CN109652188A - A kind of environmentally friendly mine hydraulic support concentrate and preparation method thereof - Google Patents
A kind of environmentally friendly mine hydraulic support concentrate and preparation method thereof Download PDFInfo
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- CN109652188A CN109652188A CN201910082781.6A CN201910082781A CN109652188A CN 109652188 A CN109652188 A CN 109652188A CN 201910082781 A CN201910082781 A CN 201910082781A CN 109652188 A CN109652188 A CN 109652188A
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- environmentally friendly
- hydraulic support
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- mine hydraulic
- acid
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- 239000012141 concentrate Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 34
- 239000000344 soap Substances 0.000 claims abstract description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000314 lubricant Substances 0.000 claims abstract description 20
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 18
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000839 emulsion Substances 0.000 claims abstract description 17
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 17
- 239000008158 vegetable oil Substances 0.000 claims abstract description 17
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 16
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 13
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 13
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 13
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012964 benzotriazole Substances 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 235000011187 glycerol Nutrition 0.000 claims abstract description 10
- 239000013538 functional additive Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000003784 tall oil Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229940049964 oleate Drugs 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 3
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical group [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 claims description 2
- -1 Alcohol amine Chemical class 0.000 claims description 2
- 125000005605 benzo group Chemical group 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000000376 reactant Substances 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 150000003851 azoles Chemical class 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000013078 crystal Substances 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000003245 coal Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- WWTBZEKOSBFBEM-SPWPXUSOSA-N (2s)-2-[[2-benzyl-3-[hydroxy-[(1r)-2-phenyl-1-(phenylmethoxycarbonylamino)ethyl]phosphoryl]propanoyl]amino]-3-(1h-indol-3-yl)propanoic acid Chemical group N([C@@H](CC=1C2=CC=CC=C2NC=1)C(=O)O)C(=O)C(CP(O)(=O)[C@H](CC=1C=CC=CC=1)NC(=O)OCC=1C=CC=CC=1)CC1=CC=CC=C1 WWTBZEKOSBFBEM-SPWPXUSOSA-N 0.000 description 1
- YSUIQYOGTINQIN-UZFYAQMZSA-N 2-amino-9-[(1S,6R,8R,9S,10R,15R,17R,18R)-8-(6-aminopurin-9-yl)-9,18-difluoro-3,12-dihydroxy-3,12-bis(sulfanylidene)-2,4,7,11,13,16-hexaoxa-3lambda5,12lambda5-diphosphatricyclo[13.2.1.06,10]octadecan-17-yl]-1H-purin-6-one Chemical group NC1=NC2=C(N=CN2[C@@H]2O[C@@H]3COP(S)(=O)O[C@@H]4[C@@H](COP(S)(=O)O[C@@H]2[C@@H]3F)O[C@H]([C@H]4F)N2C=NC3=C2N=CN=C3N)C(=O)N1 YSUIQYOGTINQIN-UZFYAQMZSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- XRWSZZJLZRKHHD-WVWIJVSJSA-N asunaprevir Chemical group O=C([C@@H]1C[C@H](CN1C(=O)[C@@H](NC(=O)OC(C)(C)C)C(C)(C)C)OC1=NC=C(C2=CC=C(Cl)C=C21)OC)N[C@]1(C(=O)NS(=O)(=O)C2CC2)C[C@H]1C=C XRWSZZJLZRKHHD-WVWIJVSJSA-N 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002817 coal dust Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- JAXFJECJQZDFJS-XHEPKHHKSA-N gtpl8555 Chemical group OC(=O)C[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@@H]1C(=O)N[C@H](B1O[C@@]2(C)[C@H]3C[C@H](C3(C)C)C[C@H]2O1)CCC1=CC=C(F)C=C1 JAXFJECJQZDFJS-XHEPKHHKSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of environmentally friendly mine hydraulic support concentrates and preparation method thereof, relate generally to a kind of hydraulic concentrate and preparation method thereof, functional additive including 35-50% (weight percent) deionized water and 50-65% (weight percent), the functional additive includes vegetable oil acid soap, polybasic carboxylic acid slushing compound, plant polyenoid phenol surfactant, extreme-pressure lubricant, EDETATE SODIUM, EDETATE SODIUM, monoethanolamine, sodium benzoate, glycerine, benzotriazole, silicone emulsion, concentrate appearance of the present invention is good, it is as clear as crystal, it has no irritating odor, non-volatile substance, used raw material is all biodegradable, it is environmentally protective.
