CN111057426A - Water-based transparent top coating and preparation method thereof - Google Patents
Water-based transparent top coating and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to the technical field of coatings, and particularly relates to a water-based transparent top coating and a preparation method thereof. The water-based transparent finish coating comprises the following components in percentage by mass: 2-3% of a formaldehyde scavenger; 3-5% of plant extract; 50-60% of acrylic emulsion; 1-3% of a defoaming agent; 0.1-0.3% of wetting agent; 1-2% of matte powder; 0.2-0.5% of a leveling agent; 2.5-3% of a film-forming assistant; 1-2% of propylene glycol; 1-1.5% of a thickening agent; 0.1-0.2% of a bactericide; 0.5-1.5% of aqueous wax dispersoid; 30-40% of water. The water-based transparent finish coat paint has good air purification and bacteria breeding inhibition effects, and also has excellent water resistance, scrub resistance, stain resistance, transparency, high hardness and anti-after-tack effects, so that the water-based transparent finish coat paint can be used for finish coat protection of various wall decoration materials such as emulsion paint on the inner wall of a building, diatom ooze paint, plates and the like.
Description
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a water-based transparent top coating and a preparation method thereof.
Background
Economic development promotes the improvement of environmental awareness of people, and environmental quality problems are widely concerned by people. Consumers use a large amount of decoration materials to improve life quality, and simultaneously cause continuous deterioration of indoor air quality, and the harm to human bodies, especially the harm to old people, children and pregnant women with poor resistance becomes a hot problem of concern. Formaldehyde has great influence on human health, has strong stimulation effect on human mucous membrane and skin, and can cause severe respiratory tract stimulation and edema when inhaled at high concentration, thereby causing eye irritation and headache; inhalation at low concentrations can lead to persistent headaches, weakness, insomnia, etc.; chronic exposure can cause dermatitis, abnormal lung, liver function and immune function, the central nervous system is also affected, and genetic materials in cells can be damaged, so that the liver and the immune function are suspicious carcinogens. Therefore, the development of healthy wall coatings capable of removing harmful gases such as formaldehyde, ammonia, benzene and the like and purifying air is one direction of interior wall coatings.
Indoor decoration innocent treatment (formaldehyde removal) means that pollutants such as formaldehyde, benzene and the like are decomposed into carbon dioxide and water at normal temperature through a series of measures, no secondary pollution is caused, and finally the pollutants are released into the air in a molecular state. At present, the interior wall high-grade decoration formaldehyde-removing paint mainly comprises various active carbon or bamboo charcoal and negative ion photocatalyst emulsion paint, diatom ooze paint and artistic texture paint. The diatom ooze coating, the liquid formaldehyde catching agent and the activated carbon coating remove formaldehyde mainly by utilizing the pure physical adsorption effect of activated carbon, have short effective adsorption time (about 8 hours) and small absorption capacity, and are difficult to quickly and efficiently remove harmful gases such as formaldehyde, ammonia, benzene and the like; the release concentration and durability of the negative ion photocatalyst coating are unstable, and the photocatalyst can remove formaldehyde and purify air only by being irradiated by a stable light source. Therefore, the traditional formaldehyde-removing coating has the defects of unobvious effect or single function, and is difficult to meet the increasing pursuit of the market on the healthy and environment-friendly environment.
Therefore, the prior art is in need of improvement.
Disclosure of Invention
The invention aims to overcome the defects in the prior art, provides a water-based transparent finish coating and a preparation method thereof, and aims to solve the technical problems of low formaldehyde removal adsorption efficiency and single function of the existing finish coating.
In order to achieve the purpose, the invention adopts the following technical scheme:
the invention provides a water-based transparent top-coat paint which comprises the following components in percentage by mass based on 100% of the total mass of the water-based transparent top-coat paint:
2-3% of a formaldehyde scavenger;
3-5% of plant extract;
50-60% of acrylic emulsion;
1-3% of a defoaming agent;
0.1-0.3% of wetting agent;
1-2% of matte powder;
0.2-0.5% of a leveling agent;
1.5-3% of a film-forming assistant;
1-2% of propylene glycol;
1-1.5% of a thickening agent;
0.1-0.2% of a bactericide;
0.5-1.5% of aqueous wax dispersoid;
18-40% of water.
