CN109474252B - Cavity film bulk acoustic resonator capable of improving Q value and preparation method thereof - Google Patents

Cavity film bulk acoustic resonator capable of improving Q value and preparation method thereof Download PDF

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CN109474252B
CN109474252B CN201811271504.1A CN201811271504A CN109474252B CN 109474252 B CN109474252 B CN 109474252B CN 201811271504 A CN201811271504 A CN 201811271504A CN 109474252 B CN109474252 B CN 109474252B
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sic
piezoelectric
substrate
layer
thin film
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CN109474252A (en
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谢英
刘胜
蔡耀
邹杨
周杰
刘婕妤
孙成亮
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Wuhan Memsonics Technologies Co Ltd
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Wuhan University WHU
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    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/02Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/02Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
    • H03H3/04Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks for obtaining desired frequency or temperature coefficient
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/02Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
    • H03H2003/023Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks the resonators or networks being of the membrane type
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/02Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
    • H03H3/04Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks for obtaining desired frequency or temperature coefficient
    • H03H2003/0407Temperature coefficient

Abstract

The invention provides a cavity film bulk acoustic resonator capable of improving a Q value and a preparation method thereof. The invention provides a cavity film bulk acoustic resonator capable of improving Q value, which is characterized by comprising the following components: a substrate, the middle part of which is provided with a groove which is opened upwards; the SiC/Diamond thin film layer is formed on the substrate, and the middle part of the SiC/Diamond thin film layer is provided with a through hole corresponding to the groove; and the piezoelectric oscillation stack part is formed on the SiC/Diamond thin film layer and is positioned right above the through hole, and sequentially comprises the following components from bottom to top: a bottom electrode, a piezoelectric layer, and a top electrode. The invention utilizes the characteristics of high sound wave propagation rate and high hardness of the SiC/Diamond film layer, can well inhibit the sound wave of a transverse vibration mode generated in the piezoelectric film, can reduce the mechanical damping introduced by the soft substrate, reduce the energy loss of the sound wave, reduce the insertion loss of the film bulk acoustic resonator, and obtain high Q value and electromechanical coupling coefficient.

