CN109393555A - A kind of preparation method of the cigarette capsule with degrading resistance property - Google Patents
A kind of preparation method of the cigarette capsule with degrading resistance property Download PDFInfo
- Publication number
- CN109393555A CN109393555A CN201811493300.2A CN201811493300A CN109393555A CN 109393555 A CN109393555 A CN 109393555A CN 201811493300 A CN201811493300 A CN 201811493300A CN 109393555 A CN109393555 A CN 109393555A
- Authority
- CN
- China
- Prior art keywords
- capsule
- weight
- parts
- preparation
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0216—Applying additives to filter materials the additive being in the form of capsules, beads or the like
Abstract
The present invention relates to a kind of preparation method of capsule with degrading resistance property, which includes preparing capsule wall material solution, dripping capsule, crosslinking and cleaning, balance and screening.There is the present invention capsule of degrading resistance property to overcome the harsh use environment requirement of existing capsule, do not adapt to puzzlement brought by the climate difference of each department, at the same overcome product produce and sell, reprocessing during ease back, deform, leakage, empty pearl and other issues.Product quality risk is reduced, guarantees consumer experience sense.
Description
[technical field]
The invention belongs to the preparation technical fields of cigarette supplementary.More particularly it relates to which a kind of have resist processing
The preparation method of the capsule of energy.
[background technique]
Pomander, the brittleness capsule, pearl of cigarette capsule also referred to as, its 1.5~6.0mm of diameter, quick-fried pearl refer to embedded in cigarette
The small glue bead of liquid in filter tip, it contains the liquid of different shaped fragrance, has quick-fried sense when racking.Generally in the filter tip of cigarette
Middle use, that is, the quick-fried pearl cigarette often said.Smoker is pinched quick-fried in smoking process, releases capsule-core substance, gives its offer
It is abundant, fragrant to moisten comfortable fragrance, mouth feeling experience.It, will also be by through natural air drying, screening, detection, packet after quick-fried pearl production molding
The processes such as dress, transport, filter stick formation processing, the processing of cigarette cigarette.Each procedure can all cause irreversible physics to capsule
Damage, in most Zhongdao finished cigarettes, the low capsule of resist processing just will appear ease back, deform, leakage, empty pearl and other issues.
Existing capsule technology of preparing is mainly emulsion process and dropping preparation method, prepared by most of use dropping preparation methods；Such as CN
200910273417 disclose the application of a kind of dripping pills of cigarette additive lapping and dripping pill and dripping pill with its package, wherein
Wall material is by sodium alginate, glycerol and water according to weight ratio (1~8): (0.5~5): (85~100) are made, since wall material only uses
Sodium alginate makes that capsule wall material brittleness is low, easily rupturable, leakage.CN 201410059949 discloses a kind of four layers of cigarette glue
Capsule and preparation method thereof, wherein forming capsule wall material by paraffin, beeswax, oil content in paraffin wax is excessively high to will affect paraffin coloration and storage
Stability, its hardness can also reduced., beeswax is integrally in yellow or yellowish-brown, opaque or sub-translucent.Its surface light
Sliding, touching has greasy feeling, and body can gently bubble through the water column, and matter is soft crisp when cold, and cataclasm face graininess, being pinched with hand rubbing can soften.US
200880125601.8 disclose a kind of brittleness capsule preparation method thereof for tobacco, wherein no using starch or modified starch etc.
Kind of starch of the same race, gelatinization point is different, and starch water imbibition is poor, is easy occur the problems such as rupture, leakage in the drying process.
Present invention seek to address that capsule has degrading resistance property in process, it is total by lot of experiments and analysis
Knot, completes the present invention finally.
[summary of the invention]
[technical problems to be solved]
The object of the present invention is to provide a kind of preparation methods of capsule with degrading resistance property.
[technical solution]
The present invention is achieved through the following technical solutions.
The present invention relates to a kind of preparation methods of capsule with degrading resistance property.
The step of preparation method, is as follows:
A, capsule wall material solution is prepared
By 5~12 parts by weight gels, 3.5~5.0 parts by weight viscose binders, 0.05~0.2 parts by weight pigment, 82~92 weights
Amount part water is uniformly mixed with 0.5~0.8 parts by weight toughener, then in changing glue tank 50~100 DEG C of temperature and revolving speed 50~
Stirring and dissolving under conditions of 200r/min obtains a kind of capsule wall material solution；
B, dripping capsule
The capsule wall material solution that step A is obtained is added in pill dripping machine glue case, allow its capsule wall material solution left standstill 20~
50min removes bubble removing, reuses pill dripping machine for its drop and crude capsule product is made；
C, crosslinking and cleaning
The crude capsule product that step B is obtained, which is added in crosslinked fluid, to be crosslinked, and is then removed using pure water cleaning
The grease stain being attached on its crude capsule product surface, it is then dry in swing rotating cage, obtain semi-finished product capsule；
D, balance and screening
The semi-finished product capsule washes of absolute alcohol for allowing step C to obtain is balanced in being then placed between balancing, then sieves
Divide and selected with lamp, then obtains the capsule with degrading resistance property.
A preferred embodiment of the invention, in step, the gel are one or more selected from general Shandong
Blue polysaccharide, carragheen, gelatin, Arabic gum, agar, gellan gum, locust bean gum or xanthan gum gel；The adhesive is one
Kind or a variety of adhesives selected from hydroxymethyl cellulose, sodium alginate, polyvinyl alcohol or starch；The pigment is a kind of or more
Kind is selected from the pigment of brilliant blue pigment, lemon yellow pigment or allured red pigment；The toughener is one or more selected from poly- second
The toughener of glycol, D-sorbite or glycerol.
According to another preferred method of implementation of the present invention, in step, the viscosity of the capsule wall material solution is 50-
400mpas。
According to another preferred method of implementation of the present invention, in stepb, the pill dripping machine is single channel pill dripping machine.
According to another preferred method of implementation of the present invention, in step C, the crosslinked fluid is handed over by 1~2 parts by weight
The aqueous solution that connection agent, 0.2~0.3 parts by weight pigment, 0.5~0.6 parts by weight toughener and 97~98 parts by weight water are formulated；
The crosslinking agent is one or more selected from acetic acid, glutaraldehyde, potassium chloride, calcium chloride, sodium chloride, citric acid
The crosslinking agent of potassium, sodium citrate or calcium lactate；The pigment is one or more selected from brilliant blue pigment, lemon yellow pigment or luring
The pigment of puzzled haematochrome；The toughener is one or more toughener in D-sorbite, glycerol or polyethylene glycol.
According to another preferred method of implementation of the present invention, in step C, the thick capsule product is in temperature 10~60
20~80min of crosslinking is carried out under conditions of DEG C.
