CN109370405A - A kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene and preparation method - Google Patents
A kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene and preparation method Download PDFInfo
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- CN109370405A CN109370405A CN201811291260.3A CN201811291260A CN109370405A CN 109370405 A CN109370405 A CN 109370405A CN 201811291260 A CN201811291260 A CN 201811291260A CN 109370405 A CN109370405 A CN 109370405A
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- woodcare paint
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- net aldehyde
- children furniture
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to woodcare paint technical field, a kind of clear taste of children furniture is refered in particular to without the net aldehyde woodcare paint of benzene, which is characterized in that be made of following raw material in parts by weight: 8-15 parts of deionization；0.1-0.3 parts of defoaming agent；0.3-1 parts of wetting agent；0.3-1 parts of dispersing agent；10-20 parts of titanium dioxide；50-70 parts of high-performance plant base resin；0.3-1 parts of thickener；0.2-1 parts of aloe antibiotic fungicide；0.6 part of cosolvent；0.3-0.6 parts of organosilicon levelling agent.The present invention selects aqueous high-performance plant base resin simultaneously to combine natural plants aloe antibiotic fungicide Successful utilization: both met it is not amine-containing can achieve the discharge of low or even zero smell, and it is very suitable for requirement of the ecological mark such as AgBB in the Europe required to coating and Northern Europe to indoor air quality.The smooth exquisiteness of paint film hand feel, high rigidity, anti-pollution effect, flexibility is good, the excellent performance of water-fast, weatherability and good permeability, and has the function of antibacterial, air cleaning and decomposing formaldehyde, organic volatile.
Description
Technical field
The present invention relates to woodcare paint technical field, a kind of clear taste of children furniture is refered in particular to without the net aldehyde woodcare paint of benzene and preparation side
Method.
Background technique
Cherishing environment has no longer been dispensable additional selection, but a kind of imperative responsibility, Global Temperature
The shortage etc. for problem, the resource of warming, environmental pollution Under the Dome, the harmful chemical volatilization under roof seriously threaten
The life security of the mankind.It is reported that the whole world has people up to a million directly or indirectly to die of pollution from coatings, correlation study data every year
It has been shown that, pollution from coatings is even more startling to the harm of children, and in China leukaemic, 90% infant family is in half a year
Interior decoration mistake, then, how does this really prevent finishing pollution from source? how the finishing neurosis of people is eliminated? how to beat
The healthy home environment of manufacturing green environmental protection? continuous concern with people to own health, household environment-friendlywater are also more weighed
Depending on coating wood furniture uses the paint compared with " environmental protection " type, but there is also the nocuousness such as contained benzene, dimethylbenzene, TDI in paint
Substance can cause serious injury to human body, for the angle of environmentally-friendly coating, if paint selection is improper, will necessarily just pollute room
Interior environment, or even be detrimental to health, the various organic solvents such as benzene kind solvent from coating is true by the World Health Organization
It is set to carcinogen, big people suck the toluene of high concentration in a short time, dimethylbenzene will appear central nervous system anesthesia
Symptom, less serious case is dizzy, headache, nausea is out of strength, clouding of consciousness, and serious person goes into a coma.But coating is using being partially turned on " environmental protection "
Banner poor quality coating, contacts for a long time and sucks although toluene, dimethylbenzene, VOC content are reduced, be detrimental to health
Also very important.Especially children compare that adult's immunity is worse, therefore children are more vulnerable to the injury of paint inferior.
It is reported that the domestic furniture for meeting national environmental standard on the market at present, does not imply that without hazardous substance, but
Hazardous substance content is lower, apparent harm will not be generated to human body, but these standards are come according to adult endurance
It formulates, it is all GB18582-2008 " indoor decorating that children furniture paint, common wealth furniture paint limits of harmful substances, which execute standard,
Limits of harmful substances in material solvent type woodwork coating ".This special group for children, family that more should be more environmentally friendly
Tool.
There are more stringent examination criteria, and these examination criterias in the developed countries and regions children furniture such as America and Europe
It is different from adult furniture, the examination criteria of European Union's toy for children is also met while meeting European Union's furniture, uses toy
Examination criteria come detect furniture be to the most harsh test of furniture environmental protection, such as Chinese exports toys standard have U.S.'s CSC regulation plus
It puts on airs " dangerous products bill ", " GB24613-2009 is played to have and be applied for European Union's toy safety instruction 2009/48/EC standard and national standard
Limit of harmful substance in material " to show.
Summary of the invention
In view of the above problems, the present invention provides a kind of clear tastes of children furniture without the net aldehyde woodcare paint of benzene, both solved existing
Water paint is protected on plate outside its physical property of ornament materials, in the aqueous woodware paint construction of the invention and product use process
Have amine-containing, can achieve the discharge of low or even zero smell, close to naturally pure and fresh smell.Have again and relatively efficiently carries antibacterial, air by force
The function anti-pollution of the organic solvents such as purification, decomposing formaldehyde acts on.