Description

Cavity film bulk acoustic resonator capable of improving Q value and preparation method thereof
Technical Field
The invention belongs to the field of sensor preparation, and particularly relates to a cavity film bulk acoustic resonator capable of improving a Q value and a preparation method thereof.
Technical Field
With the rapid development of wireless communication, wireless signals become more and more crowded, and new requirements of integration, miniaturization, low power consumption, high performance, low cost and the like are provided for a filter working in a radio frequency band. The traditional surface acoustic wave filter can not reach the technical indexes due to the limitation of frequency, bearing power and the like. Film Bulk Acoustic Resonators (FBARs) are becoming the focus of research in radio frequency filters due to their CMOS process compatibility, high quality factor (Q value), low loss, low temperature coefficient, and high power carrying capability.
Film Bulk Acoustic Wave resonators (FBARs) can be classified into air gap type, silicon back-etched type, and solid package type. The cavity type FBAR has a slightly higher Q value compared with a solid packaging type FBAR, the loss is small, and the electromechanical coupling coefficient is slightly higher; compared with the silicon back-etched FBAR, the mechanical stability and mechanical strength are good because the cavity type does not require removal of a large area of the substrate. The cavity-type FBAR is generally made of an electrode-piezoelectric film-electrode sandwich structure on a substrate silicon, and an air gap is etched between the upper surface of the substrate silicon and the lower surface of a lower electrode to form an air interface, which can confine acoustic energy in an FBAR substrate, thereby reducing the loss of the acoustic energy.
The principle of the film bulk acoustic resonator is that a piezoelectric effect of a piezoelectric film is utilized, an electric signal is applied between an upper electrode and a lower electrode, the piezoelectric effect of the piezoelectric film can generate an acoustic signal, the acoustic signal oscillates between the electrodes, the acoustic wave is divided into a thickness vibration mode and a transverse vibration mode, wherein the acoustic wave is reserved only in the thickness vibration mode meeting the total reflection condition of the acoustic wave, the acoustic wave in the transverse vibration mode is consumed, the reserved acoustic signal is converted into the electric signal to be output, and therefore frequency selection of the electric signal is achieved. The acoustic wave in the transverse vibration mode causes the loss of acoustic wave energy, reduces the energy conversion efficiency, increases the insertion loss of the FBAR, and reduces the Q value of a quality factor.
Disclosure of Invention
The present invention has been made to solve the above problems, and an object of the present invention is to provide a cavity thin film bulk acoustic resonator capable of improving a Q value and a method for manufacturing the same.
In order to achieve the purpose, the invention adopts the following scheme:
< resonator >
The invention provides a cavity film bulk acoustic resonator capable of improving Q value, which is characterized by comprising the following components: a substrate, the middle part of which is provided with a groove which is opened upwards; the SiC/Diamond thin film layer is formed on the substrate, and the middle part of the SiC/Diamond thin film layer is provided with a through hole corresponding to the groove; and the piezoelectric oscillation stack part is formed on the SiC/Diamond thin film layer and is positioned right above the through hole, and sequentially comprises the following components from bottom to top: a bottom electrode, a piezoelectric layer, and a top electrode.
Preferably, the cavity film bulk acoustic resonator capable of improving the Q value provided by the invention can also have the following characteristics: the substrate is a silicon or sapphire substrate.
Preferably, the cavity film bulk acoustic resonator capable of improving the Q value provided by the invention can also have the following characteristics: the bottom electrode and the top electrode are both metal films, and the metal films are any one of molybdenum films, platinum films, gold films, silver films and tungsten films.
Preferably, the cavity film bulk acoustic resonator capable of improving the Q value provided by the invention can also have the following characteristics: the piezoelectric layer is made of any one of AlN, ZnO and PZT piezoelectric films with C-axis orientation.
< preparation method >
Further, the present invention provides a method for manufacturing a cavity film bulk acoustic resonator capable of improving a Q value, which is characterized in that: the cavity film bulk acoustic resonator capable of improving the Q value described in the < resonator > above is prepared.
Preferably, the method for preparing the cavity film bulk acoustic resonator capable of improving the Q value provided by the invention comprises the following steps: step 1, depositing a SiC/Diamond thin film layer on a substrate; step 2, etching a preset through hole on the SiC/Diamond thin film layer; step 3, etching a preset groove on the substrate, wherein the size of the groove corresponds to that of the through hole; step 4, depositing a sacrificial layer on the SiC/Diamond thin film layer, wherein the chemical property of the material of the sacrificial layer is different from that of the substrate, so that the substrate is not affected during subsequent corrosion; step 5, removing the redundant sacrificial layer material by using a chemical mechanical polishing technology, so that the groove and the through hole are just filled with the sacrificial layer material; step 6, sequentially depositing a bottom electrode, a piezoelectric film and a top electrode on the SiC/Diamond thin film layer and the sacrificial layer to form a piezoelectric oscillation stack part; step 7, patterning the bottom electrode/the piezoelectric layer/the top electrode to reduce the pseudo mode vibration; step 8, etching release holes on the piezoelectric stack structure; and 9, introducing an etchant through the release hole, and etching off only the sacrificial layer to form a cavity in the substrate, the SiC/Diamond thin film layer and the piezoelectric oscillation stack part.
Preferably, the method for preparing the cavity film bulk acoustic resonator capable of improving the Q value provided by the invention can also have the following characteristics: in step 7, the bottom electrode/piezoelectric layer/top electrode is patterned into a polygon or circle.
Action and Effect of the invention
The cavity film bulk acoustic resonator capable of improving the Q value provided by the invention utilizes the characteristics of high transmission rate and high hardness of the SiC/Diamond film layer acoustic wave, can well inhibit the acoustic wave of a transverse vibration mode generated in the piezoelectric film, can reduce the mechanical damping introduced by the soft substrate, reduces the acoustic wave energy loss, reduces the insertion loss of the film bulk acoustic resonator, and obtains high Q value and electromechanical coupling coefficient. Moreover, when the SiC/Diamond film is used as the SiC/Diamond film layer, the thermal conductivity (40W/(m.k)) of the SiC/Diamond film is three times that of silicon, and the SiC/Diamond film is deposited between the bottom electrode and the silicon substrate, so that the temperature of the interconnection node of the FBAR can be increased, the heat dissipation is accelerated, the overheating phenomenon of the cavity type FBAR is relieved, and the thermal stress of the piezoelectric layer and the electrode and the frequency drift caused by the thermal stress are reduced.
