CN109440118A - The formula and production method of the universal water-based metal cleaning agent of novel non-phosphate environmental protection - Google Patents
The formula and production method of the universal water-based metal cleaning agent of novel non-phosphate environmental protection Download PDFInfo
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- CN109440118A CN109440118A CN201811325617.5A CN201811325617A CN109440118A CN 109440118 A CN109440118 A CN 109440118A CN 201811325617 A CN201811325617 A CN 201811325617A CN 109440118 A CN109440118 A CN 109440118A
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- agent
- phosphate
- environmental protection
- based metal
- cleaning agent
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of formulas of the universal water-based metal cleaning agent of novel non-phosphate environmental protection, by weight, its formula composition are as follows: diethanol amine 5.0-13.0%, decanedioic acid 3.0-6.0%, triazole 0.1-0.5%, n-nonanoic acid 1.0-3.0%, antirust agent 2.0-5.0%, surfactant 2.0-5.0%, organosilicon 1.0-3.0%, sodium citrate 2.0-3.0%, silicon class defoaming agent 0.1-0.3%, sodium hydroxide 5.0-10.0%, deionized water 50.0-70.0%, the present invention have excellent cleaning, low bubble property, rust-preventing characteristic and resistance to aluminium corrosivity.
Description
Technical field
The invention belongs to clean the waterborne cleaning agent technical field of metal works, a specifically novel non-phosphate environmental protection is universal
Waterborne cleaning agent.
Background technique
Metal cleaner diesel oil substitute, kerosene and gasoline can clean part well, for machining and machinery is set
The maintenance and repair of standby, automobile etc., and it is cheap, and use is safe, is well suited for mechanized cleaning operation.As the world is each
Gradually attention of the state to environmental protection, Phosphateless environmentally friendly water-based metal cleaning agent gradually become one of most important developing direction of cleaning agent.
Summary of the invention
In view of the deficiencies of the prior art, have excellent cleaning, low bubble property, rust-preventing characteristic and resistance to the present invention provides a kind of
The formula of the universal water-based metal cleaning agent of the corrosive novel non-phosphate environmental protection of aluminium
To achieve the above object, the present invention provides the following technical scheme that a kind of universal aqueous gold of novel non-phosphate environmental protection
Belong to the formula of cleaning agent, by weight, formula composition are as follows: diethanol amine 5.0-13.0%, decanedioic acid 3.0-6.0%, three
Nitrogen azoles 0.1-0.5%, n-nonanoic acid 1.0-3.0%, antirust agent 2.0-5.0%, surfactant 2.0-5.0%, organosilicon 1.0-
3.0%, sodium citrate 2.0-3.0%, silicon class defoaming agent 0.1-0.3%, sodium hydroxide 5.0-10.0%, deionized water 50.0-
70.0%.
A kind of production method of the universal water-based metal cleaning agent of novel non-phosphate environmental protection, includes the following steps, by diethanol
Amine, decanedioic acid, triazole, n-nonanoic acid, antirust agent, surfactant, organosilicon, sodium citrate, silicon class defoaming agent, sodium hydroxide and
Deionized water sequentially adds blender, stirs evenly, and the speed of agitator is 1000 turns/min, and whipping temp is 40 DEG C, stirring
Time 45min.
Compared with prior art, the beneficial effects of the present invention are: having excellent cleaning ability, foam is relatively low, fits
It is not phosphorous suitable for the cleaning of ferrous metal and non-ferrous metal workpiece for ultrasonic wave and spray cleaning, environment will not be caused
The problem of eutrophication；The present invention has excellent stability.In storage and in use, not stratified and precipitation sediment, is not easy
Corruption has excellent chemistry, thermostability and the versatility to the cleaning of all kinds of metal materials and cleaning way, has excellent
Cleaning, low bubble property, rust-preventing characteristic and resistance to aluminium corrosivity.