Description
Technical field
The invention mainly relates to a kind of hydraulic concentrate and preparation method thereof, specifically a kind of environmentally friendly mine liquid
Press bracket concentrate and preparation method thereof.
Background technique
Hydraulic support is the important mechanical equipment that coal industry coal working face is used to support top plate, mating with coalcutter
It uses, not only realizes coal mining comprehensive mechanization, improve the efficiency of coal mining and transporting equipment, and ensure to greatest extent
The life security of coal miner, the movement of bracket are not to be what the pipeline and control element of certain structure formed by pressure fluid
It is flowed in system, to realize the transmitting and conversion of energy, this pressure fluid is commonly referred to as driving medium, and hydraulic transmission medium is
Important composition part in hydraulic system, hydraulic support environment-friendly type concentrate is hydraulic bracket system " blood ", hydraulic branch
Lifting, movement and overload protection of frame etc. are required using hydraulic support environment-friendly type concentrate.
For a long time, China uses always oil emulsion, since oil emulsion has high lubricating effect and rust-proof effect apparent
Advantage is liked always by people, but is non-renewable petroleum money since the base oil in oil emulsion is mineral oil
Source, price are influenced very big by international petroleum product, and petroleum resources are fewer and fewer, and price can only gradually rise, and there are also pollute ring
The problem of border, especially there are also certain condensate oil graining phenomenons in use, and strainer is caused to block, and need often to clean filter
Net, and these oil soaps being precipitated form the dope for being difficult cleaning in conjunction with coal dust, can cause to the use of working site many
Adverse effect, the problems such as filter assemblies can be then blocked to electrohydraulic control system.
It is most of oily still based on mineral oil so far, although the widely available property of vegetable oil and environmental sound etc.
Advantage, but it not yet finds broad applicability in terms of high performance hydraulic support.On the other hand, since coal mine hydraulic supporting is used
It is directly discharged in underground after transmission fluid use, causes serious pollution of a large amount of greasy dirts to subsurface environment.
Summary of the invention
In view of the deficiencies in the prior art and defect, the present invention provides a kind of environmentally friendly mine hydraulic supports
Concentrate and preparation method thereof, environmental protection, performance is high, and Modern coal mines production is suitble to need.
In order to solve the above-mentioned technical problem, the present invention adopts the following technical scheme: a kind of hydraulic branch in environmentally friendly mine
Frame concentrate, the functional additive including 35-50% (weight percent) deionized water and 50-65% (weight percent),
The functional additive includes vegetable oil acid soap, polybasic carboxylic acid slushing compound, plant polyenoid phenol surfactant, extreme boundary lubrication
Agent, EDETATE SODIUM, monoethanolamine, sodium benzoate, glycerine, benzotriazole, silicone emulsion, each parts by weight in concentrate
For,
As a further improvement of the present invention, the vegetable oil acid soap selects tall oil acid, a tall oil acid and portion
Oleate soap lubricant is made in 2 hours in 80 DEG C of triethanolamine reactions.
As a further improvement of the present invention, the polybasic carboxylic acid slushing compound includes binary acid, ternary acid, three ethyl alcohol
Amine, using binary acid, ternary acid, triethanolamine 1:2:6 mass ratio, be warming up to 80 DEG C of -100 DEG C of reactions and be made, until reaction
Object bubble-free generates, and being considered as reaction terminates.
As a further improvement of the present invention, the plant polyenoid phenol surfactant is a kind of biodegradable water-wetted surface of energy
Activating agent.
As a further improvement of the present invention, the extreme-pressure lubricant is the double rouge of polyvinyl alcohol.
