CN101914306A - Method for preparing photinia fruit natural dye and application of photinia fruit natural dye - Google Patents
Method for preparing photinia fruit natural dye and application of photinia fruit natural dye Download PDFInfo
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- CN101914306A CN101914306A CN201010257861XA CN201010257861A CN101914306A CN 101914306 A CN101914306 A CN 101914306A CN 201010257861X A CN201010257861X A CN 201010257861XA CN 201010257861 A CN201010257861 A CN 201010257861A CN 101914306 A CN101914306 A CN 101914306A
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Abstract
The invention relates to the field of natural dyes and application thereof and aims to provide a method for preparing a photinia fruit natural dye and application of the photinia fruit natural dye. The preparation method comprises the following steps of: (1) washing and airing fresh photinia fruits and dried photinia fruits, and mechanically crushing the fruits; and (2) adding the crushed photinia fruits into aqueous solution of ethanol for reflux extraction, raising the temperature of the extract to between 70 and 90 DEG C, keeping the temperature, filtering and distilling under reduced pressure to make the volume of concentrated solution 1/6 to 1/2 of the original volume of the extract so as to obtain the concentrated photinia fruit natural dye. The method for preparing the photinia fruit natural dye has the advantages of simple extraction technology, extraction efficiency obviously higher than that of ethanol reflux and other methods, and no environmental pollution in the extraction process; and the extract has the advantages of good color fastness to protein fibers, capacity of increasing color spectrum after dyeing by using environment-friendly dye mordant treatment, gentle color and safe wear of the dyed fabrics without carcinogenic, teratogenetic actions or anaphylactic reaction, high ecological environment compatibility, biodegradation, low price, full utilization of natural resources and wide market prospect.
Description
Technical field
The present invention relates to natural dyestuff and Application Areas thereof, particularly relate to a kind of preparation method and application thereof of Chinese photinia fruit natural dyestuff.
Background technology
Chinese photinia is a Rosaceae Photinia plant, evergreen shrubs, have another name called thousand red.Be distributed in Central-South and areas such as Jiangsu, Anhui, Zhejiang, Jiangxi, Taiwan, Sichuan and Guizhou.Chinese photinia is good ornamental plants in garden, is widely used in urban afforestation at present, and it has stronger resistance to sulfurous gas, chlorine, and the sound insulation function is arranged.Contained ursolic acid has significantly stable and cooling effect in the leaf of chinese photinia, and analgesia, anti-inflammatory and antitumous effect are arranged, and gram-positive microorganism, negative bacterium and yeast are had restraining effect; But its root, branch hyoscine have the effect of promoting circulation of blood hemostasis, pain relieving, are used for the treatment of jaundice, acute mastitis, toothache.But the red especially gorgeous people of Chinese photinia fruit, achieve great success autumn, but except that having ornamental value, not seeing at present has research report, and that abandons is very unfortunate, and correlative study both at home and abroad is still blank out.And study about the preparation method and the dyeing on protein, cellulosic fibre thereof of Chinese photinia fruit natural dyestuff, not seeing both at home and abroad has report.
Summary of the invention
The technical problem to be solved in the present invention is, fills up the blank of prior art, and a kind of new purposes of Chinese photinia fruit is provided, and turns waste into wealth, and promptly extracts natural dyestuff from red Chinese photinia fruit, and is applied to textile dyeing.
Show that after deliberation the Chinese photinia fruit extract is bright-coloured sorrel, its maximum absorption wavelength is about 490～500nm.Protein fibre or fabric are had good dyeing behavior, handle to obtain distinct colors by different mordants, and colour fastness is good, is the natural plant dye of an excellent property.
Be the technical solution problem, the invention provides a kind of preparation method of Chinese photinia fruit natural dyestuff, may further comprise the steps:
(1) Chinese photinia fresh fruit or dry fruit are cleaned, dried, mechanical disintegration;
(2) Chinese photinia fruit crushed material is joined refluxing extraction in the aqueous ethanolic solution of pH value 8～10; Extracting solution is warming up to 70～90 ℃, insulation 1～2h; It is 1/6～1/2 of extracting solution original volume that filtration and underpressure distillation make the concentrated solution volume, obtains spissated Chinese photinia fruit natural dyestuff;
The concentration of volume percent of described aqueous ethanolic solution is 10～50%, and the mass ratio of Chinese photinia fruit crushed material and aqueous ethanolic solution is 1: 10～30.