The invention provides a novel multifunctional water-based transparent top-coat paint, which combines two components with formaldehyde removal functions, namely a formaldehyde catching agent and a plant extract, and can decompose and remove free formaldehyde, ammonia, benzene and other harmful gases in the air, remove various indoor peculiar smells and purify the indoor air; meanwhile, bacteria and viruses in the wall surface and the indoor air can be efficiently removed, the air in a room is far away from pollution, and the air is fresh and pleasant, so that the air quality like a park and a forest is built; in addition, the water-based transparent finish coating has good processing performance and is easy to construct by other additive components. The components of the water-based transparent finish coating act together, so that the water-based transparent finish coating has good air purification and bacteria breeding inhibition effects when being used for interior decoration, and has excellent water resistance, scrub resistance, stain resistance, transparency, high hardness and anti-after-tack effects, thereby being used for finish protection of various wall decoration materials such as emulsion paint, diatom ooze coating, plates and the like on the inner wall of a building.
In another aspect, the present invention provides a method for preparing a water-based transparent top coating, comprising the steps of:
weighing raw materials of the components according to the components and the content of the components contained in the water-based transparent top-coat paint;
carrying out first mixing treatment on the water, the wetting agent, the defoaming agent and the propylene glycol to obtain a first mixed material;
and adding the rest components into the first mixed material, and carrying out second mixed material treatment to obtain the water-based transparent top-coat coating.
The preparation method of the water-based transparent finish coating provided by the invention has the advantages of simple process, easily controlled conditions and high efficiency, the water-based transparent finish coating obtained by the preparation method can effectively improve the capability of removing harmful gases such as formaldehyde, ammonia, benzene and the like, has excellent water resistance, scrub resistance, stain resistance, transparency, high hardness and anti-sticking effect, and can be used for finish protection of various wall decoration materials such as emulsion paint on the inner wall of a building, diatom ooze coating, plates and the like.
Drawings
FIG. 1 is a schematic representation of the effect of a waterborne clear top coat provided in example 1 of the present invention;
FIG. 2 is a schematic representation of the effect of a waterborne clear top coat provided in example 2 of the present invention;
FIG. 3 is a schematic representation of the effect of a waterborne clear top coat provided in example 3 of the present invention;
FIG. 4 is a schematic representation of the effect of the waterborne clear top coat provided in example 4 of the present invention.
Detailed Description
In order to make the technical problems, technical solutions and advantageous effects to be solved by the present invention more clearly apparent, the present invention is further described in detail below with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
On one hand, the embodiment of the invention provides a water-based transparent finish coating, which comprises the following components in percentage by mass based on 100% of the total mass of the water-based transparent finish coating:
2-3% of a formaldehyde scavenger;
3-5% of plant extract;
50-60% of acrylic emulsion;
1-3% of a defoaming agent;
0.1-0.3% of wetting agent;
1-2% of matte powder;
0.2-0.5% of a leveling agent;
1.5-3% of a film-forming assistant;
1-2% of propylene glycol;
1-1.5% of a thickening agent;
0.1-0.2% of a bactericide;
0.5-1.5% of aqueous wax dispersoid;
18-40% of water.
The embodiment of the invention provides a novel multifunctional water-based transparent top-coat paint, which combines two components with formaldehyde removal functions, namely a formaldehyde scavenger and a plant extract, and can decompose and remove free formaldehyde, ammonia, benzene and other harmful gases in the air, remove various indoor peculiar smells and purify indoor air; meanwhile, bacteria and viruses in the wall surface and the indoor air can be efficiently removed, the air in a room is far away from pollution, and the air is fresh and pleasant, so that the air quality like a park and a forest is built; in addition, the water-based transparent finish coating has good processing performance and is easy to construct by other additive components. The components of the water-based transparent finish coating are combined according to different proportions, and the components act together, so that the water-based transparent finish coating has good effects of purifying air and inhibiting bacteria growth in interior decoration, and has excellent water resistance, scrubbing resistance, stain resistance, transparency, high hardness and anti-after-tack effects, and therefore, the water-based transparent finish coating can be used for finish protection of various wall decoration materials such as emulsion paint on interior walls of buildings, diatom ooze coating, plates and the like.
