CN101914306B - Method for preparing photinia fruit natural dye and application of photinia fruit natural dye - Google Patents
Method for preparing photinia fruit natural dye and application of photinia fruit natural dye Download PDFInfo
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- CN101914306B CN101914306B CN 201010257861 CN201010257861A CN101914306B CN 101914306 B CN101914306 B CN 101914306B CN 201010257861 CN201010257861 CN 201010257861 CN 201010257861 A CN201010257861 A CN 201010257861A CN 101914306 B CN101914306 B CN 101914306B
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- 229930182559 Natural dye Natural products 0.000 title abstract 7
- 239000000978 natural dye Substances 0.000 title abstract 7
- 239000000975 dye Substances 0.000 claims abstract description 95
- 239000004744 fabric Substances 0.000 claims abstract description 35
- 238000004043 dyeing Methods 0.000 claims abstract description 28
- 238000005406 washing Methods 0.000 claims abstract description 16
- 239000000284 extract Substances 0.000 claims abstract description 9
- 238000000605 extraction Methods 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 238000010992 reflux Methods 0.000 claims abstract description 5
- 238000001914 filtration Methods 0.000 claims abstract description 3
- 241001163113 Photinia glabra Species 0.000 claims description 47
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 8
- 210000002268 wool Anatomy 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 6
- 239000011790 ferrous sulphate Substances 0.000 claims description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 6
- ATINCSYRHURBSP-UHFFFAOYSA-K neodymium(iii) chloride Chemical compound Cl[Nd](Cl)Cl ATINCSYRHURBSP-UHFFFAOYSA-K 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 5
- 235000021022 fresh fruits Nutrition 0.000 claims description 5
- 239000004753 textile Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 4
- OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 claims description 4
- 229910000333 cerium(III) sulfate Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 4
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 4
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 4
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 3
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- 239000000243 solution Substances 0.000 abstract description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 5
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- 102000004169 proteins and genes Human genes 0.000 abstract description 4
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- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- WCGUUGGRBIKTOS-GPOJBZKASA-N (3beta)-3-hydroxyurs-12-en-28-oic acid Chemical compound C1C[C@H](O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C(O)=O)CC[C@@H](C)[C@H](C)[C@H]5C4=CC[C@@H]3[C@]21C WCGUUGGRBIKTOS-GPOJBZKASA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
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- STECJAGHUSJQJN-UHFFFAOYSA-N N-Methyl-scopolamin Natural products C1C(C2C3O2)N(C)C3CC1OC(=O)C(CO)C1=CC=CC=C1 STECJAGHUSJQJN-UHFFFAOYSA-N 0.000 description 1
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- 239000010957 pewter Substances 0.000 description 1
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- STECJAGHUSJQJN-FWXGHANASA-N scopolamine Chemical compound C1([C@@H](CO)C(=O)O[C@H]2C[C@@H]3N([C@H](C2)[C@@H]2[C@H]3O2)C)=CC=CC=C1 STECJAGHUSJQJN-FWXGHANASA-N 0.000 description 1
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Abstract
The invention relates to the field of natural dyes and application thereof and aims to provide a method for preparing a photinia fruit natural dye and application of the photinia fruit natural dye. The preparation method comprises the following steps of: (1) washing and airing fresh photinia fruits and dried photinia fruits, and mechanically crushing the fruits; and (2) adding the crushed photinia fruits into aqueous solution of ethanol for reflux extraction, raising the temperature of the extract to between 70 and 90 DEG C, keeping the temperature, filtering and distilling under reduced pressure to make the volume of concentrated solution 1/6 to 1/2 of the original volume of the extract so as to obtain the concentrated photinia fruit natural dye. The method for preparing the photinia fruit natural dye has the advantages of simple extraction technology, extraction efficiency obviously higher than that of ethanol reflux and other methods, and no environmental pollution in the extraction process; and the extract has the advantages of good color fastness to protein fibers, capacity of increasing color spectrum after dyeing by using environment-friendly dye mordant treatment, gentle color and safe wear of the dyed fabrics without carcinogenic, teratogenetic actions or anaphylactic reaction, high ecological environment compatibility, biodegradation, low price, full utilization of natural resources and wide market prospect.
Description
Technical field
The present invention relates to natural dyestuff and Application Areas thereof, particularly relate to a kind of preparation method and application thereof of Chinese photinia fruit natural dyestuff.