Among the present invention, the pH value of described aqueous ethanolic solution is to regulate to add an amount of sodium bicarbonate, yellow soda ash or sodium phosphate.
The present invention further provides a kind of method of utilizing aforementioned Chinese photinia fruit natural dyestuff to textile dyeing, may further comprise the steps:
(1) real silk or wool fabric are carried out pre-mordant dyeing processing, control condition is during processing: mordant weight is 1～5% of pollutant weight, and bath raio is 1: 10～50, and temperature is 60～80 ℃, and the time is 30～45min; The taking-up fabric that disposes is cleaned, and extracts;
(2) be configured to dye liquor with spissated Chinese photinia fruit natural dyestuff and water, wherein concentrate dyestuff and account for 5～25% of whole dye liquor quality, and regulate dye liquor pH value 4～6;
(3) fabric that the pre-mordant dyeing of above-mentioned warp is handled immerses in the Chinese photinia fruit dye liquor and dyes, and control condition is during dyeing: the ratio 1: 10～50 of pollutant weight and dye liquor volume, 80～100 ℃ of temperature, time 45～80min; Dye complete, the washing, the oven dry;
Described mordant is one or more in ferric sulfate, iron(ic) chloride, ferrous sulfate, iron protochloride, aluminum chloride, Tai-Ace S 150, potassium aluminium sulfate or cerous sulfate, the Neodymium trichloride.
Adaptably, the present invention also provides a kind of method of utilizing aforementioned Chinese photinia fruit natural dyestuff to textile dyeing, may further comprise the steps:
(1) is configured to dye liquor with spissated Chinese photinia fruit natural dyestuff and water, wherein concentrates dyestuff and account for 5～25% of whole dye liquor quality, and regulate dye liquor pH value 4～6;
(2) will real silk or wool fabric immerse in the Chinese photinia fruit dye liquor and dye, control condition is during dyeing: the ratio 1: 10～50 of pollutant weight and dye liquor volume, 80～100 ℃ of temperature, time 45-80min; Dye complete, the washing, the oven dry;
(3) painted fabric is carried out the back mordant dyeing and handle, control condition is: mordant weight is 1～5% of pollutant weight, and bath raio is 1: 10～50, and temperature is 60～80 ℃, and the time is 30～45min; The taking-up fabric that disposes is cleaned, oven dry;
Described mordant is one or more in ferric sulfate, iron(ic) chloride, ferrous sulfate, iron protochloride, aluminum chloride, Tai-Ace S 150, potassium aluminium sulfate or cerous sulfate, the Neodymium trichloride.
Beneficial effect of the present invention is:
The present invention adopts ethanol---and the alkaline solution circumfluence method is extracted hypernic from the Chinese photinia fruit, extraction process is simple, and extraction efficiency is apparently higher than additive methods such as alcohol refluxs, and leaching process can not cause environmental pollution; Extract is good to the protein fibre dyefastness; The dyeing back uses the environmental protection mordant to handle can increase chromatogram; Dyeing back fabric color is soft, wears safety, does not have carcinogenic, teratogenesis or causes allergic reaction; Good, biodegradable with the ecotope consistency; And utilize the Chinese photinia fruit to prepare the natural dyestuff low price, and having made full use of natural resource, market outlook will be very wide.
Embodiment
Embodiment 1:
The Chinese photinia fresh fruit is cleaned, dried, mechanical disintegration; Taking by weighing 1 kilogram of crushed material, is the aqueous ethanolic solution of 10% (v/v) of 10 (sodium phosphate adjustings) with 10 kilograms of pH values, and lixiviate 120min under 70 ℃ of temperature filters, and centrifugal and underpressure distillation is concentrated into 5 liters, is spissated Chinese photinia fruit natural dyestuff.
Embodiment 2:
The Chinese photinia fresh fruit is cleaned, dried, mechanical disintegration; Taking by weighing 1 kilogram of crushed material, is the aqueous ethanolic solution of 25% (v/v) of 9 (yellow soda ash adjustings) with 20 kilograms of pH values, and lixiviate 90min under 80 ℃ of temperature filters, and centrifugal and underpressure distillation is concentrated into 5 liters, is spissated Chinese photinia fruit natural dyestuff.