To achieve the goals above, the technical solution that the present invention applies is as follows:
A kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene, which is characterized in that is made of following raw material in parts by weight:
Furthermore, the defoaming agent is waterborne organic silicon defoaming agent.
Furthermore, the wetting agent is aqueous foam inhibition wetting agent.
Furthermore, the water-fast dispersing agent is aqueous high molecular dispersing agent.
Furthermore, the titanium dioxide is red metal and stone titanium dioxide.
Furthermore, the high-performance plant base resin aliphatic polyurethane dispersion tree fatty acid modified for no amine
Rouge.
Furthermore, the thickener is aqueous polyurethane thickener.
Furthermore, the aloe antibiotic fungicide is aloe antibiotic bactericide.
Furthermore, the organosilicon levelling agent is waterborne organic silicon levelling agent.
A kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene, and preparation method includes the following steps:
A. it sequentially adds deionized water by weight percentage in clean container and is dispersed with stirring；
B. dispersing agent, wetting agent, defoaming agent, titanium dioxide are sequentially added, and with 800-1200 revs/min of high speed dispersion of revolving speed
20-30 minutes (to fineness qualification)；
C. 600-800 revs/min of revolving speed is reduced, high-performance plant base resin, cosolvent, aloe antibiotic sterilization are sequentially added
Agent, thickener, organosilicon levelling agent are simultaneously dispersed 20-30 minutes；
D. be adjusted to viscosity be 70-80KU/25 DEG C be it is qualified, obtain mixed liquor and stir evenly up to woodcare paint.
The invention has the advantages that:
1. a kind of clear taste of children furniture of the present invention high, soft and smooth exquisiteness of sense of touch without the net aldehyde woodcare paint environmental protection of benzene belongs to
In aqueous functional wood furniture decorative product, any harmful substance composition is not contained, environmental requirement is complied fully with, especially pair
Body limits of harmful substances complies fully with national standard HJ2537-2014 to VOC, benzene class, heavy metal, halogenated hydrocarbons, glycol ether and ester
The requirement of class, and rower GB/T23999-2009 physical property Testing index requirement can be reached, antimildew and antibacterial effect is good, feel
It is super it is soft and fine it is greasy, adhesion strength is excellent, be very suitable to the water paint of indoor and children furniture decoration coating；
2. both having solved existing water paint to protect on plate outside its physical property of ornament materials, be free of in the construction process
Amine can achieve the discharge of low or even zero smell again and have to plate taste removal, carry antibacterial, air cleaning, with decomposing formaldehyde, have
The function of machine volatile matter, while hardness of paint film is up to H or so, smooth fine and smooth, efficiently anti-stick, the anti-pollution effect of feel.
Specific embodiment
In conjunction with following specific embodiments, the invention will be further described.
Raw material:
The clear taste of a kind of children furniture of the present invention is without the net aldehyde woodcare paint of benzene, which is characterized in that in parts by weight by following
Raw material composition:
More specifically, the defoaming agent is waterborne organic silicon defoaming agent.In practical application, of the present invention aqueous have
Machine silicon defoaming agent preferably uses organic defoaming agent FOAMEX8422 of Dongguan Zhan Lin chemical company.
More specifically, the wetting agent is aqueous foam inhibition wetting agent.In practical application, aqueous foam inhibition of the present invention
Wetting agent preferably uses the 104PG-50 of pottery formula chemical (former U.S.'s gas).
More specifically, the water-fast dispersing agent is aqueous high molecular dispersing agent.In practical application, water of the present invention
Property macromolecule dispersing agent preferably uses the dispers-755 of Dongguan Zhan Lin chemical company.
More specifically, the titanium dioxide is red metal and stone titanium dioxide.In practical application, red metal and stone titanium white of the present invention
Powder preferably uses the TRONOX CR-826 of import, is easily dispersed, and anti-yellowing property is excellent.
More specifically, the high-performance plant base resin aliphatic polyurethane dispersion tree fatty acid modified for no amine
Rouge.In practical application, the fatty acid modified aliphatic polyurethane resin dispersion of no amine of the present invention is preferably used
NeoPacTMPU-580XP, it is not amine-containing to can achieve the discharge of low or even zero smell, and it is very suitable for requiring coating
Europe and Northern Europe requirement of the ecological mark such as AgBB to indoor air quality, with excellent efficient anti-stick, anti-pollution
Effect, flexibility is good, water-fast, weatherability and good permeability excellent performance.
