CN109401653A - A kind of protective film of the low precipitation of high temperature resistant and its application - Google Patents
A kind of protective film of the low precipitation of high temperature resistant and its application Download PDFInfo
- Publication number
- CN109401653A CN109401653A CN201811081306.9A CN201811081306A CN109401653A CN 109401653 A CN109401653 A CN 109401653A CN 201811081306 A CN201811081306 A CN 201811081306A CN 109401653 A CN109401653 A CN 109401653A
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- China
- Prior art keywords
- high temperature
- temperature resistant
- protective film
- low precipitation
- pressure sensitive
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- Pending
Links
- 238000001556 precipitation Methods 0.000 title claims abstract description 30
- 230000001681 protective effect Effects 0.000 title claims abstract description 26
- 239000000758 substrate Substances 0.000 claims abstract description 26
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 17
- 239000000945 filler Substances 0.000 claims abstract description 11
- 239000010410 layer Substances 0.000 claims abstract description 10
- 229920006243 acrylic copolymer Polymers 0.000 claims abstract description 9
- 239000012790 adhesive layer Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 2
- 239000004642 Polyimide Substances 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 239000003292 glue Substances 0.000 abstract description 17
- 230000004224 protection Effects 0.000 abstract description 8
- 230000037303 wrinkles Effects 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 239000011521 glass Substances 0.000 abstract description 3
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 210000002469 basement membrane Anatomy 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/255—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/414—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of a copolymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of low precipitation protective film of high temperature resistant and its applications; it from top to bottom successively include release layer, adhesive layer and substrate layer; adhesive layer is acrylate pressure sensitive adhesive, and acrylate pressure sensitive adhesive includes acrylic copolymer, ethyl acetate, curing agent, high temperature resistant filler, low precipitation auxiliary agent.Substrate is connected by acrylate pressure sensitive adhesive with release film；When needing to protect screen or electronic component, directly substrate is stripped, is contacted by acrylate pressure sensitive adhesive with screen or electronic component；Substrate is high temperature resistant lower shrinkage substrate; and acrylate pressure sensitive adhesive mainly includes acrylic copolymer, ethyl acetate, curing agent, high temperature resistant filler and low precipitation auxiliary agent; thus there is good high temperature resistance; after conforming on glass; 220 DEG C of high temperature are resistant in vacuum environment; will not occur the situations such as heaving, wrinkle, there will not be white haze after opening or residue glue occurs, thus can be widely used in the technique of various high temperature resistant protections.
Description
Technical field
The present invention relates to a kind of protective film, in particular to the low precipitation protective film of a kind of high temperature resistant.
Background technique
Non- ITO conductive film belongs to the emerging industry in flexible screen, and market prospects are fine；In manufacture craft, non-ITO is led
The main body substrate surface of electrolemma not damage resistant, vulnerable to pollution, therefore need when making conductive film specific by one
Protective film plays scuffing and contamination to its surface.It is current can only mobile phone and PAD etc. include one piece of touch screen, touch screen is
The induction type liquid crystal display device in sea is tamed and dociled in a acceptable human body touch input, when mobile phone contacts the relevant range on screen,
Capacitance plate induction after screen does not sense the variation of electric signal, and touch chip is acquired place to these current signals changed
It is transported to mobile phone base band chip after reason to be handled, various instructions are issued by baseband chip, to realize mobile phone various functions；By
In can only mobile phone by camera and voice earpiece, therefore, touch screen needs the plated film on corresponding region, such as passes through PVD
Plated film, the prior art are easy to cause film to wrinkle for shielding protective film of the single film as plated film in PVD plated film, thus
So that wrinkle and MARK print and residue glue can be left in touch-control screen surfaces.
Thus, we provide the low precipitation protective film of high temperature resistant for not having white haze and residue glue after a kind of open herein.
Summary of the invention
The object of the present invention is to provide a kind of low precipitation protective films of high temperature resistant.
Above-mentioned technical purpose of the invention has the technical scheme that a kind of low precipitation protection of high temperature resistant
Film, from top to bottom successively includes release layer, adhesive layer and substrate layer, and the adhesive layer is acrylate pressure sensitive adhesive, the acrylic acid
Pressure sensitive adhesive includes acrylic copolymer, ethyl acetate, curing agent, high temperature resistant filler, low precipitation auxiliary agent.
