CN109439069A - A kind of preparation method of ceramic ink jet ink brown colorant - Google Patents
A kind of preparation method of ceramic ink jet ink brown colorant Download PDFInfo
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- CN109439069A CN109439069A CN201811082983.2A CN201811082983A CN109439069A CN 109439069 A CN109439069 A CN 109439069A CN 201811082983 A CN201811082983 A CN 201811082983A CN 109439069 A CN109439069 A CN 109439069A
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- ink jet
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
Abstract
The invention discloses a kind of preparation method of ceramic ink jet ink brown colorant, include the following steps: that S1. weighs super fine zinc oxide, superfine iron oxide, ultra-fine chromium oxide and ultra-fine alumina, is uniformly mixed；S2. the temperature lower calcination 2-4h by mixture at 1310-1350 DEG C；S3. calcined crushing material is sieved.The industrial chemicals that the present invention uses, low in cost, the brown colorant bright color of acquisition, yellow value degree are high, it is colour-stable to be in, and when the brown colorant of preparation is used for ceramic ink jet printing, resulting ceramic ink jet ink color development is stable, has widened the gamut range of colorant.
Description
Technical field
The present invention relates to ceramic pigment technical fields, more particularly to a kind of ceramic ink jet ink brown colorant
Preparation method.
Background technique
Ceramic ink jet technology is a kind of contactless digital printing technologies, it is by ink made of ceramic pigment powder
Water, by small ink droplet from the surface that the nozzle of diameter some tens of pm is sprayed onto architectural pottery, the decoration technique of colour generation after firing, decoration
Pattern shape and geometric dimension controlled by computer.Ceramic ink jet technology has abandoned the cumbersome (such as silk of Conventional decal mode
Wire mark flower and roller printing), the spray printing directly on green body improves the precision of stamp, changeable pattern modelling situation is realized,
Therefore the tile shaped produced is as more true to nature, closer to nature.
Since China in 2009 introduces First ceramic ink jet machine, the development of ceramic ink jet printing technology is advanced by leaps and bounds,
And get a lot of applications, the requirement of corresponding various ceramic ink jet ink also increases severely.Inkjet printing technology is in ceramics
Key application be the preparation of ceramic ink, ceramic ink jet ink is by colorant, solvent, dispersing agent, link stuff and other to help
Agent is formed.
Brown colorant is a kind of color that current ceramic pigment field answers usage amount very big, due to its unique spinelle knot
Structure, when firing colorant, simple process, production are stablized；Either in the application of low temperature tile or high temperature Antique Imitation Tiles, brown color
Material can keep its very strong color development ability, be also in this way, brown series colorant is in porcelain when being equally used in ceramic ink
Application on brick has the tendency that substantially being replaced by brown ceramic ink, thus reinforces to brown colorant answering in ceramic ink
With research, it is very important.Conventional ceramic ink jet ink is with brown colorant using additional a large amount of mineralizer low temperature calcinations
Method production, due to the presence of a large amount of mineralizers, the brown colorant of firing has that moisture content is high, conductivity is high,
It needs again to wash colorant when being used to prepare ceramic ink, dry, remove the salinity in colorant, reduce moisture content,
This will lead to generate a large amount of wastes in water-washing process, and the sewage for washing generation has larger pressure to sewage treatment, is unfavorable for
Environmental protection virtually increases cost；In addition, conventional brown colorant when being prepared into ceramic ink jet ink, is needed by being sanded
Machine is ground, and the partial size of brown colorant is less than 1 micron, and the appearance of existing brown colorant, color development can produce very big
Variation, reduces the gamut range of colorant.
Summary of the invention
In order to make up the defect of prior art, the present invention provides a kind of preparation side of ceramic ink jet ink brown colorant
Method.
