CN109456824A - A kind of mine hydraulic support oil emulsion - Google Patents

A kind of mine hydraulic support oil emulsion Download PDF

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Publication number
CN109456824A
CN109456824A CN201811421425.4A CN201811421425A CN109456824A CN 109456824 A CN109456824 A CN 109456824A CN 201811421425 A CN201811421425 A CN 201811421425A CN 109456824 A CN109456824 A CN 109456824A
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CN
China
Prior art keywords
oil
fatty acid
preservative
hydraulic support
lye
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811421425.4A
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Chinese (zh)
Inventor
孙雅文
张家树
郭文馨
肖文华
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Liaoning Lionmay Tektronix Technology Co Ltd
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Liaoning Lionmay Tektronix Technology Co Ltd
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Priority to CN201811421425.4A priority Critical patent/CN109456824A/en
Publication of CN109456824A publication Critical patent/CN109456824A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives

Abstract

The present invention provides a kind of mine hydraulic support oil emulsion, its technical characteristic is, transformer oil: 55%~65%, oelic acid 3%~6%, triethanolamine 6%~10%, petroleum sodium sulfonate 7%~14%, nonylphenol polyoxyethylene ether 1%~5%, sorbitan fatty acid ester 4%~10%, coco-nut oil fatty acid diethanol amine 5%~10%, preservative 0.3%~0.5%, lye 0.5%~2%, disodium ethylene diamine tetraacetate 1%~2%.Its advantage is that using deep purification base oil, emulsifier, lubricant, antirust agent, preservative etc. synthesize a kind of hardly aqueous hydraulic support emulsification oil product, not only have excellent extreme boundary lubrication, wear-resistant, cooling, antirust, cleaning performance and can guarantee stoste product cold district do not occur solidification phenomenon, reachable -30 DEG C of freezing point it is following, avoid product and occur solidifying thawing phenomenon repeatedly.The freeze-thawing resistant test of product pacifies mark central standard well beyond country.

Description

A kind of mine hydraulic support oil emulsion
Technical field
The present invention relates to a kind of hydraulic support oil emulsion, particularly a kind of mine hydraulic support oil emulsions.
Background technique
Hydraulic support oil emulsion is suitable for the power of the systems such as coal mine hydraulic supporting, hydraulic prop, hydraulic electric furnace Transfer medium can be effectively protected hydraulic system, prolong its service life.The product occurred in existing market is most of in order to save Although cost is added a certain amount of water doping and has saved production cost wherein, to a certain extent but actually along with subproblem Occur, due to water addition can exposing product cold tolerance decrease, in partially cold area due to will appear production when ground temperature is relatively low Product solidify the process of thawing repeatedly, can be easy to make that the phenomenon that cotton-shaped or layering occurs in product, this phenomenon can directly be led in this way The use of cause product, which oil soap precipitation occurs excessively, influences stability of emulsion, the abrasion reduction equipment of exacerbation transmission system uses the longevity Life serious will affect operation safety under mine and cause personal injury.
Summary of the invention
The purpose of the present invention is deficiency present in view of the above technology, a kind of mine is provided is emulsified with hydraulic support Oil.Not only there is excellent extreme boundary lubrication, wear-resistant, cooling, antirust, cleaning performance but also stoste product can be guaranteed in cold Area do not occur solidification phenomenon, reachable -30 DEG C of freezing point it is following, avoid product and solidification thawing phenomenon repeatedly occur.Product Freeze-thawing resistant test pacifies mark central standard well beyond country.
The object of the present invention is achieved like this, including transformer oil, oelic acid, triethanolamine, petroleum sodium sulfonate, nonyl Base phenol polyethenoxy ether, sorbitan fatty acid ester, coco-nut oil fatty acid diethanol amine, preservative, lye, ethylenediamine tetrem Acid disodium.It is characterized in that transformer oil: 55%~65%, oelic acid 3%~6%, triethanolamine 6%~10%, petroleum sodium sulfonate 7% ~14%, nonylphenol polyoxyethylene ether 1%~5%, sorbitan fatty acid ester 4%~10%, coco-nut oil fatty acid diethanol amine 5% ~10%, preservative 0.3%~0.5%, lye 0.5%~2%, disodium ethylene diamine tetraacetate 1%~2%.
The invention has the advantages that using synthesis such as deep purification base oil, emulsifier, lubricant, antirust agent, preservatives A kind of hardly aqueous hydraulic support emulsification oil product not only has excellent extreme boundary lubrication, wear-resistant, cooling, antirust, clearly Wash performance and can guarantee stoste product cold district do not occur solidification phenomenon, reachable -30 DEG C of freezing point or less, avoid There is solidification repeatedly and melts phenomenon in product.The freeze-thawing resistant test of product pacifies mark central standard well beyond country.
Specific embodiment
Below with reference to embodiment, the present invention will be further described
Embodiment 1:
Transformer oil 60%, oelic acid 3%, triethanolamine 6%, petroleum sodium sulfonate 10%, nonylphenol polyoxyethylene ether 5%, dehydration mountain Pears alcohol fatty acid ester 8%, coco-nut oil fatty acid diethanol amine 5%.Preservative 0.5%.Lye 1%, disodium ethylene diamine tetraacetate 1.5%.
Embodiment 2:
Transformer oil 55.5%, oelic acid 5%, triethanolamine 8%, petroleum sodium sulfonate 11%, nonylphenol polyoxyethylene ether 2%, dehydration Span 10%, coco-nut oil fatty acid diethanol amine 6%.Preservative 0.5%.Lye 2%, disodium ethylene diamine tetraacetate 1%.
Embodiment 3:
Transformer oil 58.2%, oelic acid 6%, triethanolamine 10%, petroleum sodium sulfonate 7%, nonylphenol polyoxyethylene ether 1%, dehydration Span 4%, coco-nut oil fatty acid diethanol amine 10%.Preservative 0.3%.Lye 1.5%, disodium ethylene diamine tetraacetate 2%。