By using above-mentioned technical proposal, a kind of high temperature resistant protective film disclosed in this programme mainly includes substrate, propylene
Sour pressure sensitive adhesive, release film, substrate are connected by acrylate pressure sensitive adhesive with release film；When needing to carry out to screen or electronic component
When protection, directly substrate is stripped, is contacted by acrylate pressure sensitive adhesive with screen or electronic component；Substrate is resistance to height
Warm lower shrinkage substrate, and acrylate pressure sensitive adhesive mainly includes acrylic copolymer, ethyl acetate, curing agent, high temperature resistant filling
Agent and low precipitation auxiliary agent since low precipitation auxiliary agent surface can be lower, thus have good high temperature resistance, are conforming to glass
After upper, it is resistant to 220 DEG C of high temperature in vacuum environment, will not occur the situations such as heaving, wrinkle, there will not be after opening white
Mist or residue glue occur, thus can be widely used in the technique of various high temperature resistant protections.
Preferably, each content of material in acrylate pressure sensitive adhesive is based on component:
Preferably, the substrate layer is high temperature resistant lower shrinkage substrate, the high temperature resistant lower shrinkage substrate uses high temperature resistant
PET, PI and PEN.
Preferably, the crosslinking agent is thermal cross-linking agent.
Preferably, the crosslinking agent is using amine, epoxies, isocyanates and metallic salt etc..
Preferably, the high temperature resistant filler uses containing benzene ring substance, polyimides substance or contains conjugated bonds
Class chemical substance.
Preferably, the weight average molecular weight of the acrylic copolymer is 100,000 or more, 1,000,000 or less.
Preferably, the low precipitation auxiliary agent is low-surface energy substance, the low molecular weight that auxiliary agent is precipitated is 5000-
60000。
The object of the present invention is to provide a kind of low precipitation protective films of high temperature resistant.
Above-mentioned technical purpose of the invention has the technical scheme that a kind of low precipitation protection of high temperature resistant
Application of the film on electronic device touch screen.
In conclusion the invention has the following advantages:
1. a kind of high temperature resistant protective film disclosed in this programme mainly includes substrate, acrylate pressure sensitive adhesive, release film, base
Material is connected by acrylate pressure sensitive adhesive with release film；When needing to protect screen or electronic component, directly by substrate
It strips, is contacted by acrylate pressure sensitive adhesive with screen or electronic component；Substrate is high temperature resistant lower shrinkage substrate, and third
Olefin(e) acid pressure sensitive adhesive mainly includes acrylic copolymer, ethyl acetate, curing agent, high temperature resistant filler and low precipitation auxiliary agent, by
Can be lower in low precipitation auxiliary agent surface, thus there is good high temperature resistance, after conforming on glass, in vacuum environment
In be resistant to 220 DEG C of high temperature, will not occur the situations such as heaving, wrinkle, there will not be white haze or residue glue after opening and occur, thus energy
It is widely used in the technique of various high temperature resistant protections；
2. the research about such adhesive tape is more since such adhesive tape use scope is wide；Such as application No. is
A kind of high temperature resistant protective film disclosed in the Chinese patent of " 201510843404.1 ", the high temperature resistant protective film in the program, though
So there is good viscosity, adhesion strength and spin initial bonding strength, but its mesoglea only can be long-term in the environment of -20 DEG C -120 DEG C
It keeps its performance constant, is not in the deformation such as warpage, heatproof is up to 180 DEG C in the short time；Other similar protection on the market
Film, heatproof degree is similar therewith, and temperature tolerance of the invention may be up to 220 DEG C, or even when slightly above 220 DEG C, still
With good stability.
Specific embodiment
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Embodiment:
A kind of low precipitation protective film of high temperature resistant, from top to bottom successively includes release layer, adhesive layer and substrate layer, and adhesive layer is
Acrylate pressure sensitive adhesive, acrylate pressure sensitive adhesive mainly include acrylic copolymer, ethyl acetate, curing agent, high temperature resistant filler,
Low precipitation auxiliary agent.
Each material composition is identical in embodiment 1- embodiment 5, but a content of material is different, is detailed in shown in the following table 1, test wrapper
Border is resistance to 250 DEG C of 10min under vacuum condition,.
