CN109456005A - A kind of Polymer cement materials - Google Patents

A kind of Polymer cement materials Download PDF

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Publication number
CN109456005A
CN109456005A CN201811543571.4A CN201811543571A CN109456005A CN 109456005 A CN109456005 A CN 109456005A CN 201811543571 A CN201811543571 A CN 201811543571A CN 109456005 A CN109456005 A CN 109456005A
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China
Prior art keywords
equal
filler
polymer cement
mesh
cement materials
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Granted
Application number
CN201811543571.4A
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Chinese (zh)
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CN109456005B (en
Inventor
曾翠云
戴佳骏
黄仲周
王斌
吴靖
宋丹
万德刚
董峰亮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sikadegao Shanghai Building Materials Co ltd
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Parex (shanghai) Management Co Ltd
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Priority to CN201811543571.4A priority Critical patent/CN109456005B/en
Publication of CN109456005A publication Critical patent/CN109456005A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00293Materials impermeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00508Cement paints
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/10Mortars, concrete or artificial stone characterised by specific physical values for the viscosity
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A kind of Polymer cement materials, including liquid material component and powder component, the liquid material component includes vac-veova emulsion, the powder component includes cement, filler, 40~70 mesh sands, 71~140 mesh sands, the cement is more than or equal to 200 mesh, the filler is the filler more than or equal to 600 mesh, and the vac-veova emulsion includes more than or equal to 200nm and less than or equal to the emulsion particle of 300nm, and sand, cement, filler and emulsion particle form continuous grain composition.The present invention has good wettability, it is not necessary that formation level pre-wetting, roller coating construction is uniformly accessible when calcium silicate board with microporous butt face;Continuous grain composition allows mortar preferably roller coating uniform, and mortar is easily pushed open during roller coating, is coated with more uniform smooth, reach more excellent construction effect, while improving construction effect, cost of labor and time cost are reduced, is of great significance for the construction of waterproof mortar.

