CN109431826A - A kind of sun-screening agent is spraying - Google Patents

A kind of sun-screening agent is spraying Download PDF

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Publication number
CN109431826A
CN109431826A CN201811621086.4A CN201811621086A CN109431826A CN 109431826 A CN109431826 A CN 109431826A CN 201811621086 A CN201811621086 A CN 201811621086A CN 109431826 A CN109431826 A CN 109431826A
Authority
CN
China
Prior art keywords
sun
screening agent
pouch
spraying
inhalator jar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811621086.4A
Other languages
Chinese (zh)
Inventor
温俊帆
张凯琳
梁高健
张为敬
卢金霞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongshan Tentop Fine Chemical Co Ltd
Original Assignee
Zhongshan Tentop Fine Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhongshan Tentop Fine Chemical Co Ltd filed Critical Zhongshan Tentop Fine Chemical Co Ltd
Priority to CN201811621086.4A priority Critical patent/CN109431826A/en
Publication of CN109431826A publication Critical patent/CN109431826A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • A61K8/315Halogenated hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/24Thermal properties
    • A61K2800/244Endothermic; Cooling; Cooling sensation

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

It is spraying that the present invention discloses a kind of sun-screening agent, the strong sun-prevention component of light sensitivity and emollient, solvent, cooling agent etc. are isolator stored in inhalator jar by pouch, propellant is filled between inhalator jar and pouch, cooling agent therein is preferably the chloro- trifluoro propene of anti-form-1-.The present invention is sprayed ice-cold, quick-drying, invariably euosmia.Aerosol can of the present invention when using can with 360 degree any angle spray valves, operate with safety (non-combustible), environmentally friendly (low GWP, low VOC), efficiently, it is convenient again can effective protection sun-screening agent validity and have both the aerosol-type sun-screening agent of cooling effect within the shelf-life and be sprayed.The present invention is easy to carry about with one, is easy to use, is easily stored and safe and reliable, has very superior application performance.

