Gan Qiangwei 3.0-
3.5cN/dtex；
Using the pure-cotton fabric of efficient mould proof cotton of cool feeling preparation prepared by the present invention, soft comfortable, antistatic, it is hypo-allergenic,
Good hygroscopicity, sanitation performance are superior, protection human skin health.
3, mould proof cotton of efficient cool feeling prepared by the present invention, passes through " GBT 24346-2009 textile fungicidal properties
Evaluation " standard detection, mould proof grade is 0 grade, i.e., without obvious mildew under magnifying glass, mould proof grade is highest.
4, mould proof cotton of efficient cool feeling prepared by the present invention, wearability is good, and when fracture is subjected to the number of friction: under dry state
It is 1600-1620 times, is 1800-1950 times under hygrometric state.
5, using pure-cotton fabric made of mould proof cotton of efficient cool feeling prepared by the present invention, pass through " GB/T 3920-
The test of 2008 textile color stabilities " standard detection, colour fastness to rubbing > 4-5 grades.
6, using pure-cotton fabric made of mould proof cotton of efficient cool feeling prepared by the present invention, pass through " GB/T8427-2008
Textile color stability tests the color fastness of resistance to artificial light " detection, color fastness to light > 4 grade.
7, using pure-cotton fabric made of mould proof cotton of efficient cool feeling prepared by the present invention, pass through " GB/T 18886-
2002 textile color stabilities test color fastness to saliva " standard detection, color fastness to saliva > 4-5 grades.
8, using pure-cotton fabric made of mould proof cotton of efficient cool feeling prepared by the present invention, pass through " textile color stability
Test resistance to family and commercial laundering color fastness " standard detection, fastness to soaping > 4 grade.
9, " FZ/T73023-2006 is met using pure-cotton fabric made of mould proof cotton of efficient cool feeling prepared by the present invention
Antibacterial fabric " 3A grades of antibacterial standards of standard.
10, mould proof cotton hygroscopicity of efficient cool feeling prepared by the present invention is preferable, inhales in the atmosphere that relative humidity is 65%
Moist is 16-18%.
Specific embodiment
A kind of preparation method of efficient mould proof cotton of cool feeling of embodiment 1, specifically includes the following steps:
One, the pre-treatment step of cotton fiber:
1, the cotton fiber dress cage after cotton carding cleaning is put into dye vat, and sodium hydroxide solution is added and bath is made in natural agents
Liquid；Bath foam bath raio is 1:15, is started the cycle over after then opening circulating pump, 25 kilowatts of power of motor, the speed that bath foam is projected from cage core
Degree is in 20 meter per seconds；Bath temperature is to slowly warm up to 65 DEG C according to 2 DEG C/min of speed, heat preservation 50min is spare；
The concentration of sodium hydroxide solution is 4%；Natural agents are dodecyldimethylammonium hydroxide inner salt；The dimethyl
The additional amount of base glycine betaine is the 0.3% of cotton fiber weight.
2, hydrogen peroxide is added after bath temperature being cooled to 20 DEG C after step 1 heat preservation；The concentration of hydrogen peroxide is 2g/L, is closed
Cylinder top cover, turn on pump circulation, is to slowly warm up to 96 DEG C, increases pressure to 145kPa, after heat preservation 90 minutes, opens relief valve and slowly let out
It is depressed into standard atmospheric pressure.
3, cotton fiber is washed to neutrality after emptying bath foam.
Two, the cation-modified step of cotton fiber:
1, cation-modified agent solution is configured
Cation modifier powder water soluble chitosan is dissolved in deionized water, cationic solution is made；Cationic solution
Concentration is 3.5%, is warming up to 80 DEG C of temperature, then adjusts pH value 5 with 0.5% glacial acetic acid, is stirred continuously, and keeps the temperature 60min, rear mistake
Filter obtains cation-modified liquid.
