CN108951112A - A kind of preparation method of multifunctional nano finishing agent - Google Patents
A kind of preparation method of multifunctional nano finishing agent Download PDFInfo
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- CN108951112A CN108951112A CN201810768810.XA CN201810768810A CN108951112A CN 108951112 A CN108951112 A CN 108951112A CN 201810768810 A CN201810768810 A CN 201810768810A CN 108951112 A CN108951112 A CN 108951112A
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- finishing agent
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- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 72
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- VDRSDNINOSAWIV-UHFFFAOYSA-N [F].[Si] Chemical compound [F].[Si] VDRSDNINOSAWIV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 18
- 230000000740 bleeding effect Effects 0.000 claims abstract description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 14
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims abstract description 10
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000002148 esters Chemical class 0.000 claims abstract description 10
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 9
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 9
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 9
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 9
- BIFQHCGLXZWNLN-UHFFFAOYSA-N 2,2,6-trifluoro-4-methyl-4-propyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound CCC[Si]1(C)O[SiH](F)O[Si](F)(F)O1 BIFQHCGLXZWNLN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 7
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 7
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 7
- 239000003960 organic solvent Substances 0.000 claims abstract description 7
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims abstract description 6
- 230000001376 precipitating effect Effects 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 16
- -1 polyethylene Polymers 0.000 claims description 14
- 239000003995 emulsifying agent Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 239000000376 reactant Substances 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 239000011574 phosphorus Substances 0.000 claims description 11
- 239000013049 sediment Substances 0.000 claims description 11
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 229910052593 corundum Inorganic materials 0.000 claims description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- LOGBRYZYTBQBTB-UHFFFAOYSA-N butane-1,2,4-tricarboxylic acid Chemical class OC(=O)CCC(C(O)=O)CC(O)=O LOGBRYZYTBQBTB-UHFFFAOYSA-N 0.000 claims description 7
- PFKRTWCFCOUBHS-UHFFFAOYSA-N dimethyl(octadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[NH+](C)C PFKRTWCFCOUBHS-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 6
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 4
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 3
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 3
- 229930195725 Mannitol Natural products 0.000 claims description 3
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 3
- 239000000594 mannitol Substances 0.000 claims description 3
- 235000010355 mannitol Nutrition 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 2
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 claims description 2
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 claims 1
- 239000001273 butane Substances 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 238000004945 emulsification Methods 0.000 claims 1
- 230000008595 infiltration Effects 0.000 claims 1
- 238000001764 infiltration Methods 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 33
- 239000000463 material Substances 0.000 abstract description 6
- 230000037303 wrinkles Effects 0.000 abstract description 5
- 229920002593 Polyethylene Glycol 800 Polymers 0.000 abstract description 4
- 229940085675 polyethylene glycol 800 Drugs 0.000 abstract description 4
- 238000000227 grinding Methods 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 239000002105 nanoparticle Substances 0.000 abstract description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 239000004753 textile Substances 0.000 description 6
- 238000002604 ultrasonography Methods 0.000 description 6
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002086 nanomaterial Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- CSUUDNFYSFENAE-UHFFFAOYSA-N (2-methoxyphenyl)-phenylmethanone Chemical compound COC1=CC=CC=C1C(=O)C1=CC=CC=C1 CSUUDNFYSFENAE-UHFFFAOYSA-N 0.000 description 1
- SWFHGTMLYIBPPA-UHFFFAOYSA-N (4-methoxyphenyl)-phenylmethanone Chemical compound C1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 SWFHGTMLYIBPPA-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- PNZOFKOTVXSWKQ-UHFFFAOYSA-N OCCC[Si]1(O[SiH2]O[SiH2]O1)C Chemical compound OCCC[Si]1(O[SiH2]O[SiH2]O1)C PNZOFKOTVXSWKQ-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920001992 poloxamer 407 Polymers 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 description 1
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- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
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- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
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- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
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- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/657—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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Abstract
The present invention provides a kind of preparation methods of multifunctional nano finishing agent, comprising the following steps: (1) is successively handled with cetyl trimethylammonium bromide, polyethylene glycol-800 and pentaerythritol stearate after grinding nanoparticle；(2) using n-butanol as organic solvent, silicon-fluorine polymer object is prepared using ten trifluoro monooctyl ester of methacrylic acid, trifluoro propyl methyl cyclotrisiloxane and benzoyl peroxide；(3) precipitating particle is distributed to containing polysorbas20 is added in lauryl sodium sulfate, carboxymethyl cellulose, polyvinyl alcohol water solution, adds silicon-fluorine polymer object and multiple functions auxiliary agent, finishing agent A is made；(4) γ-methacryloxypropyl trimethoxy silane, bleeding agent are added in isopropanol and prepare finishing agent B.The fabric handled through finishing agent of the present invention has good ultraviolet-resistent property, waterproofness, wrinkle resistance and the performances such as antistatic, therefore finishing agent produced by the present invention is with a wide range of applications during material treatment.
