KR20100015112A - Manufacturing method of white-porcelain with loess - Google Patents
Manufacturing method of white-porcelain with loess Download PDFInfo
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- KR20100015112A KR20100015112A KR1020080076028A KR20080076028A KR20100015112A KR 20100015112 A KR20100015112 A KR 20100015112A KR 1020080076028 A KR1020080076028 A KR 1020080076028A KR 20080076028 A KR20080076028 A KR 20080076028A KR 20100015112 A KR20100015112 A KR 20100015112A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/001—Applying decorations on shaped articles, e.g. by painting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/04—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
- B28B11/044—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers with glaze or engobe or enamel or varnish
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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Abstract
Description
본 발명은 황토백자의 제조방법에 관한 것으로, 구체적으로는 황토를 이용하여 문양을 형성시킨 백자의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing ocher white porcelain, and more particularly, to a method of producing white porcelain formed with a pattern using ocher.
백자는 자기의 일종으로, 정제된 백토를 이용하여 기물을 형성시킨 후, 표면에 유약을 입혀 고온에서 소성하여 제조한다. 백자는 사용되는 백토 및 유약의 종류에 따라 색상에 차이가 나타나며, 안료를 이용하여 무늬를 그려넣거나 음양각을 주는 등의 방법으로 다양한 문양을 생성시킬 수 있다.White porcelain is a kind of porcelain, which is formed by using refined clay to form a substance, and then glazing on the surface and baking it at a high temperature. The white porcelain is different in color depending on the type of clay and glaze used, and various patterns can be created by using a pigment to draw a pattern or give an embossed relief.
문양을 형성시킨 대표적인 백자로는 상감백자, 철화백자, 진사백자, 청화백자 등을 들 수 있다. 이중 상감백자는 기면에 음각으로 무늬를 내고 그 홈에 색상이 있는 흙을 메꿔넣는 방식으로 제조하고, 철화백자는 산화철을 주성분으로 하는 안료로 문양을 그려넣는 방식으로 제조하며, 진사백자는 산화동을 이용하여 문양을 그려넣는 방식으로 제조하고, 청화백자는 산화코발트 성분의 안료를 이용하여 무늬를 그려넣는 방식으로 제조한다. 안료를 이용하여 그려넣은 문양의 색상은 철화백 자의 경우 검은색, 진사백자의 경우 붉은색, 청화백자의 경우 푸른색을 나타낸다.Representative white porcelains that form patterns include inlaid white, iron white, cinnabar white, and blue and white. The inlaid whites are manufactured by engraving the surface with intaglio on the surface and filling the colored soil in the grooves, and the whites of iron trioxide are manufactured by drawing patterns with pigments composed mainly of iron oxide. It is prepared by drawing a pattern by using, and blue and white porcelain is prepared by drawing a pattern using a pigment of cobalt oxide component. The color of the pattern drawn using the pigment is black for white iron, white for cinnabar white, and blue for cyan white.
한편, 본 발명에서는 종래 주로 이용되던 검은색, 붉은색, 푸른색과는 차별되는 자연스러운 갈색 또는 회청색을 나타낼 뿐 아니라, 비용도 저렴하여 기면 전체에도 부담없이 도포할 수 있는 새로운 안료를 이용하여 백자에 문양을 생성시키는 방법을 제공한다.On the other hand, the present invention not only exhibits a natural brown or gray-blue color that is different from the conventionally used black, red, and blue, but also is inexpensive and uses a new pigment that can be applied to the entire surface without any burden on the white porcelain. Provides a way to create a glyph.
본 발명에서는 자연스러운 갈색 또는 회청색으로 문양을 형성시킨 백자의 제조방법을 제공하고자 한다.In the present invention, to provide a method of producing white porcelain formed a pattern of natural brown or gray-blue.
또한, 본 발명에서는 비용이 저렴하면서도 쉽게 구할 수 있을 뿐 아니라 안전하고 친환경적인 재료를 이용하여 문양을 형성시킨 백자의 제조방법을 제공하고자 한다.In addition, the present invention is to provide a method of manufacturing white porcelain, which is not only cheap and easy to obtain but also forms a pattern using a safe and environmentally friendly material.