More specifically, the thickener is aqueous polyurethane thickener.It is of the invention described aqueous in practical application
Polyurethane thickener preferably uses COAPUR XS-71.
More specifically, the aloe antibiotic fungicide is aloe antibiotic bactericide.In practical application, institute of the present invention
The aloe antibiotic bactericide stated refines the included worm of dispelling of sperm, antibacterial, air cleaning for the fermentation of aloe skin slag and has decomposition
Formaldehyde, organic volatile function.
More specifically, the organosilicon levelling agent is waterborne organic silicon levelling agent.It is of the present invention in practical application
Waterborne organic silicon levelling agent preferably uses the GLIDE-482 of Dongguan Zhan Lin chemical company, existing to help wet film levelling again
Dry film resistance to marring and smooth handling property can be promoted.
More specifically, cosolvent of the present invention preferably use the DPM of DOW company and DPnB one such or
The intermixture that person DPM and DPnB is mixed with 1:2.
Preparation method:
A kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene, and preparation method includes the following steps:
A. it sequentially adds deionized water by weight percentage in clean container and is dispersed with stirring；
B. dispersing agent, wetting agent, defoaming agent, titanium dioxide are sequentially added, and with 800-1200 revs/min of high speed dispersion of revolving speed
20-30 minutes (to fineness qualification)；
C. 600-800 revs/min of revolving speed is reduced, high-performance plant base resin, cosolvent, aloe antibiotic sterilization are sequentially added
Agent, thickener, organosilicon levelling agent are simultaneously dispersed 20-30 minutes；
D. be adjusted to viscosity be 70-80KU/25 DEG C be it is qualified, obtain mixed liquor and stir evenly up to woodcare paint.
Test formulations (as shown in Table 1):
Testing procedure:
1) various kinds paint product are prepared by formula described in table one；
2) method for referring to GB/T23986-2009, in different ground making sheet；
3) test method:
3.1) volatile organic compounds (VOC) is measured with reference to the method for GB/T23986-2009；
3.2) handle effect is detected by the way of expert opinion, evaluation method are as follows: 5. is very good；4. preferably；3.
It is good；2. general；1. poor；
3.3) hardness is detected with reference to the method for GB/T6739-2006；
3.4) scoring resistance is measured with reference to the method for GB/T9279；
3.5) stain resistance is measured with reference to the method for GB/T4893.1-2005, evaluation method are as follows: 5. is very good；4.
Preferably；3. good；2. general；1. poor；
3.6) method of the formaldehyde reference standard GB/T16129-1995 in air is measured；
3.7) boiling water resistance is measured with reference to the method for national standard GB/T4893.1-2005；
3.8) odor gradings painted use three kinds of situation (a. sample oil can opening smells；B. work progress Interior Space smell；C. sample
Smell under plate the same terms to dry 24 hours sealing dry plates), the mode of control methods expert opinion is detected, evaluation method
Are as follows: 5. is very good；4. preferably；3. good；2. general；1. poor；0. is very poor；
3.9) the clear taste of children furniture for preparing embodiment 1-3 in table one is without the net aldehyde woodcare paint of benzene according to HJ2537-2014
Benzene homologues content is carried out in national standard to be measured；
3.10) measurement of the content of benzene,toluene,xylene, ethylbenzene method with reference to as defined in GB 18582-2008 is surveyed
It is fixed；
3.11) soluble heavy metal is measured by the method for EN71-3 (2009/48/EC toy new command).
Experimental result (as shown in Table 2):
As shown in Table 2, the clear taste of aqueous children furniture prepared using 1-3 of the embodiment of the present invention is without the net aldehyde woodcare paint system of benzene
Paint film it is smooth, without particle, bubble, floating and construction trace, adhesive force is strong, and hardness is high, and the volatility of the paint film has
Machine compound (VOC) content is well below 70g/L as defined in HJ 2537-2104 (national standard), and wherein embodiment 3 is prepared
Volatile organic compounds (VOC) content of paint film is 8.8g/L, and feel is splendid, and hardness is implemented up to H for the present invention is best
Example.And use VOC, the air of comparative example 1-4 paint of the clear taste of aqueous children furniture without the net aldehyde woodcare paint preparation of benzene being prepared
In formaldehyde 48h, hardness, feel, resistance to soiling than the embodiment of the present invention 1-3 preparation paint film it is poor, it is therefore, provided by the invention
Formula arch of the clear taste of children furniture without the net aldehyde woodcare paint of benzene plays with reasonable, science and improves the clear taste of children furniture without the net aldehyde wood of benzene
The performance of the hardness of device paint, feel, scratch resistant, antifouling, anti-figure crow etc., while can effectively low or even zero smell row indoors
It puts VOC and has the function of air cleaning, decomposing formaldehyde, organic compound.