The water-based transparent top-coat paint provided by the embodiment of the invention belongs to a green and environment-friendly product, has good construction property, strong adaptability, stronger adhesive force, excellent water resistance and scrub resistance, is a novel water-based transparent top-coat paint with multiple functions of removing formaldehyde and the like, is mainly used for top coats of interior wall paints and decoration base planes, improves scrub resistance and stain resistance of the interior wall paints, simultaneously endows the common interior wall paints with functions of removing formaldehyde, sterilizing, deodorizing and the like, also can enable the current popular artistic paint to have more three-dimensional artistic feeling, meets the requirement of pursuing health and environmental protection in the market, and is a development trend of new generation of indoor high-grade decoration.
The components of the above-described aqueous clear top coating may be commercially available or self-made.
Specifically, in the embodiment of the invention, the mass percentage of the formaldehyde scavenger in the water-based transparent finish coating can be selected from 2%, 2.5%, 3% and the like. The formaldehyde scavenger preferred in this example is an aqueous urea-based modified compound (obtained by cyclizing ammonia gas released by the reaction of urea and ethylenediamine), that is, a compound quantitatively synthesized by cyclizing urea and ethylenediamine with ammonia gas released by heating at room temperature and under high pressure, and specifically, it can be obtained by reacting urea and ethylenediamine at a molar ratio of 1: 1. The formaldehyde scavenger is low-odor and nontoxic harmful substance, is safe and efficient, and is an ideal material for removing formaldehyde of a new generation. In this embodiment, the formaldehyde scavenger can covalently bond with free formaldehyde molecules to form stable, harmless and nonvolatile molecules, thereby eliminating the free formaldehyde molecules escaping from the paint or air and completely eliminating formaldehyde pollution. Within the mass percentage content range of the formaldehyde scavenger provided by the embodiment of the invention, the formaldehyde removing effect of the water-based transparent finish coating can reach the optimal effect.
Specifically, in the embodiment of the invention, the mass percentage of the plant extract in the water-based transparent finishing coating can be selected from 3%, 4%, 5% and the like. The preferable plant extract is obtained by fermenting and extracting clover, kurarinone and kurarinone as raw materials. The method comprises the steps of taking clover, kurarinone and kurarinone plants as raw materials, mixing the plant raw materials according to a certain proportion (specifically, the mass ratio of the three plant raw materials can be 1:1:1), crushing and grinding the plant raw materials to obtain powder, taking a part of the powder (such as half of the powder) to perform purification procedures of soaking, heating, cooling and filtering in a heating container to obtain an extracting solution, adding nutrient solution into the other half of the powder in a fermentation container to ferment at a certain temperature to prepare enzyme, and mixing the extracting solution and the enzyme according to a certain proportion (specifically, the mass ratio can be 1:1) to obtain a plant extract. In the plant extract, flavonoid molecules, alcohols and other substances can be extracted from the kurarinone, plant polyesters and other substances can be extracted from the kurarinone, amino acids, tannins, plant volatile oil and other substances can be extracted from the clover, and the substances have good neutralizing, decomposing, dissolving and eliminating effects on peculiar smell molecules through van der waals force effect, catalytic oxidation reaction, nucleophilic addition reaction and Lewis acid-base reaction, can kill viruses, has broad spectrum and high efficiency, and can achieve the aim of catalytically decomposing the peculiar smell molecules into inorganic substances. Within the mass percentage content range of the plant extract provided by the embodiment of the invention, the harmful gas removal performance and the antibacterial effect of the water-based transparent finish coating can be optimized.
