CN109456845A - A kind of preparation and its application of multifunctinal antiradiation impregnated wipe - Google Patents
A kind of preparation and its application of multifunctinal antiradiation impregnated wipe Download PDFInfo
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- CN109456845A CN109456845A CN201811295125.6A CN201811295125A CN109456845A CN 109456845 A CN109456845 A CN 109456845A CN 201811295125 A CN201811295125 A CN 201811295125A CN 109456845 A CN109456845 A CN 109456845A
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- radiation protection
- auxiliary agent
- impregnated wipe
- oleophobic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/16—Paper towels; Toilet paper; Holders therefor
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/16—Anti-static materials
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses the preparations and its application of a kind of multifunctinal antiradiation impregnated wipe, belong to impregnated wipe technical field.The radiation protection impregnated wipe is prepared by 31~69 parts of radiation protection and oleophobic auxiliary agent, 2~6 parts of dispersing agent, 45~75 parts of surfactant and 850~922 parts of solvent soaking non-woven cotton, using the surface after the wet tissue cleaning being prepared with edible oil contact angle up to 128 °, oleophobic effects can be kept 3 days or more；And its radiation protection efficiency is up to 95%, and radiation protection, antistatic effect can at least be kept 5 days, just meet a cleaning cycle, and it ensure that radiation proof function continues to play longer within the period, impregnated wipe prepared by the present invention has its excellent radiation protection, antistatic and oleophobic anti-pollution function, it reduces costs, more meets environmental requirement.
Description
Technical field
The present invention relates to the preparations and its application of a kind of multifunctinal antiradiation impregnated wipe, belong to impregnated wipe technology neck
Domain.
Background technique
In the information age, intelligence science and technology greatly affected the life of modern, people be also increasingly difficult to from
Convenience and real-time brought by electronic product are opened, but this also results in people to fast food information carrier --- the mistake of electronic equipment
Degree relies on.In addition, electronic equipment inherently exists, amount of radiation is big, easily produces electrostatic, damages the problems such as eyesight, this makes modern's
Physical and mental health cannot be neglected influence.When human body is chronically at static radiation, anxiety, headache, palpitation, chest are easily generated
Bored equal malaise symptoms.Therefore electromagnetic radiation caused by prevention and insulating electron equipment is for optimizing the working environment of modern, mentioning
High quality of the life has great importance.
For people during using electronic equipment, since hand is easily perspired fuel-displaced, electronic equipment is also easy to produce static electricity, therefore
Over time will adhesive dust, sweat stain and greasy dirt etc. on an electronic device, add demand of the people to electromagnetic radiation protection
Promotion, just produce therewith in the market it is some dedicated for clean electronic product screen detergents, but these detergents only
It can be used for screen surface, there is certain limitation.Chinese patent CN106544172A " radiation-proof anti-static screen detergent and its
Preparation method ", formula are as follows: 100~130 parts of antiradiation agent, 100~120 parts of cactus extraction, anionic antistatic agents
105~125 parts, 46~56 parts of neopelex, 39~49 parts of fatty alcohol polyoxyethylene ether, dimethyl ether 24
~34 parts, 33~43 parts of wetting agent, 26~36 parts of disodium ethylene diamine tetraacetate, 23~33 parts of imidazoline, chitosan carboxylate 21
~31 parts, 17~27 parts of decylene glycol ester, 14~24 parts of ethylene glycol, 32~42 parts of gardenia perfume compound and deionized water 130~150
Part, wherein the group of the antiradiation agent is divided into the polypropylene of boron doping 30%；But such formula film forming is thicker, and is not easy to do
It is dry, and then it is unfavorable for antifouling, it can be only applied to the plane of larger amplitude, surface cleaning power rough for keyboard etc. is limited.
Summary of the invention
Based on the above issues, the invention proposes a kind of multifunctinal antiradiation impregnated wipe, impregnated wipe of the invention is not
It is same as the form of similar product in the market, but the spot on electronic equipment is carried out using surfactant and environmentally friendly solvent
Removing and dissolution realize thoroughly wrapping and cleaning to uneven surface by flexibility and the stickiness of wet tissue, and volatilize
Fast speed, the surface after guaranteeing cleaning while facilitating decontamination can relatively quickly form one layer of nanoscale radiation protection and dredge
Oily film, to meet decontamination of the people to electronic equipment, antifouling and radiation protection demand.
Firstly, the present invention provides a kind of cleaning solutions for being used to prepare impregnated wipe, and by weight, the cleaning solution packet
Include 31~69 parts of radiation protection and oleophobic auxiliary agent, 2~6 parts of dispersing agent, 45~75 parts of surfactant and 850~922 parts
Solvent, wherein the radiation protection and oleophobic auxiliary agent include acetic acid, nano silicon dioxide sol, nano-cerium oxide, nano oxidized
Antimony tin, Kynoar and phenolic resin, the dispersing agent are polypropylene glycol -2000, and the surfactant includes isomery ten
Triol polyoxyethylene ether TO-7 and coconut fatty acid diethanolamine, the solvent are water, ethyl alcohol, n-propyl acetate and Methylethyl
Ketone.