Drawings
Fig. 1 is a sectional view (a) and a top view (b) of a cavity film bulk acoustic resonator capable of improving a Q value according to a first embodiment of the present invention;
fig. 2 is a sectional view (a) and a top view (b) of a cavity film bulk acoustic resonator capable of improving a Q value according to a second embodiment of the present invention;
FIG. 3 is a cross-sectional view (a) and a top view (b) of a silicon substrate according to a third embodiment of the present invention;
FIG. 4 is a cross-sectional view (a) and a top view (b) of a SiC/Diamond thin film layer grown in a third embodiment of the present invention;
fig. 5 is a cross-sectional view (a) and a top view (b) of a SiC/Diamond layer etched with a through-hole by an ICP process according to a third embodiment of the present invention;
FIG. 6 is a cross-sectional view (a) and a top view (b) of a silicon substrate after a trench is etched in accordance with a third embodiment of the present invention;
FIG. 7 is a cross-sectional view (a) and a top view (b) of a third embodiment of the present invention after a sacrificial layer is deposited;
FIG. 8 is a cross-sectional view (a) and a top view (b) of a third embodiment of the present invention after polishing a sacrificial layer by CMP;
FIG. 9 is a cross-sectional view (a) and a top view (b) of a bottom electrode metal film deposited according to a third embodiment of the present invention;
FIG. 10 is a cross-sectional view (a) and a top view (b) of a deposited AlN piezoelectric film according to a third embodiment of the present invention;
FIG. 11 is a cross-sectional view (a) and a top view (b) after depositing a top electrode film according to a third embodiment of the present invention;
fig. 12 is a cross-sectional view (a) and a top view (b) of a piezoelectric oscillator stack portion patterned into a hexagonal shape according to a third embodiment of the present invention;
FIG. 13 is a cross-sectional view (a) and a top view (b) of a third embodiment of the present invention after etching a release hole.
Detailed Description
The following describes in detail specific embodiments of the cavity film bulk acoustic resonator and the method for manufacturing the same according to the present invention with reference to the accompanying drawings.
< example one >
As shown in fig. 1, a cavity film bulk acoustic resonator 10 capable of improving Q value provided in the first embodiment includes a substrate 11, a SiC/Diamond film layer 12, and a piezoelectric resonator stack portion 13. The substrate 11 has a recess opened upward in the middle. The SiC/Diamond thin film layer 12 is formed on the substrate, a through hole corresponding to the groove is formed in the middle of the SiC/Diamond thin film layer, and the size of the through hole is consistent with that of the groove. The piezoelectric oscillation stack part 13 is formed on the SiC/Diamond thin film layer 12 and is positioned right above the through hole; piezoelectric oscillation pile part 13 includes from supreme down in proper order: a bottom electrode 13a, a piezoelectric layer 13b, and a top electrode 13 c. The recess on the substrate 11, the through-hole on the SiC/Diamond thin film layer 12, and the piezoelectric oscillator stack portion 13 together enclose a cavity 14. Four release holes 15 are uniformly formed in the piezoelectric oscillating stack portion 13, and the release holes 15 are provided for preparing the cavity 14, which will be described in the third embodiment.
As shown in fig. 1(a), in the first embodiment, the patterned piezoelectric oscillator stack portion 13 is a regular hexagon.
< example two >
As shown in fig. 2, the cavity film bulk acoustic resonator 20 capable of improving the Q value provided in the second embodiment includes a substrate 21, a SiC/Diamond film layer 22, and a piezoelectric oscillator stack portion 23. The substrate 21 has a recess opened upward in the middle. The SiC/Diamond thin film layer 22 is formed on the substrate, a through hole corresponding to the groove is formed in the middle of the SiC/Diamond thin film layer, and the size of the through hole is consistent with that of the groove. The piezoelectric oscillation stack part 23 is formed on the SiC/Diamond thin film layer 22 and is positioned right above the through hole; piezoelectric oscillation pile part 23 includes from bottom to top in proper order: a bottom electrode 23a, a piezoelectric layer 23b, and a top electrode 23 c. The recess on the substrate 21, the through-hole on the SiC/Diamond thin film layer 22, and the piezoelectric oscillator stack portion 23 together enclose a cavity 24. Four release holes 25 are uniformly formed on the piezoelectric oscillating stack portion 23, and the release holes 25 are provided for preparing the cavity 24.
As shown in fig. 2(a), in the second embodiment, the patterned piezoelectric oscillator unit 13 is circular.
< example three >
The third embodiment provides a method for manufacturing a cavity film bulk acoustic resonator capable of improving a Q value, where the resonator in the first embodiment is taken as an example for description, and the method specifically includes the following steps:
1) as shown in fig. 3, a silicon substrate 11 is prepared;
2) as shown in fig. 4, a SiC/Diamond thin film layer 12 is grown on a silicon substrate 11;
3) as shown in fig. 5, a predetermined through hole 12a is etched in the SiC/Diamond thin film layer 12:
4) as shown in fig. 6, a predetermined groove 11a is etched on the silicon substrate 11;
5) as shown in fig. 7, a sacrificial layer a is deposited on the SiC/Diamond thin film layer 12 and in the groove 11a, and the chemical property of the material of the sacrificial layer a is different from that of the silicon substrate 11, so as to ensure that the substrate is not affected during subsequent etching;
6) as shown in fig. 8, the excess sacrificial layer a material is removed by using a chemical mechanical polishing technique, so that the sacrificial layer a material just fills the grooves 11a and the through holes 12a on the silicon substrate 11 and the SiC/Diamond thin film layer 12;
7) as shown in fig. 9 to 11, a bottom electrode 13a, a piezoelectric film 13b and a top electrode 13c are sequentially deposited on the SiC/Diamond thin film layer 12 and the sacrificial layer a to form a piezoelectric oscillation stack part 13;
8) as shown in fig. 12, the piezoelectric oscillator stack portion 13 is patterned into a hexagon;
9) as shown in fig. 13, a release hole 15 is etched on the piezoelectric oscillation stack portion 13;
10) as shown in fig. 1, the sacrificial layer a is completely etched away by introducing an etchant or an etchant gas through the release holes, thereby forming the cavity 14.
The above embodiments are merely illustrative of the technical solutions of the present invention. The cavity film bulk acoustic resonator and the method for manufacturing the same according to the present invention are not limited to the description of the embodiments above, but the scope of the invention is defined by the claims. Any modification or supplement or equivalent replacement made by a person skilled in the art on the basis of this embodiment is within the scope of the invention as claimed in the claims.