The technical problems to be solved by the invention are achieved by the following technical programs:
A kind of ceramic ink jet ink preparation method of brown colorant, includes the following steps:
S1. super fine zinc oxide, superfine iron oxide, ultra-fine chromium oxide and ultra-fine alumina are weighed, is uniformly mixed；
S2. the temperature lower calcination 2-4h by mixture at 1310-1350 DEG C；
S3. calcined crushing material is sieved.
Further, the fineness D100 of the super fine zinc oxide is no more than 8 μm.
Further, the fineness D100 of the superfine iron oxide is no more than 8 μm.
Further, the fineness D100 of the ultra-fine chromium oxide is no more than 8 μm.
Further, the fineness D100 of the ultra-fine alumina is no more than 8 μm.
Further, the crystal phase of the brown colorant is made of franklinite, zinc chrome spinelle and gahnite.
Inventor is having been surprisingly found that during the test, by selecting ultra-fine raw material, makes the grain fineness of each raw material
D100 is no more than 8 μm, and the gamut range of the brown colorant of synthesis is extensively more many than conventional brown colorant, especially in cadmium yellow tone
On can be significantly improved, yellow value degree can be improved 30%.
There is no specific restriction super fine zinc oxide, superfine iron oxide, ultra-fine chromium oxide and ultra-fine aluminas in the present invention
Proportion, those skilled in the art can be adjusted according to actual needs, as long as making ceramic ink jet ink brown obtained
The crystal phase of colorant is made of franklinite, zinc chrome spinelle and gahnite.It is super by adjusting raw material in the present invention
The proportion of thin zinc oxide, superfine iron oxide, ultra-fine chromium oxide and ultra-fine alumina, and then adjust zinc in finally obtained colorant
The content ratio of hercynite, zinc chrome spinelle and gahnite, it is available by adjusting the content ratio of three kinds of spinelles
Brown colorant series is from cadmium yellow to the product of dark red tone.
It should be noted that raw material of the invention does not include mineralizer.
Mineralizer can promote the reaction of colorant group, reduce the temperature of colorant synthesis, and be prepared into ceramic ink requirement
The conductivity of colorant is as low as possible, since mineralizer belongs to soluble-salt substance, can increase substantially color containing mineralizing components
The conductivity of material can just be used to prepare ceramic ink this requires colorant needs to wash.The calcination temperature of conventional brown colorant
It is concentrated mainly on 1140-1180 DEG C, and existing its calcination temperature without using the brown colorant of mineralizer is concentrated mainly on 1250-
Between 1280 DEG C, traditionally calcination temperature is more than 1280 DEG C of qualities that can reduce colorant.But inventor surprisingly sends out in practice
It is existing, mineralizer is not added, using high-temperature calcination solid reaction process, calcination temperature is increased to 1310-1350 DEG C, can not only avoid
Colorant conductivity is excessively high, and prepare brown colorant be used for ceramic ink jet printing when, resulting ceramic ink jet ink color development is steady
Gamut range that is fixed, having widened colorant.
The invention has the following beneficial effects:
The industrial chemicals that the present invention uses, low in cost, the brown colorant bright color of acquisition, yellow value degree are high, it is colour-stable to be in, will
When the brown colorant of preparation is used for ceramic ink jet printing, resulting ceramic ink jet ink color development is stable, has widened the colour gamut of colorant
Range.
Specific embodiment
The present invention will now be described in detail with reference to examples, and the examples are only preferred embodiments of the present invention,
It is not limitation of the invention.
Embodiment 1
A kind of ceramic ink jet ink preparation method of brown colorant, includes the following steps:
S1. super fine zinc oxide, superfine iron oxide, ultra-fine chromium oxide and ultra-fine alumina are weighed, is uniformly mixed；
S2. the temperature lower calcination 3h by mixture at 1330 DEG C；
S3. calcined crushing material is sieved.
Wherein, the fineness D100 of the super fine zinc oxide is no more than 8 μm；The fineness D100 of the superfine iron oxide is no more than
8μm；The fineness D100 of the ultra-fine chromium oxide is no more than 8 μm；The fineness D100 of the ultra-fine alumina is no more than 8 μm.