2, cation-modified
Manufactured cation-modified liquid and cotton fiber to be modified are added in dye vat, are first warming up to 35 DEG C, keeps the temperature 20 minutes；
It then proceedes to be warming up to 96 DEG C, takes out washing after heat preservation 25 minutes；
The dosage of modification liquid is 0.4 times of cotton fiber weight, the bath raio 1:20 of cotton fiber and cation-modified liquid in dye vat.
Three, the complex function modification procedure of cotton fiber:
1, complex function modifying agent configures
Extracts from Plant Recourses is added in 45 DEG C of softened water according to the 3% of cotton fiber weight, sodium carboxymethylcellulose is added afterwards
And nano silicon carbide powder, stirring are filtered spare after 30 minutes；
The Extracts from Plant Recourses is the mixture of mint extract and Lotus Leafextract；In the Extracts from Plant Recourses, peppermint
The mass ratio of extract and Lotus Leafextract is 2:1；
The additional amount of the sodium carboxymethylcellulose is the 1.2% of cotton fiber weight；
The additional amount of the nano silicon carbide powder is the 2% of cotton fiber weight；
The partial size of nanometer silicon carbide is 100 nanometers, dioxide-containing silica >=98.5%, iron oxide content≤0.5%, magnetic material content
≤ 0.1%, density 3.3-3.5g/cm3。
2, heat preservation is modified
By the complex function modifying agent of above-mentioned configuration, it is cation-modified after cotton fiber be added in dye vat, bath raio 1:12, turn on pump
Circulation, carries out heat preservation modification；The speed control that bath foam is projected from cage core is in 30 meter per seconds；
Keeping the temperature modification procedure includes the heating of three phases, incubation step；First stage is to slowly warm up to 50 DEG C, keeps the temperature 20 points
Clock；The second stage is to slowly warm up to 80 DEG C, keeps the temperature 30 minutes；The phase III is to slowly warm up to 99 DEG C, covers cylinder cap
Afterwards, 150kPa is boosted to, keeps the temperature 4 hours；It is soft with 20 DEG C after being first slowly depressurized to standard atmospheric pressure after the completion of heat preservation is modified
The rapid washing cooling of water.
3, it soaps
Fiber after heat preservation modification is placed in 60 DEG C of liquid of soaping of 3g/L and is washed 10 minutes, is taken out, is washed, it is dry.
A kind of preparation method of efficient mould proof cotton of cool feeling of embodiment 2, specifically includes the following steps:
One, the pre-treatment step of cotton fiber:
1, the cotton fiber dress cage after cotton carding cleaning is put into dye vat, and sodium hydroxide solution is added and bath is made in natural agents
Liquid；Bath foam bath raio is 1:15, is started the cycle over after then opening circulating pump, 25 kilowatts of power of motor, the speed that bath foam is projected from cage core
Degree is in 21 meter per seconds；Bath temperature is to slowly warm up to 60 DEG C according to 2 DEG C/min of speed, heat preservation 30min is spare；
The concentration of sodium hydroxide solution is 5%；Natural agents are dodecyldimethylammonium hydroxide inner salt；The dimethyl
The additional amount of base glycine betaine is the 0.3% of the cotton fiber weight.
2, hydrogen peroxide is added after the bath temperature after step 1 heat preservation being cooled to 18 DEG C；The concentration of hydrogen peroxide is 3g/L, is closed
Cylinder top cover is closed, turn on pump circulation is to slowly warm up to 94 DEG C, increases pressure to 130kPa and it is slow to open relief valve after heat preservation 100 minutes
Slow pressure release is to standard atmospheric pressure.
3, cotton fiber is washed to neutrality after emptying bath foam.
Two, the cation-modified step of cotton fiber:
1, cation-modified agent solution is configured
Cation modifier powder quaternary ammonium salt is dissolved in deionized water, cationic solution is made；The concentration of cationic solution is
3.5%, be warming up to 95 DEG C of temperature, then with 1% glacial acetic acid adjust pH value 6, be stirred continuously, keep the temperature 75min, after sun is obtained by filtration
Ion modification liquid；
2, cation-modified
Manufactured cation-modified liquid and cotton fiber to be modified are added in dye vat, are first warming up to 33 DEG C, keeps the temperature 25 minutes；
It then proceedes to be warming up to 93 DEG C, takes out washing after heat preservation 25 minutes；
The dosage of modification liquid is 0.5 times of cotton fiber weight, the bath raio 1:20 of cotton fiber and cation-modified liquid in dye vat.