According to another preferred method of implementation of the present invention, in step C, the thick capsule product cleaned with pure water is in phase
Humidity 30~50% is dried with 20~30 DEG C of temperature of condition.
According to another preferred method of implementation of the present invention, in step C, the revolving speed of swing rotating cage is 20~100r/
min。
According to another preferred method of implementation of the present invention, in step D, cleaning semi-finished product capsule is balancing between balance
It is balanced 8~30 hours under conditions of 10~40 DEG C of temperature and relative humidity 20~70%.
According to another preferred method of implementation of the present invention, in step D, the semi-finished product capsule of balance is in temperature 10~40
Screening is carried out under conditions of DEG C with relative humidity 20~70% to select with lamp.
The present invention will be described in detail belows.
The present invention relates to a kind of preparation methods of capsule with degrading resistance property.
The step of preparation method, is as follows:
A, capsule wall material solution is prepared
By 5~12 parts by weight gels, 3.5~5.0 parts by weight viscose binders, 0.05~0.2 parts by weight pigment, 82~92 weights
Amount part water is uniformly mixed with 0.5~0.8 parts by weight toughener, then in changing glue tank 50~100 DEG C of temperature and revolving speed 50~
Stirring and dissolving under conditions of 200r/min obtains a kind of capsule wall material solution；
In the present invention, gel is stabilizer preparing the main function in capsule wall material solution, adjustment gel time.
The gel that the present invention uses be it is one or more selected from pulullan polysaccharide, carragheen, gelatin, Arabic gum, agar,
The gel of gellan gum, locust bean gum or xanthan gum；
Pulullan polysaccharide is a kind of extracellular water solubility by the generated similar glucan of Aureobasidium pullulans fermentation, xanthan gum
Cement polysaccharide will not cause environmental pollution because it can be degraded by microorganisms in nature, have in industries such as medicine, food wide
General application prospect.
Carragheen is also known as antler glue, carrageenan, Irish green moss glue, be one kind from marine red alga (including angle
Pitch Lepidium, Eucheuma, China fir Trentepohlia and husky Lepidium etc.) in the polysaccharide that extracts be referred to as.
Gelatin is a kind of very important native biopolymer material, has been widely used in food, medicine and chemical industry
Industry.It by the connective tissues such as animal skin, bone, sarolemma, flesh evil spirit collagenous portion degrade and become it is white or faint yellow, partly
Transparent, micro-strip gloss thin slice or powder, are a kind of colorless and odorless, non-volatility, transparent hard non-crystalline material, solvable
In hot water.
Arabic gum is also referred to as gum arabic, is a kind of the natural of the semidesert band originated on the south Sahara
Natural plant gum mainly contains pectinose, galactolipin, glucuronic acid etc., it is in food, medicine, cosmetics and other are industrial
It is widely used.
Agar (agar-agar), agar are generally called agel-agal or agar, are made of marine products agar, fragrant plant mentioned in ancient texts etc., for colourless, nothing is solid
The solid of setting shape, is dissolved in hot water.
Gellan gum main component is linear by what is formed by constitutional repeating unit of glucose, glucuronic acid and rhamnose
Polysaccharide.
Locust bean gum is the sub- glue of plant being process by locust tree tree species for originating in one band of Mediterranean, is white or yellowish
Powder mainly makees thickener, emulsifier and stabilizer in the food industry.
The gel that the present invention uses all is current market sales of food grade products, such as by Zhengzhou sky food ingredient
It is pulullan polysaccharide that Co., Ltd is sold with trade name pullulan, bright with trade name by Zhengzhou Chemical Co., Ltd. free from worldly cares
The gelatin of glue sale, agar sell with trade name agar powder by Wuxi Biotechnology Co., Ltd, Tontru, by the resistance to modern reality in Shanghai
Gellan gum that industry Co., Ltd is sold with trade name gellan gum, by Henan De Xin chemical industry Industrial Co., Ltd. with trade name xanthan gum
The xanthan gum of sale.
In the present invention, adhesive is thickener, solidifying mixture preparing the main function in capsule wall material solution, adjusts glue
Fluid viscosity.
The adhesive that the present invention uses is one or more selected from hydroxymethyl cellulose, sodium alginate, polyvinyl alcohol or shallow lake
The adhesive of powder；
Native cellulose is that the polysaccharide most wide, content is most is distributed in nature, and cellulose obtains carboxylic after carboxy methylation
There is thickening, the protection of film forming, gluing, water tariff collection, colloid, emulsification and suspension etc. to make for methylcellulose (CMC), aqueous solution
With being widely used in the industries such as petroleum, food, medicine, textile and paper, be one of most important cellulose ethers.
Sodium alginate is a kind of natural polysaccharide, stability, dissolubility, viscosity and safety needed for having pharmaceutical preparation auxiliary material
Property.
Polyethylene glycol is nontoxic, nonirritant, has good water solubility, and have good mix with many organic matter components
Property.
Polyvinyl alcohol is soluble easily in water, and as water temperature increases, solubility increases.Compared with other water soluble polymers,
Hygroscopicity is lower.Its good film-forming property, the physical properties such as tension, pulling force, frictional strength are better than other synthetic resin.
Starch is a kind of polysaccharide, and starch can be regarded as the high polymer of glucose.Starch is industrially used in addition to edible
Paste producing essence, maltose, glucose, alcohol etc., can be by extracting in the amyloid substances such as corn, sweet potato, wild acorn nut and pueraria lobata
And it obtains.
The adhesive that the present invention uses all is current market sales of food grade products, such as by Wuhan Ruian safeization
Hydroxymethyl cellulose that work Co., Ltd is sold with trade name hydroxymethyl cellulose, by Zhengzhou You Ran chemical products Co., Ltd with
The sodium alginate of trade name sodium alginate sale, the poly- second sold by Zhengzhou Hong Xiang Chemical Co., Ltd. with trade name polyvinyl alcohol
Enol.
In the present invention, pigment is preparing the main function capsule coloring in capsule wall material solution.
The pigment that the present invention uses is one or more colors selected from brilliant blue pigment, lemon yellow pigment or allured red pigment
Element, they are all current market sales of products, such as are eaten by Zhengzhou sky food ingredient Co., Ltd with trade name
The brilliant blue pigment of the sale of toner brilliant blue 85% is sold by Zhengzhou sky food ingredient Co., Ltd with trade name Tatrazine 85%
The lemon yellow pigment sold, the temptation red sold by Zhengzhou sky food ingredient Co., Ltd with the edible temptation red 85% of trade name
Element.
In the present invention, toughener is to increase wall material toughness preparing the main function in capsule wall material solution.
The toughener that the present invention uses is one or more toughener selected from polyethylene glycol, D-sorbite or glycerol.