Description

A kind of sun-screening agent is spraying
[technical field]
It is spraying that the present invention relates to a kind of sun-screening agents.
[background technique]
Conventional atomizing pump pumps out air by pressing repeatedly and makes that a vacuum state is caused to pump out feed liquid in it at present, instead Pressing again, which causes channel repeatedly to be opened, is easy to make content by the microbial contamination and accelerator liquid oxidation in air, causes interior It is tolerant to occur to go bad, it is not available.Spray pump product, generally using the bottle of the plastic materials such as translucency strong single-layer PET, PP Subpack, is easy to be influenced by extraneous illumination effect, temperature and not solvent resistant.Application method is single, is only limitted to just spray, to back, The difficult physical feeling reached of some comparisons such as leg can not voluntarily direct spraying.Mostly reach cooling effect or not bright using ethyl alcohol Aobvious cooling effect, ethyl alcohol will affect the smell of product and stimulates to skin tape.
In addition there are also a kind of aerial fog type sun-screening agents of aluminium pot packaging to be sprayed on the market, and sun-screening agent material directly (is pushed away with propellant Into agent) mixing, it is contacted with Aluminum Bottle, is easy that packaging material compatibility, the risk of material gas compatibility are influenced and be easy by ambient temperature.Gas Even there are also pole inflammability, propellant (propellant) pollution environment, increases to skin for the unitary sun-screening agent blowing portion of mist dosage form The problem of stimulation etc..Application method is opposite to limit to, and is only limitted to just spray or part can fall to spray, can not tilt in product under partial picture 30 degree of angle > uses, have certain use angle to limit to.It is more difficult to the difficult physical feeling reached of some comparisons such as back, leg from Row direct spraying.
As consumer is to safe and environment-friendly, convenient pursuit, raising to the cognition of antitan agent importance and raw to health Fine yearning living, there is an urgent need to develop new type of safe, convenience, effective sunscreen products in the market, to fill up this field Vacancy solves safety, the ease of use, validity problem in the shelf-life of sunscreen product.
[summary of the invention]
The purpose of the present invention is overcome the deficiencies of the prior art and provide it is a kind of using safe and environment-friendly, efficient, convenient and The good sun-screening agent of stability is spraying.
The present invention to achieve the above object, using following technical scheme:
A kind of sun-screening agent is spraying, it is characterised in that the strong sun-prevention component of light sensitivity and emollient, solvent, cooling agent etc. is logical It crosses pouch isolator to store in inhalator jar, propellant is filled between inhalator jar and pouch.
Cooling agent in the present invention is preferably the chloro- trifluoro propene of anti-form-1-, and the raw material and sun-screening agent and solvent compatibility It is good, the experience sense of refrigerant cooling can be brought in use, and there is environmentally friendly (low GWP, low VOC), safety (non-combustible) The advantages that.
Sun-screening agent feed liquid in the present invention includes following weight percent composition:
Sun-screening agent in the present invention, it is up to standard and sun-proof result effective by theoretical calculation and its sun-proof value of test verifying Property.It is arranged in pairs or groups by the design of the compatibility of sun-prevention component and emollient, solvent, the chloro- trifluoro propene of anti-form-1-, essence, test is protected Barrier compatibility of sun-screening agent and his raw material within the shelf-life is good, and no precipitation, enrichment, recrystallization etc. are abnormal.Skill is designed by formula Sun-screening agent is arranged in pairs or groups and is optimized, efficiently reaches the sun-proof ideal effect of effective skin using lesser amount of sun-screening agent by art.By matching The collocation of emollient and solvent is optimized, and the chloro- trifluoro propene of anti-form-1-is added and reaches ice-cold, quick-drying by square designing technique Brilliant skin sense.
Propellant in the present invention is preferably nitrogen, and isolation layer is formed in tank, reduces the influence of ambient temperature variation.Nitrogen Gas is compressibility gas, can be provided to product from opening using the motive force outstanding to the stabilization being finished.The pressure curve of nitrogen It varies with temperature gently, it is all safe that product, which is placed in family and automobile,.Nitrogen is non-combustible, non-VOC, non-GWP, it is tasteless, It is economical cheap.
A kind of sun-screening agent of the present invention is spraying, is prepared by the following method:
A, sun-prevention component, emollient and stirring solvent mixed dissolution is uniform, essence and balance solvent is added, is stirred Uniformly, the chloro- trifluoro propene of anti-form-1-is added, is uniformly mixed, examines qualified filtering and standing to get sun-screening agent feed liquid;
B, it is put into pouch in inhalator jar, propellant nitrogen is filled between inhalator jar and pouch, seals, is completed preparing Sun-screening agent feed liquid quantitatively fill and be fitted into pouch.
When the present invention prepares sun-screening agent feed liquid, 50-85 DEG C can be heated and accelerate sun-prevention component, emollient in a solvent molten Solution, essence are cooled to 45 DEG C or less additions, continue to add the chloro- trifluoro propene of anti-form-1-under room temperature during cooling down.
25 DEG C of internal pressures are 0.55-0.85MPa in inhalator jar of the present invention, maintain normal pressure in the effective use process of product, keep away Exempt from the invasion of the pollutants such as outside air, microorganism.
Aerosol can of the present invention uses 360 degree of any angle spray valves, past by the nitrogen pushed at high pressure sun-screening agent between tank bag Outer ejection enables sun-screening agent to be sprayed by high speed shear with mist, no matter user can be released effectively from any angle.
The preferred vinyon pouch of pouch or aluminium foil pouch in the present invention, it is possible to provide to sun-screening agent, anti-form-1-chloro- three The effective protection of fluoropropene, isolation air, illumination, temperature contact and the contact of propellant, packaging material, enables product to protect without chemistry It protects the preservation of the downward long products of addition of agent and uses the time, so that reaching sun-proof result of the protection sun-screening agent within the shelf-life has Effect property.The content of ejection does not have propellant to the additional increased burden of skin.
Lid retrofilling nitrogen is used when prepared by the present invention, is consistent product pressure, production process quality and safety has It ensures.25 DEG C of internal pressures are 0.55-0.85MPa in inhalator jar of the present invention, maintain normal pressure in the effective use process of product, are avoided outer The invasion of the pollutants such as boundary's air, microorganism.Nitrogen is filled between tank bag, forms isolation layer in tank, reduces ambient temperature variation It influences.Nitrogen is compressibility gas, can be provided to product from opening using the motive force outstanding to the stabilization being finished.The pressure of nitrogen Force curve varies with temperature gently, and it is all safe that product, which is placed in family and automobile,.Nitrogen is non-combustible, non-VOC, non-GWP, It is tasteless, economical cheap.
Compared with prior art, the present invention has the following advantages:
The present invention is sprayed ice-cold, quick-drying, invariably euosmia.The present invention passes through sun-prevention component and emollient, solvent, anti- The design of the compatibility of the chloro- trifluoro propene of formula -1-, essence is arranged in pairs or groups, and test ensures matching within shelf-life sun-screening agent and his raw material 5 property are good, and no precipitation, enrichment, recrystallization etc. are abnormal.By being formulated designing technique, sun-screening agent is arranged in pairs or groups and is optimized, less amount is used Sun-screening agent efficiently reach the sun-proof ideal effect of effective skin;The collocation of emollient and solvent is optimized, and is added anti- The chloro- trifluoro propene of formula -1- reaches ice-cold, quick-drying brilliant skin sense.
Aerosol can of the present invention can operate with safety (non-combustible), environmental protection when using with 360 degree of any angle spray valves (low GWP, low VOC), efficiently, it is convenient again can effective protection sun-screening agent validity and have both the aerosol of cooling effect within the shelf-life Dosage form sun-screening agent is spraying.
The present invention is easy to carry about with one, is easy to use, is easily stored and safe and reliable, has very superior application performance.
[specific embodiment]
Further more detailed description is done to the present invention below by way of specific embodiment, the percentage in embodiment is Mass percent.
Embodiment 1:
Sun-prevention component 10.0%, emollient 20.0% and partial solvent are stirred and is heated to 80 DEG C and is uniformly dissolved, is dropped Temperature is uniformly mixed to 45 DEG C and hereinafter, essence 0.5% and balance solvent is added, and continues to cool down, anti-form-1-chloro- three is added Fluoropropene 0.5%, is uniformly mixed, and examines qualified filtering and standing;It is put into pouch in inhalator jar, uses filling and sealing equipment Propellant nitrogen is filled in inhalator jar, is sealed, the sun-screening agent feed liquid for preparing completion is quantitatively filled and is fitted into pouch, product pressure Power is in 0.60MPa.
Implementation column 2:
Sun-prevention component 15.0%, emollient 30.0% and partial solvent are stirred and is heated to 80 DEG C and is uniformly dissolved, temperature It is uniformly mixed to 45 DEG C and hereinafter, balance solvent is added, continues to cool down, the chloro- trifluoro propene 1.0% of anti-form-1-is added, stirs Mix uniformly mixed, the qualified filtering and standing of inspection;It is put into pouch in inhalator jar, is filled propellant nitrogen using filling and sealing equipment Enter in inhalator jar, seal, the sun-screening agent feed liquid for preparing completion is quantitatively filled and is fitted into pouch, product pressure is in 0.70MPa It can.
Embodiment 3:
Sun-prevention component 50.0%, emollient 15.0% and partial solvent are stirred and is heated to 80 DEG C and is uniformly dissolved, temperature It is uniformly mixed to 45 DEG C and hereinafter, essence 0.2% and balance solvent is added, continues to cool down, add anti-form-1-chloro- three Fluoropropene 2.0%, is uniformly mixed, and examines qualified filtering and standing;It is put into pouch in inhalator jar, uses filling and sealing equipment Propellant nitrogen is filled in inhalator jar, is sealed, the sun-screening agent feed liquid for preparing completion is quantitatively filled and is fitted into pouch, product pressure Power is in 0.75MPa.
Embodiment 4:
Sun-prevention component 15.0%, emollient 20.0% and partial solvent are uniformly mixed, essence 0.5% and remaining is added It measures stirring solvent to be uniformly mixed, adds the chloro- trifluoro propene 5.0% of anti-form-1-, be uniformly mixed, examine qualified filtering quiet It sets;It is put into pouch in inhalator jar, propellant nitrogen is filled in inhalator jar using filling and sealing equipment, seals, will prepare At sun-screening agent feed liquid quantitatively fill and be fitted into pouch, product pressure is in 0.85MPa.
Embodiment 5:
Sun-prevention component 20.0%, emollient 10.0% and partial solvent are uniformly mixed, essence 0.5% and remaining is added It measures stirring solvent to be uniformly mixed, the chloro- trifluoro propene 10.0% of anti-form-1-is added, is uniformly mixed, examine qualified filtering quiet It sets;It is put into pouch in inhalator jar, propellant nitrogen is filled in inhalator jar using filling and sealing equipment, seals, will prepare At sun-screening agent feed liquid quantitatively fill and be fitted into pouch, product pressure is in 0.70MPa.
Embodiment 6:
It is uniformly mixed by formula sun-prevention component 5.0%, emollient 10.0% and partial solvent, essence 0.2% is added It is uniformly mixed with balance solvent, the chloro- trifluoro propene 10.0% of anti-form-1-is added, is uniformly mixed, examine qualified filtering It stands;It is put into pouch in inhalator jar, propellant nitrogen is filled in inhalator jar using filling and sealing equipment, seals, will prepare The sun-screening agent feed liquid of completion, which quantitatively fills, to be fitted into pouch, and product pressure is in 0.55MPa.
Embodiment 7:
Sun-prevention component 10.0%, emollient 20.0% and partial solvent are uniformly mixed, essence 1.0% and remaining is added It measures stirring solvent to be uniformly mixed, adds the chloro- trifluoro propene 20.0% of anti-form-1-, be uniformly mixed, examine qualified filtering quiet It sets;It is put into pouch in inhalator jar, propellant nitrogen is filled in inhalator jar using filling and sealing equipment, seals, will prepare At sun-screening agent feed liquid quantitatively fill and be fitted into pouch, product pressure is in 0.70MPa.
Embodiment 8:
Sun-prevention component 5%, emollient 15% and partial solvent are uniformly mixed, essence 0.3% is added and surplus is molten Agent is uniformly mixed, and is added the chloro- trifluoro propene 15.0% of anti-form-1-, is uniformly mixed, and qualified filtering and standing is examined; It is put into pouch in inhalator jar, propellant nitrogen is filled in inhalator jar using filling and sealing equipment, seals, completion will be prepared Sun-screening agent feed liquid is quantitatively filled and is fitted into pouch, and product pressure is in 0.70MPa.
Embodiment 9:
The stirring of sun-prevention component 0.5%, emollient 1.0% and partial solvent is added to 50 DEG C to be uniformly mixed, is cooled to 45 DEG C Hereinafter, addition essence 0.3% and balance solvent are uniformly mixed, continue to cool down, the chloro- trifluoro propene of anti-form-1-is added 0.1%, it is uniformly mixed, examines qualified filtering and standing;It is put into pouch in inhalator jar, will be promoted using filling and sealing equipment Agent nitrogen is filled in inhalator jar, sealing, and the sun-screening agent feed liquid for preparing completion is quantitatively filled and is fitted into pouch, product pressure exists 0.65MPa.
It is as follows to the technical indicator detection of embodiment 1-9 product:
Agent liquid appearance: colourless to yellow transparent liquid
Product appearance: soft uniformly misty
Emission rate (25 DEG C): >=95%
Heat resistance: 40 DEG C ± 2 DEG C, for 24 hours, restoring can normal use to (25 DEG C) of room temperature.
Cold tolerance: -5 DEG C ± 2 DEG C, for 24 hours, restoring can normal use to (25 DEG C) of room temperature.
Product of the present invention good airproof performance and there is constant positive pressure offer, protection sun-screening agent avoids light, temperature, air, micro- Biology etc. and or other extraneous adverse effects.Using environmentally friendly propellant nitrogen, gently presses to spray and continue soft mist Sun-screening agent is not needed firmly to go to press repeatedly with finger as using the conventional non-common pump spray of aerosol, be can avoid normal Advising propellant (propellant) caused by unitary aerosol sunscreen product stimulates.Environmentally friendly (low GWP, low VOC), safety is (no in the extreme It is flammable), it is convenient, comfortable, efficiently, and have both surface cooling effect, discharge the finger of user humanizedly, 360 degree without dead angle Spraying, ice-cold salubrious skin sense greatly improve usage experience sense.Therefore potentiality and application prospect are had a vast market.