상기 목적을 달성하기 위하여, 본 발명에서는 황토를 이용하여 백자에 문양을 형성시키는 방법을 제공한다.In order to achieve the above object, the present invention provides a method for forming a pattern on the white porcelain using ocher.
황토는 손쉽게 구할 수 있을 뿐 아니라 인체에 무해한 재료이므로, 자기의 안료로 사용하기에 적합한 특징이 있다. 그러나, 통상적인 황토를 그대로 이용하여 채색할 경우에는 고르지 못한 입자로 인하여 채색면의 질감이 거칠 뿐 아니라, 황토에 포함되어 있는 철 성분이 소성과정에서 검게 변하여 반점 형태의 얼룩이 생성되는 문제가 있다. 따라서, 상대적으로 질이 떨어지는 토기의 재료로 사용하거나, 또는 유약 등 재료의 일부로 소량을 혼합하여 사용하는 경우에는 문제가 없으나, 황토 자체의 갈색을 살려 본격적인 안료로 사용할 경우에는 제품의 가치가 떨어지므로 실질적으로 안료로 사용하기에는 무리가 있었다.Ocher is not only easily available but also harmless to the human body, so it is suitable for use as a pigment of porcelain. However, in the case of coloring using conventional loess as it is, there is a problem that not only the texture of the colored surface is rough due to the uneven particles, but also the iron component contained in the loess turns black during the calcination process, resulting in spot-like stains. Therefore, there is no problem in using a small amount of earthenware as a material of relatively poor quality or by mixing a small amount as a part of a material such as glaze. It was practically impossible to use it as a pigment.
따라서, 본 발명에서는 자석을 이용하여 황토로부터 철 성분을 제거한 후 이를 안료로 사용한다. 이때, 황토로 둘러쌓여 상대적으로 입자가 큰 철 성분의 경우 자석을 이용하여 제거되지 못하고 남아있는 경우가 종종 발생하며, 이는 소성 후 얼룩이 생기는 원인이 되어 제품의 가치를 떨어뜨리는 원인이 되므로, 철 성분의 제거에 앞서 황토분말을 미세하게 분쇄함으로써 상기 문제를 사전에 방지한다.Therefore, in the present invention, after removing the iron component from the loess using a magnet, it is used as a pigment. In this case, iron particles surrounded by ocher and relatively large particles are often left unremoved by using magnets, which causes stains after firing, thereby degrading the value of the product. The problem is prevented in advance by finely pulverizing the ocher powder prior to its removal.
본 발명에 따른 황토백자의 제조공정은 성형단계, 황토액제조단계, 문양형성단계, 초벌구이단계, 시유단계, 재벌구이단계로 이루어진다. The manufacturing process of ocher white porcelain according to the present invention comprises a molding step, an ocher solution manufacturing step, a pattern forming step, a first roasting step, an oiling step, and a chaebol roasting step.
우선 성형단계에서는 고령토, 산청토, 밀양백토, 슈퍼화이트 등의 자기제조용 백토를 준비하여 토련한 후, 물레, 또는 석고틀을 이용하여 성형한 다음, 굽깎기하여 원하는 형태의 기물을 제조한다. First, in the molding step, the porcelain clay, such as kaolin, sancheong, miyang clay, and super white, is prepared and refined, and then molded using a spinning wheel or a plaster mold, and then bent to produce a desired shape.