D-sorbite is 50% or 70% sorbitol aqueous solution, is in sticky shape transparency liquid, there is optical activity, slightly sweet taste,
With hygroscopicity, various metals can be dissolved, it is unstable under high temperature.
Glycerol can be used as solvent, lubricant, medicament and sweetener, be colourless sweet clear and bright thick liquid, odorless, there is warm sweet tea
Taste can absorb moisture from air.
The toughener that the present invention uses all is current market sales of product, such as by Changzhou Chi Yuan Chemical Co., Ltd.
With trade name polyethylene glycol PEG400-4000 sale polyethylene glycol, by Jinan Xin Shunhang Biotechnology Co., Ltd with commodity
The D-sorbite of name D-sorbite sale.
According to the present invention, according to GB standard using -4 glasss of method detections are applied, the viscosity of the capsule wall material solution is 50-
400mpas。
In the present invention, if the viscosity of the capsule wall material solution be more than the range be it is worthless, this be because
It is more than the range for gelatin viscosity, it is very big on dripping process and capsule quality influence, so, it is undesirable more than the range
?.
B, dripping capsule
The capsule wall material solution that step A is obtained is added in pill dripping machine glue case, allow its capsule wall material solution left standstill 20~
50min removes bubble removing, reuses pill dripping machine for its drop and crude capsule product is made；
The pill dripping machine used in this step is single channel pill dripping machine, it is current market sales of product, such as
The single channel pill dripping machine sold by Zhifu Plastic Machinery Co., Ltd., Tangshan City with trade name trickle irrigation drilling pill device.
When the present invention uses the single channel pill dripping machine, usually pill dripping machine glue box temperature degree and water dropper temperature are controlled respectively 50
~90 DEG C and 60~90 DEG C.If can all cause capsule wall material solution viscosity excessively high at a temperature below 50 DEG C or 60 DEG C, occur
Situations such as wire drawing, if temperature be higher than 90 DEG C if will lead to package fluid viscosity it is too low, influence dripping capsule quality.
C, crosslinking and cleaning
The crude capsule product that step B is obtained, which is added in crosslinked fluid, to be crosslinked, and is then removed using pure water cleaning
The grease stain being attached on its crude capsule product surface, it is then dry in swing rotating cage, obtain semi-finished product capsule；
According to the present invention, crude capsule product is crosslinked it should be understood that strengthening to crude capsule in crosslinked fluid.
In the present invention, the crosslinked fluid be by 1~2 parts by weight of crosslinking agent, 0.2~0.3 parts by weight pigment, 0.5~
The aqueous solution that 0.6 parts by weight toughener and 97~98 parts by weight water are formulated；
In the present invention, main function of the crosslinking agent in crosslinked fluid is to play a part of to strengthen, be dehydrated.
The crosslinking agent that the present invention uses is one or more selected from acetic acid, glutaraldehyde, potassium chloride, calcium chloride, sodium chloride, lemon
The crosslinking agent of lemon acid potassium, sodium citrate or calcium lactate, they are all current market sales of products, such as by Huangshan Bath
The glutaraldehyde that intelligent auxiliary chemicals Co., Ltd is sold with trade name glutaraldehyde；
In the present invention, main function of the pigment in crosslinked fluid is to colour for crude capsule or capsule color is kept not move back
Color.
The pigment that the present invention uses is one or more colors selected from brilliant blue pigment, lemon yellow pigment or allured red pigment
Element, they are all current market sales of products, such as are eaten by Zhengzhou sky food ingredient Co., Ltd with trade name
The brilliant blue pigment of the sale of toner brilliant blue 85% is sold by Zhengzhou sky food ingredient Co., Ltd with trade name Tatrazine 85%
The lemon yellow pigment sold, the temptation red sold by Zhengzhou sky food ingredient Co., Ltd with the edible temptation red 85% of trade name
Element；
In the present invention, main function of the toughener in crosslinked fluid is the moisture for guaranteeing crude capsule.
The toughener that the present invention uses is one or more toughener in D-sorbite, glycerol or polyethylene glycol,
They are all current market sales of products, such as by Jinan Xin Shunhang Biotechnology Co., Ltd with trade name D-sorbite
The D-sorbite of sale.
In the present invention, when other amounts of components are in the range, if dosage of crosslinking agent is lower than 1 parts by weight, by force
Change, dehydration are unobvious；If dosage of crosslinking agent is higher than 2 parts by weight, there is no strengthen dehydration；Therefore, crosslinking agent
Dosage is that 1~2 parts by weight are suitable, preferably 1.2~1.8 parts by weight；
When other amounts of components are in the range, if pigment dosage is lower than 0.2 parts by weight, capsule color is too shallow；
If pigment dosage is higher than 0.3 parts by weight, capsule color is too deep；Therefore, it is appropriate that pigment dosage, which is 0.2~0.3 parts by weight,
, preferably 0.22~0.28 parts by weight；
When other amounts of components are in the range, if toughener dosage is lower than 1 parts by weight, capsule is excessively crisp；If
Toughener dosage is higher than 2 parts by weight, then capsule is really up to the mark；Therefore, toughener dosage be 0.5~0.6 parts by weight be it is feasible, preferably
Ground is 0.52~0.58 parts by weight；
When other amounts of components are in the range, if water consumption is lower than 97 parts by weight, gelatin viscosity is too small；If
Water consumption is higher than 98 parts by weight, then gelatin viscosity is excessive；Therefore, water consumption be 97~98 parts by weight be it is appropriate, preferably
97.2~97.8 parts by weight；
According to the present invention, the thick capsule product carries out 20~80min of crosslinking under conditions of 10~60 DEG C of temperature.
In this step, the thick capsule product cleaned with pure water is in swing rotating cage in 20~100r/ of revolving speed
Min, relative humidity 30~50% with 20~30 DEG C of temperature under conditions of be dried, removing is attached to its crude capsule product table
Grease stain on face.
The swing rotating cage that the present invention uses is current market sales of product, such as is had by Wuxi ring precious jade machinery science and technology
Limit company is with the product of the swing rotational molding machine sale of trade name.
D, balance and screening
The semi-finished product capsule washes of absolute alcohol for allowing step C to obtain is balanced in being then placed between balancing, then sieves
Divide and selected with lamp, then obtains the capsule with degrading resistance property.
According to the present invention, the basic role that cleaning semi-finished product capsule balances between balance is volatilization dehydrated alcohol.
Certain temperature and certain humidity range are to maintain between the balance, for balance after washes of absolute alcohol half at
Product capsule.
It is flat under conditions of 10~40 DEG C of equilibrium temperature and relative humidity 20~70% between balance to clean semi-finished product capsule
Weighing apparatus 8~30 hours.