Claims (8)

1. a kind of sun-screening agent is spraying, it is characterised in that pass through the strong sun-prevention component of light sensitivity and emollient, solvent, cooling agent etc. Pouch is isolator stored in inhalator jar, and propellant is filled between inhalator jar and pouch.
2. a kind of sun-screening agent according to claim 1 is spraying, it is characterised in that the cooling agent is the chloro- trifluoro of anti-form-1- Propylene.
3. a kind of sun-screening agent according to claim 2 is spraying, it is characterised in that the sun-screening agent feed liquid includes following heavy Measure percent composition:
4. a kind of sun-screening agent according to claim 1 is spraying, it is characterised in that the pouch is vinyon pouch Or aluminium foil pouch.
5. a kind of sun-screening agent according to claim 1 is spraying, it is characterised in that the propellant is nitrogen.
6. a kind of sun-screening agent according to claim 1 is spraying, it is characterised in that 25 DEG C of internal pressures are 0.55- in the inhalator jar 0.85MPa。
7. a kind of sun-screening agent according to claim 1 is spraying, it is characterised in that it is prepared by the following method:
A, sun-prevention component, emollient and partial solvent are stirred and are uniformly dissolved, essence and balance solvent is added, is stirred Uniformly, the chloro- trifluoro propene of anti-form-1-is added, is uniformly mixed, examines qualified filtering and standing to get sun-screening agent feed liquid;
B, it is put into pouch in inhalator jar, propellant nitrogen is filled between inhalator jar and pouch, seals, the anti-of completion will be prepared Solarization agent feed liquid, which quantitatively fills, to be fitted into pouch.
8. a kind of sun-screening agent according to claim 7 is spraying, it is characterised in that the inhalator jar uses 360 degree of random angles Spend spray valve.
CN201811621086.4A 2018-12-28 2018-12-28 A kind of sun-screening agent is spraying Pending CN109431826A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111175310A (en) * 2019-12-30 2020-05-19 苏州新美达探伤器材有限公司 Nonflammable aerosol can penetrating agent and preparation method thereof
CN113710216A (en) * 2019-04-01 2021-11-26 霍尼韦尔国际公司 Personal care aerosol compositions, methods and devices

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN113710216A (en) * 2019-04-01 2021-11-26 霍尼韦尔国际公司 Personal care aerosol compositions, methods and devices
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Application publication date: 20190308

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