CN109399883A - A kind of method for anaerobic sludge digestion - Google Patents

A kind of method for anaerobic sludge digestion Download PDF

Info

Publication number
CN109399883A
CN109399883A CN201811507587.XA CN201811507587A CN109399883A CN 109399883 A CN109399883 A CN 109399883A CN 201811507587 A CN201811507587 A CN 201811507587A CN 109399883 A CN109399883 A CN 109399883A
Authority
CN
China
Prior art keywords
sludge
plant
digestion
dry slag
anaerobic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811507587.XA
Other languages
Chinese (zh)
Inventor
蒋蓉
宋宁凡
石敬华
古励
何强
姜沁
祝瑞麟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing University
Original Assignee
Chongqing University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chongqing University filed Critical Chongqing University
Priority to CN201811507587.XA priority Critical patent/CN109399883A/en
Publication of CN109399883A publication Critical patent/CN109399883A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M1/00Apparatus for enzymology or microbiology
    • C12M1/107Apparatus for enzymology or microbiology with means for collecting fermentation gases, e.g. methane
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/16Total nitrogen (tkN-N)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/20Total organic carbon [TOC]

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Hydrology & Water Resources (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Microbiology (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Biochemistry (AREA)
  • Sustainable Development (AREA)
  • Biomedical Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses a kind of method for anaerobic sludge digestion, it includes step 1, food and drink grease is added in the dry slag of plant is stirred, and adds excess sludge and is mixed;Mixture obtained in the step 1 is carried out anaerobic digestion by step 2;The dry slag of plant is the withered dry slag of emergent aquactic plant or the dry slag of agricultural stalk;Excess sludge, food and drink grease, the dry slag of plant VS mass ratio be 1: 2: 0.2~2.The present invention improves the methane production of sludge, sludge can be prevented to be acidified again.