Specifically, in the embodiment of the invention, the acrylic emulsion in the water-based transparent finish coating can be selected from 50%, 55%, 60% and the like in percentage by mass. The acrylic emulsion used in embodiments of the present invention may be a self-crosslinking acrylic emulsion having excellent scrub resistance, stain resistance, water resistance, as well as high transparency, high hardness, and breathability. Within the mass percentage content range of the acrylic emulsion provided by the embodiment of the invention, the water-based transparent finish coating can achieve the best decorative protection effect on the base material, and simultaneously, the high transparency does not influence any color and artistic effect of the base material.
Specifically, in the embodiment of the invention, the mass percentage of the defoaming agent in the water-based transparent finish coating can be selected from 1%, 2%, 3% and the like. The defoaming agent used in the embodiment of the invention comprises an organic silicon defoaming agent, a polyether siloxane copolymer defoaming agent or a combination of the two (specifically, the combination can be combined according to the mass ratio of 1:1), and the combined defoaming agent has a better defoaming function. Within the mass percentage content range of the defoaming agent provided by the embodiment of the invention, the defoaming effect of the multifunctional water-based transparent top-coat paint can be optimized.
Specifically, in the embodiment of the invention, the content of the wetting agent in the water-based transparent finish coating can be selected from 0.1%, 0.2%, 0.3% and the like in percentage by mass. The wetting agent used in the embodiments of the present invention is preferably a polysiloxane-polyether copolymer humectant having an excellent wetting effect on a substrate which is difficult to wet.
Specifically, in the embodiment of the invention, the weight percentage of the matte powder in the water-based transparent finishing coating can be selected from 1%, 1.5%, 2% and the like. The matte powder used in the embodiment of the invention can be special matting powder for paint, such as fumed silica matte powder, and is used for reducing the gloss of the product to achieve the matte effect without influencing other performances of the product.
Specifically, in the embodiment of the invention, the mass percentage of the leveling agent in the water-based transparent top coating can be selected from 0.2%, 0.3%, 0.5% and the like. The leveling agent used in the embodiment of the present invention is preferably a PU (polyurethane) leveling agent, a polyether-silicon-oxygen copolymer silicon-containing leveling agent, or a combination of both (specifically, a combination of both in a mass ratio of 1: 1). Within the mass percentage content range of the PU leveling agent provided by the embodiment of the invention, the construction performance of the water-based transparent finish coating can reach the optimum.
Specifically, in the embodiment of the invention, the mass percentage of the film-forming assistant in the water-based transparent top coating can be 1.5%, 2.5% or 3%. The film forming aid used in the embodiment of the invention comprises at least one of alcohol ester and ether ester, specifically, the ether ester is dipropylene glycol butyl ether, dipropylene glycol methyl ether or a combination of the two (such as a combination of 1:1 by mass ratio), and the alcohol ester can be dodecyl alcohol ester. Within the mass percentage content range of the film-forming additive provided by the embodiment of the invention, the film-forming performance of the multifunctional water-based transparent finish coating can reach the optimum.
Specifically, in the embodiment of the invention, the propylene glycol mass percentage in the water-based transparent top coating can be selected from 1% or 2%, and the like. The propylene glycol can be mutually dissolved with water to be used as a solvent, can be used as a film forming aid and also has anti-freezing performance, so that the propylene glycol has a multifunctional effect, and the dissolving and film forming performance and the low-temperature storage performance of the water-based transparent finish coating can be optimized within the mass percentage content range of the propylene glycol provided by the embodiment of the invention.
Specifically, in the embodiment of the invention, the mass percentage of the thickener in the water-based transparent finish coating can be selected from 1% or 1.5%, and the like. The thickener may preferably be a PU thickener, such as a PU associative thickener, in particular a nonionic solvent-free hydrophobically modified ethylene oxide polyurethane (HEUR) thickener. Within the mass percentage content range of the thickening agent provided by the embodiment of the invention, the construction viscosity performance of the water-based transparent finish coating can reach the optimal value.
Specifically, in the embodiment of the invention, the mass percentage of the bactericide in the water-based transparent finish coating can be selected from 0.1%, 0.2% and the like. The bactericide is preferably isothiazolinone bactericide which does not contain formaldehyde and Volatile Organic Compounds (VOC), and has high-efficiency sterilization and corrosion prevention performance. Within the mass percentage content range of the bactericide provided by the embodiment of the invention, the anticorrosive effect of the water-based transparent finish coating can reach the optimal.