The crystal phase of the brown colorant is made of franklinite, zinc chrome spinelle and gahnite.
Embodiment 2
A kind of ceramic ink jet ink preparation method of brown colorant, includes the following steps:
S1. super fine zinc oxide, superfine iron oxide, ultra-fine chromium oxide and ultra-fine alumina are weighed, is uniformly mixed；
S2. the temperature lower calcination 2h by mixture at 1310 DEG C；
S3. calcined crushing material is sieved.
Wherein, the fineness D100 of the super fine zinc oxide is no more than 8 μm；The fineness D100 of the superfine iron oxide is no more than
8μm；The fineness D100 of the ultra-fine chromium oxide is no more than 8 μm；The fineness D100 of the ultra-fine alumina is no more than 8 μm.
The crystal phase of the brown colorant is made of franklinite, zinc chrome spinelle and gahnite.
Embodiment 3
A kind of ceramic ink jet ink preparation method of brown colorant, includes the following steps:
S1. super fine zinc oxide, superfine iron oxide, ultra-fine chromium oxide and ultra-fine alumina are weighed, is uniformly mixed；
S2. the temperature lower calcination 4h by mixture at 1350 DEG C；
S3. calcined crushing material is sieved.
Wherein, the fineness D100 of the super fine zinc oxide is no more than 8 μm；The fineness D100 of the superfine iron oxide is no more than
8μm；The fineness D100 of the ultra-fine chromium oxide is no more than 8 μm；The fineness D100 of the ultra-fine alumina is no more than 8 μm.
The crystal phase of the brown colorant is made of franklinite, zinc chrome spinelle and gahnite.
Embodiments of the present invention above described embodiment only expresses, the description thereof is more specific and detailed, but can not
Therefore limitations on the scope of the patent of the present invention are interpreted as, as long as skill obtained in the form of equivalent substitutions or equivalent transformations
Art scheme should all be fallen within the scope and spirit of the invention.
Claims (6)
1. a kind of ceramic ink jet ink preparation method of brown colorant, includes the following steps:
S1. super fine zinc oxide, superfine iron oxide, ultra-fine chromium oxide and ultra-fine alumina are weighed, is uniformly mixed；
S2. the temperature lower calcination 2-4h by mixture at 1310-1350 DEG C；
S3. calcined crushing material is sieved.
2. the preparation method of ceramic ink jet ink brown colorant as described in claim 1, which is characterized in that the ultra-fine oxygen
The fineness D100 for changing zinc is no more than 8 μm.
3. the preparation method of ceramic ink jet ink brown colorant as described in claim 1, which is characterized in that the ultra-fine oxygen
The fineness D100 for changing iron is no more than 8 μm.
4. the preparation method of ceramic ink jet ink brown colorant as described in claim 1, which is characterized in that the ultra-fine oxygen
The fineness D100 for changing chromium is no more than 8 μm.
5. the preparation method of ceramic ink jet ink brown colorant as described in claim 1, which is characterized in that the ultra-fine oxygen
The fineness D100 for changing aluminium is no more than 8 μm.
6. the preparation method of ceramic ink jet ink brown colorant as described in claim 1, which is characterized in that the brown color
The crystal phase of material is made of franklinite, zinc chrome spinelle and gahnite.