Description

A kind of Polymer cement materials
Technical field
The invention belongs to technical field of chemical paint, and in particular to a kind of Polymer cement materials.
Background technique
Polymer cement materials are made using cement, fine aggregate as main material, and building roofing is mainly used for And reparation or impervious processing, all kinds of ponds and the waterproof, seepage control of swimming pool of inside and outside wall leakage etc..Polymer-modified cement is anti- The history of existing more than 60 years of the application of water sand slurry only uses cement base hydraulicity waterproof material different, passes through polymer from traditional Modification, become double adhesive systems, and form a kind of state of complementation, high, the easy for construction, corrosion resistant with adhesion strength Erosion, high temperature resistant, ageing-resistant advantage.Polymer-modified cement waterproof mortar can be divided into one-component mortar and two-component mortar, root According to the difference of use scope and performance, bi-component water-proof mortar can be divided into flexible water mortar and rigid waterproofing mortar.
Flexible water mortar is the waterproof coating material with cracking resistance and extension power for resistance to compression or dampproofing location, GB/T 23445-2009 standard is executed mostly, and since its liquid powder is relatively high, and the lotion dosage in liquid material is more, therefore flexible Waterproof mortar has fabulous flexibility and cracking resistance, either brushes or roller coating all can be very smooth, workability is good.
For rigid waterproofing mortar for having certain bearing capacity or not needing the position of bearing capacity, cracking resistance is poor, holds mostly Row JC/T 2090-2011 or JC/T 984-2011 standard, since the liquid powder of the prior art is relatively low, wettability is lower, to applying The humidification of work basal plane is poor, and construction personnel just can be used after needing in advance to soak formation level with water, therefore existing skill Art is mainly constructed by the way of brushing, and is even needed to criticize sometimes to scrape construction, is not suitable for except a variety of condition of construction, applies Work efficiency rate is greatly reduced.
It batch scraping, brushing, in three kinds of construction technologies of roller coating, the construction efficiency of roller coating is higher, the more simple side of construction method Just and construction effect is good, thus provide it is a exempt to moisten, roller coating smoothly two-component polymer cement waterproofing mortar to waterproof Construction is necessary.
Summary of the invention
To solve defect and deficiency existing in the prior art, the main purpose of the present invention is to provide a kind of polymer waters Mud waterproof mortar, the waterproof mortar include vac-veova emulsion and continuous grain composition, the waterproof mortar before construction without pair The mode of roller coating can be used to construct for formation level pre-wetting, and roller coating is uniformly accessible, improves construction efficiency, have good Good construction effect, construction surface is flat and smooth, does not have granular concave sense.
In order to achieve the above objectives, the invention is realized by the following technical scheme:
A kind of Polymer cement materials, which is characterized in that including liquid material component and powder component, according to quality specific gravity The liquid material component includes:
Vac-veova emulsion 25%~45%;
Liquid defoaming agent 0.2%~0.4%;
Preservative 0.1%~0.3%;
Water 50%~74%;
Include: according to powder component described in quality specific gravity
40~70 mesh sands 10%~20%;
71~140 mesh sands 9%~37%;
Cement 40%~60%;
Filler 2%~10%;
Water-reducing agent 0.05%~0.2%;
Powder state defoaming agent 0.1~0.2%;
Hydrophober 0.2~0.4%;
Water-retaining agent 0.07~0.1%;
The cement is more than or equal to 200 mesh, and the filler is the filler more than or equal to 600 mesh, and the vac-veova emulsion includes More than or equal to 200nm and less than or equal to the emulsion particle of 300nm, the sand, cement, filler and vac-veova emulsion are formed continuously Grain composition.
Preferably, the mass ratio of the liquid material component and the powder component is 0.28:1~0.4:1.
Preferably, the vac-veova emulsion, be by vinylacetate, tertiary ethylene carbonate be main monomer copolymerizable at height Molecule lotion.
Preferably, the liquid defoaming agent includes organic silicon defoaming agent.
Preferably, the cement includes portland cement.
Preferably, the filler includes at least one of silicon ash, metakaolin, slag.
Preferably, the water-reducing agent includes in melamine water reducing agent, formal benzene sulfonic acid sodium salt and polycarboxylate water-reducer At least one.
Preferably, the powder state defoaming agent includes mineral oil defoaming agent.
Preferably, the hydrophober includes at least one of organosilicon moisture repellent, zinc stearate, calcium stearate.
Preferably, the water-retaining agent includes ethoxyl methyl cellulose ether, at least one in hydroxypropyl methyl cellulose ether Kind, viscosity is more than or equal to 10000mPa.S and is less than or equal to 40000mPa.S.
The invention has the following advantages:
1, the filler in this product has certain activity, can participate in alkaline reaction, is conducive to improve waterproof mortar Compactness makes waterproof mortar be not easy to sink to the bottom, and reaches good impervious effect;
2, the sand of this product is 40 mesh~70 mesh and 70 mesh~140 mesh quartz sand, due to 40 mesh~70 mesh quartz Sand is too thick, therefore is seldom used in waterproof mortar, but this product the quartz sand of two granular-grades is added in water inlet cement mortar, In coating, all particles are stacked, and the gap that big and small particle can mutually between filler particles, connection causes Close, compared with prior art, coating is more uniform, reaches better construction effect;
3, in this product granular size have 40 mesh~70 mesh sands, 70 mesh~140 mesh sand, cement more than 200 mesh, The emulsion particle of more than 600 mesh filler and 200nm~300nm forms a continuous grain composition, wetness degree Height does not need dry metope wetting process in the prior art so that mortar is conducive to roller coating construction in use, and Construction surface roller coating is uniform, and construction surface is flat and smooth, adhesion strength height, high temperature resistant, ageing-resistant advantages.
4, for the present inventor by many experiments, final choice is anti-as having for primary emulsion using nonionic surfactant Vac-veova emulsion is mainly applied in emulsion paint by the vac-veova emulsion of water alkali resistant ability in the prior art, since cement has by force Alkalinity, lotion can be demulsified when being added, thus decline emulsion intercalation method, and the present invention is added with water-proof alkali-resistant The vac-veova emulsion of ability, emulsion intercalation method improve, and can largely improve the wettability of waterproof mortar, the vinegar uncle cream Liquid based on non-ionic emulsifier system, have Calcium ion stability, be total to by vinylacetate, tertiary ethylene carbonate for principal monomer The macromolecule emulsion aggregated into, solid content 55%;