Claims (5)

1. a kind of mine hydraulic support oil emulsion, including transformer oil, oelic acid, triethanolamine, petroleum sodium sulfonate, nonyl Base phenol polyethenoxy ether, sorbitan fatty acid ester, coco-nut oil fatty acid diethanol amine, preservative, lye, ethylenediamine tetrem Acid disodium, characterized in that transformer oil: 55%~65%, oelic acid 3%~6%, triethanolamine 6%~10%, petroleum sodium sulfonate 7% ~14%, nonylphenol polyoxyethylene ether 1%~5%, sorbitan fatty acid ester 4%~10%, coco-nut oil fatty acid diethanol amine 5% ~10%, preservative 0.3%~0.5%, lye 0.5%~2%, disodium ethylene diamine tetraacetate 1%~2%.
2. a kind of mine hydraulic support oil emulsion according to claim 1, it is characterized in that transformer oil 60%, purification Oleic acid 3%, triethanolamine 6%, petroleum sodium sulfonate 10%, nonylphenol polyoxyethylene ether 5%, sorbitan fatty acid ester 8%, coconut Fatty acid oil diethanol amine 5%, preservative 0.5%, lye 1%, disodium ethylene diamine tetraacetate 1.5%.
3. a kind of mine hydraulic support oil emulsion according to claim 1, characterized in that
Transformer oil 55.5%, oelic acid 5%, triethanolamine 8%, petroleum sodium sulfonate 11%, nonylphenol polyoxyethylene ether 2%, dehydration Span 10%, coco-nut oil fatty acid diethanol amine 6%, preservative 0.5%, lye 2%, disodium ethylene diamine tetraacetate 1%。
4. a kind of mine hydraulic support oil emulsion according to claim 1, characterized in that
Transformer oil 58.2%, oelic acid 6%, triethanolamine 10%, petroleum sodium sulfonate 7%, nonylphenol polyoxyethylene ether 1%, dehydration Span 4%, coco-nut oil fatty acid diethanol amine 10%, preservative 0.3%, lye 1.5%, disodium ethylene diamine tetraacetate 2%, transformer oil 55.5%, oelic acid 5%, triethanolamine 8%, petroleum sodium sulfonate 11%, nonylphenol polyoxyethylene ether 2%, dehydration Span 10%, coco-nut oil fatty acid diethanol amine 6%, preservative 0.5%, lye 2%, disodium ethylene diamine tetraacetate 1%。
5. a kind of mine hydraulic support oil emulsion according to claim 1, characterized in that
Transformer oil 58.2%, oelic acid 6%, triethanolamine 10%, petroleum sodium sulfonate 7%, nonylphenol polyoxyethylene ether 1%, dehydration Span 4%, coco-nut oil fatty acid diethanol amine 10%, preservative 0.3%, lye 1.5%, disodium ethylene diamine tetraacetate 2%。
CN201811421425.4A 2018-11-27 2018-11-27 A kind of mine hydraulic support oil emulsion Pending CN109456824A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811421425.4A CN109456824A (en) 2018-11-27 2018-11-27 A kind of mine hydraulic support oil emulsion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811421425.4A CN109456824A (en) 2018-11-27 2018-11-27 A kind of mine hydraulic support oil emulsion

