CN109337468A - The anti-lost powder coating of hydrophobic type for aerogel blanket surface, preparation method and application - Google Patents

The anti-lost powder coating of hydrophobic type for aerogel blanket surface, preparation method and application Download PDF

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Publication number
CN109337468A
CN109337468A CN201811187194.5A CN201811187194A CN109337468A CN 109337468 A CN109337468 A CN 109337468A CN 201811187194 A CN201811187194 A CN 201811187194A CN 109337468 A CN109337468 A CN 109337468A
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Prior art keywords
aerogel blanket
powder coating
blanket surface
lost powder
lost
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Granted
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CN201811187194.5A
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CN109337468B (en
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闫方
邵芳琪
胡晓曼
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Zhejiang Rock Valley Technology Co Ltd
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Zhejiang Rock Valley Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/322Ammonium phosphate
    • C08K2003/323Ammonium polyphosphate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of anti-lost powder coating of hydrophobic type for aerogel blanket surface including hydrophober, furthermore the invention also discloses the production method of the coating and applications, hydrophober is used in anti-lost powder coating by the present invention, coating is applied to aerogel blanket surface, can effectively prevent the processing of aerogel blanket surface, transport, aerosil in bending process the picking that falls off, furthermore, the coating maintains the hydrophobicity performance of aeroge fibrofelt, long term storage, transport, that is, the stability of aeroge when improving construction usage are able under moist environmental conditions.