In this step, the semi-finished product capsule of balance is under conditions of 10~40 DEG C of temperature with relative humidity 20~70%
Screening is carried out to select with lamp.
In the present invention, screening be using by the new Machinery Co., Ltd. of Xinxiang City's Condar with trade name stainless steel punched-plate net
The stamped sieve of standard screen sale carries out partial size screening, obtains the capsule of 3.3~3.6mm of partial size.These capsules are then in lamp channel selection
The underproof product of appearance is with the naked eye picked out under fluorescent lamp.
Dry breakage rate and screening breakage rate have been carried out to the capsule being prepared using quantitative approach according to national standard
Detection, testing result are listed in Table 1 below.
[beneficial effect]
It is compared with the prior art, the invention has the following advantages:
1, crosslinking time of the present invention is shorter, and the crude product obtained after the completion of being crosslinked is harder compared to prior art, is easy
Realize industrialization.
2, crude product of the present invention has resist processing characteristic, improves capsule finished product yield.
3, finished capsule product of the present invention due to degrading resistance property, occur when solving following process it is rotten, become
Shape even ruptures leakage problems.
4, product of the present invention overcomes the harsh use environment requirement of existing capsule, does not adapt to each department climate difference institute
Bring puzzlement, at the same overcome product produce and sell, reprocessing during ease back, deform, leakage, the quality such as empty pearl are asked
Topic.Product quality risk is reduced, guarantees consumer experience sense.
[specific embodiment]
It will be better understood that the present invention by following embodiments.
Embodiment 1: the preparation with degrading resistance property capsule
The implementation steps of the embodiment are as follows:
A, capsule wall material solution is prepared
By 9 parts by weight pulullan polysaccharide gels, 3.5 parts by weight hydroxymethyl cellulose adhesives, 0.18 parts by weight sapphirine
Plain color element, 90 parts by weight water are uniformly mixed with 0.5 parts by weight polyethylene glycol toughener, then in changing glue tank in 90 DEG C of temperature and
Stirring and dissolving under conditions of revolving speed 50r/min obtains a kind of capsule wall material solution, detects it using the method that this specification describes
Viscosity be 50mpas；
B, dripping capsule
The capsule wall material solution that step A is obtained is added to by Zhifu Plastic Machinery Co., Ltd., Tangshan City with trade name trickle irrigation
In the pill dripping machine glue case of the single channel pill dripping machine of drilling pill device sale, its capsule wall material solution left standstill 50min is allowed to remove bubble removing, then
It is dripped under conditions of pill dripping machine glue case temperature 50 C and water dropper temperature 60 C using pill dripping machine, crude capsule product is made；
C, crosslinking and cleaning
The crude capsule product that step B is obtained, which is added in crosslinked fluid, carries out crosslinking 68min under conditions of 20 DEG C of temperature,
The crosslinked fluid is increased by 2.0 parts by weight glutaraldehyde cross-linking agent, 0.2 parts by weight brilliant blue pigmentary color element, 0.5 parts by weight D-sorbite
Tough dose is formulated with 97 parts by weight water；Then the oil being attached on its crude capsule product surface is removed using pure water cleaning
Stain, then in the swing rotating cage sold by Wuxi ring precious jade machinery Science and Technology Ltd. with the swing rotational molding machine of trade name,
It is dry under conditions of revolving speed 100r/min, relative humidity 35% and 30 DEG C of temperature, obtain semi-finished product capsule；
D, balance and screening
The semi-finished product capsule for allowing step C to obtain is cleaned with alcoholic solution, at 34 DEG C of equilibrium temperature in being then placed between balancing
Balanced 25 hours under conditions of relative humidity 40%, then under conditions of 22 DEG C of temperature is with relative humidity 40% use by Xinxiang
Condar new Machinery Co., Ltd. in city's carries out partial size screening with the stamped sieve that trade name stainless steel punched-plate net standard screen is sold, and obtains
Then the capsule of 3.3~3.6mm of partial size with the naked eye picks out the underproof product of appearance under lamp channel selection fluorescent lamp, then
To the capsule with degrading resistance property.
Dry breakage rate and screening breakage rate have been carried out to the capsule being prepared using quantitative approach according to national standard
Detection, testing result are listed in Table 1 below.
Embodiment 2: the preparation with degrading resistance property capsule
The implementation steps of the embodiment are as follows:
A, capsule wall material solution is prepared
By 6 parts by weight OK a karaoke club glue gels, 3.8 parts by weight sodium alginate adhesives, 0.08 parts by weight of lemon uranidin pigment,
82 parts by weight water are uniformly mixed with 0.6 parts by weight D-sorbite toughener, then in 80 DEG C of temperature and revolving speed in changing glue tank
Stirring and dissolving under conditions of 200r/min obtains a kind of capsule wall material solution, detects its using the method that this specification describes
Viscosity is 260mpas；
B, dripping capsule
The capsule wall material solution that step A is obtained is added to by Zhifu Plastic Machinery Co., Ltd., Tangshan City with trade name trickle irrigation
In the pill dripping machine glue case of the single channel pill dripping machine of drilling pill device sale, its capsule wall material solution left standstill 20min is allowed to remove bubble removing, then
It is dripped under conditions of pill dripping machine glue case temperature 60 C is with 84 DEG C of water dropper temperature using pill dripping machine, crude capsule product is made；
C, crosslinking and cleaning
The crude capsule product that step B is obtained, which is added in crosslinked fluid, carries out crosslinking 56min under conditions of 30 DEG C of temperature,
The crosslinked fluid is by 1.2 parts by weight potassium chloride crosslinking agents, 0.3 parts by weight of lemon uranidin pigment, 0.6 parts by weight of glycerin toughening
Agent is formulated with 98 parts by weight water；Then the oil being attached on its crude capsule product surface is removed using pure water cleaning
Stain, then in the swing rotating cage sold by Wuxi ring precious jade machinery Science and Technology Ltd. with the swing rotational molding machine of trade name,
It is dry under conditions of revolving speed 50r/min, relative humidity 40% and 20 DEG C of temperature, obtain semi-finished product capsule；
D, balance and screening
The semi-finished product capsule for allowing step C to obtain is cleaned with alcoholic solution, at 10 DEG C of equilibrium temperature in being then placed between balancing
Balanced 30 hours under conditions of relative humidity 50%, then under conditions of 28 DEG C of temperature is with relative humidity 50% use by Xinxiang
Condar new Machinery Co., Ltd. in city's carries out partial size screening with the stamped sieve that trade name stainless steel punched-plate net standard screen is sold, and obtains
Then the capsule of 3.3~3.6mm of partial size with the naked eye picks out the underproof product of appearance under lamp channel selection fluorescent lamp, then
To the capsule with degrading resistance property.