Description
Technical field
The invention belongs to textile technology fields, and in particular to a kind of preparation method of multifunctional nano finishing agent.
Background technique
Fabric finishing agent is a kind of function additive applied to fabric, it can change the surface property of fabric, to assign
The special function of fabric.Such as it is to handle fabric with the finishing agent with low surface tension that hydrophobic and oil repellent, which arranges, changes fiber
Surface characteristic is not easy fabric surface by water or glossy wet and sprawl, to achieve the purpose that hydrophobic and oil repellent.Soil resistant finish and easily
It is to make fabric be not easy to attach dirt under dress, use condition by the surface property or surface state of change fiber that decontamination, which arranges,
Dirt, or the dirt attached is easy to wash the processing technology of not recontamination.
With the development of nanosecond science and technology, nano material has become the hot spot in current new material research field, nano material
Refer to size in the material of 1-100nm, there is the general material institutes such as surface area is big, Active sites are more, adsorption capacity is strong not
The excellent properties that can be compared, research field have been expanded to electronics, metallurgy, space flight and aviation, chemical industry, environment, biology and medicine etc.
Every field.Nano material also has a wide range of applications in field of textiles, is such as added in finishing agent and arranges to fabric, mentions
For performances such as antibacterial fabric, uvioresistants.
With the improvement of living standards, people also increasingly increase the safety of textile and functional requirement, especially
That there is the textile of persistence, safety, more kinetic energy increasingly to attract people's attention, there are also the comfort level of textile and
Aesthetics also has higher requirement, and textile finishing is also increasing to the effect of textile therewith.However current finishing agent
Can be relatively simple, be not able to satisfy the growing multi-functional demand of people, it is therefore necessary to existing finishing agent carry out into
The exploitation of one step.
Summary of the invention
Above of the existing technology in order to solve the problems, such as, the purpose of the present invention is to provide a kind of arrangements of multifunctional nano
The preparation method of agent, the fabric after being arranged using the finishing agent have multiple functions characteristic.
