CN109337751B - 一种通用型切削液 - Google Patents
一种通用型切削液 Download PDFInfo
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- CN109337751B CN109337751B CN201811345588.9A CN201811345588A CN109337751B CN 109337751 B CN109337751 B CN 109337751B CN 201811345588 A CN201811345588 A CN 201811345588A CN 109337751 B CN109337751 B CN 109337751B
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- cutting fluid
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- mineral oil
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- 239000002173 cutting fluid Substances 0.000 title claims abstract description 35
- -1 alcohol amine Chemical class 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 10
- 239000003899 bactericide agent Substances 0.000 claims abstract description 10
- 239000002480 mineral oil Substances 0.000 claims abstract description 10
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 10
- 239000007822 coupling agent Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 7
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000005642 Oleic acid Substances 0.000 claims abstract description 7
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 7
- 235000013311 vegetables Nutrition 0.000 claims abstract description 7
- 239000003755 preservative agent Substances 0.000 claims abstract description 5
- 230000002335 preservative effect Effects 0.000 claims abstract description 5
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 229940055577 oleyl alcohol Drugs 0.000 claims description 6
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 5
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 5
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical group CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
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- AGLSQWBSHDEAHB-UHFFFAOYSA-N azane;boric acid Chemical compound N.OB(O)O AGLSQWBSHDEAHB-UHFFFAOYSA-N 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
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- 239000008233 hard water Substances 0.000 abstract description 5
- 238000003754 machining Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
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- 238000005553 drilling Methods 0.000 abstract description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000012530 fluid Substances 0.000 abstract description 2
- 238000012423 maintenance Methods 0.000 abstract description 2
- 239000007769 metal material Substances 0.000 abstract description 2
- 238000005536 corrosion prevention Methods 0.000 abstract 1
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- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
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- 238000001816 cooling Methods 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 230000002421 anti-septic effect Effects 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
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- 238000005260 corrosion Methods 0.000 description 2
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- 230000001050 lubricating effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
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- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