Specifically, in the embodiment of the invention, the mass percentage of the aqueous wax dispersion in the aqueous transparent top coating can be selected from 0.5%, 1%, 1.5% and the like. The aqueous wax dispersion of the present invention is preferably a polyethylene wax dispersion, which improves the tack-back resistance and hardness of the product. Within the mass percentage content range of the aqueous wax dispersoid provided by the embodiment of the invention, the anti-after-tack and hardness performance effects of the aqueous transparent finish coating can reach the optimal.
On the other hand, the embodiment of the invention also provides a preparation method of the water-based transparent top coating, which comprises the following steps:
s01: weighing raw materials of the components respectively according to the components and the content of the components contained in the water-based transparent top-coat paint;
s02: carrying out first mixing treatment on the water, the wetting agent, the defoaming agent and the propylene glycol to obtain a first mixed material;
s03: and adding the rest components into the first mixed material, and carrying out second mixed material treatment to obtain the water-based transparent top-coat coating.
The preparation method of the water-based transparent top-coat paint provided by the embodiment of the invention has the advantages of simple process, easily controlled conditions and high efficiency, the water-based transparent top-coat paint prepared by the preparation method can effectively improve the capability of removing harmful gases such as formaldehyde, ammonia, benzene and the like, has excellent water resistance, scrub resistance, stain resistance, transparency, high hardness and anti-after-tack effect, and can be used for top-coat protection of various wall decoration materials such as emulsion paint on the inner wall of a building, diatom ooze paint, plates and the like.
Specifically, in the preparation method, the step of processing the first mixed material includes: stirring at 200-; the second mixed material processing step comprises: stirring at 600 and 900rpm for 30-45 min. Under the above conditions, the effect of mixing is better.
The invention is described in further detail with reference to a part of the test results, which are described in detail below with reference to specific examples. In the following examples, the detection standards are finishing varnish standard HG/T5065-.
Example 1
The formula (total content 100%) of the novel multifunctional water-based transparent top-coat paint provided by the embodiment is as follows:
formaldehyde scavenger (made by reacting urea with ethylenediamine): 2 percent of
Plant extracts (extracts prepared from clover, kurarinone and kurarinone plants as raw materials): 3 percent of
Acrylic emulsion: 50 percent of
Antifoam (silicone antifoam and polyether siloxane copolymer antifoam): 2 percent of
Wetting agent (polyether modified siloxane): 0.2 percent of
Matte powder (fumed silica matte powder): 1.5 percent
Leveling agent (PU leveling agent): 0.4 percent
Coalescent (dodecanol ester): 2.5 percent
Propylene glycol: 1.5 percent
Thickener (PU thickener): 1 percent of
Fungicides (isothiazolinone fungicides): 0.1 percent of
Aqueous wax dispersion (polyethylene wax dispersion): 1 percent of
Deionized water: 34.8 percent.
The preparation method of the multifunctional water-based transparent top-coat paint comprises the following steps:
s11: weighing the raw materials according to the formula proportion;
s12: adding deionized water, a wetting agent, a defoaming agent and propylene glycol in sequence at a low speed stage, and stirring at a low speed of 200rpm for 15 minutes;
s13: then adding a formaldehyde catching agent, a plant extract, matte powder, acrylic emulsion, a film forming aid, a thickening agent, a leveling agent, a bactericide, an aqueous wax dispersoid and other residual components, dispersing and stirring at a low speed of 600rpm for 45 minutes after the raw materials are added, and uniformly stirring.
And after the quality control inspection is qualified, weighing, packaging and warehousing. The wall surface with the artistic coating effect is coated with a qualified finished product, and the effect similar to a dolomitic cloud is manufactured by a batch knife in a multi-batch scraping mode, as shown in figure 1 (a schematic view of a cloud effect), the result is vivid, and the multifunctional water-based transparent top-coat coating has good transparency and does not influence the color and the artistic effect of a base layer.