Background technology
Chinese photinia is Rosaceae Photinia plant, evergreen shrubs, have another name called thousand red.Be distributed in Central-South and the areas such as Jiangsu, Anhui, Zhejiang, Jiangxi, Taiwan, Sichuan and Guizhou.Chinese photinia is good ornamental plants in garden, is widely used at present urban afforestation, and it has stronger resistance to sulfurous gas, chlorine, and the sound insulation function is arranged.Contained ursolic acid has significantly stable and cooling effect in the leaf of chinese photinia, and analgesia, anti-inflammatory and antitumous effect are arranged, and gram-positive microorganism, negative bacterium and yeast are had restraining effect; But its root, branch hyoscine have the effect of promoting circulation of blood hemostasis, pain relieving, are used for the treatment of jaundice, acute mastitis, toothache.But the Chinese photinia fruit is red gorgeous people especially, and achieve great success autumn, but except having ornamental value, at present there are no research report, that abandons is very unfortunate, and correlative study both at home and abroad is still blank out.And study about preparation method and the dyeing on protein, cellulosic fibre thereof of Chinese photinia fruit natural dyestuff, both at home and abroad there are no report.
Summary of the invention
The technical problem to be solved in the present invention is, fills up the blank of prior art, and a kind of new purposes of Chinese photinia fruit is provided, and turns waste into wealth, and namely extracts natural dyestuff from red Chinese photinia fruit, and is applied to textile dyeing.
Show after deliberation, the Chinese photinia fruit extract is bright-coloured sorrel, and its maximum absorption wavelength is about 490～500nm.Protein fibre or fabric are had good dyeing behavior, process to obtain distinct colors by different mordants, and colour fastness is good, is the natural plant dye of an excellent property.
Be the technical solution problem, the invention provides a kind of preparation method of Chinese photinia fruit natural dyestuff, may further comprise the steps:
(1) Chinese photinia fresh fruit or dry fruit are cleaned, dried, mechanical disintegration;
(2) Chinese photinia fruit crushed material is joined refluxing extraction in the aqueous ethanolic solution of pH value 8～10; Extracting solution is warming up to 70～90 ℃, insulation 1～2h; It is 1/6～1/2 of extracting solution original volume that filtration and underpressure distillation make the concentrated solution volume, the Chinese photinia fruit natural dyestuff that obtains concentrating;
The concentration of volume percent of described aqueous ethanolic solution is 10～50%, and the mass ratio of Chinese photinia fruit crushed material and aqueous ethanolic solution is 1: 10～30.
Among the present invention, the pH value of described aqueous ethanolic solution is to add an amount of sodium bicarbonate, yellow soda ash or sodium phosphate to regulate.
The present invention further provides and a kind ofly utilized aforementioned Chinese photinia fruit natural dyestuff to the method for textile dyeing, may further comprise the steps:
(1) real silk or wool fabric are carried out pre-mordant dyeing processing, control condition is during processing: mordant weight is 1～5% of pollutant weight, and bath raio is 1: 10～50, and temperature is 60～80 ℃, and the time is 30～45min; The taking-up fabric that is disposed is cleaned, and extracts;
(2) be configured to dye liquor with concentrated Chinese photinia fruit natural dyestuff and water, wherein concentrated dyestuff accounts for 5～25% of whole dye liquor quality, and regulates dye liquor pH value 4～6;
(3) fabric of the pre-mordant dyeing of above-mentioned warp being processed immerses in the Chinese photinia fruit dye liquor and dyes, and control condition is during dyeing: the ratio 1: 10～50 of pollutant weight and dye liquor volume, 80～100 ℃ of temperature, time 45～80min; Dye complete, the washing, the oven dry;
Described mordant is one or more in ferric sulfate, iron(ic) chloride, ferrous sulfate, iron protochloride, aluminum chloride, Tai-Ace S 150, potassium aluminium sulfate or cerous sulfate, the Neodymium trichloride.