As a further improvement of the present invention, the EDETATE SODIUM is disodium ethylene diamine tetraacetate.
As a further improvement of the present invention, the monoethanolamine concentration is 99%.
A kind of preparation method of environmentally friendly mine hydraulic support concentrate, it is characterised in that:
Step 1: deionized water, monoethanolamine, EDETATE SODIUM, sodium benzoate, glycerine, benzo is added with this in blending kettle 1
Triazole, silicone emulsion, are sufficiently stirred, and are uniformly dissolved spare.
Step 2: vegetable oil acid soap, polybasic carboxylic acid slushing compound, plant polyenoid phenol table being added with this in blending kettle 2 and lived
Agent, extreme-pressure lubricant heat 70-80 degree, sufficiently dissolve, stir evenly.
Step 3: the material being uniformly dissolved in blending kettle 1 being added in blending kettle 2 through filter, blending kettle 2 stops adding
2 hours are sufficiently stirred in heat, and until stirring evenly, sample examination is qualified, and production finishes.
Compared with prior art, the device have the advantages that are as follows: concentrate appearance of the present invention is good, as clear as crystal, nothing
Penetrating odor, non-volatile substance, used raw material is all biodegradable, environmentally protective.
Specific embodiment
In order to which technical solution of the present invention and beneficial effect are more clearly understood, combined with specific embodiments below to the present invention
It is described in further detail, it should be understood that the specific embodiments described herein are only used for understanding the present invention, and do not have to
Of the invention, the every other implementation obtained by those of ordinary skill in the art without making creative efforts in limiting
Example,
A kind of environmentally friendly mine hydraulic support concentrate, including 35-50% (weight percent) deionized water and 50-
The functional additive of 65% (weight percent), the functional additive include vegetable oil acid soap, polybasic carboxylic acid antirust profit
Lubrication prescription, plant polyenoid phenol surfactant, extreme-pressure lubricant, EDETATE SODIUM, EDTA disodium, monoethanolamine, sodium benzoate, glycerine,
Benzotriazole, silicone emulsion, each parts by weight are in concentrate,
The vegetable oil acid soap selects tall oil acid, and a tall oil acid reacts 2 hours with a 80 DEG C of triethanolamine to be made
At oleate soap lubricant.
The polybasic carboxylic acid slushing compound includes binary acid, ternary acid, triethanolamine, using binary acid, ternary acid, three
The mass ratio of ethanol amine 1:2:6 is warming up to 80 DEG C of -100 DEG C of reactions and is made, and until the generation of reactant bubble-free, is considered as reaction knot
Beam.
The plant polyenoid phenol surfactant is a kind of biodegradable hydrophilic surfactant of energy.
The extreme-pressure lubricant is the double rouge of polyvinyl alcohol.
The EDETATE SODIUM is disodium ethylene diamine tetraacetate.
The monoethanolamine concentration is 99%.
Embodiment 1
Each parts by weight in concentrate are as follows: 35 parts of deionized water, 6 parts of vegetable oil acid soap, polybasic carboxylic acid slushing compound 26
Part, 6 parts of surfactant of plant polyenoid phenol, 6 parts of extreme-pressure lubricant, 2 parts of EDETATE SODIUM, monoethanolamine 2, part, 2 parts of sodium benzoate, third
6 parts of triol, 0.1 part of benzotriazole, 0.1 part of silicone emulsion.
Step 1: 35 parts of deionized water, 2 parts of monoethanolamine, 2 parts of EDETATE SODIUM, sodium benzoate 2 is added with this in blending kettle 1
Part, 6 parts of glycerine, 0.1 part of benzotriazole, 0.1 part of silicone emulsion, are sufficiently stirred, are uniformly dissolved spare.
Step 2: it is mostly dilute that 6 parts of vegetable oil acid soap, 26 parts of polybasic carboxylic acid slushing compound, plant being added with this in blending kettle 2
6 parts of phenol surfactant, 6 parts of extreme-pressure lubricant.80 degree of heating is sufficiently dissolved, is stirred evenly.