Publications (1)

Publication Number Publication Date
CN109456824A true CN109456824A (en) 2019-03-12

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6280120B1 (en) * 1998-07-27 2001-08-28 Nippon Shokubai Co., Ltd. Adhesion preventing method and support body extracting method
CN102839038A (en) * 2012-09-13 2012-12-26 济南库伦特科技有限公司 Additive composition for producing emulsified oil, preparation method of additive composition and application of additive composition
CN103074150A (en) * 2012-12-26 2013-05-01 山东梁山三晶石化有限责任公司 Emulsified oil for hydraulic support for mines and preparation method
CN103305327A (en) * 2013-07-10 2013-09-18 哈尔滨紫杉油脂有限责任公司 Preparation method of emulsified oil for hydraulic support
CN107955687A (en) * 2017-12-14 2018-04-24 徐州瀚德润滑技术服务有限公司 A kind of Emulsified oil for hydraulic support for mines composition
CN108048191A (en) * 2017-12-18 2018-05-18 煤炭科学技术研究院有限公司 A kind of hydraulic support oil emulsion and preparation method
CN108485772A (en) * 2018-05-25 2018-09-04 富地润滑科技股份有限公司 A kind of environmentally protective mine hydraulic support fluid
CN108559605A (en) * 2018-05-25 2018-09-21 富地润滑科技股份有限公司 A kind of preparation method of environmentally protective mine hydraulic support fluid

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6280120B1 (en) * 1998-07-27 2001-08-28 Nippon Shokubai Co., Ltd. Adhesion preventing method and support body extracting method
CN102839038A (en) * 2012-09-13 2012-12-26 济南库伦特科技有限公司 Additive composition for producing emulsified oil, preparation method of additive composition and application of additive composition
CN103074150A (en) * 2012-12-26 2013-05-01 山东梁山三晶石化有限责任公司 Emulsified oil for hydraulic support for mines and preparation method
CN103305327A (en) * 2013-07-10 2013-09-18 哈尔滨紫杉油脂有限责任公司 Preparation method of emulsified oil for hydraulic support
CN107955687A (en) * 2017-12-14 2018-04-24 徐州瀚德润滑技术服务有限公司 A kind of Emulsified oil for hydraulic support for mines composition
CN108048191A (en) * 2017-12-18 2018-05-18 煤炭科学技术研究院有限公司 A kind of hydraulic support oil emulsion and preparation method
CN108485772A (en) * 2018-05-25 2018-09-04 富地润滑科技股份有限公司 A kind of environmentally protective mine hydraulic support fluid
CN108559605A (en) * 2018-05-25 2018-09-21 富地润滑科技股份有限公司 A kind of preparation method of environmentally protective mine hydraulic support fluid

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