Adaptably, the present invention also provides a kind of and has utilized aforementioned Chinese photinia fruit natural dyestuff to the method for textile dyeing, may further comprise the steps:
(1) be configured to dye liquor with concentrated Chinese photinia fruit natural dyestuff and water, wherein concentrated dyestuff accounts for 5～25% of whole dye liquor quality, and regulates dye liquor pH value 4～6;
(2) will real silk or wool fabric immerse in the Chinese photinia fruit dye liquor and dye, control condition is during dyeing: the ratio 1: 10～50 of pollutant weight and dye liquor volume, 80～100 ℃ of temperature, time 45-80min; Dye complete, the washing, the oven dry;
(3) fabric that has dyeed is carried out rear mordant dyeing and process, control condition is: mordant weight is 1～5% of pollutant weight, and bath raio is 1: 10～50, and temperature is 60～80 ℃, and the time is 30～45min; The taking-up fabric that is disposed is cleaned, oven dry;
Described mordant is one or more in ferric sulfate, iron(ic) chloride, ferrous sulfate, iron protochloride, aluminum chloride, Tai-Ace S 150, potassium aluminium sulfate or cerous sulfate, the Neodymium trichloride.
Beneficial effect of the present invention is:
The present invention adopts ethanol---and the alkaline solution circumfluence method is extracted hypernic from the Chinese photinia fruit, extraction process is simple, and extraction efficiency is apparently higher than additive methods such as alcohol refluxs, and leaching process can not cause environmental pollution; Extract is good to the protein fibre dyefastness; Use the environmental protection mordant to process after the dyeing and can increase chromatogram; Fabric color is soft after the dyeing, wears safety, does not have carcinogenic, teratogenesis or causes allergic reaction; Good, biodegradable with the ecotope consistency; And utilize the Chinese photinia fruit to prepare the natural dyestuff low price, and taking full advantage of natural resource, market outlook will be very wide.
Embodiment
Embodiment 1:
The Chinese photinia fresh fruit is cleaned, dried, mechanical disintegration; Taking by weighing 1 kilogram of crushed material, is the aqueous ethanolic solution of 10% (v/v) of 10 (sodium phosphate adjustings) with 10 kilograms of pH values, and lixiviate 120min under 70 ℃ of temperature filters, and centrifugal and underpressure distillation is concentrated into 5 liters, is concentrated Chinese photinia fruit natural dyestuff.
Embodiment 2:
The Chinese photinia fresh fruit is cleaned, dried, mechanical disintegration; Taking by weighing 1 kilogram of crushed material, is the aqueous ethanolic solution of 25% (v/v) of 9 (yellow soda ash adjustings) with 20 kilograms of pH values, and lixiviate 90min under 80 ℃ of temperature filters, and centrifugal and underpressure distillation is concentrated into 5 liters, is concentrated Chinese photinia fruit natural dyestuff.
Embodiment 3:
The Chinese photinia fresh fruit is cleaned, dried, mechanical disintegration; Taking by weighing 1 kilogram of crushed material, is the aqueous ethanolic solution of 8 (sodium bicarbonate adjusting) 50% (v/v) with 30 kilograms of pH values, and lixiviate 60min under 90 ℃ of temperature filters, and centrifugal and underpressure distillation is concentrated into 5 liters, is concentrated Chinese photinia fruit natural dyestuff.
Embodiment 4:
(1) real silk fabric is joined carry out pre-mordant dyeing in the ferrous sulfate aqueous solution of pollutant weight 5% and process, bath raio is 1: 50, temperature 60 C, time 30 minutes, and the taking-up fabric that is disposed, washing is extracted;
(2) concentrated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration of concentrated dyestuff is 25% (m/m) in the dye liquor, and pH value 4, bath raio 1: 50 are processed 80min under 95 ℃ temperature, washing, oven dry.
(3) sample as calculated machine color measurement and color match instrument record its color feature value L*, a*, b*, c*, K/S value and be respectively 51.17,9.21,16.77,19.13,5.40.
Embodiment 5:
(1) wool fabric is joined carry out pre-mordant dyeing in the alum solution of pollutant weight 3% and process, bath raio is 1: 30,80 ℃ of temperature, 45 minutes time, and the taking-up fabric that is disposed, washing is extracted;
(2) concentrated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration of concentrated dyestuff is 15% (m/m), pH value 6 in the dye liquor, bath raio 1: 30, and after above-mentioned fabrics immersed dye liquor, 100 ℃ of dyeing 60min dyed completely, wash, and dry.
(3) sample as calculated machine color measurement and color match instrument record its color feature value L*, a*, b*, c*, K/S value and be respectively 50.60,10.03,21.12,23.38,7.33.