Embodiment 3:
The Chinese photinia fresh fruit is cleaned, dried, mechanical disintegration; Taking by weighing 1 kilogram of crushed material, is the aqueous ethanolic solution of 8 (sodium bicarbonate adjusting) 50% (v/v) with 30 kilograms of pH values, and lixiviate 60min under 90 ℃ of temperature filters, and centrifugal and underpressure distillation is concentrated into 5 liters, is spissated Chinese photinia fruit natural dyestuff.
Embodiment 4:
(1) real silk fabric is joined carry out pre-mordant dyeing in the ferrous sulfate aqueous solution of pollutant weight 5% and handle, bath raio is 1: 50,60 ℃ of temperature, 30 minutes time, and the taking-up fabric that disposes, washing is extracted;
(2) spissated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration that concentrates dyestuff in the dye liquor is 25% (m/m), and pH value 4, bath raio 1: 50 are handled 80min under 95 ℃ temperature, washing, oven dry.
(3) sample as calculated machine color measurement and color match instrument record its color feature value L*, a*, b*, c*, K/S value and be respectively 51.17,9.21,16.77,19.13,5.40.
Embodiment 5:
(1) wool fabric is joined carry out pre-mordant dyeing in the alum solution of pollutant weight 3% and handle, bath raio is 1: 30,80 ℃ of temperature, 45 minutes time, and the taking-up fabric that disposes, washing is extracted;
(2) spissated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration that concentrates dyestuff in the dye liquor is 15% (m/m), pH value 6, bath raio 1: 30, and after above-mentioned fabrics immersed dye liquor, 100 ℃ of dyeing 60min dyed completely, and washing is dried.
(3) sample as calculated machine color measurement and color match instrument record its color feature value L*, a*, b*, c*, K/S value and be respectively 50.60,10.03,21.12,23.38,7.33.
Embodiment 6:
(1) real silk fabric is joined carry out pre-mordant dyeing in the Neodymium trichloride aqueous solution of pollutant weight 1% and handle, bath raio is 1: 10,70 ℃ of temperature, 40 minutes time, and the taking-up fabric that disposes, washing is extracted;
(2) spissated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration that concentrates dyestuff in the dye liquor is 5% (m/m), and the pH value is 5, bath raio 1: 10, and after above-mentioned fabrics immerses dye liquor, 80 ℃ of dyeing 45min.Dye complete, the washing, the oven dry;
(3) sample as calculated machine color measurement and color match instrument record its color feature value L*, a*, b*, c*, K/S value and be respectively 51.91,8.98,16.52,18.80,5.08.
Embodiment 7:
(1) spissated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration that concentrates dyestuff in the dye liquor is 25% (m/m), and pH value is 5, bath raio 1: 30, wool fabric immersed dye liquor after, 100 ℃ of 45min that dye.Dye complete, the washing, the oven dry;
(2) the back wool fabric that will dye joins and carries out back mordant dyeing in the alum solution of pollutant weight 5% and handle, and bath raio is 1: 30,80 ℃ of temperature, time 30min, the taking-up fabric that disposes, washing, oven dry, the sorrel wool fabric;
Embodiment 8:
(1) spissated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration that concentrates dyestuff in the dye liquor is 15% (m/m), and pH value is 6, bath raio 1: 50, real silk fabric immersed dye liquor after, 80 ℃ of 80min that dye.Dye complete, the washing, the oven dry;
(2) the back real silk fabric that will dye joins and carries out back mordant dyeing in the ferrous sulfate aqueous solution of pollutant weight 3% and handle, and bath raio is 1: 50,60 ℃ of temperature, time 45min, and the taking-up fabric that disposes, washing is dried; Get the pewter real silk fabric;
Embodiment 9:
(1) spissated Chinese photinia fruit natural dyestuff and water are made into dye liquor, the concentration that concentrates dyestuff in the dye liquor is 5% (m/m), and pH value is 4, bath raio 1: 10, real silk fabric immersed dye liquor after, 90 ℃ of 60min that dye.Dye complete, the washing, the oven dry;
(2) the back real silk fabric that will dye joins and carries out back mordant dyeing in the Neodymium trichloride aqueous solution of pollutant weight 1% and handle, and bath raio is 1: 10,70 ℃ of temperature, time 40min, and the taking-up fabric that disposes, washing is dried; Get the sorrel real silk fabric;
At last, it is also to be noted that, obviously the invention is not restricted to above embodiment, many distortion can also be arranged, all distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.