To achieve the goals above, the present invention the following technical schemes are provided:
A kind of preparation method of multifunctional nano finishing agent, comprising the following steps:
(1) by nanoscale TiO2 10-20 parts, 15-25 parts of ZnO, 8-16 parts of Ag, 5-10 parts of MgO, Al2O3 7-14 parts of progress
Mixing is placed in grinder and is ground the obtained nano-mixture of 15min, nano-mixture is then added to 30-50
In the aqueous solution of part 10-30% cetyl trimethylammonium bromide, mixing 20-40min is stirred at room temperature, then places it in
Then ultrasonic disperse 10-20min in Ultrasound Instrument adds 6-13 parts of polyethylene glycol-800,7-15 parts of pentaerythritol stearate,
Continue to be ultrasonically treated 30-60min at a temperature of 40-50 DEG C, reactant is cooled to room temperature, is collected by centrifugation removal solvent
Lower sediment particle；
(2) 20-40 parts of n-butanols are added in reaction flask as organic solvent, ten trifluoro monooctyl ester 5- of methacrylic acid is then added
10 parts,
4-8 parts of trifluoro propyl methyl cyclotrisiloxane and 0.1-0.5 parts of benzoyl peroxides, under 80-90 DEG C of water bath condition
Stirring is condensed back reaction 2-4h, then cools to room temperature, reactant is placed on Rotary Evaporators and is spin-dried for solvent to get fluorine silicon
Polymer；
(3) 4-8 containing lauryl sodium sulfate parts, carboxymethyl fibre are distributed to by 20-40 parts of lower sediment particle made from step (1)
In the 15-30 part aqueous solution for tieing up 2-6 parts of element, 6-10 parts of polyvinyl alcohol, 1-4 parts of polysorbas20 of addition, while stirring plus
Enter 20-40 parts of silicon-fluorine polymer object made from step (2), 4-9 parts of triethanolamine, 6-12 parts of 2- phosphorus base butane -1,2,4- tricarboxylic acids,
5-10 parts of maleic anhydride, 3-8 parts of ESCALOL 567,2-6 parts of octadecyldimethyl ammonium chloride, acrylic acid
7-13 parts of dimethylaminoethyl, 1-4 parts of emulsifier, persistently stir 1-3h in room temperature, and finishing agent A is made；
(4) γ -15-30 parts of methacryloxypropyl trimethoxy silane, 10-20 parts of bleeding agent are added to 30-50 parts
Aqueous isopropanol in, stir 20-40min at room temperature, be made finishing agent B.
Preferably, in the step (1) each raw material parts by weight are as follows: nanoscale TiO2 15 parts, 20 parts of ZnO, 12 parts of Ag,
8 parts of MgO, Al2O3 In the aqueous solution of 10 parts, 40 parts 10-30% cetyl trimethylammonium bromides, 10 parts of polyethylene glycol-800,
11 parts of pentaerythritol stearate.
Preferably, in the step (2) each raw material parts by weight are as follows: 30 parts of n-butanol, ten trifluoro monooctyl ester 7 of methacrylic acid
Part, 6 parts of trifluoro propyl methyl cyclotrisiloxane, 0.3 part of benzoyl peroxide.
Preferably, in the step (3) each raw material parts by weight are as follows: precipitating 30 parts of particle, 6 parts of lauryl sodium sulfate,
4 parts of carboxymethyl cellulose, 8 parts of polyvinyl alcohol, 23 parts of aqueous solution, 2.5 parts of polysorbas20,30 parts of silicon-fluorine polymer object, triethanolamine
6.5 parts, 9 parts of 2- phosphorus base butane -1,2,4- tricarboxylic acids, 8 parts of maleic anhydride, 5.5 parts of ESCALOL 567, ten
Eight 4 parts of alkyl dimethyl ammonium chlorides, 10 parts of dimethylaminoethyl acrylate, 2.5 parts of emulsifier.
Preferably, in the step (4) each raw material parts by weight are as follows: γ-methacryloxypropyl trimethoxy silicon
23 parts of alkane, 15 parts of bleeding agent, 40 parts of isopropanol.
Preferably, the emulsifier is octyl phenol polyoxyethylene ether, dodecyl benzyl dimethyl ammonium chloride or fat
One of alcohol Pluronic F-127 ether.
Preferably, the bleeding agent is one kind of Aerosol OT, mannitol or Di-phosphorus pentonide.
The technique that fabric is arranged using the finishing agent are as follows: fabric is dipped in finishing agent B first, is impregnated at room temperature
After 1h, it is washed with distilled water clean, drying；Then it is dipped in finishing agent A, carries out second dipping and rolling processing, pick-up rate is
80%, the single impregnation time is 1h, dries fabric washing after the completion of processing.