Step 3: the material being uniformly dissolved in blending kettle 1 being added in blending kettle 2 through filter, blending kettle 2 stops adding
2 hours are sufficiently stirred in heat, and until stirring evenly, sample examination is qualified, and production finishes.
Embodiment 2
Each parts by weight in concentrate are as follows: 45 parts of deionized water, 7 parts of vegetable oil acid soap, polybasic carboxylic acid slushing compound 20
Part, 8 parts of surfactant of plant polyenoid phenol, 4 parts of extreme-pressure lubricant, 4 parts of EDETATE SODIUM, 3 parts of monoethanolamine, 3 parts of sodium benzoate, the third three
7 parts of alcohol, 0.2 part of benzotriazole, 0.3 part of silicone emulsion.
Step 1: 45 parts of deionized water, 3 parts of monoethanolamine, 4 parts of EDETATE SODIUM, sodium benzoate 3 is added with this in blending kettle 1
Part, 7 parts of glycerine, 0.2 part of benzotriazole, 0.3 part of silicone emulsion, are sufficiently stirred, are uniformly dissolved spare.
Step 2: it is mostly dilute that 7 parts of vegetable oil acid soap, 20 parts of polybasic carboxylic acid slushing compound, plant being added with this in blending kettle 2
8 parts of phenol surfactant, 4 parts of extreme-pressure lubricant.80 degree of heating is sufficiently dissolved, is stirred evenly.
Step 3: the material being uniformly dissolved in blending kettle 1 being added in blending kettle 2 through filter, blending kettle 2 stops adding
2 hours are sufficiently stirred in heat, and until stirring evenly, sample examination is qualified, and production finishes.
Embodiment 3
Each parts by weight in concentrate are as follows: 40 parts of deionized water, 9 parts of vegetable oil acid soap, polybasic carboxylic acid slushing compound 24
Part, 6 parts of surfactant of plant polyenoid phenol, 3 parts of extreme-pressure lubricant, 4 parts of EDETATE SODIUM, 4 parts of monoethanolamine, 2 parts of sodium benzoate, the third three
8 parts of alcohol, 0.2 part of benzotriazole, 0.2 part of silicone emulsion.
Step 1: 40 parts of deionized water, 4 parts of monoethanolamine, 4 parts of EDETATE SODIUM, sodium benzoate 2 is added with this in blending kettle 1
Part, 8 parts of glycerine, 0.2 part of benzotriazole, 0.2 part of silicone emulsion, are sufficiently stirred, are uniformly dissolved spare.
Step 2: it is mostly dilute that 9 parts of vegetable oil acid soap, 24 parts of polybasic carboxylic acid slushing compound, plant being added with this in blending kettle 2
6 parts of phenol surfactant, 3 parts of extreme-pressure lubricant.80 degree of heating is sufficiently dissolved, is stirred evenly.
Step 3: the material being uniformly dissolved in blending kettle 1 being added in blending kettle 2 through filter, blending kettle 2 stops adding
2 hours are sufficiently stirred in heat, and until stirring evenly, sample examination is qualified, and production finishes.
Embodiment 4
Each parts by weight in concentrate are as follows: 50 parts of deionized water, 12 parts of vegetable oil acid soap, polybasic carboxylic acid slushing compound 22
Part, 7 parts of surfactant of plant polyenoid phenol, 2 parts of extreme-pressure lubricant, 3 parts of EDETATE SODIUM, monoethanolamine 4, part, 4 parts of sodium benzoate, third
9 parts of triol, 0.3 part of benzotriazole, 0.5 part of silicone emulsion.
Step 1: 50 parts of deionized water, 4 parts of monoethanolamine, 3 parts of EDETATE SODIUM, sodium benzoate 4 is added with this in blending kettle 1
Part, 9 parts of glycerine, 0.3 part of benzotriazole, 0.5 part of silicone emulsion, are sufficiently stirred, are uniformly dissolved spare.