Table 1:
Each material composition and its test result in embodiment 6- embodiment 9 and comparative example, are detailed in shown in the following table 2；
Table 2:
△ representative has residue glue, and zero representative has white haze, and X representative has residue glue and white haze, and OK is represented without white haze and residue glue, and is represented
Fold with heave
Only change the low amount that auxiliary agent is precipitated in embodiment 1, embodiment 2 and embodiment 3, other are remained unchanged, and verify low analysis
Influence of the amount of auxiliary agent to white haze residue glue, Tai Shaoshi out do not have effect, so having white haze, can be precipitated when too many, float on by
Object surface is pasted, also will form white haze；
The amount of embodiment 2, embodiment 4 and embodiment 5 change high temperature resistant fillers, other are remained unchanged, and verify resistance to height
Influence of the amount of warm filler to white haze residue glue, Tai Shaoshi do not have effect, so having residue glue, can be precipitated, float on when too many
Affixed object surface, will form white haze；
Only change the amount of crosslinking agent in embodiment 2, embodiment 6 and embodiment 7, other are remained unchanged, and verify crosslinking agent
The influence to white haze residue glue is measured, Tai Shaoshi, crosslink density is low, and molecular weight is small, so being easy residue glue, can be precipitated when too many, small point
Son floats on affixed object surface, will form white haze；
Only change the type of substrate in embodiment 2, embodiment 8, embodiment 9 and comparative example, other are remained unchanged, and verifying is not
With the substrate influence apparent to white haze residue glue and protective film, the results showed that the white haze residue glue of common PET and apparent all bad,
Because the heat-resisting quantity of common PET is bad, has substance and be precipitated or decompose, therefore can deform and generate white haze residue glue.
In summary the performance of basement membrane and curing agent and heatproof auxiliary agent and it is low be precipitated auxiliary agent to the white haze of heatproof protective film and
The performances such as residue glue have an impact.
Claims (9)
1. a kind of low precipitation protective film of high temperature resistant, it is characterised in that: from top to bottom successively include release layer, adhesive layer and substrate
Layer, the adhesive layer are acrylate pressure sensitive adhesive, and the acrylate pressure sensitive adhesive includes acrylic copolymer, ethyl acetate, solidification
Agent, high temperature resistant filler, low precipitation auxiliary agent.
2. a kind of low precipitation protective film of high temperature resistant according to claim 1, which is characterized in that each in acrylate pressure sensitive adhesive
Content of material is based on component:
3. a kind of low precipitation protective film of high temperature resistant according to claim 2, it is characterised in that: the substrate layer is high temperature resistant
Lower shrinkage substrate, the high temperature resistant lower shrinkage substrate use high temperature resistant PET, PI or PEN.
4. a kind of low precipitation protective film of high temperature resistant according to claim 3, it is characterised in that: the crosslinking agent is heat cross-linking
Agent.
5. a kind of low precipitation protective film of high temperature resistant according to claim 4, it is characterised in that: the crosslinking agent uses amine
Class, epoxies, isocyanates and metallic salt.
6. a kind of low precipitation protective film of high temperature resistant according to claim 5, it is characterised in that: the high temperature resistant filler is adopted
With containing benzene ring substance, polyimides substance or contain conjugated bonds class chemical substance.
7. a kind of low precipitation protective film of high temperature resistant according to claim 6, it is characterised in that: the acrylic copolymer
Weight average molecular weight be 100,000 or more, 1,000,000 or less.
8. a kind of low precipitation protective film of high temperature resistant according to claim 7, it is characterised in that: the low precipitation auxiliary agent is low
Surface energy substance, the low molecular weight that auxiliary agent is precipitated is 5000-60000.
9. a kind of low precipitation protective film of high temperature resistant according to any one of claims 1 to 8 is on electronic device touch screen
Using.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811081306.9A CN109401653A (en) | 2018-09-17 | 2018-09-17 | A kind of protective film of the low precipitation of high temperature resistant and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811081306.9A CN109401653A (en) | 2018-09-17 | 2018-09-17 | A kind of protective film of the low precipitation of high temperature resistant and its application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109401653A true CN109401653A (en) | 2019-03-01 |
Family
ID=65464854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811081306.9A Pending CN109401653A (en) | 2018-09-17 | 2018-09-17 | A kind of protective film of the low precipitation of high temperature resistant and its application |
Country Status (1)
| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110724469A (en) * | 2019-11-07 | 2020-01-24 | 新纶科技（常州）有限公司 | High-temperature-resistant flexible protective film capable of preventing micromolecules from being separated out and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102311710A (en) * | 2010-07-02 | 2012-01-11 | 第一毛织株式会社 | Binder compsn and utilize the optical element of this tackiness agent |
| CN105647411A (en) * | 2015-11-27 | 2016-06-08 | 东莞市航达电子有限公司 | High temperature resistant protective film |
-
2018
- 2018-09-17 CN CN201811081306.9A patent/CN109401653A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102311710A (en) * | 2010-07-02 | 2012-01-11 | 第一毛织株式会社 | Binder compsn and utilize the optical element of this tackiness agent |
| CN105647411A (en) * | 2015-11-27 | 2016-06-08 | 东莞市航达电子有限公司 | High temperature resistant protective film |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110724469A (en) * | 2019-11-07 | 2020-01-24 | 新纶科技（常州）有限公司 | High-temperature-resistant flexible protective film capable of preventing micromolecules from being separated out and preparation method thereof |
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Application publication date: 20190301 |