The utility model has the advantages that the present invention provides a kind of preparation methods of multifunctional nano finishing agent, first by several nanoscales
Functional particulate is handled with cetyl trimethylammonium bromide, so that nano grain surface forms positive charge environment, then again
It is modified with polyethylene glycol-800 and pentaerythritol stearate, nano particle is adsorbed by electrostatic adsorption
Surface, so that nano grain surface generates a large amount of alcoholic OH groups；Ten trifluoro monooctyl ester of methacrylic acid and trifluoro first
Hydroxypropyl methyl cyclotrisiloxane
Silicon-fluorine polymer object is prepared, the surface free energy of silicon-fluorine polymer object is lower, while having excellent hydrophobic, oleophobic and stain resistant
Performance, and provide finishing agent good film forming；By the nanometer hybrid particles of modification and silicon-fluorine polymer object, other function auxiliary agent into
Multi-function finish A liquid is made in row hybrid reaction.It include γ-methacryloxypropyl trimethoxy in finishing agent B liquid
Silane and
Bleeding agent, γ-methacryloxypropyl trimethoxy silane assigns fabric surface more hydroxyl, thus with nanometer
The hydroxyl on hybrid particles surface is combined by hydrogen bond action, is improved nanometer hybrid particles in the adhesive force of web surface, is seeped
The addition of saturating agent promotes finishing agent A liquid to the osmosis of fabric, to improve finishing agent to the ability to function of fabric, fills
The function of finishing agent is waved in distribution.
The fabric UPF value handled through finishing agent of the present invention is up to 128.62, and surface and water contact angle are up to 205.21 °, because
This is with good uvioresistant performance and waterproof performance；The creasy recovery angle of processed fabric is up to 324.3 °, breaking strength
Retention rate is up to 95.6%, and therefore, fabric, which is made, in the present invention has excellent wrinkle resistance；The surface resistivity of fabric is down to 4.8
×106Ω, volume resistivity are down to 2.2 × 106Ω, therefore fabric has good antistatic effect.Therefore it is obtained from experimental configuration
To know, the fabric handled through finishing agent of the present invention has good ultraviolet-resistent property, waterproofness, wrinkle resistance and the performances such as antistatic,
Therefore finishing agent produced by the present invention is with a wide range of applications during material treatment.
Specific embodiment
The invention will now be further described with reference to specific embodiments, but examples are merely exemplary, not to this hair
Bright range constitutes any restrictions.It will be understood by those skilled in the art that without departing from the spirit and scope of the invention
Can with the details and forms of the technical scheme of the invention are modified or replaced, but these modification and replacement each fall within it is of the invention
In protection scope.
In following embodiment and comparative example, fabric is arranged using the finishing agent technique are as follows: first by fabric
It is dipped in finishing agent B, after impregnating 1h at room temperature, is washed with distilled water clean, drying；Then it is dipped in finishing agent A, is carried out
Second dipping and rolling processing, pick-up rate 80%, single impregnation time are 1h, dry fabric washing after the completion of processing.
Embodiment 1
A kind of preparation method of multifunctional nano finishing agent, comprising the following steps:
(1) by nanoscale TiO2 15 parts, 20 parts of ZnO, 12 parts of Ag, 8 parts of MgO, Al2O3 10 parts are mixed, and grinding is placed in
It is ground 15min in machine, nano-mixture is made, nano-mixture is then added to 40 part of 20% cetyl front three
In the aqueous solution of base ammonium bromide, mixing 30min is stirred at room temperature, then places it in ultrasonic disperse 15min in Ultrasound Instrument, so
After add 10 parts of polyethylene glycol-800,11 parts of pentaerythritol stearate, continue to be ultrasonically treated at a temperature of 45 DEG C
Reactant is cooled to room temperature by 45min, collects lower sediment particle by centrifugation removal solvent；
(2) in reaction flask be added 30 parts of n-butanols be used as organic solvent, then addition 7 parts of ten trifluoro monooctyl ester of methacrylic acid,
6 parts and 0.3 part benzoyl peroxide of trifluoro propyl methyl cyclotrisiloxane, stirs under 85 DEG C of water bath condition and is condensed back to
Stream reaction 3h, then cools to room temperature, reactant is placed on Rotary Evaporators and is spin-dried for solvent to get silicon-fluorine polymer object；
(3) 30 parts of lower sediment particle made from step (1) are distributed to containing 6 parts of lauryl sodium sulfate, carboxymethyl cellulose 4
In part, 8 parts of polyvinyl alcohol of 23 parts of aqueous solutions, 2.5 parts of polysorbas20 is added, step (2) are added while stirring and are made
30 parts of silicon-fluorine polymer object, 6.5 parts of triethanolamine, 9 parts of 2- phosphorus base butane -1,2,4- tricarboxylic acids, 8 parts of maleic anhydride, 2- hydroxyl -
5.5 parts of 4- methoxy benzophenone, 4 parts of octadecyldimethyl ammonium chloride, 10 parts of dimethylaminoethyl acrylate, emulsifier
2.5 parts, 2h is persistently stirred in room temperature, finishing agent A is made；
(4) 15 parts of 23 parts of γ-methacryloxypropyl trimethoxy silane, bleeding agent isopropanols for being added to 40 parts are molten
In liquid, 30min is stirred at room temperature, and finishing agent B is made.