Three, the complex function modification procedure of cotton fiber:
1, complex function modifying agent configures
By Extracts from Plant Recourses, it is added in 48 DEG C of softened water according to the 6% of cotton fiber weight, carboxymethyl cellulose is added afterwards
Sodium and nano silicon carbide powder, stirring are filtered spare after 30 minutes；The additional amount of sodium carboxymethylcellulose is cotton fiber weight
1.2%；The additional amount of nano silicon carbide powder is the 2% of cotton fiber weight；
The Extracts from Plant Recourses is the mixture of mint extract and isatis root extract；It is thin in the Extracts from Plant Recourses
The mass ratio of lotus extract and isatis root extract is 2:1；
The partial size of nanometer silicon carbide is 150-170 nanometers, dioxide-containing silica >=98.5%, iron oxide content≤0.5%, magnetic material
Content≤0.1%, density 3.3-3.5g/cm3。
2, heat preservation is modified
By the complex function modifying agent of configuration, it is cation-modified after cotton fiber be added in dye vat, bath raio 1:14, turn on pump follows
Ring carries out heat preservation modification；The speed control that bath foam is projected from cage core is in 35 meter per seconds；
Heat preservation modification procedure specifically includes the heating of three phases, incubation step；
First stage is to slowly warm up to 51 DEG C, keeps the temperature 20 minutes；Second stage is to slowly warm up to 82 DEG C, keeps the temperature 30 minutes；Third
Stage is to slowly warm up to 98 DEG C, after covering cylinder cap, boosts to 160kPa, keeps the temperature 3 hours；After the completion of heat preservation is modified, first slowly drop
After being depressed into standard atmospheric pressure, with the rapid washing cooling of 20 DEG C of soft water.
3, it soaps
Fiber after heat preservation modification is placed in 50 DEG C of liquid of soaping of 4g/L and is washed 12 minutes, is taken out, is washed, it is dry.
A kind of preparation method of efficient mould proof cotton of cool feeling of embodiment 3, specifically includes the following steps:
One, the pre-treatment step of cotton fiber:
1, the cotton fiber dress cage after cotton carding cleaning is put into dye vat, and sodium hydroxide solution is added and bath is made in natural agents
Liquid；Bath foam bath raio is 1:15, is started the cycle over after then opening circulating pump, 30 kilowatts of power of motor, the speed that bath foam is projected from cage core
Degree is in 22 meter per seconds；Bath temperature is to slowly warm up to 70 DEG C according to 3 DEG C/min of speed, heat preservation 45min is spare；
The concentration of sodium hydroxide solution is 6%；Natural agents are dodecyldimethylammonium hydroxide inner salt；The dimethyl
The additional amount of base glycine betaine is the 0.4% of cotton fiber weight.
2, hydrogen peroxide is added after the bath temperature after step 1 heat preservation being cooled to 23 DEG C；The concentration of hydrogen peroxide is 3g/L, is closed
Cylinder top cover is closed, turn on pump circulation is to slowly warm up to 97 DEG C, increases pressure to 150kPa and it is slow to open relief valve after heat preservation 90 minutes
Pressure release is to standard atmospheric pressure.
3, cotton fiber is washed to neutrality after emptying bath foam.
Two, the cation-modified step of cotton fiber:
1, cation-modified agent solution is configured
Cation modifier powder water soluble chitosan is dissolved in deionized water, and cationic solution is made；Cationic solution it is dense
Degree is 3.5%, is warming up to 95 DEG C of temperature, then adjusts pH value 5 with 0.5% glacial acetic acid, is stirred continuously, and keeps the temperature 80min, rear to filter
Obtain cation-modified liquid；
2, cation-modified
Manufactured cation-modified liquid and cotton fiber to be modified are added in dye vat, are first warming up to 38 DEG C, keeps the temperature 20 minutes；
It then proceedes to be warming up to 95 DEG C, takes out washing after heat preservation 30 minutes；
The dosage of modification liquid is 0.6 times of cotton fiber weight, the bath raio 1:20 of cotton fiber and cation-modified liquid in dye vat.