Claims (4)
1. the preparation method of a Chinese photinia fruit natural dyestuff may further comprise the steps:
(1) Chinese photinia fresh fruit or dry fruit are cleaned, dried, mechanical disintegration;
(2) Chinese photinia fruit crushed material is joined refluxing extraction in the aqueous ethanolic solution of pH value 8～10; Extracting solution is warming up to 70～90 ℃, insulation 1～2h; It is 1/6～1/2 of extracting solution original volume that filtration and underpressure distillation make the concentrated solution volume, obtains spissated Chinese photinia fruit natural dyestuff;
The concentration of volume percent of described aqueous ethanolic solution is 10～50%, and the mass ratio of Chinese photinia fruit crushed material and aqueous ethanolic solution is 1: 10～30.
2. the preparation method of Chinese photinia fruit natural dyestuff according to claim 1 is characterized in that, the pH value of described aqueous ethanolic solution is to regulate to add an amount of sodium bicarbonate, yellow soda ash or sodium phosphate.
3. method of utilizing the fruit of Chinese photinia described in the claim 1 natural dyestuff to textile dyeing may further comprise the steps:
(1) real silk or wool fabric are carried out pre-mordant dyeing processing, control condition is during processing: mordant weight is 1～5% of pollutant weight, and bath raio is 1: 10～50, and temperature is 60～80 ℃, and the time is 30～45min; The taking-up fabric that disposes is cleaned, and extracts;
(2) be configured to dye liquor with spissated Chinese photinia fruit natural dyestuff and water, wherein concentrate dyestuff and account for 5～25% of whole dye liquor quality, and regulate dye liquor pH value 4～6;
(3) fabric that the pre-mordant dyeing of above-mentioned warp is handled immerses in the Chinese photinia fruit dye liquor and dyes, and control condition is during dyeing: the ratio 1: 10～50 of pollutant weight and dye liquor volume, 80～100 ℃ of temperature, time 45～80min; Dye complete, the washing, the oven dry;
Described mordant is one or more in ferric sulfate, iron(ic) chloride, ferrous sulfate, iron protochloride, aluminum chloride, Tai-Ace S 150, potassium aluminium sulfate or cerous sulfate, the Neodymium trichloride.
4. method of utilizing the fruit of Chinese photinia described in the claim 1 natural dyestuff to textile dyeing may further comprise the steps:
(1) is configured to dye liquor with spissated Chinese photinia fruit natural dyestuff and water, wherein concentrates dyestuff and account for 5～25% of whole dye liquor quality, and regulate dye liquor pH value 4～6;
(2) will real silk or wool fabric immerse in the Chinese photinia fruit dye liquor and dye, control condition is during dyeing: the ratio 1: 10～50 of pollutant weight and dye liquor volume, 80～100 ℃ of temperature, time 45～80min; Dye complete, the washing, extract;
(3) painted fabric is carried out the back mordant dyeing and handle, control condition is: mordant weight is 1～5% of pollutant weight, and bath raio is 1: 10～50, and temperature is 60～80 ℃, and the time is 30～45min; The taking-up fabric that disposes is cleaned, oven dry;
Described mordant is one or more in ferric sulfate, iron(ic) chloride, ferrous sulfate, iron protochloride, aluminum chloride, Tai-Ace S 150, potassium aluminium sulfate or cerous sulfate, the Neodymium trichloride.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201010257861 CN101914306B (en) | 2010-08-19 | 2010-08-19 | Method for preparing photinia fruit natural dye and application of photinia fruit natural dye |
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| CN 201010257861 CN101914306B (en) | 2010-08-19 | 2010-08-19 | Method for preparing photinia fruit natural dye and application of photinia fruit natural dye |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102220705A (en) * | 2011-04-20 | 2011-10-19 | 盐城纺织职业技术学院 | Method for dying silk fabric by using natural dye of Suaeda salsa |