The emulsifier is octyl phenol polyoxyethylene ether.
The bleeding agent is Aerosol OT.
Embodiment 2
A kind of preparation method of multifunctional nano finishing agent, comprising the following steps:
(1) by nanoscale TiO2 10 parts, 15 parts of ZnO, 8 parts of Ag, 5 parts of MgO, Al2O3 7 parts are mixed, and grinder is placed in
In be ground 15min be made nano-mixture, nano-mixture is then added to 30 part of 10% cetyl trimethyl
In the aqueous solution of ammonium bromide, mixing 20min is stirred at room temperature, then places it in ultrasonic disperse 10min in Ultrasound Instrument, then
6 parts of polyethylene glycol-800,7 parts of pentaerythritol stearate are added, continues to be ultrasonically treated 30min at a temperature of 40 DEG C, it will
Reactant is cooled to room temperature, and collects lower sediment particle by centrifugation removal solvent；
(2) in reaction flask be added 20 parts of n-butanols be used as organic solvent, then addition 5 parts of ten trifluoro monooctyl ester of methacrylic acid,
4 parts and 0.1 part benzoyl peroxide of trifluoro propyl methyl cyclotrisiloxane, stirs under 80 DEG C of water bath condition and is condensed back to
Stream reaction 2h, then cools to room temperature, reactant is placed on Rotary Evaporators and is spin-dried for solvent to get silicon-fluorine polymer object；
(3) 20 parts of lower sediment particle made from step (1) are distributed to containing 4 parts of lauryl sodium sulfate, carboxymethyl cellulose 2
In part, 6 parts of polyvinyl alcohol of 15 parts of aqueous solutions, 1 part of polysorbas20 is added, it is obtained that step (2) are added while stirring
20 parts of silicon-fluorine polymer object, 4 parts of triethanolamine, 6 parts of 2- phosphorus base butane -1,2,4- tricarboxylic acids, 5 parts of maleic anhydride, 2- hydroxyl -4- first
3 parts of oxygroup benzophenone, 2 parts of octadecyldimethyl ammonium chloride, 7 parts of dimethylaminoethyl acrylate, 1 part of emulsifier, in room
Temperature persistently stirs 1h, and finishing agent A is made；
(4) 10 parts of 15 parts of γ-methacryloxypropyl trimethoxy silane, bleeding agent isopropanols for being added to 30 parts are molten
In liquid, 20min is stirred at room temperature, and finishing agent B is made.
The emulsifier is dodecyl benzyl dimethyl ammonium chloride.
The bleeding agent is mannitol.