Three, the complex function modification procedure of cotton fiber:
1, complex function modifying agent configures
Extracts from Plant Recourses is added in 50 DEG C of softened water according to the 8% of cotton fiber weight, sodium carboxymethylcellulose is added afterwards
And nano silicon carbide powder, stirring are filtered spare after 30-40 minutes；
The Extracts from Plant Recourses is the mixture of mint extract and wormwood extract；In the Extracts from Plant Recourses, peppermint
Extract and the mass ratio of wormwood extract are 2:1；
The additional amount of sodium carboxymethylcellulose is the 1.5% of cotton fiber weight；
The additional amount of nano silicon carbide powder is the 4% of cotton fiber weight；
The partial size of nanometer silicon carbide is 100-200 nanometers, dioxide-containing silica >=98.5%, iron oxide content≤0.5%, magnetic material
Content≤0.1%, density 3.3-3.5g/cm3。
2, heat preservation is modified
By the complex function modifying agent of above-mentioned configuration, it is cation-modified after cotton fiber be added in dye vat, bath raio 1:15 is opened
Pump circulation carries out heat preservation modification；The speed control that bath foam is projected from cage core is in 40 meter per seconds；
Heat preservation modification procedure specifically includes the heating of three phases, incubation step；
First stage is to slowly warm up to 53 DEG C, keeps the temperature 20 minutes；The second stage is to slowly warm up to 83 DEG C, keeps the temperature 30 minutes；
The phase III is to slowly warm up to 102 DEG C, after covering cylinder cap, boosts to 170kPa, keeps the temperature 4 hours；After the completion of heat preservation is modified,
After being first slowly depressurized to standard atmospheric pressure, with the rapid washing cooling of 23 DEG C of soft water.
3, it soaps
Fiber after heat preservation modification is placed in 60 DEG C of liquid of soaping of 5g/L and is washed 15 minutes, is taken out, is washed, it is dry.
Mould proof cotton of efficient cool feeling prepared by the present invention has suitable intensity, the functionality such as good contact cool feeling
With preferable practical performance, it is particularly suitable for the production of children's garment, specific Testing index is shown in Table 2
Table 2
As can be seen from Table 2, mould proof cotton of efficient cool feeling prepared by the present invention, Gan Qiangwei 3.0-3.5cN/dtex；
Under regular situation, cotton fiber contains more cellulose, is conducive to the growth of mould, by mildew after, cotton fiber it is strong
Power is by large effect；Mould proof cotton of efficient cool feeling prepared by the present invention, by the way that " GBT 24346-2009 textile is anti-
The evaluation of mouldiness energy " standard detection, mould proof grade is 0 grade, without obvious mildew under magnifying glass；
Mould proof cotton wearability of efficient cool feeling prepared by the present invention is good, and when fracture is subjected to the number of friction: being 1600- under dry state
1620 times, be 1800-1950 times under hygrometric state.
Using the pure-cotton fabric of efficient mould proof cotton of cool feeling preparation prepared by the present invention, soft comfortable, antistatic, anti-mistake
Quick, good hygroscopicity, sanitation performance are superior, protection human skin health.
Mould proof cotton of efficient cool feeling prepared by the present invention has good color fastness using fabric made of it, specifically
Testing index is shown in Table 3
Table 3
As can be seen from Table 3, mould proof cotton of efficient cool feeling prepared by the present invention has good color fastness, wherein rub resistance
Color fastness > 4-5 grades, color fastness to light > 4 grade, color fastness to saliva > 4-5 grades, fastness to soaping > 4 grade.