Dry breakage rate and screening breakage rate have been carried out to the capsule being prepared using quantitative approach according to national standard
Detection, testing result are listed in Table 1 below.
Embodiment 3: the preparation with degrading resistance property capsule
The implementation steps of the embodiment are as follows:
A, capsule wall material solution is prepared
By 5 parts by weight gelatin and Arabic gum mixture (weight ratio 1:2) gel, 4.0 weight account polyethylene alcohol adhesives,
0.05 parts by weight allured red pigment pigment, 92 parts by weight water are uniformly mixed with 0.8 parts by weight of glycerin toughener, are then changing glue tank
In in temperature 50 C and stirring and dissolving under conditions of revolving speed 140r/min, a kind of capsule wall material solution is obtained, using this specification
The viscosity that the method for description detects it is 190mpas；
B, dripping capsule
The capsule wall material solution that step A is obtained is added to by Zhifu Plastic Machinery Co., Ltd., Tangshan City with trade name trickle irrigation
In the pill dripping machine glue case of the single channel pill dripping machine of drilling pill device sale, its capsule wall material solution left standstill 26min is allowed to remove bubble removing, then
It is dripped under conditions of 90 DEG C of pill dripping machine glue box temperature degree with 90 DEG C of water dropper temperature using pill dripping machine, crude capsule product is made；
C, crosslinking and cleaning
The crude capsule product that step B is obtained is added in crosslinked fluid carries out crosslinking 20min under conditions of temperature 60 C,
The crosslinked fluid is by 1.4 parts by weight potassium chloride crosslinking agents, 0.2 parts by weight allured red pigment pigment, 0.5 parts by weight polyethylene glycol
Toughener is formulated with 97 parts by weight water；Then it is removed and is attached on its crude capsule product surface using pure water cleaning
Grease stain, then in the swing rotating cage sold by Wuxi ring precious jade machinery Science and Technology Ltd. with the swing rotational molding machine of trade name,
It is dry under conditions of revolving speed 60r/min, relative humidity 30% are with 28 DEG C of temperature, obtain semi-finished product capsule；
D, balance and screening
The semi-finished product capsule for allowing step C to obtain is cleaned with alcoholic solution, at 16 DEG C of equilibrium temperature in being then placed between balancing
Balanced 12 hours under conditions of relative humidity 20%, then under conditions of 34 DEG C of temperature is with relative humidity 60% use by Xinxiang
Condar new Machinery Co., Ltd. in city's carries out partial size screening with the stamped sieve that trade name stainless steel punched-plate net standard screen is sold, and obtains
Then the capsule of 3.3~3.6mm of partial size with the naked eye picks out the underproof product of appearance under lamp channel selection fluorescent lamp, then
To the capsule with degrading resistance property.
Dry breakage rate and screening breakage rate have been carried out to the capsule being prepared using quantitative approach according to national standard
Detection, testing result are listed in Table 1 below.
Embodiment 4: the preparation with degrading resistance property capsule
The implementation steps of the embodiment are as follows:
A, capsule wall material solution is prepared
96512810 parts by weight agar and gellan gum mixture (weight ratio 1:1) gel, 5.0 weight starch are bonded
Agent, 0.12 parts by weight brilliant blue pigment and lemon yellow pigment mixture (weight ratio 1:1) pigment, 88 parts by weight water and 0.7 parts by weight
D-sorbite is uniformly mixed with glycerol mixture (weight ratio 1:3) toughener, then in 100 DEG C of temperature and revolving speed in changing glue tank
Stirring and dissolving under conditions of 170r/min obtains a kind of capsule wall material solution, detects its using the method that this specification describes
Viscosity is 400mpas；
B, dripping capsule
The capsule wall material solution that step A is obtained is added to by Zhifu Plastic Machinery Co., Ltd., Tangshan City with trade name trickle irrigation
In the pill dripping machine glue case of the single channel pill dripping machine of drilling pill device sale, its capsule wall material solution left standstill 32min is allowed to remove bubble removing, then
It is dripped under conditions of 80 DEG C of pill dripping machine glue box temperature degree with 78 DEG C of water dropper temperature using pill dripping machine, crude capsule product is made；
C, crosslinking and cleaning
The crude capsule product that step B is obtained, which is added in crosslinked fluid, carries out crosslinking 80min under conditions of 10 DEG C of temperature,
The crosslinked fluid is by 1.0 parts by weight calcium chloride and sodium chloride mixture (weight ratio 2:1) crosslinking agent, 0.3 parts by weight sapphirine
Element and lemon yellow pigment (weight ratio 2:1) pigment, 0.6 parts by weight D-sorbite and glycerol mixture (weight ratio 1:4) toughener
It is formulated with 98 parts by weight water；Then the grease stain being attached on its crude capsule product surface is removed using pure water cleaning,
Then in the swing rotating cage sold by Wuxi ring precious jade machinery Science and Technology Ltd. with the swing rotational molding machine of trade name, in revolving speed
It is dry under conditions of 20r/min, relative humidity 50% and 22 DEG C of temperature, obtain semi-finished product capsule；
D, balance and screening
The semi-finished product capsule for allowing step C to obtain is cleaned with alcoholic solution, at 22 DEG C of equilibrium temperature in being then placed between balancing
Balanced 16 hours under conditions of relative humidity 30%, then under conditions of 16 DEG C of temperature is with relative humidity 30% use by Xinxiang
Condar new Machinery Co., Ltd. in city's carries out partial size screening with the stamped sieve that trade name stainless steel punched-plate net standard screen is sold, and obtains
Then the capsule of 3.3~3.6mm of partial size with the naked eye picks out the underproof product of appearance under lamp channel selection fluorescent lamp, then
To the capsule with degrading resistance property.
Dry breakage rate and screening breakage rate have been carried out to the capsule being prepared using quantitative approach according to national standard
Detection, testing result are listed in Table 1 below.