Description

A kind of method for anaerobic sludge digestion
Technical field
The present invention relates to field of environment protection, and in particular to a kind of method for anaerobic sludge digestion.
Background technique
In operation, sewage can generate a large amount of excess sludge for sewage treatment plant, by the end of the year in 2014, national sludge Disposition amount is only 224.81 ten thousand tons/year, and up to 30,000,000 tons of sludge yield that China is annual, harmless treatment rate are practical not Foot 10%.
It is more and more because anaerobic sludge digestion can be realized " minimizing, innoxious, recycling " processing to sludge People is advocated, and in recent years, China also gradually recognizes the importance of anaerobic sludge digestion processing, has been carried out a series of theory and has been ground Study carefully, carried out many engineering practices in succession, such as Shanghai White Long Gang, Hubei Xiangyang fishgarth continent, Dalian Dong Taixia man river, Qingdao City The large size specific resistance to filtration case history such as Mai Dao, achieves certain achievement.Chongqing also establishes man, Tang Tuo Wushuichu in succession The a batch such as reason factory, realgar sewage treatment plant are configured with the sewage treatment plant of specific resistance to filtration equipment, however, because of Chongqing region Sludge shale is bad (sand content is big, the content of organic matter is low), and actual operational effect and expected design is caused still to have certain difference Away from.Therefore, it is the key that limitation anaerobic sludge digestion technique is run in Chongqing region or even nationwide interior promote that shale is bad.
Chinese maintain the habit with grease culinary art cuisines all the time, and this cooking method is along with remaining grease Discharge, especially in the area of the grease culinary art accustomed to using abundant such as Chongqing, Sichuan.Chongqing is known as the good reputation in " city of chafing dish ", Flourishing chafing dish industry generates food and drink grease of the number in terms of ten thousand kilograms daily, contains a large amount of fat, grease, carbon in food and drink grease Hydrate, carbohydrate and other organic matters, the content of organic matter is high, has very high calorific value, and the every kg volatility of food and drink grease is solid Weight theory methane phase ability is up to 1014L.
If the food and drink grease of high organic content is added in sludge to be formed and digests matrix altogether, the methane production of sludge Raising will be changed significantly.Although sludge oiling rouge improves methane phase ability, the disadvantage is that being easy acidification.
Summary of the invention
In view of the problems of the existing technology, the technical problem to be solved by the invention is to provide a kind of sludge anaerobics to disappear Change method, it can improve the methane production of sludge, sludge can be prevented to be acidified again.
The technical problem to be solved by the present invention is in this way technical solution realize, it the following steps are included:
Food and drink grease is added in the dry slag of plant and is stirred by step 1, adds excess sludge and is mixed;
Mixture obtained in the step 1 is carried out anaerobic digestion by step 2.
The dry slag of plant is the withered dry slag of emergent aquactic plant or the dry slag of agricultural stalk.
The solution have the advantages that:
1, the dry slag of plant and three kinds of grease, sludge substances act synergistically, so that methane phase ability enhances, improve methane production Rate;
2, the dry slag of plant digests after mixing with grease, alleviates the influence of mortifier, buffers noxious material, provides more alkali Degree, it is therefore prevented that sludge acidification;
3, digestion matrix organic matter composition is adjusted, so that degradable material increases, hydrolysis rate increases.
Specific embodiment
Below with reference to embodiment, the invention will be further described:
The present embodiment are as follows:
Implement to prepare: gravity concentration being carried out to excess sludge, moisture content is about 96% after concentration;By the dry slag of plant rub to About 2mm partial size, the fundamental property parameter of measurement digestion matrix: pH, TS (total solid), VS (volatile solid), TOC, TN.
Volatile solid VS refers to the part solid that can be volatilized under 550 degree of high temperature in total solid;Volatile solid VS For biodegradable organic object amount can be passed through in sludge, food and drink grease and the dry slag of plant.
Step 1, food and drink grease are added in the dry slag of plant and are stirred mixing, add excess sludge and seed sludge into Row mixing, the VS mass ratio of setting excess sludge, food and drink grease and the dry slag of plant, and mixed digestion substrate moisture content is Between 20~30, seed sludge adds ratio and can be added according to volume ratio 96%~98%, C/N ratio (TOC/TN), The volume ratio of seed sludge and digestion substrate to be seeded is 1: 1~3.
The mixture of step 1 is placed in anaerobic digestor by step 2, and inert gas is filled with after sealing ensures anaerobic environment, Mix digestion substrate constantly using the mode of stirring or oscillation, reaction temperature is 37 DEG C ± 1, and pH value maintains 7~7.5, instead It is 40~50 days between seasonable, reactor, which no longer generates biogas and reacts, to be stopped, and wherein the domestication time of seed sludge is 3~7 days, Seed sludge dosage is bigger, and the domestication time is shorter.
It is collected using the gas that collection airbag generates reaction, and the micro flowmeter of using gas carries out gas volume Test.The methane content in analysis measurement biogas is carried out using methane content analyzer or gas chromatographicanalyzer.
Excess sludge, food and drink grease, the dry slag of plant VS mass ratio be respectively 1: 0: 0,1: 0: 2,1: 2: 0,1: 2: 0.2,1 :2:1,1:2:2.Experimental measuring and gas production are shown in Table 1:
Table 1: example test result
As seen from Table 1: under conditions of VS is added than being 1: 2: 1, unit dosage methane production (341.5mL/g) is surplus 3.87 times of the remaining independent anaerobic digestion methane production (88.1mL/g) of sludge, are excess sludge and food and drink grease (1: 2: 0) methane 1.41 times of yield (241.6mL/g).
Test result shows: the present invention is 1: 2: 0.2~2 in the VS mass ratio of excess sludge, food and drink grease, the dry slag of plant It is fairly obvious to the promotion of methane phase performance in range, improve methane production.

Claims (5)

1. a kind of method for anaerobic sludge digestion, characterized in that the following steps are included:
Food and drink grease is added in the dry slag of plant and is stirred by step 1, adds excess sludge and is mixed;
Mixture obtained in the step 1 is carried out anaerobic digestion by step 2.
2. method for anaerobic sludge digestion according to claim 1, it is characterized in that: the dry slag of the plant is withered emergent aquactic plant Dry slag or the dry slag of agricultural stalk.
3. method for anaerobic sludge digestion according to claim 2, it is characterized in that: excess sludge, food and drink grease and plant are dry The VS mass ratio of slag is 1: 2: 0.2~2.
4. method for anaerobic sludge digestion according to claim 3, it is characterized in that: excess sludge, food and drink grease and plant are dry It is 20 ~ 30 that the mixed digestion substrate moisture content of the VS of slag, which is 96% ~ 98%, C/N ratio,.
5. method for anaerobic sludge digestion according to claim 4, it is characterized in that: the seed sludge of anaerobic digestion with mix after Digestion substrate volume ratio be 1: 1~3.
CN201811507587.XA 2018-12-11 2018-12-11 A kind of method for anaerobic sludge digestion Pending CN109399883A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811507587.XA CN109399883A (en) 2018-12-11 2018-12-11 A kind of method for anaerobic sludge digestion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811507587.XA CN109399883A (en) 2018-12-11 2018-12-11 A kind of method for anaerobic sludge digestion