황토액제조단계에서는 황토분말을 분쇄기에 투입하여 미세분말로 분쇄한 후 체거름 장치에 투입시키되, 이때 배출구에 자석이 장착된 체거름 장치를 이용함으로써 체거름과 동시에 철 성분이 제거되도록 하며, 체거름한 황토분말을 물에 개어 황토액을 제조한다. 황토분말의 입자가 너무 클 경우에는 철 성분의 제거가 불완전할 수 있으며, 이로 인하여 완성품에 미관상 좋지 못한 반점 형태의 얼룩이 생길 수 있고, 분말의 입자를 작게 하기 위해서는 분쇄공정에 더 많은 시간 및 비용이 소요되므로, 본 발명에서는 325메시의 체를 통과하는 크기의 황토분말을 이용하는 것이 바람직하다. 한편, 황토분말과 물을 혼합시 그 혼합비율에는 특별한 제약이 없으나, 공정상 편의를 위하여 황토액을 기물에 도포시 흘러내리지 않을 수준의 농도범위 내에서 혼합하는 것이 바람직하다. In the ocher liquid manufacturing step, the ocher powder is put into a grinder, pulverized into fine powder, and then put into a sieve device. At this time, by using a sieve device equipped with a magnet at the outlet, the iron component is removed at the same time as the sieve is removed. The fertilized ocher powder is opened in water to prepare an ocher solution. If the particles of ocher powder are too large, the removal of iron components may be incomplete, which may result in uneven appearance of spots on the finished product, and in order to reduce the particle size of the powder, more time and cost are required for the grinding process. In this invention, it is preferable to use the loess powder of the size which passes through the sieve of 325 mesh. On the other hand, the mixing ratio of the ocher powder and water is not particularly limited in the mixing ratio, but for the convenience of the process it is preferable to mix within the concentration range of the level that will not flow down when the ocher liquid is applied to the substrate.
문양형성단계에서는 성형한 기물에 황토액을 도포하여 문양을 형성시킨다. 문양 형성시에는 귀얄기법, 인화문기법, 박지기법, 철화기법 등의 문양형성방법을 응용하여 자유롭게 문양을 형성시키되, 청화백자에서 사용하는 코발트계 안료를 비롯한 통상의 안료를 대신하여 상기 제조한 황토액을 이용하여 도색한다. In the glyph forming step, the ocher is applied to the molded article to form a glyph. When the pattern is formed, the pattern is freely formed by applying a pattern forming method such as a guiding technique, a printing technique, a gilding technique, and an ironing technique, and instead of the conventional pigments including cobalt-based pigments used in blue and white porcelain, Color using liquid.
초벌구이단계에서는 문양을 형성시킨 기물을 850~950℃의 온도에서 10~15시간 동안 소성한다. In the first roasting step, the product having a pattern is calcined for 10-15 hours at a temperature of 850 ~ 950 ℃.
시유단계에서는 초벌구이를 마친 기물에 유약을 입힌다. 이때, 유약으로는 장석, 석회석 등을 주성분으로 하는 투명유약을 사용함으로써 황토의 색상을 해치지 않도록 하며, 시유 시에는 기물의 크기나 형태를 고려하여 담금, 분사, 도포 중에서 편리한 방법을 선택하여 사용한다. In the lactation phase, glazes on the finished roast. At this time, the glaze does not harm the color of ocher by using transparent glaze mainly composed of feldspar, limestone, etc., and when using oil, choose a convenient method among immersion, spraying, and coating in consideration of the size and shape of the object. .
재벌구이단계에서는 유약을 입힌 기물을 1250~1265℃의 온도에서 12~20시간 동안 소성한다. 이때, 산화소성 또는 환원소성을 선택함에 따라 완성된 자기의 색상을 조절할 수 있으며, 산화소성시에는 갈색을, 환원소성시에는 회청색을 나타낸다.In the chaebol roasting step, glazed items are fired at a temperature of 1250 ~ 1265 ° C. for 12-20 hours. At this time, the color of the finished porcelain can be adjusted by selecting the oxidizing or reducing firing, and the brown color on the oxidizing firing, and the grayish blue color on the reducing firing.
상기 공정에 따라 제조한 자기는 상온으로 식힌 다음 선별작업을 수행하여 본 발명에 따른 황토백자를 수득한다. The porcelain prepared according to the above process is cooled to room temperature and then screened to obtain ocher white according to the present invention.