Embodiment 6:
(1) real silk fabric is joined carry out pre-mordant dyeing in the Neodymium trichloride aqueous solution of pollutant weight 1% and process, bath raio is 1: 10, temperature 70 C, time 40 minutes, and the taking-up fabric that is disposed, washing is extracted;
(2) concentrated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration of concentrated dyestuff is 5% (m/m) in the dye liquor, and the pH value is 5, bath raio 1: 10, and after above-mentioned fabrics immerses dye liquor, 80 ℃ of dyeing 45min.Dye complete, the washing, the oven dry;
(3) sample as calculated machine color measurement and color match instrument record its color feature value L*, a*, b*, c*, K/S value and be respectively 51.91,8.98,16.52,18.80,5.08.
Embodiment 7:
(1) concentrated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration of concentrated dyestuff is 25% (m/m) in the dye liquor, and the pH value is 5, bath raio 1: 30, wool fabric immersed dye liquor after, 100 ℃ of 45min that dye.Dye complete, the washing, the oven dry;
(2) will dye after wool fabric join and carry out rear mordant dyeing in the alum solution of pollutant weight 5% and process, bath raio is 1: 30,80 ℃ of temperature, time 30min, the taking-up fabric that is disposed, washing, oven dry gets the sorrel wool fabric;
Embodiment 8:
(1) concentrated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration of concentrated dyestuff is 15% (m/m) in the dye liquor, and the pH value is 6, bath raio 1: 50, real silk fabric immersed dye liquor after, 80 ℃ of 80min that dye.Dye complete, the washing, the oven dry;
(2) will dye after real silk fabric join and carry out rear mordant dyeing in the ferrous sulfate aqueous solution of pollutant weight 3% and process, bath raio is 1: 50, temperature 60 C, time 45min, the taking-up fabric that is disposed, washing, oven dry; Get the pewter real silk fabric;
Embodiment 9:
(1) concentrated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration of concentrated dyestuff is 5% (m/m) in the dye liquor, and the pH value is 4, bath raio 1: 10, real silk fabric immersed dye liquor after, 90 ℃ of 60min that dye.Dye complete, the washing, the oven dry;
(2) will dye after real silk fabric join and carry out rear mordant dyeing in the Neodymium trichloride aqueous solution of pollutant weight 1% and process, bath raio is 1: 10, temperature 70 C, time 40min, the taking-up fabric that is disposed, washing, oven dry; Get the sorrel real silk fabric;
At last, it is also to be noted that, obviously the invention is not restricted to above embodiment, many distortion can also be arranged, all distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.
Claims (4)
1. the preparation method of a Chinese photinia fruit natural dyestuff may further comprise the steps:
(1) Chinese photinia fresh fruit or dry fruit are cleaned, dried, mechanical disintegration;
(2) Chinese photinia fruit crushed material is joined refluxing extraction in the aqueous ethanolic solution of pH value 8～10; Extracting solution is warming up to 70～90 ℃, insulation 1～2h; It is 1/6～1/2 of extracting solution original volume that filtration and underpressure distillation make the concentrated solution volume, the Chinese photinia fruit natural dyestuff that obtains concentrating;
The concentration of volume percent of described aqueous ethanolic solution is 10～50%, and the mass ratio of Chinese photinia fruit crushed material and aqueous ethanolic solution is 1: 10～30.
2. the preparation method of Chinese photinia fruit natural dyestuff according to claim 1 is characterized in that, the pH value of described aqueous ethanolic solution is to add an amount of sodium bicarbonate, yellow soda ash or sodium phosphate to regulate.
3. one kind is utilized the fruit of Chinese photinia described in the claim 1 natural dyestuff to the method for textile dyeing, may further comprise the steps:
(1) real silk or wool fabric are carried out pre-mordant dyeing processing, control condition is during processing: mordant weight is 1～5% of pollutant weight, and bath raio is 1: 10～50, and temperature is 60～80 ℃, and the time is 30～45min; The taking-up fabric that is disposed is cleaned, and extracts;
(2) be configured to dye liquor with concentrated Chinese photinia fruit natural dyestuff and water, wherein concentrated dyestuff accounts for 5～25% of whole dye liquor quality, and regulates dye liquor pH value 4～6;
(3) fabric of the pre-mordant dyeing of above-mentioned warp being processed immerses in the Chinese photinia fruit dye liquor and dyes, and control condition is during dyeing: the ratio 1: 10～50 of pollutant weight and dye liquor volume, 80～100 ℃ of temperature, time 45～80min; Dye complete, the washing, the oven dry;
Described mordant is one or more in ferric sulfate, iron(ic) chloride, ferrous sulfate, iron protochloride, aluminum chloride, Tai-Ace S 150, potassium aluminium sulfate or cerous sulfate, the Neodymium trichloride.