Embodiment 5: the preparation with degrading resistance property capsule
The implementation steps of the embodiment are as follows:
A, capsule wall material solution is prepared
By 8 parts by weight locust bean glue gels, 4.6 parts by weight hydroxymethyl celluloses and sodium alginate mixture (weight ratio 1:1)
Adhesive, 0.2 parts by weight of lemon uranidin and allured red pigment mixture (weight ratio 1:1) pigment, 86 parts by weight water and 0.6 weight
Amount part polyethylene glycol is uniformly mixed with D-sorbite mixture (weight ratio 2:1) toughener, then in temperature 60 in changing glue tank
Stirring and dissolving under conditions of DEG C with revolving speed 110r/min, obtains a kind of capsule wall material solution, the method described using this specification
The viscosity for detecting it is 330mpas；
B, dripping capsule
The capsule wall material solution that step A is obtained is added to by Zhifu Plastic Machinery Co., Ltd., Tangshan City with trade name trickle irrigation
In the pill dripping machine glue case of the single channel pill dripping machine of drilling pill device sale, its capsule wall material solution left standstill 38min is allowed to remove bubble removing, then
It is dripped under conditions of pill dripping machine glue case temperature 60 C is with 66 DEG C of water dropper temperature using pill dripping machine, crude capsule product is made；
C, crosslinking and cleaning
The crude capsule product that step B is obtained, which is added in crosslinked fluid, carries out crosslinking 44min under conditions of 40 DEG C of temperature,
The crosslinked fluid is bright by 1.6 parts by weight of lemon acid potassium and sodium citrate mixture (weight ratio 3:1) crosslinking agent, 0.2 parts by weight
Cyanine and allured red pigment mixture (weight ratio 1:1) pigment, 0.5 parts by weight D-sorbite and polyethylene glycol mixture (weight
Amount is than 1:2) toughener is formulated with 98 parts by weight water；Then it is removed using pure water cleaning and is attached to its crude capsule product
Grease stain on surface, then by Wuxi ring precious jade machinery Science and Technology Ltd. with the swing of trade name swing rotational molding machine sale
It is dry under conditions of revolving speed 40r/min, relative humidity 45% are with 26 DEG C of temperature in rotating cage, obtain semi-finished product capsule；
D, balance and screening
The semi-finished product capsule for allowing step C to obtain is cleaned with alcoholic solution, at 28 DEG C of equilibrium temperature in being then placed between balancing
Balanced 20 hours under conditions of relative humidity 60%, then under conditions of 10 DEG C of temperature is with relative humidity 20% use by Xinxiang
Condar new Machinery Co., Ltd. in city's carries out partial size screening with the stamped sieve that trade name stainless steel punched-plate net standard screen is sold, and obtains
Then the capsule of 3.3~3.6mm of partial size with the naked eye picks out the underproof product of appearance under lamp channel selection fluorescent lamp, then
To the capsule with degrading resistance property.
Dry breakage rate and screening breakage rate have been carried out to the capsule being prepared using quantitative approach according to national standard
Detection, testing result are listed in Table 1 below.
Embodiment 6: the preparation with degrading resistance property capsule
The implementation steps of the embodiment are as follows:
A, capsule wall material solution is prepared
By 10 parts by weight xanthan glue gels, 4.2 weight account polyethylene alcohol and starch mixture (weight ratio 1:3) adhesive,
0.15 parts by weight brilliant blue pigment and allured red pigment mixture (weight ratio 2:1) pigment, 84 parts by weight water and the poly- second of 0.5 parts by weight
Glycol is uniformly mixed with glycerol mixture (weight ratio 1:2) toughener, then in temperature 70 C and revolving speed 80r/ in changing glue tank
Stirring and dissolving under conditions of min obtains a kind of capsule wall material solution, use this specification describe method detect its viscosity for
120mpas；
B, dripping capsule
The capsule wall material solution that step A is obtained is added to by Zhifu Plastic Machinery Co., Ltd., Tangshan City with trade name trickle irrigation
In the pill dripping machine glue case of the single channel pill dripping machine of drilling pill device sale, its capsule wall material solution left standstill 44min is allowed to remove bubble removing, then
It is dripped under conditions of pill dripping machine glue case temperature 70 C is with 72 DEG C of water dropper temperature using pill dripping machine, crude capsule product is made；
C, crosslinking and cleaning
The crude capsule product that step B is obtained is added in crosslinked fluid carries out crosslinking 32min under conditions of temperature 50 C,
The crosslinked fluid is by 1.8 parts by weight calcium lactate crosslinking agents, 0.3 parts by weight brilliant blue pigment and allured red pigment mixture (weight
Than 1:1) pigment, 0.6 parts by weight D-sorbite and polyethylene glycol mixture (weight ratio 1:2) toughener and 97 parts by weight water prepare
It forms；Then the grease stain being attached on its crude capsule product surface is removed using pure water cleaning, then by Wuxi ring precious jade
Mechanical Science and Technology Ltd. is in the swing rotating cage of trade name swing rotational molding machine sale, in revolving speed 80r/min, relative humidity
40% with 24 DEG C of temperature under conditions of it is dry, obtain semi-finished product capsule；
D, balance and screening
The semi-finished product capsule for allowing step C to obtain is cleaned with alcoholic solution, at 40 DEG C of equilibrium temperature in being then placed between balancing
Balanced 8 hours under conditions of relative humidity 70%, then under conditions of 40 DEG C of temperature is with relative humidity 70% use by Xinxiang
Condar new Machinery Co., Ltd. in city's carries out partial size screening with the stamped sieve that trade name stainless steel punched-plate net standard screen is sold, and obtains
Then the capsule of 3.3~3.6mm of partial size with the naked eye picks out the underproof product of appearance under lamp channel selection fluorescent lamp, then
To the capsule with degrading resistance property.
Dry breakage rate and screening breakage rate have been carried out to the capsule being prepared using quantitative approach according to national standard
Detection, testing result are listed in Table 1 below.
Control sample is the capsule of conventional capsule capsule material dripping, and drying breakage rate is also arranged with screening breakage rate testing result
In table 1.
Table 1: dry breakage rate and screening breakage rate testing result
| Sample serial number | Dry breakage rate (%) | It sieves breakage rate (%) |
| Control sample | 0.05 | 0.06 |
| Embodiment 1 | 0.02 | 0.03 |
| Embodiment 2 | 0.021 | 0.022 |
| Embodiment 3 | 0.015 | 0.02 |
| Embodiment 4 | 0.01 | 0.012 |
| Embodiment 5 | 0.032 | 0.021 |
| Embodiment 6 | 0.025 | 0.019 |
The result that table 1 is listed clearly shows compared with control sample, cigarette of the present invention with degrading resistance property capsule dry and
Breakage rate is low in screening process, has resist processing characteristic.
Claims (10)
1. a kind of preparation method of the capsule with degrading resistance property, it is characterised in that the step of preparation method is as follows:
A, capsule wall material solution is prepared
By 5~12 parts by weight gels, 3.5~5.0 parts by weight viscose binders, 0.05~0.2 parts by weight pigment, 82~92 parts by weight
Water is uniformly mixed with 0.5~0.8 parts by weight toughener, then in 50~100 DEG C of temperature and 50~200r/ of revolving speed in changing glue tank
Stirring and dissolving under conditions of min obtains a kind of capsule wall material solution；
B, dripping capsule
The capsule wall material solution that step A is obtained is added in pill dripping machine glue case, 20~50min of its capsule wall material solution left standstill is allowed to go
Bubble removing reuses pill dripping machine for its drop and crude capsule product is made；
C, crosslinking and cleaning
The crude capsule product that step B is obtained, which is added in crosslinked fluid, to be crosslinked, and then removes attachment removal using pure water cleaning
Grease stain on its crude capsule product surface, it is then dry in swing rotating cage, obtain semi-finished product capsule
D, balance and screening
The semi-finished product capsule washes of absolute alcohol for allowing step C to obtain, be then placed within balance between in be balanced, then sieve with
Lamp choosing, then obtains the capsule with degrading resistance property.