5, waterproof mortar of the invention has good wettability, and construction personnel is not necessarily to moisten formation level using preceding Wet, roller coating construction is uniformly accessible when calcium silicate board with microporous butt face, can preferably roller coating it is uniform, and mortar easily pushes away during roller coating Open, be coated with it is more uniform smooth, can reach more excellent construction effect, while improving construction effect, reduction manually at Sheet and time cost, are of great significance for the construction of waterproof mortar.
Specific embodiment
Above content of the invention is described in further detail again below by way of specific embodiment.But this should not be managed Solution is limited only to embodiment below for the range of the above-mentioned theme of the present invention.The case where not departing from above-mentioned technical idea of the invention Under, the various replacements or change made according to ordinary skill knowledge and customary means, should all include in model of the invention In enclosing.
Embodiment 1
The present invention provides a kind of Polymer cement materials, including liquid material component and powder component, in the present embodiment The ratio of liquid material component and powder component is 0.28:1, and the concrete content of each component is as shown in table 1-1:
The formula components table of table 1-1 embodiment 1
Above-mentioned liquid material is poured into clean stirring container, is then proportionally slowly added to powder while stirring, It is sufficiently stirred 3~5 minutes until generating without powder ball, uniform rubber cement.
It is tested according to Polymer cement materials of the national standard to the present embodiment, testing result such as table 1-2 institute Show:
The testing result table of table 1-2 embodiment 1
Embodiment 2
The present invention provides a kind of Polymer cement materials, including liquid material component and powder component, in the present embodiment The ratio of liquid material component and powder component is 0.34:1, and the concrete content of each component is as shown in table 2-1:
The formula components table of table 2-1 embodiment 2
Above-mentioned liquid material is poured into clean stirring container, is then proportionally slowly added to powder while stirring, It is sufficiently stirred 3~5 minutes until generating without powder ball, uniform rubber cement.
It is tested according to Polymer cement materials of the national standard to the present embodiment, testing result such as table 2-2 institute Show:
The testing result table of table 2-2 embodiment 2
Embodiment 3
The present invention provides a kind of Polymer cement materials, including liquid material component and powder component, in the present embodiment The ratio of liquid material component and powder component is 0.37:1, and the concrete content of each component is as shown in table 3-1:
The formula components table of table 3-1 embodiment 3
Above-mentioned liquid material is poured into clean stirring container, is then proportionally slowly added to powder while stirring, It is sufficiently stirred 3~5 minutes until generating without powder ball, uniform rubber cement.
It is tested according to Polymer cement materials of the national standard to the present embodiment, testing result such as table 3-2 institute Show:
The testing result table of table 3-2 embodiment 3
Embodiment 4
The present invention provides a kind of Polymer cement materials, including liquid material component and powder component, in the present embodiment The ratio of liquid material component and powder component is 0.40:1, and the concrete content of each component is as shown in table 4-1:
The formula components table of table 4-1 embodiment 4
Above-mentioned liquid material is poured into clean stirring container, is then proportionally slowly added to powder while stirring, It is sufficiently stirred 3~5 minutes until generating without powder ball, uniform rubber cement.
It is tested according to Polymer cement materials of the national standard to the present embodiment, testing result such as table 4-2 institute Show:
The testing result table of table 4-2 embodiment 4
Embodiment 5
The test experiments of waterproof mortar coating homogeneity provided by the invention, the specific steps are as follows:
(1) existing waterproof mortar and the waterproof mortar of Examples 1 to 4 are distinguished into uniform roller coating in (mixed on substrate with roller Solidifying soil layer, cement mortar coat of plaster) twice of roller coating, it, can roller coating second after first layer is solid (2~3 hours, just tack-free) Layer, roller coating direction are vertical with the roller coating direction of first layer;
(2) coating of the waterproof mortar of existing waterproof mortar and Examples 1 to 4 is measured respectively in the range of 1 square metre Bubble number, waterproof membrane thickness difference and mortar error.
Testing result is as shown in table 5:
5 waterproof mortar coating homogeneity test result of table
By table 5 and roller coating process it is found that when waterproof mortar of the invention is coated on butt face, without in advance to butt face Carry out wet processing, mortar is easily pushed open during roller coating, will not due to basal plane drying and generate obstruction;When coating is completed, this Bubble in invention mortar is few compared with the bubble of existing waterproof mortar, and coating is more uniform smooth, therefore this product is with good Wettability;
Waterproof mortar roller coating of the invention makes roller coating smooth when butt face, due to grain composition distinctive in mortar Without hindrance, mortar roller coating is uniform, and the difference of minimum and maximum coating layer thickness is about 8%~9% in 1 square metre, more existing waterproof Mortar is small, and roller coating waterproof mortar dosage error is about 8%~9% in 1 square metre, and horizontal and vertical roller coating effect is consistent, no The problems such as bulge, hangover can be generated and the more apply the more thin, the more existing waterproof mortar of roller coating effect is more smooth, uniform, therefore has Good roller coating application property.
In conclusion the indices of Polymer cement materials of the invention are up to state standards, have good Wettability can be preferably it is not necessary that formation level pre-wetting, roller coating construction is uniformly accessible when calcium silicate board with microporous butt face Roller coating is uniform, and mortar is easily pushed open during roller coating, and coating is more uniform smooth, can reach more excellent construction effect, While improving construction effect, cost of labor and time cost are reduced, is of great significance for the construction of waterproof mortar.
Each technical characteristic of above embodiments can be combined arbitrarily, for simplicity of description, not to above-described embodiment In each technical characteristic it is all possible combination be all described, as long as however, the combination of these technical characteristics be not present lance Shield all should be considered as described in this specification.
Only several embodiments of the present invention are expressed for above embodiments, and the description thereof is more specific and detailed, but can not Therefore it is construed as limiting the scope of the patent.It should be pointed out that for those of ordinary skill in the art, Under the premise of not departing from present inventive concept, various modifications and improvements can be made, and these are all within the scope of protection of the present invention. Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (10)