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- 238000009826 distribution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
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- 238000010422 painting Methods 0.000 description 1
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- 239000000243 solution Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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Abstract
本发明公开了一种通用型切削液，该通用型切削液按重量份数计，包括：矿物油300‑400份、植物油酸65‑73份、醇胺40‑60份、防腐剂102‑160份、表面活性剂55‑80份、耦合剂2‑6份、杀菌剂5‑10份、消泡剂1‑3份、水400‑500份。本发明通用型切削液不含亚硝酸盐及硫化物，属于环境友好型产品，工作液稳定，并具有优异的抗硬水能力，能适用于不同地区的多种水质条件，能够满足多种CNC、龙门数控、钻床、磨床等机械加工的工艺要求和各类常规金属材料的防腐要求，简化大型机加工企业生产过程中的油品维护及管理规程，降低综合使用成本。
Description
技术领域
本发明属于金属切削加工领域，具体涉及一种通用型切削液。
背景技术
切削液是一种在车削、磨削等金属加工过程中用于冷却、润滑加工件和刀具的工业介质，为适应于加工工况及产品要求同时需具备一定的清洗、防锈等性能。
但是目前应用的切削液存在以下缺陷，
1.随着金属切削加工的形式趋于丰富，常用工艺包括铣削、钻孔、刨、拉削、车削和磨削，工艺适用种类少，工况适应性低的切削液产品已不能适合大型金属加工工况的特点，因其设备数量大、加工工序多，种类庞杂的切削液使用会给生产管理及成本造成负担。
2.除黑色金属广泛应用于设备构件，包括碳素钢、合金钢、不锈钢、铸铁等，有色金属也大量作为工程材料使用，包括铝合金、铜合金、镁合金。例如，铝合金加工过程中易发黑、粘刀，铸铁件加工后上漆困难，铜合金加工表面光亮度差，切削不锈钢往往伴随着断刀、粘刀现象的发生。种类繁多的被加工材质也对切削液提出越来越多的要求。传统的切削液产品已不能满足多种类金属工件的不同种类的加工工艺。
3.除此之外，金属切削加工作为广泛应用的生产作业方式，由于其分布范围广，对作业用水质也提出更多要求。目前在用切削液产品普遍存在和稀释水中的钙盐、镁盐等反应，造成工作液不稳定，并伴随油和皂析出的现象。
针对目前切削液存在的问题，一种能够符合目前切削液生产加工形式丰富、加工工件材质多样的加工条件，并对作业水质种类适应性强的切削液产品，将能够为切削加工过程带来极大的便利，满足客户使用要求的前提下还能够为使用方节约管理成本。
发明内容
针对现有切削液产品的缺陷，本发明的目的在于提供一种通用型切削液。
为实现上述目的，本发明提供如下技术方案：
一种通用型切削液，按重量份数计，包括：矿物油300～400份、植物油酸65-73份、醇胺40-60份、防腐剂102-160份、表面活性剂55-80份、耦合剂2-6份、杀菌剂5-10份、消泡剂1-3份、水400-500份。
优选地，所述矿物油为150SN矿物油，所述植物油酸为棉籽油酸。
优选地，所述醇胺为单乙醇胺。
优选地，所述防腐剂为硼酸醇胺酯、二环己胺和苯并三氮唑。
更优选地，所述硼酸醇胺酯、二环己胺和苯并三氮唑的重量比为80-120:20-30:2-10。
优选地，所述表面活性剂为壬基酚聚氧乙烯醚、司盘80和油醇醚羧酸。
更优选地，所述壬基酚聚氧乙烯醚、司盘80和油醇醚羧酸的重量比为20-30:30-40:5-10。
优选地，所述耦合剂为C16格尔伯特醇。
优选地，所述杀菌剂为吗啉类杀菌剂，所述消泡剂为水溶性含硅消泡剂。
本发明的有益效果
1.本发明通用型切削液不含亚硝酸盐及硫化物，属于环境友好型产品；
2.本发明通用型切削液使用壬基酚聚氧乙烯醚、司盘80、油醇醚羧酸作为乳化剂组合物，工作液稳定，并具有优异的抗硬水能力，能适用于不同地区的多种水质条件；
3.本发明通用型切削液中植物油酸、硼酸醇胺酯、C16格尔伯特醇均具有提高产品润滑能力的功能，能够满足多种CNC、龙门数控、钻床、磨床等机械加工的工艺要求；
4.本发明通用型切削液中硼酸醇胺酯、二环己胺、苯并三氮唑三种防腐添加剂的使用，使产品能够满足各类常规金属材料的防腐要求；
5.具有工艺、加工材质、配液水质的广泛适应能力，能够简化大型机加工企业生产过程中的油品维护及管理规程，降低综合使用成本。
具体实施方式
下面将对本发明内容中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
切削液的制备过程：加热矿物油到60℃后依次加入植物油酸、耦合剂、单乙醇胺、防腐剂、表面活性剂后搅拌0.5h，加入水，搅拌0.5h后，降温至30℃，加入杀菌剂、消泡剂，搅拌1h，静置1-2h，过滤灌装即可。
切削液对硬水的稳定性实验：
实验过程：将用硬水稀释的浓度为5％切削液100ml液置于具塞量筒，室温静置24h。
注：析油为透明液层，析皂表现为白色至黄色絮状悬浮物。
稳定性实验结果表明，壬基酚聚氧乙烯醚、司盘80、油醇醚羧酸具有协同效果，能显著提高切削液的抗硬水能力。
实施例2
切削液的制备过程：加热矿物油到60℃后依次加入植物油酸、耦合剂、单乙醇胺、防腐剂、表面活性剂后搅拌0.5h，加入水，搅拌0.5h后，降温至30℃，加入杀菌剂、消泡剂，搅拌1h，静置1-2h，过滤灌装即可。
实施例3
切削液的制备过程：加热矿物油到60℃后依次加入植物油酸、耦合剂、单乙醇胺、防腐剂、表面活性剂后搅拌0.5h，加入水，搅拌0.5h后，降温至30℃，加入杀菌剂、消泡剂，搅拌1h，静置1-2h，过滤灌装即可。
以上三个实施例均通过GB/T6144-2010标准所要求的技术指标，从经济成本考虑，实施例1较佳。实施例1检测结果见下表：
最后应说明的是：以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (7)
1.一种通用型切削液，按重量份数计，包括：矿物油300-400份、植物油酸65-73份、醇胺40-60份、防腐剂102-160份、表面活性剂55-80份、耦合剂2-6份、杀菌剂5-10份、消泡剂1-3份、水400-500份；
所述表面活性剂为壬基酚聚氧乙烯醚、司盘80和油醇醚羧酸；
所述壬基酚聚氧乙烯醚、司盘80和油醇醚羧酸的重量比为20-30:30-40:5-10。
2.根据权利要求1所述的通用型切削液，其特征在于：所述矿物油为150SN矿物油，所述植物油酸为棉籽油酸。
3.根据权利要求1所述的通用型切削液，其特征在于：所述醇胺为单乙醇胺。
4.根据权利要求1所述的通用型切削液，其特征在于：所述防腐剂为硼酸醇胺酯、二环己胺和苯并三氮唑。
5.根据权利要求4所述的通用型切削液，其特征在于：所述硼酸醇胺酯、二环己胺和苯并三氮唑的重量比为80-120:20-30:2-10。
6.根据权利要求1所述的通用型切削液，其特征在于：所述耦合剂为C16格尔伯特醇。
7.根据权利要求1所述的通用型切削液，其特征在于：所述杀菌剂为吗啉类杀菌剂，所述消泡剂为水溶性含硅消泡剂。
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