2. preparation method according to claim 1, it is characterised in that in step, the gel is one or more
Gel selected from pulullan polysaccharide, carragheen, gelatin, Arabic gum, agar, gellan gum, locust bean gum or xanthan gum；Described is viscous
Mixture is one or more adhesives selected from hydroxymethyl cellulose, sodium alginate, polyvinyl alcohol or starch；The pigment is
One or more pigments selected from brilliant blue pigment, lemon yellow pigment or allured red pigment；The toughener is one or more
Toughener selected from polyethylene glycol, D-sorbite or glycerol.
3. preparation method according to claim 1, it is characterised in that in step, the viscosity of the capsule wall material solution
It is 50-400mpas.
4. preparation method according to claim 1, it is characterised in that in stepb, the pill dripping machine is single channel drop
Ball machine.
5. preparation method according to claim 1, it is characterised in that in step C, the crosslinked fluid is by 1~2 weight
What amount part crosslinking agent, 0.2~0.3 parts by weight pigment, 0.5~0.6 parts by weight toughener and 97~98 parts by weight water were formulated
Aqueous solution；
The crosslinking agent is one or more selected from acetic acid, glutaraldehyde, potassium chloride, calcium chloride, sodium chloride, potassium citrate, second
The crosslinking agent of acid, sodium citrate or calcium lactate；The pigment is one or more selected from brilliant blue pigment, lemon yellow pigment or luring
The pigment of puzzled haematochrome；The toughener is one or more toughener in D-sorbite, glycerol or polyethylene glycol.
6. preparation method according to claim 1, it is characterised in that in step C, the thick capsule product is in temperature
20~80min of crosslinking is carried out under conditions of 10~60 DEG C.
7. preparation method according to claim 1, it is characterised in that in step C, produced with the thick capsule that pure water cleans
Product are dried in relative humidity 30~50% and 20~30 DEG C of temperature of condition.
8. preparation method according to claim 1, it is characterised in that in step C, the revolving speed of swing rotating cage is 20~
100r/min。
9. preparation method according to claim 1, it is characterised in that in step C, clean semi-finished product capsule between balance
It is balanced 8~30 hours under conditions of 10~40 DEG C of equilibrium temperature with relative humidity 20~70%.
10. preparation method according to claim 1, it is characterised in that in step D, the semi-finished product capsule of balance is in temperature
10~40 DEG C with relative humidity 20~70% under conditions of carry out screening and selected with lamp.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811493300.2A CN109393555B (en) | 2018-12-07 | 2018-12-07 | Preparation method of cigarette capsule with processing resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811493300.2A CN109393555B (en) | 2018-12-07 | 2018-12-07 | Preparation method of cigarette capsule with processing resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109393555A true CN109393555A (en) | 2019-03-01 |
| CN109393555B CN109393555B (en) | 2021-03-26 |
Family
ID=65457741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811493300.2A Active CN109393555B (en) | 2018-12-07 | 2018-12-07 | Preparation method of cigarette capsule with processing resistance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109393555B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396225A (en) * | 2019-08-06 | 2019-11-01 | 河南金瑞香精香料有限公司 | A kind of quick-fried pearl wall material and preparation method thereof and dripping pill method |
| CN110560418A (en) * | 2019-09-25 | 2019-12-13 | 云南南中科技有限公司 | Wet capsule pill washing machine for cigarettes |
| CN110859320A (en) * | 2019-10-11 | 2020-03-06 | 国药控股星鲨制药（厦门）有限公司 | Plant brittle capsule for cigarettes and preparation method thereof |
| CN110897195A (en) * | 2019-12-23 | 2020-03-24 | 安徽中烟工业有限责任公司 | Cigarette capsule wall material capable of wrapping low-boiling-point essence and cigarette capsule based on same |
| CN111019158A (en) * | 2019-12-11 | 2020-04-17 | 山东将军烟草新材料科技有限公司 | Solid water and preparation method and application thereof |
| CN111393781A (en) * | 2020-05-12 | 2020-07-10 | 武汉市昱宸峰科技有限公司 | Water-based bead blasting wall material for cigarettes and preparation method thereof |
| CN111632560A (en) * | 2020-05-08 | 2020-09-08 | 云南巴菰生物科技有限公司 | Preparation method of crystal ball particles capable of continuously releasing fragrance |
| CN112574475A (en) * | 2020-12-22 | 2021-03-30 | 武汉市昱宸峰科技有限公司 | Brittle wall material for cigarette blasting bead |
| CN113046034A (en) * | 2021-04-01 | 2021-06-29 | 云南巴菰生物科技有限公司 | Phase-change cooling material for heating non-combustible cigarettes and preparation method thereof |
| CN113475752A (en) * | 2021-06-30 | 2021-10-08 | 河南中烟工业有限责任公司 | Noctilucent bead blasting wall material, noctilucent cigarette bead blasting and preparation method thereof, and bead blasting cigarette |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101766332A (en) * | 2009-12-31 | 2010-07-07 | 云南烟草科学研究院 | Pills capable of adding fragrance to cigarettes |
| CN102824887A (en) * | 2012-09-14 | 2012-12-19 | 云南烟草科学研究院 | Preparation method of controlled-release soft capsules for cigarettes |
| CN102977412A (en) * | 2011-09-02 | 2013-03-20 | 湖北工业大学 | Finger extrusion-frangible soft capsule and its preparation method and use |
| WO2015101511A1 (en) * | 2013-12-31 | 2015-07-09 | Philip Morris Products S.A. | Smoking article with liquid release component |
| CN105400215A (en) * | 2015-12-14 | 2016-03-16 | 贵州中烟工业有限责任公司 | Heatproof and moisture-proof cigarette capsule material and applications thereof |
| CN106497088A (en) * | 2016-12-07 | 2017-03-15 | 湖北中烟工业有限责任公司 | A kind of high-weatherability cigarette quick-fried pearl rubber material and preparation method thereof |
| WO2017218110A1 (en) * | 2016-06-16 | 2017-12-21 | Altria Client Services Llc | Breakable capsules and methods of forming thereof |
-
2018
- 2018-12-07 CN CN201811493300.2A patent/CN109393555B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101766332A (en) * | 2009-12-31 | 2010-07-07 | 云南烟草科学研究院 | Pills capable of adding fragrance to cigarettes |