Embodiment 3
A kind of preparation method of multifunctional nano finishing agent, comprising the following steps:
(1) by nanoscale TiO2 12 parts, 18 parts of ZnO, 10 parts of Ag, 6 parts of MgO, Al2O3 8 parts are mixed, and grinder is placed in
In be ground 15min be made nano-mixture, nano-mixture is then added to 35 part of 15% cetyl trimethyl
In the aqueous solution of ammonium bromide, mixing 20-40min is stirred at room temperature, then places it in ultrasonic disperse 12min in Ultrasound Instrument,
Then 8 parts of polyethylene glycol-800,8 parts of pentaerythritol stearate are added, continues to be ultrasonically treated at a temperature of 42 DEG C
Reactant is cooled to room temperature by 40min, collects lower sediment particle by centrifugation removal solvent；
(2) in reaction flask be added 25 parts of n-butanols be used as organic solvent, then addition 6 parts of ten trifluoro monooctyl ester of methacrylic acid,
5 parts and 0.2 part benzoyl peroxide of trifluoro propyl methyl cyclotrisiloxane, stirs under 82 DEG C of water bath condition and is condensed back to
Stream reaction 2.5h, then cools to room temperature, reactant is placed on Rotary Evaporators and is spin-dried for solvent to get silicon-fluorine polymer object；
(3) 25 parts of lower sediment particle made from step (1) are distributed to containing 5 parts of lauryl sodium sulfate, carboxymethyl cellulose 3
In part, 7 parts of polyvinyl alcohol of 20 parts of aqueous solutions, 2 parts of polysorbas20 is added, it is obtained that step (2) are added while stirring
25 parts of silicon-fluorine polymer object, 5 parts of triethanolamine, 8 parts of 2- phosphorus base butane -1,2,4- tricarboxylic acids, 6 parts of maleic anhydride, 2- hydroxyl -4- first
4 parts of oxygroup benzophenone, 3 parts of octadecyldimethyl ammonium chloride, 8 parts of dimethylaminoethyl acrylate, 2 parts of emulsifier, in room
Temperature persistently stirs 1.5h, and finishing agent A is made；
(4) 12 parts of 20 parts of γ-methacryloxypropyl trimethoxy silane, bleeding agent isopropanols for being added to 35 parts are molten
In liquid, 25min is stirred at room temperature, and finishing agent B is made.
The emulsifier is poly alkyl alcohol oxireme ether.
The bleeding agent is Di-phosphorus pentonide.
Embodiment 4
A kind of preparation method of multifunctional nano finishing agent, comprising the following steps:
(1) by nanoscale TiO2 20 parts, 25 parts of ZnO, 16 parts of Ag, 10 parts of MgO, Al2O3 14 parts are mixed, and grinding is placed in
It is ground 15min in machine, nano-mixture is made, nano-mixture is then added to 50 parts of 10-30% cetyls
In the aqueous solution of trimethylammonium bromide, mixing 40min is stirred at room temperature, then places it in ultrasonic disperse in Ultrasound Instrument
Then 20min adds 13 parts of polyethylene glycol-800,15 parts of pentaerythritol stearate, continue ultrasound at a temperature of 50 DEG C
60min is handled, reactant is cooled to room temperature, lower sediment particle is collected by centrifugation removal solvent；
(2) 40 parts of n-butanols are added in reaction flask as organic solvent, ten trifluoro monooctyl ester 5-10 of methacrylic acid is then added
Part,
8 parts and 0.5 part benzoyl peroxide of trifluoro propyl methyl cyclotrisiloxane, is stirred cold under 80-90 DEG C of water bath condition
Solidifying back flow reaction 4h, then cools to room temperature, reactant is placed on Rotary Evaporators and is spin-dried for solvent to get silicon-fluorine polymer object；
(3) 40 parts of lower sediment particle made from step (1) are distributed to containing 8 parts of lauryl sodium sulfate, carboxymethyl cellulose 6
In part, 10 parts of polyvinyl alcohol of 30 parts of aqueous solutions, 4 parts of polysorbas20 is added, it is obtained that step (2) are added while stirring
40 parts of silicon-fluorine polymer object, 9 parts of triethanolamine, 12 parts of 2- phosphorus base butane -1,2,4- tricarboxylic acids, 10 parts of maleic anhydride, 2- hydroxyl -4-
8 parts of methoxy benzophenone, 6 parts of octadecyldimethyl ammonium chloride, 13 parts of dimethylaminoethyl acrylate, 4 parts of emulsifier, in
Room temperature persistently stirs 3h, and finishing agent A is made；
(4) 20 parts of 30 parts of γ-methacryloxypropyl trimethoxy silane, bleeding agent isopropanols for being added to 50 parts are molten
In liquid, 40min is stirred at room temperature, and finishing agent B is made.