In one embodiment of the invention, in the radiation protection and oleophobic auxiliary agent, acetic acid, nano silica are molten
Glue, nano-cerium oxide, nanometer antimony oxide tin, Kynoar and phenolic resin account for 1~3 part, 3~7 parts, 2~5.5 parts, 4 respectively
~8.5 parts, 9~20 parts, 12~25 parts.
In one embodiment of the invention, in the surfactant, isomerous tridecanol polyoxyethylene ether TO-7 and
Coconut fatty acid diethanolamine accounts for 20~35 parts, 25~40 parts respectively.
In one embodiment of the invention, in the solvent, water, ethyl alcohol, n-propyl acetate and methyl ethyl ketone point
340~360 parts, 260~280 parts, 170~190 parts, 80~92 parts are not accounted for.
Secondly, the wet tissue is that non-woven fabrics dipping is above-mentioned the present invention also provides a kind of multifunctinal antiradiation impregnated wipe
Cleaning solution forms, wherein the liquid content of wet tissue is 200%~360%.
In one embodiment of the invention, the non-woven fabrics is preferably non-woven cotton.
In one embodiment of the invention, the grammes per square metre of the non-woven cotton is 35~70g/m2。
Third, the present invention provides a kind of preparation method of multifunctinal antiradiation impregnated wipe, the methods are as follows:
(1) 30~66 parts of radiation protection in addition to acetic acid is sequentially added in a reservoir and oleophobic auxiliary agent and is stirred evenly, then
2~6 parts of dispersing agent and 45~75 parts of surfactant is added, 850~922 parts of solvent is added later and stirs together, most
1~3 part of acetic acid is added afterwards and stirs evenly, obtains colourless to light yellow translucent solution；
(2) Collator Mode for using an immersing and rolling, is soaked in 3~5min in solution for non-woven cotton, then to roll
Vehicle, which is crossed, to be rolled, and makes pick-up control 200%~360%, and the non-woven fabrics padded is then cut into required specification again, is sealed
Packaging.
In one embodiment of the invention, the bag material in the packaging has≤2.0g/ (hm2) it is saturating
Wet rate.
In one embodiment of the invention, described to remove in a kind of preparation method of multifunctinal antiradiation impregnated wipe
Radiation protection and oleophobic auxiliary agent outside acetic acid are according to micron order radiation protection and oleophobic auxiliary agent and nanoscale radiation protection and oleophobic auxiliary agent
Sequencing addition, wherein micron order radiation protection and oleophobic auxiliary agent include Kynoar and phenolic resin, nanoscale radiation protection
And oleophobic auxiliary agent includes nano silicon dioxide sol, nano-cerium oxide and nanometer antimony oxide tin.
In one embodiment of the invention, the order of addition between Kynoar and phenolic resin is unlimited；Nanometer
Silicon dioxide gel, nano-cerium oxide, the order of addition between nanometer antimony oxide tin are unlimited.
In one embodiment of the invention, the water is deionized water.
It is that the present invention obtains the utility model has the advantages that
1, multifunctinal antiradiation impregnated wipe of the invention, wherein the environment-friendly type solvent based on water is not only reduced into
This, more meets environmental requirement；The clean effect of the wet tissue be by the release effect of surfactant, the dissolution of solvent,
What the mechanism of wet tissue itself was realized jointly, various surfactants, the eurythmy of solvent are extremely important, solvent i.e. go from
There is synergetic, obtained by its individually a kind of or other ratios between sub- water, ethyl alcohol, n-propyl acetate and methyl ethyl ketone
Wet tissue, clean effect will substantially reduce, similarly between isomerous tridecanol polyoxyethylene ether and coconut fatty acid diethanolamine
With synergetic.
2, multifunctinal antiradiation impregnated wipe of the invention, after the use of electronic equipment surface, surface after cleaning with
Up to 128 °, oleophobic effects can be kept 3 days or more edible oil contact angle；And its radiation protection efficiency is up to 95%, and radiation protection, anti-
Electrostatic efficiency can at least be kept 5 days, meet a cleaning cycle just, and ensure that radiation proof function is persistently grown within the period
Effect ground plays.