Example 1 test results by HG/T5065-: construction property: the roller coating is smooth and free from obstacles; surface drying time: less than or equal to 1 h; water/alkali resistance: no bulging, cracking, peeling and discoloration after 48 hours; washing and brushing resistance: not less than 300 times. According to the test result of JC/T1074-: the formaldehyde purification rate: 92 percent; the formaldehyde purification effect is durable: 82%; the toluene purification rate is 85%, and the toluene purification effect durability is as follows: 51 percent; the mould-proof performance is as follows: level 0; the mould-proof performance is grade I; meets the national standard requirements.
Example 2
The formula (weight percentage) of the novel multifunctional water-based transparent top-coat paint provided by the embodiment is as follows:
formaldehyde scavenger (made by reacting urea with ethylenediamine): 2.5 percent
Plant extracts (extracts prepared from clover, kurarinone and kurarinone plants as raw materials): 4 percent of
Acrylic emulsion: 55 percent of
Antifoam agent (silicone antifoam agent): 2 percent of
Wetting agent (polyether modified siloxane): 0.3 percent of
Matte powder (fumed silica matte powder): 2 percent of
Leveling agent (PU leveling agent): 0.3 percent of
Coalescent (dipropylene glycol butyl ether): 3 percent of
Propylene glycol: 2 percent of
Thickener (PU thickener): 1.5 percent
Fungicides (isothiazolinone fungicides): 0.1 percent of
Aqueous wax dispersion (polyethylene wax dispersion): 1.5 percent
Deionized water: 25.8 percent.
The preparation of the multifunctional water-based transparent top-coat paint was the same as in example 1.
And after the quality control inspection is qualified, weighing, packaging and warehousing. After the qualified finished product is coated on the wall surface with the effect of the artistic coating, the effect similar to the orange peel texture is obtained by repeatedly rolling and coating by using a honeycomb roller, as shown in figure 2 (an orange peel effect schematic diagram), the texture is clear, uniform and consistent, and the multifunctional water-based transparent top coating is good in transparency and does not influence the color and the artistic effect of a base layer.
Example 2 test results by HG/T5065-: construction property: the roller coating is smooth and free from obstacles; surface drying time: less than or equal to 1 h; water/alkali resistance: no bulging, cracking, peeling and discoloration after 48 hours; washing and brushing resistance: not less than 300 times. According to the test result of JC/T1074-: the formaldehyde purification rate: 93 percent; the formaldehyde purification effect is durable: 84.5 percent; the toluene purification rate is 88%, and the toluene purification effect durability is as follows: 52.5 percent; the mould-proof performance is as follows: level 0; the mould-proof performance is grade I; meets the national standard requirements.
Example 3
The formula (weight percentage) of the novel multifunctional water-based transparent top-coat paint provided by the embodiment is as follows:
formaldehyde scavenger (made by reacting urea with ethylenediamine): 3 percent of
Plant extracts (extracts prepared from clover, kurarinone and kurarinone plants as raw materials): 5 percent of
Acrylic emulsion: 60 percent of
Antifoam (polyether siloxane copolymer antifoam): 3 percent of
Wetting agent (polyether modified siloxane): 0.3 percent of
Matte powder (fumed silica matte powder): 2 percent of
Leveling agents (PU leveling agent and polyether siloxane copolymer silicon-containing leveling agent): 0.5 percent
Coalescent (dodecanol ester): 3 percent of
Propylene glycol: 2 percent of
Thickener (PU thickener): 1.5 percent
Fungicides (isothiazolinone fungicides): 0.1 percent of
Aqueous wax dispersion (polyethylene wax dispersion): 1.5 percent
Deionized water: 18.1 percent.
The preparation of the multifunctional water-based transparent top-coat paint was the same as in example 1.
And after the quality control inspection is qualified, weighing, packaging and warehousing. The finished product which is qualified after inspection is coated on the wall surface with the effect of the artistic coating, and the effect similar to the ghost is manufactured by multiple batch scraping and color correction, as shown in figure 3 (a schematic diagram of the ghost effect), the figure shows that the texture is clear, uniform and consistent, and the multifunctional water-based transparent top coating has good transparency and does not influence the color and the artistic effect of a base layer.