The emulsifier is octyl phenol polyoxyethylene ether.
The bleeding agent is Aerosol OT.
Comparative example 1
Comparative example 1 the difference from embodiment 1 is that, unused polyethylene glycol-800 and pentaerythrite are hard in (1) the step of comparative example 1
Resin acid ester is handled.
Comparative example 2
Comparative example 2 the difference from embodiment 1 is that, silicon-fluorine polymer object is not added in comparative example 2.
Fabric after embodiment 1-4, comparative example 1-2 are arranged carries out the test of following performance, test result such as 1 institute of table
Show.
(1) it is penetrated using KHF2BP032 type UV resistance and preventing coating protection test macro (SDLAtlas company) measures it and resists
Ultraviolet effect, same sample measure 5 times in different location, take its average value；(2) OCA40 type video contact angle measuring instrument is used
Contact angle determination is carried out, same sample measures 5 times in different location, takes its average value；(3) creasy recovery angle presses GB 3819-
1997 measurements, every kind of sample are surveyed 5 through 5 latitudes and are averaged, and the creasy recovery angle measured is fabric through returning to the wrinkle with broadwise
The sum of multiple angle；(4) finished tensile strength is measured referring to GB 3923.1-1997, and every kind of sample is through 3 times and being averaged to surveying；
(5) it is measured using bending resistance length of the pliability analyzer to sample；(6) by fabric made from embodiment 1-4 referring to GB/T
16801-1997 " measurement of fabric conditioner antistatic property ", with the surface of the high insulation measurement instrument measurement fabric of ZC36 type
Resistivity and volume resistivity.Obtained from table 1, the fabric UPF value handled through finishing agent of the present invention is up to 128.62, surface with
Water contact angle is up to 205.21 °, therefore has good uvioresistant performance and waterproof performance；The crease recovery of processed fabric
Angle is up to 324.3 °, and breaking strength retention is up to 95.6%, and therefore, fabric, which is made, in the present invention has excellent wrinkle resistance；Face
The surface resistivity of material is down to 4.8 × 106Ω, volume resistivity are down to 2.2 × 106Ω, therefore fabric is with good antistatic
Effect.
Table 1
Claims (7)
1. a kind of preparation method of multifunctional nano finishing agent, which comprises the following steps:
(1) by nanoscale TiO2 10-20 parts, 15-25 parts of ZnO, 8-16 parts of Ag, 5-10 parts of MgO, Al2O3 7-14 parts are mixed
It closes, is placed in grinder and is ground the obtained nano-mixture of 15min, nano-mixture is then added to 30-50 parts
In the aqueous solution of 10-30% cetyl trimethylammonium bromide, mixing 20-40min is stirred at room temperature, then places it in super
Then ultrasonic disperse 10-20min on sound instrument adds 6-13 parts of polyethylene glycol-800,7-15 parts of pentaerythritol stearate, in
Continue to be ultrasonically treated 30-60min at a temperature of 40-50 DEG C, reactant is cooled to room temperature, under being collected by centrifugation removal solvent
Layer precipitating particle；
(2) 20-40 parts of n-butanols are added in reaction flask as organic solvent, ten trifluoro monooctyl ester 5- of methacrylic acid is then added
10 parts,
4-8 parts of trifluoro propyl methyl cyclotrisiloxane and 0.1-0.5 parts of benzoyl peroxides, under 80-90 DEG C of water bath condition
Stirring is condensed back reaction 2-4h, then cools to room temperature, reactant is placed on Rotary Evaporators and is spin-dried for solvent to get fluorine silicon
Polymer；
(3) 4-8 containing lauryl sodium sulfate parts, carboxymethyl fibre are distributed to by 20-40 parts of lower sediment particle made from step (1)
In the 15-30 part aqueous solution for tieing up 2-6 parts of element, 6-10 parts of polyvinyl alcohol, 1-4 parts of polysorbas20 of addition, while stirring plus
Enter 20-40 parts of silicon-fluorine polymer object made from step (2), 4-9 parts of triethanolamine, 6-12 parts of 2- phosphorus base butane -1,2,4- tricarboxylic acids,
5-10 parts of maleic anhydride, 3-8 parts of ESCALOL 567,2-6 parts of octadecyldimethyl ammonium chloride, acrylic acid
7-13 parts of dimethylaminoethyl, 1-4 parts of emulsifier, persistently stir 1-3h in room temperature, and finishing agent A is made；
(4) γ -15-30 parts of methacryloxypropyl trimethoxy silane, 10-20 parts of bleeding agent are added to 30-50 parts
Aqueous isopropanol in, stir 20-40min at room temperature, be made finishing agent B.