3, multifunctinal antiradiation impregnated wipe of the invention, radiation protection, antistatic, oleophobic anti-fouling effect realization depend on
Ratio is proper between its radiation protection and oleophobic auxiliary agent, cooperates with the effect promoted: firstly, during the preparation process, sequentially adding
Kynoar, phenolic resin and nano silicon dioxide sol, nano-cerium oxide, nanometer antimony oxide tin etc., after mixing evenly,
Constitute uniform solid phase, even if being dissolved in solvent overall situation then, they also can with micron-sized even particulate dispersion in
In liquid phase；Secondly as micron order macromolecular structure carrier, nano silica provided by Kynoar, phenolic resin
The nano-scale particles such as colloidal sol, nano-cerium oxide, nanometer antimony oxide tin are finally embedding to be invested wherein, in addition the acid effect of acetic acid, makes
It is dissolved to obtain part nano-cerium oxide, nanometer antimony oxide tin, so that it is tiny to form nanoscale on macromolecular structure carrier
Micropore has finally constituted coarse micro nano structure, so obtaining preferable oleophobic anti-pollution；In addition, trivalent cerium and receiving
Rice antimony tin itself be with radiation protection performance, when they uniformly it is embedding invest on macromolecular structure carrier when, radiation protection
Performance has obtained more fully playing, and unexpectedly obtains antistatic property；To sum up, of the invention multi-functional anti-
Radiate impregnated wipe, possessed good synergistic function between the main components such as radiation protection and oleophobic auxiliary agent, solvent
And stringent addition and reaction sequence in preparation process, its excellent radiation protection, antistatic and oleophobic anti-pollution function are imparted,
To realize the exploitation vision of product, the market demand is greatly met.
Specific embodiment
The neutral silica solution of nanometer: Jinan Xin Yi Chemical Co., Ltd. provides；
Nano-cerium oxide: Suzhou Kang Peng Chemical Co., Ltd. provides；
Nanometer antimony oxide tin: Jiangsu Tian Hang new material Co., Ltd provides.
Performance test:
It tests pre-treatment: preparing the clean keyboard of several same brand styles, it is ensured that clean level phase of all keyboards itself
When vaseline and water, NaCl, dust being uniformly mixed with the mass ratio of 4:14:1:1, simulation human body oil sweat spot are made, with dry
The simulation spot that dry rag dips 5mL respectively is evenly coated on each keyboard, naturally dry 2h.Then with corresponding embodiment or
Wet tissue made from the formula of reference examples wipes and cleans each keyboard, and method is tiling wet tissue on the left of keyboard, opens from this
Unidirectional wiping to the right begin to upper keyboard, dynamics control is advisable without blocking when taking advantage of a situation and pressing the button to right translation, speed
Control is about unidirectionally being wiped with 5s once, is in this way wiped each keyboard 5 times, as cleaning terminates.
1, it radiation protection and antistatic property test: is measured with electro-magnetic wave absorption efficiency, radiation protection efficiency, surface resistivity
The radiation protection of impregnated wipe and antistatic property are tested after using wet tissue 3min, electro-magnetic wave absorption efficiency, radiation protection efficiency
Test method measures surface resistivity referring to SJ20524-1995, and with 189 type digital multimeter of VICTOR.
2, oleophobic performance test: measuring the oleophobic performance of impregnated wipe with contact angle, surveys after using wet tissue 3min
Examination, used the surface of impregnated wipe and connecing for soybean oil specifically by KRUSS DSA100 type Drop Shape Analyzer measurement
Feeler.
3, cleaning effect is evaluated: being evaluated group by five people's composition described above, is carried out visual evaluation, it is specified that 5 grades best, 1 grade most
Difference.All keyboards cleaned are listed in together first, primary election is carried out by the worst exclusion of a part of cleaning effect and is chosen as 1
Grade, after primary election, then selects a wheel, is chosen as 2 grades, and remaining keyboard is carried out arranged in sequence, obtains 3 to 5 grades, finally calculates average
Value.
Embodiment 1
Sequentially add in a reservoir 14.5 parts of Kynoar, 16.5 parts of phenolic resin, 6 parts of nano silicon dioxide sols,
4.5 parts of nano-cerium oxides, 6.5 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts of polypropylene glycols -2000,27 parts of isomeries ten
86 parts of methyl ethyl ketones, 180 parts of acetic acid are being added just later in triol polyoxyethylene ether TO-7 and 33 parts of coconut fatty acid diethanolamines
Propyl ester, 270 parts of ethyl alcohol, 350 parts of deionized waters stir together, are eventually adding 2 parts of acetic acid and stir evenly, obtain colourless to shallow
The translucent solution of yellow；Using the Collator Mode of an immersing and rolling, by non-woven cotton (grammes per square metre 40g/m2) be soaked in it is molten
5min in liquid, then crossed and rolled with padding machine, and make pick-up control 250%~300%, then the non-woven fabrics padded is cut again
At required specification, sealed package (can make bag material have≤2.0g/ (hm2) rate of perviousness).
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has good removal effect, and cleaning effect grading reaches 4.8 grades；Its electromagnetic wave (50Hz
~25.6GHz) absorption efficiency is 3.5~14.8dB, and theoretically radiation protection efficiency is 95% or more, and surface resistivity is 1.86 ×
109Ω, the surface and edible oil contact angle after cleaning are up to 128 °.
