CN109369119A - 基于铝冶废渣的改性磷石膏路用材料的制备与应用方法 - Google Patents
基于铝冶废渣的改性磷石膏路用材料的制备与应用方法 Download PDFInfo
- Publication number
- CN109369119A CN109369119A CN201811268754.XA CN201811268754A CN109369119A CN 109369119 A CN109369119 A CN 109369119A CN 201811268754 A CN201811268754 A CN 201811268754A CN 109369119 A CN109369119 A CN 109369119A
- Authority
- CN
- China
- Prior art keywords
- ardealite
- waste residue
- aluminium
- smelting waste
- roadbed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004411 aluminium Substances 0.000 title claims abstract description 40
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 40
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000002699 waste material Substances 0.000 title claims abstract description 37
- 238000003723 Smelting Methods 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 239000002893 slag Substances 0.000 claims abstract description 10
- DKFCNIGGENJIJN-UHFFFAOYSA-L aluminum;iron(2+);sulfate Chemical compound [Al+3].[Fe+2].[O-]S([O-])(=O)=O DKFCNIGGENJIJN-UHFFFAOYSA-L 0.000 claims abstract description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000004568 cement Substances 0.000 claims abstract description 7
- 229910021653 sulphate ion Inorganic materials 0.000 claims abstract description 6
- 238000000227 grinding Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000284 extract Substances 0.000 claims description 3
- 238000010276 construction Methods 0.000 abstract description 5
- 238000012360 testing method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 241001370940 Dercas lycorias Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 235000019691 monocalcium phosphate Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/143—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being phosphogypsum
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Road Paving Structures (AREA)
- Processing Of Solid Wastes (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201811268754.XA CN109369119B (zh) | 2018-10-29 | 2018-10-29 | 基于铝冶废渣的改性磷石膏路用材料的制备与应用方法 |
Applications Claiming Priority (1)
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CN201811268754.XA CN109369119B (zh) | 2018-10-29 | 2018-10-29 | 基于铝冶废渣的改性磷石膏路用材料的制备与应用方法 |
Publications (2)
Publication Number | Publication Date |
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CN109369119A true CN109369119A (zh) | 2019-02-22 |
CN109369119B CN109369119B (zh) | 2021-02-02 |
Family
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Family Applications (1)
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CN201811268754.XA Active CN109369119B (zh) | 2018-10-29 | 2018-10-29 | 基于铝冶废渣的改性磷石膏路用材料的制备与应用方法 |
Country Status (1)
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CN (1) | CN109369119B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111622041A (zh) * | 2020-06-05 | 2020-09-04 | 交通运输部科学研究院 | 一种用于强氯盐渍土地区的道路基层稳定材料及施工方法 |
CN111848083A (zh) * | 2020-07-21 | 2020-10-30 | 中南安全环境技术研究院股份有限公司 | 一种环境友好型磷石膏复合稳定材料及其制备方法 |
CN112479614A (zh) * | 2020-12-01 | 2021-03-12 | 济南大学 | 一种固化石膏中可溶性磷和氟的处理剂及其固化方法与应用 |
CN116903286A (zh) * | 2023-07-14 | 2023-10-20 | 长江水利委员会长江科学院 | 一种改性磷石膏及其制备方法与应用 |
Citations (8)
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CN101684675A (zh) * | 2009-08-19 | 2010-03-31 | 四川宏达股份有限公司 | 一种蒸压磷石膏砖及其制造方法 |
JP4463524B2 (ja) * | 2003-10-20 | 2010-05-19 | 日新鋼管株式会社 | 亜鉛系めっき鋼材と水硬性組成物との複合構造体 |
CN103011726A (zh) * | 2012-12-25 | 2013-04-03 | 陕西理工学院 | 一种铅锌冶炼废渣的固化处理工艺 |
CN103708747A (zh) * | 2013-12-02 | 2014-04-09 | 贵州开磷(集团)有限责任公司 | 一种可用于填海造地工程的改性磷石膏材料 |
CN103708748A (zh) * | 2013-12-02 | 2014-04-09 | 贵州开磷(集团)有限责任公司 | 一种填海造地用改性磷石膏材料 |
CN105669140A (zh) * | 2016-02-16 | 2016-06-15 | 湖北固益生环保科技有限公司 | 一种磷石膏路面材料及其制备方法 |
CN106478020A (zh) * | 2016-10-10 | 2017-03-08 | 浙江师范大学 | 一种用废弃铝灰渣制备免烧砖的方法 |
CN108409276A (zh) * | 2018-05-09 | 2018-08-17 | 王晓春 | 一种改性磷石膏路基材料 |
-
2018
- 2018-10-29 CN CN201811268754.XA patent/CN109369119B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4463524B2 (ja) * | 2003-10-20 | 2010-05-19 | 日新鋼管株式会社 | 亜鉛系めっき鋼材と水硬性組成物との複合構造体 |
CN101684675A (zh) * | 2009-08-19 | 2010-03-31 | 四川宏达股份有限公司 | 一种蒸压磷石膏砖及其制造方法 |
CN103011726A (zh) * | 2012-12-25 | 2013-04-03 | 陕西理工学院 | 一种铅锌冶炼废渣的固化处理工艺 |
CN103708747A (zh) * | 2013-12-02 | 2014-04-09 | 贵州开磷(集团)有限责任公司 | 一种可用于填海造地工程的改性磷石膏材料 |
CN103708748A (zh) * | 2013-12-02 | 2014-04-09 | 贵州开磷(集团)有限责任公司 | 一种填海造地用改性磷石膏材料 |
CN105669140A (zh) * | 2016-02-16 | 2016-06-15 | 湖北固益生环保科技有限公司 | 一种磷石膏路面材料及其制备方法 |
CN106478020A (zh) * | 2016-10-10 | 2017-03-08 | 浙江师范大学 | 一种用废弃铝灰渣制备免烧砖的方法 |
CN108409276A (zh) * | 2018-05-09 | 2018-08-17 | 王晓春 | 一种改性磷石膏路基材料 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111622041A (zh) * | 2020-06-05 | 2020-09-04 | 交通运输部科学研究院 | 一种用于强氯盐渍土地区的道路基层稳定材料及施工方法 |
CN111622041B (zh) * | 2020-06-05 | 2021-12-14 | 交通运输部科学研究院 | 一种用于强氯盐渍土地区的道路基层稳定材料及施工方法 |
CN111848083A (zh) * | 2020-07-21 | 2020-10-30 | 中南安全环境技术研究院股份有限公司 | 一种环境友好型磷石膏复合稳定材料及其制备方法 |
CN111848083B (zh) * | 2020-07-21 | 2022-03-22 | 中南安全环境技术研究院股份有限公司 | 一种环境友好型磷石膏复合稳定材料及其制备方法 |
CN112479614A (zh) * | 2020-12-01 | 2021-03-12 | 济南大学 | 一种固化石膏中可溶性磷和氟的处理剂及其固化方法与应用 |
CN116903286A (zh) * | 2023-07-14 | 2023-10-20 | 长江水利委员会长江科学院 | 一种改性磷石膏及其制备方法与应用 |
CN116903286B (zh) * | 2023-07-14 | 2024-01-30 | 长江水利委员会长江科学院 | 一种改性磷石膏及其制备方法与应用 |
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Denomination of invention: Preparation and application of modified phosphogypsum road material based on aluminum smelting waste residue Effective date of registration: 20211123 Granted publication date: 20210202 Pledgee: Bank of Beijing Co., Ltd. Jinan Branch Pledgor: Shandong harbour Traffic Technology Co.,Ltd. Registration number: Y2021370000143 |
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