Specific embodiment
Embodiment one:
A kind of formula of the universal water-based metal cleaning agent of novel non-phosphate environmental protection, by weight, formula composition are as follows: two
Ethanol amine 7.0%, triazole 0.1%, n-nonanoic acid 2.0%, antirust agent 3.0%, surfactant 2.5%, has decanedioic acid 4.0%
Machine silicon 2.3%, sodium citrate 2.0%, silicon class defoaming agent 0.1%, 7.0% sodium hydroxide, deionized water 70%.
Production method are as follows: by diethanol amine 7.0%, decanedioic acid 4.0%, triazole 0.1%, n-nonanoic acid 2.0%, antirust agent
3.0%, surfactant 2.5%, organosilicon 2.3%, sodium citrate 2.0%, silicon class defoaming agent 0.1%, 7.0% hydroxide
Sodium, deionized water 70% sequentially adds blender, stirs evenly, and the speed of agitator is 1000 turns/min, whipping temp 40
DEG C, mixing time 45min is to get to the colorless and transparent universal water-based metal cleaning agent of Phosphateless environmentally friendly of the present invention.
Embodiment two:
A kind of formula of the universal water-based metal cleaning agent of novel non-phosphate environmental protection, by weight, formula composition are as follows: two
Ethanol amine 8.0%, triazole 0.1%, n-nonanoic acid 2.5%, antirust agent 3.0%, surfactant 2.6%, has decanedioic acid 5.0%
Machine silicon 1.5%, sodium citrate 2.0%, silicon class defoaming agent 0.1%, sodium hydroxide 6.0%, deionized water 69.2%.
Production method are as follows: by diethanol amine 8.0%, decanedioic acid 5.0%, triazole 0.1%, n-nonanoic acid 2.5%, antirust agent
3.0%, surfactant 2.6%, organosilicon 1.5%, sodium citrate 2.0%, silicon class defoaming agent 0.1%, sodium hydroxide
6.0%, deionized water 69.2% sequentially adds blender, stirs evenly, and the speed of agitator is 1000 turns/min, whipping temp
It is 40 DEG C, mixing time 45min is to get to the colorless and transparent universal water-based metal cleaning agent of Phosphateless environmentally friendly of the present invention.
Embodiment three:
A kind of formula of the universal water-based metal cleaning agent of novel non-phosphate environmental protection, by weight, formula composition are as follows: two
Ethanol amine 8.5%, triazole 0.1%, n-nonanoic acid 3.0%, antirust agent 3.0%, surfactant 3.0%, has decanedioic acid 5.5%
Machine silicon 2.5%, sodium citrate 2.5%, silicon class defoaming agent 0.1%, 6.0% sodium hydroxide, deionized water 65.8%.
Production method are as follows: by diethanol amine 8.5%, decanedioic acid 5.5%, triazole 0.1%, n-nonanoic acid 3.0%, antirust agent
3.0%, surfactant 3.0%, organosilicon 2.5%, sodium citrate 2.5%, silicon class defoaming agent 0.1%, 6.0% hydroxide
Sodium, deionized water 65.8%, sequentially add blender, stir evenly, and the speed of agitator is 1000 turns/min, and whipping temp is
40 DEG C, mixing time 45min is to get to the colorless and transparent universal water-based metal cleaning agent of Phosphateless environmentally friendly of the present invention.
Embodiment 1-3 cleaning agent is tested for the property, as a result as shown in the table.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (2)
1. a kind of formula of the universal water-based metal cleaning agent of novel non-phosphate environmental protection, which is characterized in that by weight, formula
Composition are as follows: diethanol amine 5.0-13.0%, decanedioic acid 3.0-6.0%, triazole 0.1-0.5%, n-nonanoic acid 1.0-3.0%, antirust
Agent 2.0-5.0%, surfactant 2.0-5.0%, organosilicon 1.0-3.0%, sodium citrate 2.0-3.0%, silicon class defoaming agent
0.1-0.3%, sodium hydroxide 5.0-10.0%, deionized water 50.0-70.0%.