Embodiment 2
16 parts of phenolic resin, 15 parts of Kynoar, 6.25 parts of nanometer antimony oxide tin, 5.75 parts are sequentially added in a reservoir
Nano silicon dioxide sol, 5 parts of nano-cerium oxides, stir evenly, and add 4 parts of polypropylene glycols -2000,27.5 parts of isomeries 13
85 parts of methyl ethyl ketones, 178 parts of acetic acid are being added just later in alcohol polyoxyethylene ether TO-7 and 32.5 parts of coconut fatty acid diethanolamines
Propyl ester, 273 parts of ethyl alcohol, 350 parts of deionized waters stir together, are eventually adding 2 parts of acetic acid and stir evenly, obtain colourless to shallow
The translucent solution of yellow；Using the Collator Mode of an immersing and rolling, by non-woven cotton (grammes per square metre 65g/m2) be soaked in it is molten
5min in liquid, then crossed and rolled with padding machine, and make pick-up control 250%~300%, then the non-woven fabrics padded is cut again
At required specification, sealed package (can make bag material have≤2.0g/ (hm2) rate of perviousness).
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has good removal effect, and cleaning effect grading reaches 4.6 grades；Its electromagnetic wave (50Hz
~25.6GHz) absorption efficiency is 3.8~15.2dB, and theoretically radiation protection efficiency is 95% or more, and surface resistivity is 1.82 ×
109Ω, the surface and edible oil contact angle after cleaning are up to 125 °.
Embodiment 3
14.75 parts of Kynoar, 16.25 parts of phenolic resin, 5.75 parts of nano silicas are sequentially added in a reservoir
Colloidal sol, 4.75 parts of nano-cerium oxides, 6.5 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts of polypropylene glycols -2000,27.5
Part isomerous tridecanol polyoxyethylene ether TO-7 and 32.75 parts of coconut fatty acid diethanolamines, be added later 85 parts of methyl ethyl ketones,
180 portions of n-propyl acetates, 270.5 parts of ethyl alcohol, 350 parts of deionized waters stir together, are eventually adding 2.25 parts of acetic acid and stirring
Uniformly, colourless to light yellow translucent solution is obtained；Using the Collator Mode of an immersing and rolling, by non-woven cotton (grammes per square metre
For 55g/m2) it is soaked in 5min in solution, then crossed and rolled with padding machine, and make pick-up control 250%~300%, then again will
The non-woven fabrics padded is cut into required specification, and sealed package (can make bag material have≤2.0g/ (hm2) it is saturating
Wet rate).
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has good removal effect, and cleaning effect grading reaches 5.0 grades；Its electromagnetic wave (50Hz
~25.6GHz) absorption efficiency is 3.6~15.0dB, and theoretically radiation protection efficiency is 95% or more, and surface resistivity is 1.84 ×
109Ω, the surface and edible oil contact angle after cleaning are up to 127 °.
Reference examples 1
Sequentially add in a reservoir 8.5 parts of Kynoar, 8.5 parts of phenolic resin, 9.75 parts of nano silicon dioxide sols,
9.75 parts of nano-cerium oxides, 9.5 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts of polypropylene glycols -2000,27.5 parts of isomeries
85 parts of methyl ethyl ketones, 180 portions of vinegar are added in tridecanol polyoxyethylene ether TO-7,32.75 parts of coconut fatty acid diethanolamines later
Sour n-propyl, 270.5 parts of ethyl alcohol, 350 parts of deionized waters stir together, are eventually adding 4.25 parts of acetic acid and stir evenly, obtain
To colourless to light yellow translucent solution；Using the Collator Mode of an immersing and rolling, by non-woven cotton (grammes per square metre 55g/
m2) it is soaked in 5min in solution, then crossed and rolled with padding machine, and make pick-up control 250%~300%, then it will pad again
Non-woven fabrics be cut into required specification, sealed package (can make bag material have≤2.0g/ (hm2) rate of perviousness).
Compared with Example 3, the proportion of radiation protection and oleophobic auxiliary agent is different, and other compositions are identical as proportion for reference examples 1.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has preferable removal effect, and cleaning effect grading reaches 4.2 grades；Its electromagnetic wave (50Hz
~25.6GHz) absorb efficiency only have 0.5~1.8dB, surface resistivity is up to 1.43 × 1013Ω, surface after cleaning and edible
Oily contact angle only has 96 °, therefore radiation protection, antistatic and oleophobic performance are poor.
Reference examples 2
It is molten that 9.75 parts of Kynoar, 10.75 parts of phenolic resin, 9.75 parts of nano silicas are sequentially added in a reservoir
Glue, 9.75 parts of nano-cerium oxides, 9.75 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts of polypropylene glycols -2000,27.5 parts
85 parts of methyl ethyl ketones, 180 are added in isomerous tridecanol polyoxyethylene ether TO-7,32.75 parts of coconut fatty acid diethanolamines later
Part n-propyl acetate, 270.5 parts of ethyl alcohol, 350 parts of deionized waters stir together, and last 0.5 part of acetic acid simultaneously stirs evenly, and obtains
Colourless to light yellow translucent solution；Using the Collator Mode of an immersing and rolling, by non-woven cotton (grammes per square metre 55g/m2)
It is soaked in 5min in solution, then is crossed and is rolled with padding machine, and makes pick-up control 250%~300%, the nothing that then will be padded again
Woven fabric is cut into required specification, and sealed package (can make bag material have≤2.0g/ (hm2) rate of perviousness).