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| CN201811082983.2A CN109439069A (en) | 2018-09-17 | 2018-09-17 | A kind of preparation method of ceramic ink jet ink brown colorant |
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| CN201811082983.2A CN109439069A (en) | 2018-09-17 | 2018-09-17 | A kind of preparation method of ceramic ink jet ink brown colorant |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115011174A (en) * | 2022-06-17 | 2022-09-06 | 佛山市三水区康立泰无机合成材料有限公司 | Black-brown ceramic pigment, black-brown ceramic ink and preparation method and application thereof |
| CN115304276A (en) * | 2022-08-03 | 2022-11-08 | 江西唯美陶瓷有限公司 | Composite glaze layer, ceramic plate and preparation method thereof |
| CN115572494A (en) * | 2022-09-27 | 2023-01-06 | 佛山市三水区康立泰无机合成材料有限公司 | Red-brown ceramic pigment, preparation method thereof and application of red-brown ceramic pigment in ceramic ink-jet printing ink |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717274A (en) * | 2009-12-19 | 2010-06-02 | 江门市道氏标准制釉股份有限公司 | Brown pigment for ceramic ink jet printing and preparation method thereof |
| CN102584339A (en) * | 2012-03-12 | 2012-07-18 | 佛山市三水金鹰无机材料有限公司 | Method for preparing brown ceramic pigment from red mud |
| US8440584B1 (en) * | 2010-12-23 | 2013-05-14 | Lehigh University | Methods for decontamination of powders |
| CN103224331A (en) * | 2013-04-27 | 2013-07-31 | 广东道氏技术股份有限公司 | Frit dry granules with characteristics of one-time sintering and golden brown color, and preparation method thereof |
| CN106145938A (en) * | 2015-04-27 | 2016-11-23 | 深圳市商德先进陶瓷有限公司 | Zirconia composite ceramics and preparation method thereof |
| CN108047763A (en) * | 2017-12-12 | 2018-05-18 | 佛山市大千色釉料有限公司 | A kind of ceramic pigment and preparation method thereof |
-
2018
- 2018-09-17 CN CN201811082983.2A patent/CN109439069A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717274A (en) * | 2009-12-19 | 2010-06-02 | 江门市道氏标准制釉股份有限公司 | Brown pigment for ceramic ink jet printing and preparation method thereof |
| US8440584B1 (en) * | 2010-12-23 | 2013-05-14 | Lehigh University | Methods for decontamination of powders |
| CN102584339A (en) * | 2012-03-12 | 2012-07-18 | 佛山市三水金鹰无机材料有限公司 | Method for preparing brown ceramic pigment from red mud |
| CN103224331A (en) * | 2013-04-27 | 2013-07-31 | 广东道氏技术股份有限公司 | Frit dry granules with characteristics of one-time sintering and golden brown color, and preparation method thereof |
| CN106145938A (en) * | 2015-04-27 | 2016-11-23 | 深圳市商德先进陶瓷有限公司 | Zirconia composite ceramics and preparation method thereof |
| CN108047763A (en) * | 2017-12-12 | 2018-05-18 | 佛山市大千色釉料有限公司 | A kind of ceramic pigment and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115011174A (en) * | 2022-06-17 | 2022-09-06 | 佛山市三水区康立泰无机合成材料有限公司 | Black-brown ceramic pigment, black-brown ceramic ink and preparation method and application thereof |
| CN115011174B (en) * | 2022-06-17 | 2023-09-12 | 佛山市三水区康立泰无机合成材料有限公司 | Black brown ceramic pigment, black brown ceramic ink, and preparation methods and applications thereof |
| CN115304276A (en) * | 2022-08-03 | 2022-11-08 | 江西唯美陶瓷有限公司 | Composite glaze layer, ceramic plate and preparation method thereof |
| CN115304276B (en) * | 2022-08-03 | 2023-12-26 | 东莞市唯美陶瓷工业园有限公司 | Composite glaze layer, ceramic plate and preparation method thereof |
| CN115572494A (en) * | 2022-09-27 | 2023-01-06 | 佛山市三水区康立泰无机合成材料有限公司 | Red-brown ceramic pigment, preparation method thereof and application of red-brown ceramic pigment in ceramic ink-jet printing ink |
| CN115572494B (en) * | 2022-09-27 | 2024-02-02 | 佛山市三水区康立泰无机合成材料有限公司 | Red brown ceramic pigment, preparation method thereof and application thereof in ceramic inkjet printing ink |
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