Publications (1)

Publication Number Publication Date
CN109399883A true CN109399883A (en) 2019-03-01

Family

ID=65458313

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811507587.XA Pending CN109399883A (en) 2018-12-11 2018-12-11 A kind of method for anaerobic sludge digestion

Country Status (1)

Country Link
CN (1) CN109399883A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002015945A1 (en) * 2000-08-22 2002-02-28 Green Farm Energy A/S Concept for slurry separation and biogas production
CN102352380A (en) * 2011-10-14 2012-02-15 大连力达环境工程有限公司 Food residue and sludge mixing anaerobic treatment method and system
CN102747107A (en) * 2012-07-20 2012-10-24 北京化工大学 Methane fermenting method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002015945A1 (en) * 2000-08-22 2002-02-28 Green Farm Energy A/S Concept for slurry separation and biogas production
CN102352380A (en) * 2011-10-14 2012-02-15 大连力达环境工程有限公司 Food residue and sludge mixing anaerobic treatment method and system
CN102747107A (en) * 2012-07-20 2012-10-24 北京化工大学 Methane fermenting method

Similar Documents

Publication Publication Date Title
El-Mashad et al. Biogas production from co-digestion of dairy manure and food waste
Bah et al. Evaluation of batch anaerobic co-digestion of palm pressed fiber and cattle manure under mesophilic conditions
Kusch et al. Biogas production with horse dung in solid-phase digestion systems
Tambone et al. Nitrogen mineralization from digestate in comparison to sewage sludge, compost and urea in a laboratory incubated soil experiment
CN102559773B (en) A kind of many raw materials mix the method that nearly synchronous fermentation synergism improves gas generation property
Sales et al. Use of Brazilian sugarcane bagasse ash in concrete as sand replacement
Provenzano et al. Chemical and spectroscopic characterization of organic matter during the anaerobic digestion and successive composting of pig slurry
Fernández et al. Use of thermal analysis techniques (TG–DSC) for the characterization of diverse organic municipal waste streams to predict biological stability prior to land application
CN103588519A (en) MS preparation organic bio-fertilizer and preparation method thereof
CN102898196A (en) Organic fertilizer using chicken manure and mushroom dreg as raw materials and preparation technology
Siles et al. Biomethanization of waste derived from strawberry processing: Advantages of pretreatment
CN1673191A (en) Organic fertilizer prepared with bamboo waste and its prepn process
CN102603379A (en) Processing method for organic solid waste
CN105084957A (en) Method for preparing bio-organic fertilizer from filter residues produced after anaerobic fermentation of kitchen waste and application of bio-organic fertilizer
Cheng et al. Promoting the production of methane on the co-digestion of food waste and sewage sludge by aerobic pre-treatment
Zazouli et al. Evaluation of cow manure effect as bulking agent on concentration of heavy metals in municipal sewage sludge vermicomposting
Pangallo et al. The fate of biodegradable plastic during the anaerobic co-digestion of excess sludge and organic fraction of municipal solid waste
CN109399883A (en) A kind of method for anaerobic sludge digestion
Shaarani et al. Co-composting landfill leachate with sugarcane bagasse for biofertilizer production
Odekanle et al. Anaerobic treatment of abattoir waste: biogas production and correlation parameter in a batch reactor system
CN108358719A (en) Organic fertilizer and preparation method thereof is made using multiclass stalk
Ebunilo et al. Comparative analysis of biogas yield from different composition of domestic wastes from Benin City, Nigeria
CN105439507B (en) Body of residue stabilization containing cadmium and preparation method thereof
CN109206161A (en) A kind of organic fertilizer based on the fermentation of miscellaneous tree branch
Bień et al. Composting process as an alternative method for the disposal of sewage sludge and organic fraction of municipal solid waste

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190301