4. one kind is utilized the fruit of Chinese photinia described in the claim 1 natural dyestuff to the method for textile dyeing, may further comprise the steps:
(1) be configured to dye liquor with concentrated Chinese photinia fruit natural dyestuff and water, wherein concentrated dyestuff accounts for 5～25% of whole dye liquor quality, and regulates dye liquor pH value 4～6;
(2) will real silk or wool fabric immerse in the Chinese photinia fruit dye liquor and dye, control condition is during dyeing: the ratio 1: 10～50 of pollutant weight and dye liquor volume, 80～100 ℃ of temperature, time 45～80min; Dye complete, the washing, extract;
(3) fabric that has dyeed is carried out rear mordant dyeing and process, control condition is: mordant weight is 1～5% of pollutant weight, and bath raio is 1: 10～50, and temperature is 60～80 ℃, and the time is 30～45min; The taking-up fabric that is disposed is cleaned, oven dry;
Described mordant is one or more in ferric sulfate, iron(ic) chloride, ferrous sulfate, iron protochloride, aluminum chloride, Tai-Ace S 150, potassium aluminium sulfate or cerous sulfate, the Neodymium trichloride.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201010257861 CN101914306B (en) | 2010-08-19 | 2010-08-19 | Method for preparing photinia fruit natural dye and application of photinia fruit natural dye |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201010257861 CN101914306B (en) | 2010-08-19 | 2010-08-19 | Method for preparing photinia fruit natural dye and application of photinia fruit natural dye |
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| CN101914306B true CN101914306B (en) | 2013-04-24 |
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| CN102220705A (en) * | 2011-04-20 | 2011-10-19 | 盐城纺织职业技术学院 | Method for dying silk fabric by using natural dye of Suaeda salsa |
| CN102321383B (en) * | 2011-06-15 | 2013-12-04 | 华南农业大学 | Preparation method for vegetable tannin dye liquor and application thereof in dyeing aspect of real silk fabric |
| CN103725035B (en) * | 2014-01-13 | 2015-05-13 | 安徽新华学院 | Method for extracting natural haematochrome and marennin from folium photiniae |
| CN104073021A (en) * | 2014-06-26 | 2014-10-01 | 南通润启时装有限公司 | Preparation and application of grape natural dye |
| CN104189140B (en) * | 2014-08-08 | 2017-02-15 | 西北农林科技大学 | Photinia serrulata procyanidine as well as preparation method and application thereof |
| CN104499309A (en) * | 2014-12-15 | 2015-04-08 | 常熟市启弘纺织实业有限公司 | Environment-friendly printing and dyeing method of fabric |
| CN104910642B (en) * | 2015-05-25 | 2018-03-06 | 浙江理工大学 | The preparation method and applications of garden burnet natural dye |
| CN105038301B (en) * | 2015-07-14 | 2017-03-15 | 浙江理工大学 | A kind of extracting method of Cortex cinnamomi japonici (Ramulus Cinnamomi) natural dye and its preparation of dyed fabric |
| CN106835759A (en) * | 2017-01-21 | 2017-06-13 | 达利(中国)有限公司 | The preparation method and applications of natural dye Freehandhand-drawing real silk fabric |
| CN108978264A (en) * | 2018-08-10 | 2018-12-11 | 三亚新动力文化传播有限公司 | A kind of vegetation dye formula and its colouring method |
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2010
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Non-Patent Citations (2)
| Title |
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| 4种木本植物红色素最佳提取条件的研究;陈文荣等;《浙江师范大学学报(自然科学版)》;20090331;第32卷(第01期);13-17 * |
| 陈文荣等.4种木本植物红色素最佳提取条件的研究.《浙江师范大学学报(自然科学版)》.2009,第32卷(第01期), |
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