| CN102977412A (en) * | 2011-09-02 | 2013-03-20 | 湖北工业大学 | Finger extrusion-frangible soft capsule and its preparation method and use |
| CN102824887A (en) * | 2012-09-14 | 2012-12-19 | 云南烟草科学研究院 | Preparation method of controlled-release soft capsules for cigarettes |
| WO2015101511A1 (en) * | 2013-12-31 | 2015-07-09 | Philip Morris Products S.A. | Smoking article with liquid release component |
| CN105400215A (en) * | 2015-12-14 | 2016-03-16 | 贵州中烟工业有限责任公司 | Heatproof and moisture-proof cigarette capsule material and applications thereof |
| WO2017218110A1 (en) * | 2016-06-16 | 2017-12-21 | Altria Client Services Llc | Breakable capsules and methods of forming thereof |
| CN106497088A (en) * | 2016-12-07 | 2017-03-15 | 湖北中烟工业有限责任公司 | A kind of high-weatherability cigarette quick-fried pearl rubber material and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396225A (en) * | 2019-08-06 | 2019-11-01 | 河南金瑞香精香料有限公司 | A kind of quick-fried pearl wall material and preparation method thereof and dripping pill method |
| CN110560418A (en) * | 2019-09-25 | 2019-12-13 | 云南南中科技有限公司 | Wet capsule pill washing machine for cigarettes |
| CN110859320A (en) * | 2019-10-11 | 2020-03-06 | 国药控股星鲨制药（厦门）有限公司 | Plant brittle capsule for cigarettes and preparation method thereof |
| CN111019158A (en) * | 2019-12-11 | 2020-04-17 | 山东将军烟草新材料科技有限公司 | Solid water and preparation method and application thereof |
| CN110897195A (en) * | 2019-12-23 | 2020-03-24 | 安徽中烟工业有限责任公司 | Cigarette capsule wall material capable of wrapping low-boiling-point essence and cigarette capsule based on same |
| CN111632560A (en) * | 2020-05-08 | 2020-09-08 | 云南巴菰生物科技有限公司 | Preparation method of crystal ball particles capable of continuously releasing fragrance |
| CN111393781A (en) * | 2020-05-12 | 2020-07-10 | 武汉市昱宸峰科技有限公司 | Water-based bead blasting wall material for cigarettes and preparation method thereof |
| CN112574475A (en) * | 2020-12-22 | 2021-03-30 | 武汉市昱宸峰科技有限公司 | Brittle wall material for cigarette blasting bead |
| CN113046034A (en) * | 2021-04-01 | 2021-06-29 | 云南巴菰生物科技有限公司 | Phase-change cooling material for heating non-combustible cigarettes and preparation method thereof |
| CN113475752A (en) * | 2021-06-30 | 2021-10-08 | 河南中烟工业有限责任公司 | Noctilucent bead blasting wall material, noctilucent cigarette bead blasting and preparation method thereof, and bead blasting cigarette |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109393555B (en) | 2021-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109393555A (en) | A kind of preparation method of the cigarette capsule with degrading resistance property | |
| CN105400215B (en) | Temperature-resistant and moisture-resistant capsule material for cigarettes and application thereof | |
| JP5860480B2 (en) | New hard capsule containing pullulan | |
| CN104726199B (en) | Water-bearing capsule and preparation method thereof | |
| CN104886554B (en) | Quick-fried pearl soft capsule and preparation method thereof | |
| US6887307B1 (en) | Pullulan film compositions | |
| CA2272633C (en) | Polymer film compositions for capsules | |
| US3539380A (en) | Methylcellulose and polyalkylene glycol coating of solid medicinal dosage forms | |
| CN104666275B (en) | Starch-based plant empty capsule | |
| CN109480329A (en) | A kind of emulsion process prepares the cigarette method of quick-fried pearl | |
| CN105380924B (en) | A kind of chitosan oligosaccharide capsule agent and preparation method thereof | |
| FR2562899A1 (en) | MOLDED ARTICLE WITH PROGRESSIVE DISINTEGRATION | |
| CN105051129A (en) | Film-forming compostions for the film-coating of solid forms | |
| CN110283661A (en) | A kind of quick-fried pearl of cigarette gel and preparation method thereof | |
| CN104840447A (en) | Preparation method of pulullan vacant capsules | |
| CN107616546A (en) | The preparation method of the quick-fried pearl lapping of cigarette | |
| CN105540073A (en) | Brittle capsule for cigarettes and preparation method thereof | |
| CN108721632A (en) | A kind of high molecular weight pullulan additive and its application in capsule preparation | |
| CN105985449B (en) | A kind of modified hydroxypropul starch and preparation method thereof, a kind of plant hollow capsule and preparation method thereof | |
| CN104784148B (en) | A kind of film-forming composition for preparing plant capsule and preparation method thereof | |
| CN107456581A (en) | A kind of selenium-rich rice Selenium in Plants protein capsule material and preparation method thereof | |
| CN111454490B (en) | Composition for preparing edible plant plasma membrane and application thereof | |
| CN106519310A (en) | Cigarette bursting bead noctilucence coating film material, and production method of cigarette bursting bead | |
| CN111280479A (en) | Preparation method of blasting beads for improving cigarette blasting bead loading by aid of auxiliary agents | |
| CN104800189A (en) | Starch plant hollow capsule |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20210210 Address after: Room 501-513, 502-526, 5 / F, building 2, Yunnan returnees Pioneer Park, 80 chunman Avenue, information industry base, Kunming Economic and Technological Development Zone, Kunming, Yunnan 650220 Applicant after: YUNNAN BAGU BIOTECHNOLOGY Co.,Ltd. Applicant after: Yunnan Nanzhong Technology Co.,Ltd. Address before: Room 501-513 502-526, 5th floor, building 2, Yunnan returnees Pioneer Park, 80 chunman Avenue, information industry base, Kunming Economic and Technological Development Zone, Kunming, Yunnan 650220 Applicant before: YUNNAN BAGU BIOTECHNOLOGY Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 650220 floor 5, building 2, Yunnan returnees Pioneer Park, No. 80, chunman Avenue, Luoyang sub district office, Kunming area, China (Yunnan) pilot Free Trade Zone, Kunming, Yunnan Patentee after: Yunnan Bazi Biotechnology Co.,Ltd. Patentee after: Yunnan Nanzhong Technology Co.,Ltd. Address before: Room 501-513, 502-526, 5 / F, building 2, Yunnan returnees Pioneer Park, 80 chunman Avenue, information industry base, Kunming Economic and Technological Development Zone, Kunming, Yunnan 650220 Patentee before: YUNNAN BAGU BIOTECHNOLOGY Co.,Ltd. Patentee before: Yunnan Nanzhong Technology Co.,Ltd. |