2. a kind of production method of the universal water-based metal cleaning agent of novel non-phosphate environmental protection, it is characterised in that: include the following steps,
By diethanol amine, decanedioic acid, triazole, n-nonanoic acid, antirust agent, surfactant, organosilicon, sodium citrate, silicon class defoaming agent, hydrogen
Sodium oxide molybdena and deionized water sequentially add blender, stir evenly, and the speed of agitator is 1000 turns/min, whipping temp 40
DEG C, mixing time 45min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811325617.5A CN109440118A (en) | 2018-11-08 | 2018-11-08 | The formula and production method of the universal water-based metal cleaning agent of novel non-phosphate environmental protection |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811325617.5A CN109440118A (en) | 2018-11-08 | 2018-11-08 | The formula and production method of the universal water-based metal cleaning agent of novel non-phosphate environmental protection |
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| Publication Number | Publication Date |
|---|---|
| CN109440118A true CN109440118A (en) | 2019-03-08 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811325617.5A Pending CN109440118A (en) | 2018-11-08 | 2018-11-08 | The formula and production method of the universal water-based metal cleaning agent of novel non-phosphate environmental protection |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103046066A (en) * | 2013-01-08 | 2013-04-17 | 上海尤希路化学工业有限公司 | High-performance and environment-friendly water-based cleaning agent |
| CN107904028A (en) * | 2017-11-24 | 2018-04-13 | 重庆信人科技发展有限公司 | A kind of environment-friendly aqueous industrial cleaning agent of low cod value |
| CN108034954A (en) * | 2017-11-30 | 2018-05-15 | 珠海横琴思国科技发展有限公司 | A kind of anti-rust cleaning agent of aluminium and aluminium alloy and preparation method thereof |
| CN108315748A (en) * | 2018-02-09 | 2018-07-24 | 东莞华拓研磨材料有限公司 | A kind of metal cleaner and preparation method thereof |
| CN108385121A (en) * | 2018-04-20 | 2018-08-10 | 苏州龙腾万里化工科技有限公司 | A kind of cleaning agent that dirt-removing power is strong |
| CN108425123A (en) * | 2018-06-14 | 2018-08-21 | 如皋市华阳铝制品有限公司 | A kind of anti-rust cleaning agent and preparation method thereof of aluminium and aluminium alloy |
| CN108728855A (en) * | 2018-07-04 | 2018-11-02 | 怀宁县恒源再生科技有限公司 | A kind of steel surface cleaning agent and preparation method thereof |
-
2018
- 2018-11-08 CN CN201811325617.5A patent/CN109440118A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103046066A (en) * | 2013-01-08 | 2013-04-17 | 上海尤希路化学工业有限公司 | High-performance and environment-friendly water-based cleaning agent |
| CN107904028A (en) * | 2017-11-24 | 2018-04-13 | 重庆信人科技发展有限公司 | A kind of environment-friendly aqueous industrial cleaning agent of low cod value |
| CN108034954A (en) * | 2017-11-30 | 2018-05-15 | 珠海横琴思国科技发展有限公司 | A kind of anti-rust cleaning agent of aluminium and aluminium alloy and preparation method thereof |
| CN108315748A (en) * | 2018-02-09 | 2018-07-24 | 东莞华拓研磨材料有限公司 | A kind of metal cleaner and preparation method thereof |
| CN108385121A (en) * | 2018-04-20 | 2018-08-10 | 苏州龙腾万里化工科技有限公司 | A kind of cleaning agent that dirt-removing power is strong |
| CN108425123A (en) * | 2018-06-14 | 2018-08-21 | 如皋市华阳铝制品有限公司 | A kind of anti-rust cleaning agent and preparation method thereof of aluminium and aluminium alloy |
| CN108728855A (en) * | 2018-07-04 | 2018-11-02 | 怀宁县恒源再生科技有限公司 | A kind of steel surface cleaning agent and preparation method thereof |
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| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190308 |