Step 2: it is mostly dilute that 12 parts of vegetable oil acid soap, 22 parts of polybasic carboxylic acid slushing compound, plant being added with this in blending kettle 2
7 parts of phenol surfactant, extreme-pressure lubricant, 2 parts.80 degree of heating is sufficiently dissolved, is stirred evenly.
Step 3: the material being uniformly dissolved in blending kettle 1 being added in blending kettle 2 through filter, blending kettle 2 stops adding
2 hours are sufficiently stirred in heat, and until stirring evenly, sample examination is qualified, and production finishes.
Claims (8)
1. a kind of environmentally friendly mine hydraulic support concentrate, it is characterised in that: including 35-50% (weight percent) go from
The functional additive of sub- water and 50-65% (weight percent), the functional additive include vegetable oil acid soap, polynary carboxylic
Sour slushing compound, plant polyenoid phenol surfactant NSF10, extreme-pressure lubricant, EDETATE SODIUM, EDETATE SODIUM, monoethanolamine, benzene first
Sour sodium, glycerine, benzotriazole, silicone emulsion, each parts by weight are in concentrate,
2. a kind of environmentally friendly mine hydraulic support concentrate according to claim 1, it is characterised in that: the plant
Oleate soap selects tall oil acid, and a tall oil acid reacts 2 hours with a 80 DEG C of triethanolamine is made oleate soap lubricant.
3. a kind of environmentally friendly mine hydraulic support concentrate according to claim 1, it is characterised in that: described polynary
Carboxylic acid slushing compound includes binary acid, ternary acid, triethanolamine, using the matter of binary acid, ternary acid, triethanolamine 1:2:6
Ratio is measured, 80 DEG C of -100 DEG C of reactions is warming up to and is made, until reactant bubble-free generates, being considered as reaction terminates.
4. a kind of environmentally friendly mine hydraulic support concentrate according to claim 1, it is characterised in that: the plant
Polyenoid phenol surfactant NSF10 is a kind of biodegradable hydrophilic surfactant of energy.
5. a kind of environmentally friendly mine hydraulic support concentrate according to claim 1, it is characterised in that: the extreme pressure
Lubricant is the double rouge of polyvinyl alcohol.
6. a kind of environmentally friendly mine hydraulic support concentrate according to claim 1, it is characterised in that: the EDTA
Disodium is disodium ethylene diamine tetraacetate.
7. a kind of environmentally friendly mine hydraulic support concentrate according to claim 1, it is characterised in that: a second
Alcohol amine concentration is 99%.
8. a kind of a kind of preparation side of -7 any environmentally friendly mine hydraulic support concentrates according to claim 1
Method, it is characterised in that:
Step 1: deionized water, monoethanolamine, EDETATE SODIUM, sodium benzoate, glycerine, three nitrogen of benzo is added with this in blending kettle 1
Azoles, silicone emulsion, are sufficiently stirred, and are uniformly dissolved spare.
Step 2: vegetable oil acid soap, polybasic carboxylic acid slushing compound, plant polyenoid phenol surfactant being added with this in blending kettle 2
NSF10, extreme-pressure lubricant heat 70-80 degree, sufficiently dissolve, stir evenly.
Step 3: the material being uniformly dissolved in blending kettle 1 being added in blending kettle 2 through filter, blending kettle 2 stops heating, fills
Divide 2 hours of stirring, until stirring evenly, sample examination is qualified, and production finishes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910082781.6A CN109652188A (en) | 2019-01-29 | 2019-01-29 | A kind of environmentally friendly mine hydraulic support concentrate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910082781.6A CN109652188A (en) | 2019-01-29 | 2019-01-29 | A kind of environmentally friendly mine hydraulic support concentrate and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109652188A true CN109652188A (en) | 2019-04-19 |
Family
ID=66120902
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| CN114214103A (en) * | 2021-12-22 | 2022-03-22 | 河北中煤神海科技发展有限公司 | Hard water resistant lubricant, concentrated solution for hydraulic support and preparation method thereof |
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Application publication date: 20190419 |