Embodiment 1-3, comparative example 1-4 are prepared into the clear taste of children furniture and prepare lacquering according to spray coating method without the net aldehyde woodcare paint of benzene
Film carries out resistance to boiling water to paint film and construction each stage carries out smell comparative determination, evaluation method are as follows: 5. is very good；4. preferably；3.
It is good；2. general；1. poor；0. is very poor (as shown in Table 3):
The clear taste of children furniture provided by the invention is without the net aldehyde woodenware paint formula arch of benzene with reasonable, science, each ingredient phase interaction
With feel, hardness and the pollution resistance for playing enhancing aqueous woodware paint paint film, keep appearance it is smooth, without particle, bubble, floating and construction
Trace, but also there is construction and when use effectively to control indoor formaldehyde, effectively low in volatile organic compounds room or even zero
Smell discharge VOC and have the function of air cleaning, decomposing formaldehyde, organic volatile, low excellent of soluble heavy metal content
Point, be it is a kind of have excellent performance, health, environmental protection the clear taste of the dedicated children furniture of children furniture without the net aldehyde woodcare paint of benzene.
The present invention selects aqueous high-performance plant base resin and combines natural plants aloe antibiotic fungicide Successful utilization: both
Meet it is not amine-containing can achieve the discharge of low or even zero smell, and it is very suitable for the Europe required to coating and Northern Europe
Requirement of the ecological mark such as AgBB to indoor air quality.The smooth exquisiteness of paint film hand feel, high rigidity, anti-pollution effect, flexibility
The excellent performance of good, water-fast, weatherability and good permeability, and with antibacterial, air cleaning and decomposing formaldehyde, organic volatile
Function.
The above technical solution in the embodiment of the present invention is described, but the invention is not limited to above-mentioned specific
Embodiment, the above mentioned embodiment is only schematical, rather than restrictive, those skilled in the art
Under the inspiration of the present invention, without breaking away from the scope protected by the purposes and claims of the present invention, it can also make very much
Form, these are all belonged to the scope of protection of the present invention.
Claims (10)
1. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene, which is characterized in that be made of following raw material in parts by weight:
2. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene according to claim 1, which is characterized in that the defoaming agent is
Waterborne organic silicon defoaming agent.
3. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene according to claim 1, which is characterized in that the wetting agent is
Aqueous foam inhibition wetting agent.
4. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene according to claim 1, which is characterized in that the water-fast dispersion
Agent is aqueous high molecular dispersing agent.
5. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene according to claim 1, which is characterized in that the titanium dioxide is
Red metal and stone titanium dioxide.
6. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene according to claim 1, which is characterized in that the high-performance is planted
The object base resin aliphatic polyurethane resin dispersion fatty acid modified for no amine.
7. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene according to claim 1, which is characterized in that the thickener is
Aqueous polyurethane thickener.
8. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene according to claim 1, which is characterized in that the aloe antibiotic
Fungicide is aloe antibiotic bactericide.
9. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene according to claim 1, which is characterized in that the organosilicon stream
Flat agent is waterborne organic silicon levelling agent.
10. a kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene according to claim 1, which is characterized in that preparation method
The following steps are included:
A. it sequentially adds deionized water by weight percentage in clean container and is dispersed with stirring；
B. dispersing agent, wetting agent, defoaming agent, titanium dioxide are sequentially added, and with 800-1200 revs/min of revolving speed of high speed dispersion 20-
30 minutes (to fineness qualification)；
C. 600-800 revs/min of revolving speed is reduced, high-performance plant base resin is sequentially added, cosolvent, aloe antibiotic fungicide, increases
Thick dose, organosilicon levelling agent and disperse 20-30 minutes；
D. be adjusted to viscosity be 70-80KU/25 DEG C be it is qualified, obtain mixed liquor and stir evenly up to woodcare paint.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811291260.3A CN109370405A (en) | 2018-10-31 | 2018-10-31 | A kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811291260.3A CN109370405A (en) | 2018-10-31 | 2018-10-31 | A kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene and preparation method |
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|---|---|
| CN109370405A true CN109370405A (en) | 2019-02-22 |
Family
ID=65396765
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| CN201811291260.3A Pending CN109370405A (en) | 2018-10-31 | 2018-10-31 | A kind of clear taste of children furniture is without the net aldehyde woodcare paint of benzene and preparation method |
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Cited By (1)
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| CN115109490A (en) * | 2022-08-11 | 2022-09-27 | 中山永辉化工股份有限公司 | Environment-friendly coating for toy and preparation method thereof |
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| CN115109490A (en) * | 2022-08-11 | 2022-09-27 | 中山永辉化工股份有限公司 | Environment-friendly coating for toy and preparation method thereof |
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