Compared with Example 3, the proportion of radiation protection and oleophobic auxiliary agent is different, and other compositions are identical as proportion for reference examples 2.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has preferable removal effect, and cleaning effect grading reaches 4.2 grades；Its electromagnetic wave (50Hz
~25.6GHz) absorb efficiency have 1.2~7.5dB, surface resistivity is up to 6.58 × 1012Ω, surface and edible oil after cleaning
Contact angle only has 89 °, therefore radiation protection, antistatic property are general, oleophobic poor performance.
Reference examples 3
14.75 parts of Kynoar, 16.25 parts of phenolic resin, 5.75 parts of nano silicas are sequentially added in a reservoir
Colloidal sol, 4.75 parts of carbon nanotubes, 6.5 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts of polypropylene glycols -2000,27.5 parts
85 parts of methyl ethyl ketones, 180 are added in isomerous tridecanol polyoxyethylene ether TO-7,32.75 parts of coconut fatty acid diethanolamines later
Part n-propyl acetate, 270.5 parts of ethyl alcohol, 350 parts of deionized waters stir together, are eventually adding 2.25 parts of acetic acid and stir equal
It is even, obtain colourless to light yellow translucent solution；Using the Collator Mode of an immersing and rolling, by non-woven cotton, (grammes per square metre is
55g/m2) it is soaked in 5min in solution, then crossed and rolled with padding machine, and make pick-up control 250%~300%, it then again will leaching
The non-woven fabrics rolled is cut into required specification, and sealed package (can make bag material have≤2.0g/ (hm2) moisture-inhibiting
Rate).
Compared with Example 3, nano-cerium oxide has been replaced by carbon nanotube to reference examples 3, and other compositions are identical as proportion.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has preferable removal effect, and cleaning effect grading reaches 4.3 grades；Its electromagnetic wave (50Hz
~25.6GHz) absorb efficiency only have 0.05~0.6dB, surface resistivity is up to 1.46 × 1013Ω, surface and food after cleaning
There are 114 ° with oily contact angle, therefore radiation protection, antistatic property are very poor, oleophobic performance is general.
Reference examples 4
14.75 parts of Kynoar, 16.25 parts of phenolic resin, 5.75 parts of nano silicas are sequentially added in a reservoir
Colloidal sol, 4.75 parts of nano-cerium oxides, 6.5 parts of nanometer antimony oxide tin, stir evenly, and add 00,27.5 part of 4 parts of polyethylene glycol-8
85 parts of methyl ethyl ketones, 180 are added in isomerous tridecanol polyoxyethylene ether TO-7,32.75 parts of coconut fatty acid diethanolamines later
Part n-propyl acetate, 270.5 parts of ethyl alcohol, 350 parts of deionized waters stir together, are eventually adding 2.25 parts of acetic acid and stir equal
It is even, obtain colourless to light yellow translucent solution；Using the Collator Mode of an immersing and rolling, by non-woven cotton, (grammes per square metre is
55g/m2) it is soaked in 5min in solution, then crossed and rolled with padding machine, and make pick-up control 250%~300%, it then again will leaching
The non-woven fabrics rolled is cut into required specification, and sealed package (can make bag material have≤2.0g/ (hm2) moisture-inhibiting
Rate).
Compared with Example 3, polypropylene glycol -2000 has been replaced by polyethylene glycol-8 00, other compositions and proportion to reference examples 4
It is identical.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has preferable removal effect, and cleaning effect grading reaches 4.0 grades；Its electromagnetic wave (50Hz
~25.6GHz) absorption efficiency is 1.8~8.4dB, surface resistivity reaches 4.92 × 1012Ω, surface and edible oil after cleaning
Contact angle only has 93 °, therefore shielding property is general, and antistatic and oleophobic performance is poor.
Reference examples 5
14.75 parts of Kynoar, 16.25 parts of phenolic resin, 5.75 parts of nano silicas are sequentially added in a reservoir
Colloidal sol, 4.75 parts of nano-cerium oxides, 6.5 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts of polypropylene glycols -2000,37.5
Part isomerous tridecanol polyoxyethylene ether TO-7,22.75 parts of coconut fatty acid diethanolamines, be added later 85 parts of methyl ethyl ketones,
180 portions of n-propyl acetates, 270.5 parts of ethyl alcohol, 350 parts of deionized waters stir together, are eventually adding 2.25 parts of acetic acid and stirring
Uniformly, colourless to light yellow translucent solution is obtained；Using the Collator Mode of an immersing and rolling, by non-woven cotton (grammes per square metre
For 55g/m2) it is soaked in 5min in solution, then crossed and rolled with padding machine, and make pick-up control 250%~300%, then again will
The non-woven fabrics padded is cut into required specification, and sealed package (can make bag material have≤2.0g/ (hm2) it is saturating
Wet rate).
Compared with Example 3, the proportion of surfactant is different, and other compositions are identical as proportion for reference examples 5.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt only 2.5 grades of cleaning effect grading, needs to apply larger friction and makees as the removal effect of dust, sweat stain, greasy dirt etc.