Examination criteria are as follows:
Colour fastness to rubbing: " test of GB/T 3920-2008 textile color stability "；
Color fastness to light: " GB/T8427-2008 textile color stability tests the color fastness of resistance to artificial light "；
Color fastness to saliva: " GB/T 18886-2002 textile color stability tests color fastness to saliva "；
Fastness to soaping: " GB/T 12490-2014 textile color stability tests resistance to family and commercial laundering color fastness "；
In addition to this, applicant is allowed unexpectedly to use pure made of the mould proof herbal cotton spinning of efficient cool feeling prepared by the present invention
Cotton face fabric, anti-microbial property are 3A grades.
By table 2-3 it is found that on the whole, comprehensive physical intensity index, anti-microbial property, color fastness etc. comprehensively consider,
Embodiment 2 is highly preferred embodiment of the present invention.
In the preparation method of the efficient mould proof cotton of cool feeling of plant of the invention, the pre-treatment step of cotton fiber is to preparation
The color fastness of efficient mould proof cotton of cool feeling has important influence, in order to further illustrate the necessity of the technical solution,
Inventor has carried out following comparative testing.
Comparative example 1,2,3 respectively with it is almost the same with technical solution used by embodiment 1,2,3, difference only exist
In: the pre-treatment step of cotton fiber is omitted, other are implemented technical solution and remain unchanged.
The fastness properties index of mould proof cotton of efficient cool feeling prepared by comparative example 1 is specifically shown in Table 4
Table 4
As can be seen from Table 4, after the pre-treatment step of comparative example 1-3 omission cotton fiber, color fastness decreases drastically, special
Be not colour fastness to rubbing, color fastness to saliva, fastness to soaping decline it is the most obvious, color fastness to light has a degree of
Decline.
Embodiment 4
Used Extracts from Plant Recourses is more in process of production in the present invention, in order to further find out opposite comprehensive performance ratio
Advantageous kinds of fibers, the method for using embodiment 2 below, in the case where the amount of the Extracts from Plant Recourses of addition is constant,
Only change the addition type of Extracts from Plant Recourses, then analysis, more all kinds of Extracts from Plant Recourses are being added to preparation of the present invention
After during fiber, influence to the mould proof cotton of efficient cool feeling of preparation, and find out optimal technical solution or technology
The combination of scheme, specific test result are shown in Table 5.(it should be noted that the citing of exhaustive is tested since experimental condition is limited
Obviously it is not possible that, therefore, test below is the explanation of some examples formula)
Table 5
By table 5 it may be concluded that when selecting Extracts from Plant Recourses for mint extract and isatis root extract, system of the present invention
Standby mould proof cotton of efficient cool feeling has best fastness properties.
When selecting Extracts from Plant Recourses for mint extract, Herba Pileae Scriptae extract, efficient cool feeling prepared by the present invention is anti-
Mould cotton has best cool feeling characteristic.
Unless otherwise indicated, percentage employed in the present invention is weight percent, ratio of the present invention,
For mass ratio.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (9)
1. a kind of mould proof cotton of efficient cool feeling, it is characterised in that: contain Extracts from Plant Recourses in the book on Chinese herbal medicine cotton fiber, it is described
The dry of herbal cotton fiber is 3.0-3.5cN/dtex by force；The Extracts from Plant Recourses is mint extract and Lotus Leafextract, tea
Leaf extract, Herba Lysimachiae foenumgraeci extract, isatis root extract, wormwood extract, one kind or several of Chinese rhubarb extract, licorice
Kind.
2. a kind of mould proof cotton of efficient cool feeling according to claim 1, it is characterised in that: the system of the book on Chinese herbal medicine cotton fiber
Preparation Method includes the pre-treatment step of cotton fiber, the cation-modified step of cotton fiber, the complex function modification procedure of cotton fiber；
The pre-treatment step of the cotton fiber includes:
(1) the cotton fiber dress cage after cotton carding cleaning is put into dye vat, and sodium hydroxide solution is added and bath is made in natural agents
Liquid carries out isothermal holding；The bath foam bath raio is 1:15；Bath temperature is to slowly warm up to according to 2-3 DEG C/min of speed
60-80 DEG C, keep the temperature 30-50min；
(2) bath temperature after step 1 heat preservation is cooled to 20 ± 3 DEG C, it is rear that the hydrogen peroxide that concentration is 2-3g/L is added, slowly rise
Temperature increases pressure to 130-150kPa, keeps the temperature 90-120 minutes to 95 ± 3 DEG C.