Example 3 test results as HG/T5065-: construction property: the roller coating is smooth and free from obstacles; surface drying time: less than or equal to 1 h; water/alkali resistance: no bulging, cracking, peeling and discoloration after 48 hours; washing and brushing resistance: not less than 300 times. According to the test result of JC/T1074-: the formaldehyde purification rate: 93.3 percent; the formaldehyde purification effect is durable: 88.5 percent; the toluene purification rate is 91.5%, and the toluene purification effect is durable: 56 percent; the mould-proof performance is as follows: level 0; the mould-proof performance is grade I; meets the national standard requirements.
Example 4
The formula (weight percentage) of the novel multifunctional water-based transparent top-coat paint provided by the embodiment is as follows:
formaldehyde scavenger (made by reacting urea with ethylenediamine): 2 percent of
Plant extracts (extracts prepared from clover, kurarinone and kurarinone plants as raw materials): 3.5 percent
Acrylic emulsion: 52 percent
Antifoam agent (silicone antifoam agent): 2 percent of
Wetting agent (polyether modified siloxane): 0.2 percent of
Matte powder (fumed silica matte powder): 1 percent of
Leveling agent (PU leveling agent): 0.3 percent of
Coalescents (dipropylene glycol butyl ether and dipropylene glycol methyl ether): 1.5 percent
Propylene glycol: 1 percent of
Thickener (PU thickener): 1 percent of
Fungicides (isothiazolinone fungicides): 0.1 percent of
Aqueous wax dispersion (polyethylene wax dispersion): 1 percent of
Deionized water: 34.4 percent.
The preparation of the multifunctional water-based transparent top-coat paint was the same as in example 1.
And after the quality control inspection is qualified, weighing, packaging and warehousing. The sandstone effect manufactured by painting the qualified finished product on the wall surface with the artistic coating effect and adopting the method of spraying dots and scraping in batches is shown in figure 4 (sandstone effect schematic diagram), and the figure shows that the texture is clear, uniform and consistent, so that the multifunctional water-based transparent finish coating has good transparency and does not influence the color and the artistic effect of the base layer.
Example 4 test results by HG/T5065-: construction property: the roller coating is smooth and free from obstacles; surface drying time: less than or equal to 1 h; water/alkali resistance: no bulging, cracking, peeling and discoloration after 48 hours; washing and brushing resistance: not less than 300 times. According to the test result of JC/T1074-: the formaldehyde purification rate: 92.5 percent; the formaldehyde purification effect is durable: 85.5 percent; the toluene purification rate is 89.5%, and the toluene purification effect is durable: 52.3 percent; the mould-proof performance is as follows: level 0; the mould-proof performance is grade I; meets the national standard requirements.
The above detection results of the embodiments 1 to 4 of the present invention show that, compared with the existing common formaldehyde removing coating, the novel multifunctional water-based transparent top coating provided by the embodiments of the present invention has great advantages in performance, especially has incomparable advantages in removing harmful gases such as formaldehyde, ammonia, benzene, etc.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.
Claims (10)
1. The water-based transparent top-coat paint is characterized by comprising the following components in percentage by mass based on 100% of the total mass of the water-based transparent top-coat paint:
2-3% of a formaldehyde scavenger;
3-5% of plant extract;
50-60% of acrylic emulsion;
1-3% of a defoaming agent;
0.1-0.3% of wetting agent;
1-2% of matte powder;
0.2-0.5% of a leveling agent;
1.5-3% of a film-forming assistant;
1-2% of propylene glycol;
1-1.5% of a thickening agent;
0.1-0.2% of a bactericide;
0.5-1.5% of aqueous wax dispersoid;
18-40% of water.
2. The aqueous transparent top coat of claim 1 wherein the formaldehyde scavenger is obtained by cyclization of ammonia gas evolved from the reaction of urea and ethylenediamine.
3. The aqueous transparent overcoat of claim 1, wherein the plant extract comprises extracts from clover, kurarinone, and kurarinone by fermentation.