1. a kind of Polymer cement materials, which is characterized in that including liquid material component and powder component, according to quality specific gravity institute Stating liquid material component includes:
Vac-veova emulsion 25%~45%;
Liquid defoaming agent 0.2%~0.4%;
Preservative 0.1%~0.3%;
Water 50%~74%;
Include: according to powder component described in quality specific gravity
40~70 mesh sands 10%~20%;
71~140 mesh sands 9%~37%;
Cement 40%~60%;
Filler 2%~10%;
Water-reducing agent 0.05%~0.2%;
Powder state defoaming agent 0.1~0.2%;
Hydrophober 0.2~0.4%;
Water-retaining agent 0.07~0.1%;
The cement is more than or equal to 200 mesh, and the filler is the filler more than or equal to 600 mesh, and the vac-veova emulsion includes being greater than Equal to 200nm and less than or equal to the emulsion particle of 300nm, the sand, cement, filler and vac-veova emulsion form continuous particle Gradation.
2. a kind of Polymer cement materials according to claim 1, which is characterized in that the liquid material component with it is described The mass ratio of powder component is 0.28:1~0.4:1.
3. a kind of Polymer cement materials according to claim 1, which is characterized in that the vac-veova emulsion, be by Vinylacetate, tertiary ethylene carbonate be main monomer copolymerizable at macromolecule emulsion.
4. a kind of Polymer cement materials according to claim 1, which is characterized in that the liquid defoaming agent includes Organic silicon defoaming agent.
5. a kind of Polymer cement materials according to claim 1, which is characterized in that the cement includes silicate Cement.
6. a kind of Polymer cement materials according to claim 1, which is characterized in that the filler include silicon ash, At least one of metakaolin, slag.
7. a kind of Polymer cement materials according to claim 1, which is characterized in that the water-reducing agent includes trimerization At least one of cyanamide water-reducing agent, formal benzene sulfonic acid sodium salt and polycarboxylate water-reducer.
8. a kind of Polymer cement materials according to claim 1, which is characterized in that the powder state defoaming agent includes Mineral oil defoaming agent.
9. a kind of Polymer cement materials according to claim 1, which is characterized in that the hydrophober includes organic At least one of silicon hydrophober, zinc stearate, calcium stearate.
10. a kind of Polymer cement materials according to claim 1, which is characterized in that the water-retaining agent includes hydroxyl At least one of ethylmethylcellulose ether, hydroxypropyl methyl cellulose ether, viscosity are more than or equal to 10000mPa.S and are less than Equal to 40000mPa.S.
CN201811543571.4A 2018-12-17 2018-12-17 Polymer cement waterproof mortar Active CN109456005B (en)

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Application Number Priority Date Filing Date Title
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CN109456005B CN109456005B (en) 2022-03-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111470818A (en) * 2020-04-01 2020-07-31 苏州市兴邦化学建材有限公司 Polymer cement-based interface agent for self-leveling material and construction method
CN112226116A (en) * 2020-09-14 2021-01-15 西卡(上海)管理有限公司 Quick-drying waterproof facing slurry
CN112321230A (en) * 2020-11-02 2021-02-05 清远市德居新型建筑材料有限公司 Novel double-component polymer light mortar formula

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111470818A (en) * 2020-04-01 2020-07-31 苏州市兴邦化学建材有限公司 Polymer cement-based interface agent for self-leveling material and construction method
CN112226116A (en) * 2020-09-14 2021-01-15 西卡(上海)管理有限公司 Quick-drying waterproof facing slurry
CN112321230A (en) * 2020-11-02 2021-02-05 清远市德居新型建筑材料有限公司 Novel double-component polymer light mortar formula

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