Firmly can just it clean；Its electromagnetic wave (50Hz~25.6GHz) absorb efficiency be 2.3~11.0dB, surface resistivity be 8.11 ×
1010Ω, surface and edible oil contact angle after cleaning have 117 °.
Reference examples 6
14.75 parts of Kynoar, 16.25 parts of phenolic resin, 5.75 parts of nano silicas are sequentially added in a reservoir
Colloidal sol, 4.75 parts of nano-cerium oxides, 6.5 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts of polypropylene glycols -2000,27.5
Part isomerous tridecanol polyoxyethylene ether TO-7,32.75 parts of triethanolamines, are being added 85 parts of methyl ethyl ketones, 180 parts of acetic acid just later
Propyl ester, 270.5 parts of ethyl alcohol, 350 parts of deionized waters stir together, are eventually adding 2.25 parts of acetic acid and stir evenly, obtain nothing
Color is to light yellow translucent solution；Using the Collator Mode of an immersing and rolling, by non-woven cotton (grammes per square metre 55g/m2) leaching
The 5min in solution is steeped, then is crossed and is rolled with padding machine, and makes pick-up control 250%~300%, the nonwoven that then will be padded again
Cloth is cut into required specification, and sealed package (can make bag material have≤2.0g/ (hm2) rate of perviousness).
Compared with Example 3, coconut fatty acid diethanolamine has been replaced by triethanolamine to reference examples 6, other compositions with match
Than identical.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has preferable removal effect, and cleaning effect is rated 3.8 grades, but to copper, aluminium, screen protection
There is larger corrosivity on the surfaces such as film；It is 2.0~10.5dB, surface resistivity that its electromagnetic wave (50Hz~25.6GHz), which absorbs efficiency,
It is 1.29 × 1011Ω, surface and edible oil contact angle after cleaning have 115 °.
Reference examples 7
14.75 parts of Kynoar, 16.25 parts of phenolic resin, 5.75 parts of nano silicas are sequentially added in a reservoir
Colloidal sol, 4.75 parts of nano-cerium oxides, 6.5 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts of polypropylene glycols -2000,27.5
Part isomerous tridecanol polyoxyethylene ether TO-7,32.75 parts of coconut fatty acid diethanolamines, be added later 255 parts of methyl ethyl ketones,
280 portions of n-propyl acetates, 280.5 parts of ethyl alcohol, 70 parts of deionized waters stir together, are eventually adding 2.25 parts of acetic acid and stir equal
It is even, obtain colourless to light yellow translucent solution；Using the Collator Mode of an immersing and rolling, by non-woven cotton, (grammes per square metre is
55g/m2) it is soaked in 5min in solution, then crossed and rolled with padding machine, and make pick-up control 250%~300%, it then again will leaching
The non-woven fabrics rolled is cut into required specification, and sealed package (can make bag material have≤2.0g/ (hm2) moisture-inhibiting
Rate).
Compared with Example 3, solvent burden ratio is different for reference examples 7, and other compositions are identical as proportion.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt is as the removal effect of dust, sweat stain, greasy dirt etc., and only 2.8 grades of cleaning effect grading, and it is also easy to produce residual；Its electricity
It is 1.0~6.25dB that magnetic wave (50Hz~25.6GHz), which absorbs efficiency, and surface resistivity is 2.85 × 1010Ω, the surface after cleaning
There are 110 ° with edible oil contact angle, therefore radiation protection, antistatic and oleophobic performance are general.
Reference examples 8
14.75 parts of Kynoar, 16.25 parts of phenolic resin, 5.75 parts of nano silicas are sequentially added in a reservoir
Colloidal sol, 4.75 parts of nano-cerium oxides, 6.5 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts of polypropylene glycols -2000,27.5
Part isomerous tridecanol polyoxyethylene ether TO-7,32.75 parts of coconut fatty acid diethanolamines, be added later 85 parts of methyl ethyl ketones,
180 parts of ethyl acetates, 270.5 parts of ethyl alcohol, 350 parts of deionized waters stir together, are eventually adding 2.25 parts of acetic acid and stir equal
It is even, obtain colourless to light yellow translucent solution；Using the Collator Mode of an immersing and rolling, by non-woven cotton, (grammes per square metre is
55g/m2) it is soaked in 5min in solution, then crossed and rolled with padding machine, and make pick-up control 250%~300%, it then again will leaching
The non-woven fabrics rolled is cut into required specification, and sealed package (can make bag material have≤2.0g/ (hm2) moisture-inhibiting
Rate).
Compared with Example 3, n-propyl acetate has been replaced by ethyl acetate to reference examples 8, and other compositions are identical as proportion.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has certain removal effect, and cleaning effect is rated 3.6 grades, but has slightly to certain materials
Corrosion；It is 2.1~10.5dB that its electromagnetic wave (50Hz~25.6GHz), which absorbs efficiency, but surface resistivity is up to 4.35 × 1012
Ω, surface and edible oil contact angle after cleaning have 112 °, therefore radiation protection and oleophobic performance are general, and antistatic property is poor.