2. a kind of preparation method of multifunctional nano finishing agent according to claim 1, which is characterized in that the step
(1) parts by weight of each raw material in are as follows: nanoscale TiO2 15 parts, 20 parts of ZnO, 12 parts of Ag, 8 parts of MgO, Al2O3 10 parts, 40 parts
In the aqueous solution of 10-30% cetyl trimethylammonium bromide, 10 parts of polyethylene glycol-800,11 parts of pentaerythritol stearate.
3. a kind of preparation method of multifunctional nano finishing agent according to claim 1, which is characterized in that the step
(2) parts by weight of each raw material in are as follows: 30 parts of n-butanol, 7 parts of ten trifluoro monooctyl ester of methacrylic acid, three silicon oxygen of trifluoro propyl methyl ring
6 parts of alkane, 0.3 part of benzoyl peroxide.
4. a kind of preparation method of multifunctional nano finishing agent according to claim 1, which is characterized in that the step
(3) parts by weight of each raw material in are as follows: precipitating 30 parts of particle, 6 parts of lauryl sodium sulfate, 4 parts of carboxymethyl cellulose, polyvinyl alcohol
8 parts, 23 parts of aqueous solution, 2.5 parts of polysorbas20,30 parts of silicon-fluorine polymer object, 6.5 parts of triethanolamine, 2- phosphorus base butane -1,2,4- three
9 parts of carboxylic acid, 8 parts of maleic anhydride, 5.5 parts of ESCALOL 567,4 parts of octadecyldimethyl ammonium chloride, propylene
10 parts of sour dimethylaminoethyl, 2.5 parts of emulsifier.
5. a kind of preparation method of multifunctional nano finishing agent according to claim 1, which is characterized in that the step
(4) parts by weight of each raw material in are as follows: 23 parts of γ-methacryloxypropyl trimethoxy silane, 15 parts of bleeding agent, isopropanol
40 parts.
6. a kind of preparation method of multifunctional nano finishing agent according to claim 1, which is characterized in that the emulsification
Agent is one of octyl phenol polyoxyethylene ether, dodecyl benzyl dimethyl ammonium chloride or poly alkyl alcohol oxireme ether.
7. a kind of preparation method of multifunctional nano finishing agent according to claim 1, which is characterized in that the infiltration
Agent is one kind of Aerosol OT, mannitol or Di-phosphorus pentonide.
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| CN109914093A (en) * | 2019-03-11 | 2019-06-21 | 苏州经贸职业技术学院 | Sun-proof textile fabric of resistance to greasy dirt of one kind and preparation method thereof |
| CN110158304A (en) * | 2019-05-31 | 2019-08-23 | 苏州经贸职业技术学院 | A kind of fabric nano functional finishing agent and preparation method thereof |
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| CN1869321A (en) * | 2005-10-21 | 2006-11-29 | 安徽理工大学 | Finishing process for vehicle internal decoration cloth with antibacerial and peculiar smell removing function |
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| CN102535163A (en) * | 2011-09-30 | 2012-07-04 | 江苏红运果服饰有限公司 | Multifunctional nano composite fabric |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109914093A (en) * | 2019-03-11 | 2019-06-21 | 苏州经贸职业技术学院 | Sun-proof textile fabric of resistance to greasy dirt of one kind and preparation method thereof |
| CN110158304A (en) * | 2019-05-31 | 2019-08-23 | 苏州经贸职业技术学院 | A kind of fabric nano functional finishing agent and preparation method thereof |
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Application publication date: 20181207 |