| CN102321383A (en) * | 2011-06-15 | 2012-01-18 | 华南农业大学 | The preparation method of vegatable tannin dye liquor and the application aspect silk fabric dyeing thereof |
| CN103725035A (en) * | 2014-01-13 | 2014-04-16 | 安徽新华学院 | Method for extracting natural haematochrome and marennin from folium photiniae |
| CN104073021A (en) * | 2014-06-26 | 2014-10-01 | 南通润启时装有限公司 | Preparation and application of grape natural dye |
| CN104189140A (en) * | 2014-08-08 | 2014-12-10 | 西北农林科技大学 | Photinia serrulata procyanidine as well as preparation method and application thereof |
| CN104499309A (en) * | 2014-12-15 | 2015-04-08 | 常熟市启弘纺织实业有限公司 | Environment-friendly printing and dyeing method of fabric |
| CN104910642A (en) * | 2015-05-25 | 2015-09-16 | 浙江理工大学 | Preparation method and use of garden burnet natural dye |
| CN105038301A (en) * | 2015-07-14 | 2015-11-11 | 浙江理工大学 | Method for extracting natural cassia dye and preparation of textile soaked in natural cassia dye |
| CN106835759A (en) * | 2017-01-21 | 2017-06-13 | 达利(中国)有限公司 | The preparation method and applications of natural dye Freehandhand-drawing real silk fabric |
| CN108978264A (en) * | 2018-08-10 | 2018-12-11 | 三亚新动力文化传播有限公司 | A kind of vegetation dye formula and its colouring method |
-
2010
- 2010-08-19 CN CN 201010257861 patent/CN101914306B/en active Active
Non-Patent Citations (1)
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| 陈文荣等: "4种木本植物红色素最佳提取条件的研究", 《浙江师范大学学报(自然科学版)》 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102220705A (en) * | 2011-04-20 | 2011-10-19 | 盐城纺织职业技术学院 | Method for dying silk fabric by using natural dye of Suaeda salsa |
| CN102321383A (en) * | 2011-06-15 | 2012-01-18 | 华南农业大学 | The preparation method of vegatable tannin dye liquor and the application aspect silk fabric dyeing thereof |
| CN102321383B (en) * | 2011-06-15 | 2013-12-04 | 华南农业大学 | Preparation method for vegetable tannin dye liquor and application thereof in dyeing aspect of real silk fabric |
| CN103725035B (en) * | 2014-01-13 | 2015-05-13 | 安徽新华学院 | Method for extracting natural haematochrome and marennin from folium photiniae |
| CN103725035A (en) * | 2014-01-13 | 2014-04-16 | 安徽新华学院 | Method for extracting natural haematochrome and marennin from folium photiniae |
| CN104073021A (en) * | 2014-06-26 | 2014-10-01 | 南通润启时装有限公司 | Preparation and application of grape natural dye |
| CN104189140A (en) * | 2014-08-08 | 2014-12-10 | 西北农林科技大学 | Photinia serrulata procyanidine as well as preparation method and application thereof |
| CN104499309A (en) * | 2014-12-15 | 2015-04-08 | 常熟市启弘纺织实业有限公司 | Environment-friendly printing and dyeing method of fabric |
| CN104910642A (en) * | 2015-05-25 | 2015-09-16 | 浙江理工大学 | Preparation method and use of garden burnet natural dye |
| CN104910642B (en) * | 2015-05-25 | 2018-03-06 | 浙江理工大学 | The preparation method and applications of garden burnet natural dye |
| CN105038301A (en) * | 2015-07-14 | 2015-11-11 | 浙江理工大学 | Method for extracting natural cassia dye and preparation of textile soaked in natural cassia dye |
| CN106835759A (en) * | 2017-01-21 | 2017-06-13 | 达利(中国)有限公司 | The preparation method and applications of natural dye Freehandhand-drawing real silk fabric |
| CN108978264A (en) * | 2018-08-10 | 2018-12-11 | 三亚新动力文化传播有限公司 | A kind of vegetation dye formula and its colouring method |
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| CN101914306B (en) | 2013-04-24 |
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Application publication date: 20101215 Assignee: Zhejiang Sci-Tech University Shangyu Industrial Technology Research Institute Co., Ltd. Assignor: Zhejiang University of Technology Contract record no.: X2019330000038 Denomination of invention: Method for preparing photinia fruit natural dye and application of photinia fruit natural dye Granted publication date: 20130424 License type: Common License Record date: 20191108 |
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