Reference examples 9
2.25 parts of acetic acid, 14.75 parts of Kynoar, 16.25 parts of phenolic resin, 5.75 parts are sequentially added in a reservoir
Nano silicon dioxide sol, 4.75 parts of nano-cerium oxides, 6.5 parts of nanometer antimony oxide tin, stir evenly, and add 4 parts poly- the third two
Alcohol -2000,27.5 parts of isomerous tridecanol polyoxyethylene ether TO-7,32.75 parts of coconut fatty acid diethanolamines are added 85 parts later
Methyl ethyl ketone, 180 portions of n-propyl acetates, 270.5 parts of ethyl alcohol, 350 parts of deionized waters, obtain after mixing evenly completely it is colourless extremely
Light yellow translucent solution；Using the Collator Mode of an immersing and rolling, by non-woven cotton (grammes per square metre 55g/m2) be soaked in
5min in solution, then crossed and rolled with padding machine, and make pick-up control 250%~300%, then the non-woven fabrics padded is cut out again
It is cut into required specification, sealed package (can make bag material have≤2.0g/ (hm2) rate of perviousness).
Compared with Example 3, the order of addition of acetic acid changes reference examples 9, remaining is consistent with embodiment 3.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has good removal effect, and cleaning effect grading reaches 4.5 grades；Its electromagnetic wave (50Hz~
25.6GHz) absorbing efficiency is 1.5~6.7dB, and surface resistivity is up to 3.27 × 1012Ω, the surface after cleaning connect with edible oil
Feeler only has 95 °, therefore shielding property is general, and antistatic and oleophobic performance is poor.
Reference examples 10
Sequentially add in a reservoir 5.75 parts of nano silicon dioxide sols, 4.75 parts of nano-cerium oxides, 6.5 parts it is nano oxidized
Antimony tin, 14.75 parts of Kynoar, 16.25 parts of phenolic resin, stir evenly, and add 4 parts of polypropylene glycols -2000,27.5 parts
85 parts of methyl ethyl ketones, 180 are added in isomerous tridecanol polyoxyethylene ether TO-7,32.75 parts of coconut fatty acid diethanolamines later
Part n-propyl acetate, 270.5 parts of ethyl alcohol, 350 parts of deionized waters, add 2.25 parts of acetic acid and stirring after mixing evenly completely
For several times, colourless to light yellow translucent solution is obtained；Using the Collator Mode of an immersing and rolling, by non-woven cotton (grammes per square metre
It is soaked in 5min in solution for 55g/m2), then is crossed and is rolled with padding machine, and makes pick-up control 250%~300%, then again will
The non-woven fabrics padded is cut into required specification, sealed package can (make bag material have≤2.0g/ (hm2) it is saturating
Wet rate).
Reference examples 9 compared with Example 3, micron order radiation protection and oleophobic in the radiation protection and oleophobic auxiliary agent in addition to acetic acid
The order of addition of auxiliary agent and nanoscale radiation protection and oleophobic auxiliary agent changes, remaining is consistent with embodiment 3.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has good removal effect, and cleaning effect grading reaches 4.8 grades；Its electromagnetic wave (50Hz~
25.6GHz) absorbing efficiency is 2.2~10.4dB, and surface resistivity is 6.35 × 109Ω, the surface after cleaning connect with edible oil
Feeler only has 107 °, therefore shielding property is general, and antistatic and oleophobic performance is poor.
Reference examples 11
It is not added with acetic acid herein, remaining step and condition and embodiment 3 are unanimously.
Test: the overwhelming majority on gained radiation protection wet tissue electronic equipments various for screen, keyboard, mouse, sound equipment etc.
Dirt such as dust, sweat stain, greasy dirt etc. has good removal effect, and cleaning effect grading reaches 4.8 grades；Its electromagnetic wave (50Hz~
25.6GHz) absorbing efficiency is 1.8~8.7dB, and surface resistivity is 7.46 × 1012Ω, the surface after cleaning are contacted with edible oil
Angle only has 88 °, therefore shielding property is general, and antistatic and oleophobic performance is poor.
Although the present invention has been described by way of example and in terms of the preferred embodiments, it is not intended to limit the invention, any to be familiar with this skill
The people of art can do various change and modification, therefore protection model of the invention without departing from the spirit and scope of the present invention
Enclosing subject to the definition of the claims.
Claims (10)
1. a kind of cleaning solution for being used to prepare impregnated wipe, which is characterized in that by weight, the cleaning solution includes 31~69
The radiation protection of part and oleophobic auxiliary agent, 2~6 parts of dispersing agent, 45~75 parts of surfactant and 850~922 parts of solvent,
In, the radiation protection and oleophobic auxiliary agent include acetic acid, nano silicon dioxide sol, nano-cerium oxide, nanometer antimony oxide tin, gather partially
Vinyl fluoride and phenolic resin, the dispersing agent are polypropylene glycol -2000, and the surfactant includes isomerous tridecanol polyoxy second
Alkene ether TO-7 and coconut fatty acid diethanolamine, the solvent are water, ethyl alcohol, n-propyl acetate and methyl ethyl ketone.