4. The aqueous transparent topcoat of claim 1, wherein the acrylic emulsion comprises a self-crosslinking acrylic emulsion; and/or the presence of a gas in the gas,
the defoaming agent comprises an organic silicon defoaming agent and a polyether siloxane copolymer defoaming agent.
5. The aqueous transparent topcoat of claim 1, wherein the wetting agent comprises a polysiloxane-polyether copolymer wetting agent; and/or the presence of a gas in the gas,
the leveling agent comprises a PU leveling agent and a silicon-containing leveling agent of polyether silicon-oxygen copolymer.
6. The aqueous transparent topcoat of claim 1, wherein the coalescent comprises at least one of an ether ester and an alcohol ester.
7. The aqueous clear overcoat of claim 1 wherein the biocide is an isothiazolinone biocide; and/or the presence of a gas in the gas,
the thickener is a PU thickener.
8. The aqueous transparent topcoat of claim 1, wherein the aqueous wax dispersion is a polyethylene wax dispersion.
9. A preparation method of a water-based transparent finish coating is characterized by comprising the following steps:
weighing the raw materials of the components and the contents thereof respectively according to the components contained in the water-based transparent top-coat paint of any one of claims 1 to 8;
carrying out first mixing treatment on the water, the wetting agent, the defoaming agent and the propylene glycol to obtain a first mixed material;
and adding the rest components into the first mixed material, and carrying out second mixed material treatment to obtain the water-based transparent top-coat coating.
10. The method of preparing an aqueous transparent top coat according to claim 9, wherein the step of treating the first batch comprises: stirring at 200-; and/or the presence of a gas in the gas,
the second mixed material processing step comprises: stirring at 600 and 900rpm for 30-45 min.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111876038A (en) * | 2020-06-24 | 2020-11-03 | 雷帝(中国)建筑材料有限公司 | Finish paint for decorative mortar and preparation method thereof |
| CN114015309A (en) * | 2021-12-06 | 2022-02-08 | 三棵树(上海)新材料研究有限公司 | High-hardness scratch-resistant interior wall finish coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1739821A (en) * | 2005-09-20 | 2006-03-01 | 沈阳化工学院 | Ethylene carbamido amino derivative as formaldehyde eliminator |
| CN101824277A (en) * | 2010-03-11 | 2010-09-08 | 湖北饰乃康涂料有限公司 | Latex paint and aqueous wood ware paint for eliminating formaldehyde and preparation method thereof |
| CN103788855A (en) * | 2014-02-11 | 2014-05-14 | 广东华兹卜化学工业有限公司 | Preparation method of plant health-maintaining water-borne wood paint |
-
2019
- 2019-12-17 CN CN201911304070.5A patent/CN111057426A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1739821A (en) * | 2005-09-20 | 2006-03-01 | 沈阳化工学院 | Ethylene carbamido amino derivative as formaldehyde eliminator |
| CN101824277A (en) * | 2010-03-11 | 2010-09-08 | 湖北饰乃康涂料有限公司 | Latex paint and aqueous wood ware paint for eliminating formaldehyde and preparation method thereof |
| CN103788855A (en) * | 2014-02-11 | 2014-05-14 | 广东华兹卜化学工业有限公司 | Preparation method of plant health-maintaining water-borne wood paint |
Non-Patent Citations (4)
| Title |
|---|
| （新西兰）希尔著: "《自然的超级食品 迷你蔬菜乐活DIY》", 30 November 2011 * |
| 周孝虎编: "《回归大自然的生物防治》", 31 July 2011 * |
| 熊辅信，寸树芬编著: "《中药现代研究荟萃》", 31 May 2002 * |
| 贾志坚，武宇芳，李文娟主编: "《有机化学理论及发展研究》", 30 April 2018 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111876038A (en) * | 2020-06-24 | 2020-11-03 | 雷帝(中国)建筑材料有限公司 | Finish paint for decorative mortar and preparation method thereof |
| CN114015309A (en) * | 2021-12-06 | 2022-02-08 | 三棵树(上海)新材料研究有限公司 | High-hardness scratch-resistant interior wall finish coating and preparation method thereof |
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Application publication date: 20200424 |