본 발명에 따라 제조한 황토백자는 통상의 백자와 유사한 강도를 나타내므로, 식기, 장식품, 타일 등을 비롯하여 다방면으로 사용이 가능하며, 황토로 채색한 부분이 갈색, 또는 회청색으로 발색되어 자연스럽고 편안한 분위기를 연출할 수 있다.The ocher white produced according to the present invention exhibits a strength similar to that of ordinary white porcelain, and thus can be used in various fields, including tableware, ornaments, tiles, etc., and the part colored with ocher is colored brown or gray-blue to be natural and comfortable. Can create an atmosphere.
본 발명에 따른 황토백자는 황토로부터 철 성분을 제거한 후 사용하므로 철 성분으로 인한 검은 얼룩이 생성되지 않고 자연스러운 갈색을 표현하는 것이 가능하며, 기물에의 흡착력도 우수하여 채색공정도 용이한 특징이 있다. 또한, 본 발명에 따른 황토백자는 안료로써 황토를 사용하므로, 통상적인 안료의 사용시에 비하여 비용을 절약할 수 있을 뿐 아니라, 인체에 무해한 안전한 재료이므로 식기류에도 안심하고 사용할 수 있으며, 추후 폐기시에도 친환경적인 특징이 있다.Since the ocher white according to the present invention is used after removing the iron component from the loess, it is possible to express natural brown without generating black stains due to the iron component. In addition, since the ocher white according to the present invention uses ocher as a pigment, it can not only save costs compared to the use of ordinary pigments, but also can be used safely in tableware as it is a safe material that is harmless to the human body. It is environmentally friendly.
이하 제시하는 실시예는 본 발명에 대한 이해를 돕기 위한 것으로, 본 발명이 하기 실시예로 한정되지는 않는다.The following examples are provided to help the understanding of the present invention, and the present invention is not limited to the following examples.
[실시예 1]Example 1
산청백토를 준비하여 토련한 후, 물레를 이용하여 용기의 형태로 성형하고 한나절 동안 건조한 후 굽깎기하여 용기 형태의 기물을 제조하였다. 한편, 황토분 말을 분쇄한 후 325메시의 체를 이용하여 체거름하되, 배출구 주변에 자석을 장착하여 분쇄물에 포함되어 있는 철 성분을 제거하면서 체거름하였다. 체거름한 황토분말은 물에 개어 황토액을 제조하였다. After preparing and buffing the coarse blue clay, it was molded in the form of a container using a spinning wheel, dried for half a day, and then bent to prepare a container-shaped product. On the other hand, after the crushed ocher powder was sieved using a 325 mesh sieve, a magnet was mounted around the outlet to sieve while removing the iron component contained in the pulverized product. The filtered ocher powder was opened in water to prepare an ocher solution.
성형한 기물의 외면에 황토액을 이용하여 문양을 그려넣고, 또 다른 성형한 기물의 외면에는 황토액을 전체적으로 고르게 도포한 후, 산화철을 이용하여 문양을 그려넣었다. 문양을 형성시킨 기물들의 도포액이 마르기를 기다린 후, 약 850℃의 가마에 넣어 12시간 동안 1차소성하였다. 1차소성한 기물들이 상온으로 식기를 기다린 후, 장석, 규석, 석회석으로 이루어진 투명유약에 기물들을 담갔다 꺼낸 다음, 약 1260℃의 가마에 넣어 15시간 동안 2차소성하였다.A pattern was drawn on the outer surface of the molded article using ocher solution. On the outer surface of another molded article, the ocher solution was evenly applied on the entire surface, and then a pattern was drawn using iron oxide. After the coating liquid of the patterns forming the pattern was allowed to dry, it was placed in a kiln at about 850 ° C. and first baked for 12 hours. After the first baked items waited at room temperature, they were immersed in a transparent glaze consisting of feldspar, quartz and limestone, and then placed in a kiln at about 1260 ° C. for two hours.
2차소성을 마친 자기들이 상온으로 식기를 기다린 후, 불량품을 골라 제거한 후, 황토백자 완성품을 선별하였다.After the second firing, they waited for the dishes at room temperature, and after removing the defective products, selected the ocher white porcelain.
도 1은 본 발명에 따른 황토백자의 제조공정을 나타낸 흐름도이다.1 is a flow chart showing a manufacturing process of ocher white according to the present invention.
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