2. a kind of cleaning solution for being used to prepare impregnated wipe according to claim 1, which is characterized in that described anti-
In radiation and oleophobic auxiliary agent, acetic acid, nano silicon dioxide sol, nano-cerium oxide, nanometer antimony oxide tin, Kynoar and phenol
Urea formaldehyde accounts for 1~3 part, 3~7 parts, 2~5.5 parts, 4~8.5 parts, 9~20 parts, 12~25 parts respectively.
3. a kind of cleaning solution for being used to prepare impregnated wipe according to claim 1 or 2, which is characterized in that institute
It states in surfactant, isomerous tridecanol polyoxyethylene ether TO-7 and coconut fatty acid diethanolamine account for 20~35 parts, 25 respectively
~40 parts.
4. a kind of cleaning solution for being used to prepare impregnated wipe according to claim 1 to 3, which is characterized in that
In the solvent, water, ethyl alcohol, n-propyl acetate and methyl ethyl ketone account for 340~360 parts, 260~280 parts, 170~190 respectively
Part, 80~92 parts.
5. a kind of multifunctinal antiradiation impregnated wipe, the wet tissue is that non-woven fabrics impregnates any cleaning of claim 1-4
Liquid forms, wherein the liquid content of wet tissue is 200%~360%.
6. a kind of multifunctinal antiradiation impregnated wipe according to claim 5, which is characterized in that the non-woven fabrics
Preferably non-woven cotton.
7. a kind of preparation method of multifunctinal antiradiation impregnated wipe described in claim 5 or 6, which is characterized in that the side
Method are as follows:
(1) 30~66 parts of radiation protection in addition to acetic acid is sequentially added in a reservoir and oleophobic auxiliary agent and is stirred evenly, and adds 2
850~922 parts of solvent is added later and stirs together, is eventually adding for~6 parts of dispersing agent and 45~75 parts of surfactant
1~3 part of acetic acid simultaneously stirs evenly, and obtains colourless to light yellow translucent solution；
(2) Collator Mode for using an immersing and rolling, is soaked in 3~5min in solution for non-woven fabrics, then cross and roll with padding machine, and make to roll
Then the non-woven fabrics padded is cut into required specification, sealed package again 200%~360% by remaining rate control.
8. a kind of preparation method of multifunctinal antiradiation impregnated wipe according to claim 7, which is characterized in that described to remove
Radiation protection and oleophobic auxiliary agent outside acetic acid are according to micron order radiation protection and oleophobic auxiliary agent and nanoscale radiation protection and oleophobic auxiliary agent
Sequencing addition, wherein micron order radiation protection and oleophobic auxiliary agent include Kynoar and phenolic resin, nanoscale radiation protection
And oleophobic auxiliary agent includes nano silicon dioxide sol, nano-cerium oxide and nanometer antimony oxide tin.
9. detergent or wet tissue comprising any cleaning solution of claim 1-4.
10. including a kind of multifunctinal antiradiation cleaning of claim the 1-4 any cleaning solution or claim 5 or 6
The cleaning supplies of wet tissue.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114540105A (en) * | 2022-02-15 | 2022-05-27 | 王宇 | Portable wet tissue for cleaning and maintaining fishing gear and preparation method thereof |
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| CN1203292A (en) * | 1997-08-25 | 1998-12-30 | 曲功伟 | Method of making dedusting antistatic wet towel for microcomputer and television set |
| CN1693377A (en) * | 2004-05-09 | 2005-11-09 | 中国科学院化学研究所 | Application of super hydrophilicity and/or super lipophilicity nano pore material |
| US20140302107A1 (en) * | 2007-06-18 | 2014-10-09 | The Clorox Company | Oxidizing bleach composition |
| CN107513174A (en) * | 2017-09-07 | 2017-12-26 | 江南大学 | A kind of preparation method of cellulose/nanometer cerium oxide composite membrane |
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2018
- 2018-11-01 CN CN201811295125.6A patent/CN109456845B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203292A (en) * | 1997-08-25 | 1998-12-30 | 曲功伟 | Method of making dedusting antistatic wet towel for microcomputer and television set |
| CN1693377A (en) * | 2004-05-09 | 2005-11-09 | 中国科学院化学研究所 | Application of super hydrophilicity and/or super lipophilicity nano pore material |
| US20140302107A1 (en) * | 2007-06-18 | 2014-10-09 | The Clorox Company | Oxidizing bleach composition |
| CN107513174A (en) * | 2017-09-07 | 2017-12-26 | 江南大学 | A kind of preparation method of cellulose/nanometer cerium oxide composite membrane |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114540105A (en) * | 2022-02-15 | 2022-05-27 | 王宇 | Portable wet tissue for cleaning and maintaining fishing gear and preparation method thereof |
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