Claims (5)

1. A cavity film bulk acoustic resonator capable of improving Q value, comprising:
a substrate, the middle part of which is provided with a groove which is opened upwards;
the SiC/Diamond thin film layer is formed on the substrate, and the middle part of the SiC/Diamond thin film layer is provided with a through hole corresponding to the groove; and
piezoelectric oscillation pile portion, form on the SiC/Diamond thin film layer to be located directly over the through-hole, from supreme down include in proper order: a bottom electrode, a piezoelectric layer, and a top electrode,
wherein the bottom electrode/the piezoelectric layer/the top electrode are patterned into a polygon or a circle, and the size of the through opening is consistent with that of the groove.
2. The improved Q-factor cavity film bulk acoustic resonator of claim 1, wherein:
wherein the substrate is a silicon or sapphire substrate.
3. The improved Q-factor cavity film bulk acoustic resonator of claim 1, wherein:
the bottom electrode and the top electrode are both metal films, and the metal films are any one of molybdenum films, platinum films, gold films, silver films and tungsten films.
4. The improved Q-factor cavity film bulk acoustic resonator of claim 1, wherein:
wherein, the piezoelectric layer adopts any one of AlN, ZnO and PZT piezoelectric films with C-axis orientation.
5. The method for manufacturing a cavity film bulk acoustic resonator capable of improving a Q-value according to any one of claims 1 to 4, comprising the steps of:
step 1, depositing a SiC/Diamond thin film layer on a substrate;
step 2, etching a preset through hole on the SiC/Diamond thin film layer;
step 3, etching a preset groove on the substrate, wherein the size of the groove corresponds to that of the through hole;
step 4, depositing a sacrificial layer on the SiC/Diamond thin film layer, wherein the chemical property of the sacrificial layer is different from that of the substrate, and the subsequent corrosion is guaranteed without influencing the substrate;
step 5, removing the redundant sacrificial layer by using a chemical mechanical polishing technology, so that the sacrificial layer just fills the groove and the through hole;
step 6, sequentially depositing a bottom electrode, a piezoelectric film and a top electrode on the SiC/Diamond thin film layer and the sacrificial layer to form a piezoelectric oscillation stack part;
step 7, patterning the bottom electrode/the piezoelectric layer/the top electrode;
step 8, etching a release hole on the piezoelectric oscillation stack part;
step 9, introducing an etchant through the release hole, etching off only the sacrificial layer, forming a cavity in the substrate, the SiC/Diamond thin film layer and the piezoelectric oscillation stack part,
wherein, in step 7, the bottom electrode/the piezoelectric layer/the top electrode is patterned into a polygon or a circle.
CN201811271504.1A 2018-10-29 2018-10-29 Cavity film bulk acoustic resonator capable of improving Q value and preparation method thereof Active CN109474252B (en)

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