3. a kind of mould proof cotton of efficient cool feeling according to claim 2, it is characterised in that: the sodium hydroxide solution
Concentration is 4-6%；The natural agents are dodecyldimethylammonium hydroxide inner salt；The dodecyldimethylammonium hydroxide inner salt adds
Enter the 0.2-0.4% that amount is the cotton fiber weight.
4. a kind of mould proof cotton of efficient cool feeling according to claim 2, it is characterised in that: the cation of the cotton fiber
Modification procedure includes:
(1) cation-modified agent solution is configured
Cation modifier powder is dissolved in deionized water, cationic solution is made；The concentration of the cationic solution is
3.5%, it is warming up to 80-95 DEG C of temperature, then pH value 5-8 is adjusted with 0.5%-1% glacial acetic acid, is stirred continuously, keeps the temperature 60-80min,
After cation-modified liquid is obtained by filtration；
(2) cation-modified
Manufactured cation-modified liquid and cotton fiber to be modified are added in dye vat, are first warming up to 35 ± 3 DEG C, keeps the temperature 20-
25 minutes；It then proceedes to be warming up to 95 ± 3 DEG C, takes out washing after heat preservation 25-30 minutes；
The dosage of the modification liquid is 0.4-0.6 times of cotton fiber weight, the bath of cotton fiber and cation-modified liquid in the dye vat
Compare 1:20.
5. a kind of mould proof cotton of efficient cool feeling according to claim 4, it is characterised in that: the cation modifier powder
End be water soluble chitosan, quaternary ammonium salt, polyquaternium it is one or more.
6. a kind of mould proof cotton of efficient cool feeling according to claim 2, it is characterised in that: the compound function of the cotton fiber
Energy modification procedure, specifically includes as follows:
(1) complex function modifying agent configures
Extracts from Plant Recourses is added in 45-50 DEG C of softened water according to the 3-8% of cotton fiber weight, it is rear that carboxymethyl fibre is added
Plain sodium and nano silicon carbide powder are tieed up, is stirred 30-40 minutes；
(2) heat preservation is modified
By the complex function modifying agent of configuration, it is cation-modified after cotton fiber be added in dye vat, bath raio 1:12-15, turn on pump
Circulation, carries out heat preservation modification；The speed control that bath foam is projected from cage core is in 30-40 meter per second.
7. a kind of mould proof cotton of efficient cool feeling according to claim 6, it is characterised in that: the sodium carboxymethylcellulose
Additional amount be cotton fiber weight 1.2-1.5%.
8. a kind of mould proof cotton of efficient cool feeling according to claim 6, it is characterised in that: the nano silicon carbide powder
Additional amount be cotton fiber weight 2-4%.
9. a kind of mould proof cotton of efficient cool feeling according to claim 6, it is characterised in that: the heat preservation modification procedure packet
Include heating, the incubation step of three phases；Wherein the first stage is to slowly warm up to 50 ± 3 DEG C, keeps the temperature 20 minutes；Second stage is slow
Slowly 80 ± 3 DEG C are warming up to, keeps the temperature 30 minutes；Phase III is to slowly warm up to 99 ± 3 DEG C, after covering cylinder cap, boosts to 150-
170kPa keeps the temperature 2-4 hours；After the completion of heat preservation is modified, after being first slowly depressurized to standard atmospheric pressure, the soft water with 20 ± 3 DEG C is cold
But.
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| CN111118717A (en) * | 2019-12-31 | 2020-05-08 | 江苏东源纺织科技实业有限公司 | Production process of natural antibacterial skin-friendly environment-friendly knitted fabric |
| CN111300920A (en) * | 2020-03-30 | 2020-06-19 | 泉州梵兜服装有限公司 | Wormwood modified fiber fabric |
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