Description

The anti-lost powder coating of hydrophobic type for aerogel blanket surface, preparation method and application
Technical field
The present invention relates to a kind of preparation methods of the anti-lost powder coating of hydrophobic type, in particular to aerosil felt surface The anti-lost powder coating of the hydrophobic type used.
Background technique
The characteristics of Present Global energy background is to need to reduce energy consumption, delays fossil fuel shortages and slows down greenhouse Gas discharge.The thermal insulation property for increasing heat-barrier material is to reduce the most effective approach of energy consumption, and traditional thermal insulation material is thermally conductive Coefficient is higher, and the application that the thickness by increasing heat-barrier material improves thermal insulation property and it is made fields such as to keep the temperature indoors receives limit System.Aerosil has network structure that is continuous, three-dimensional, connecting in skeleton, is that a kind of low-density is nano-meter porous amorphous The heat-barrier material of state, skeleton size are in Nano grade, and skeleton thickness is no more than 100nm, this makes hot-fluid in aeroge skeleton It is middle to generate the one-way transmission for being similar to One-dimensional heat transfer, and volume shared by solid is usually less than 5% in aerogel structure, this But also solid state heat transfer specific gravity shared in internal heat transfer type substantially reduces.Bayerische Motorne Werke Aktiengeellschaft is by wrapping up aerogel layer On water-cooled radiator, the effect of automobile tolerance to cold is improved.The aerogel material aerospace that U.S. Aspen Aerogels is developed Clothes, can bear subzero 130 degree of ultralow temperature, to protect the personal safety of astronaut.Show that aeroge is excellent above Heat-proof quality is significant to the reduction of energy consumption.
High porosity, low thermal conductivity and low-k, these good characteristics make aeroge in more fields It is used widely.But the inorganic nano skeleton structure characteristic of aerosil itself also makes its brittleness big, and bend resistance resists Frictional behaviour is poor, is difficult to realize industrial applications.It is obviously mentioned by aerogel blanket intensity prepared by complex fiber material It is high.But the addition of fibrous material, the aerosil for also resulting in aerogel blanket surface are easier to fall off, and are especially transporting In defeated, work progress, aerogel blanket surface phase mutual friction, a large amount of dust falls off, and forms fugitive dust, causes apparent dirt to environment Dye, while to the health of construction personnel there is also certain hidden danger, persistently falling off for aerogel powder finally is possible to drop The thermal insulation property of low aeroge fibrofelt.
In order to solve this problem, patent CN106838547A by fibrofelt surface dip-coating or spraying adhesive, then To the mode of bonding layer surface sprinkling nanoaperture heat-barrier material particle, it is desirable to particle is fixed on fibrous material, but this side Method obviously cannot solve the brittleness problems of aerogel particle itself, and there are bright between the nanoaperture heat-barrier material particle being bonded Aobvious hole, causes material overall thermal conductivity poor;Patent CN103192582A i.e. will be inorganic anti-using inorganic or Organic adhesive The method that fiery cloth and aerogel material are bonded prevents aerogel material surface picking.But the presence of inorganic fire cloth hole, Equally cannot be from solving the problems, such as at all, in addition, the material buckles after cladding are difficult, and the bound edges such as edge of materials, gap are cumbersome tired Difficulty, material thickness and density increase obvious.Patent CN103589258A and CN106631154A be prepared for respectively a kind of coating and A kind of composite material improves Aerogel substrates material dusting problems, but two methods are all made of waterborne film-forming substance and additive, Apply behind aeroge surface, there is apparent hydrophily, in wet environment long term storage and construction, steam in air or Water droplet is readily adsorbed in coating surface, and progresses into aeroge hole, and aeroge stability is caused to decline, in addition, this It in two methods, is required to mill by ball mill, causes production technology complicated, the production cycle is longer, and cleaning container is difficult.Shen Please patent CN107337420A provide a kind of manufacturing method of hydrophobic heat-insulating calcium silicate spray paint for building heat preservation, will hate Water calcium silicates is mixed with white glue with vinyl, adhesive powder for wall paper, reinforcing fiber, fire retardant, which is only applicable to be sprayed on metope, roofing etc. Building surface is not suitable for needing the aerogel blanket surface that bends, and preparation process is complex is unfavorable for industrialized production. The present invention develops a kind of anti-lost powder coating of the hydrophobic type for aerogel blanket surface, not only solves aerogel blanket picking and asks Topic, hydrophobicity performance also greatly improve, and it is convenient and low in cost to operate.
Summary of the invention
The purpose of the present invention is to provide one kind to be used for aerogel blanket surface (especially bending surface), prevents aerogel blanket The aerosil on surface falls off the coating of picking.
In order to achieve the above objectives, concrete scheme of the invention is as follows:
A kind of anti-lost powder coating of hydrophobic type for aerogel blanket surface, including hydrophober.
Preferably,
The anti-lost powder coating of hydrophobic type for aerogel blanket surface, further includes film forming matter, crosslinking agent, and film forming helps Agent, expanding material, fire retardant, defoaming agent and water.
The anti-lost powder coating of hydrophobic type for aerogel blanket surface, the component including following portions by weight:
Film forming matter 60-80;
Crosslinking agent 0.5-15;
Coalescing agent 4-12;
Expanding material 0.2-10;
Fire retardant 40-70;
Defoaming agent 0.3-2.5;
Water 40-180;
Hydrophober 0.2-60.
To improve hydrophobic rate of the anti-lost powder coating of hydrophobic type after application to 98.0% or more, the hydrophober is organic Silicon hydrophober, by one or more of the processed powder of organosilicon moisture repellent, particle;
To improve hydrophobic rate of the anti-lost powder coating of hydrophobic type after application to 98.0% or more, the organosilicon moisture repellent For hexamethyldisiloxane, hexamethyldisilazane, dimethyl diethoxysilane, one hydrogen silane of monomethyl diethoxy, first Ethyl triethoxy silicane alkane, methyltrimethoxysilane, poly- methyltriethoxysilane, poly- methyltrimethoxysilane, methyl hydroxyl One of base silicone oil, hydroxyl hydrogen silicone oil, methyl trifluoro propyl silicone oil or methyl vinyl silicon oil are a variety of.
The expanding material is γ-methacryloxypropyl trimethoxy silane, vinyltrimethoxysilane, ethylene One or more of ethyl triethoxy silicane alkane.
The film forming matter is acrylic resin, polysiloxanes, phenolic resin, Lauxite, Corvic, crosses chlorine One or more of vinyl, vinyl chloride Vinylidene Chloride Copolymers, NC Nitroncellulose, acetic acid butyl cellulose.
The crosslinking agent is one or more of potassium methyl silicate, sodium methyl silicate.
The coalescing agent is alcohol ester 12, glycol propyl ether, butyl glycol ether, propylene glycol propyl ether, propandiol butyl ether, two Glycol ether, diethylene glycol (DEG) propyl ether, butyl carbitol, two propyl alcohol butyl ether, diethylene glycol ether acetic acid rouge, in butyl carbitol acetic acid rouge One or more.
The fire retardant is aluminium hydroxide, magnesium hydroxide, ammonium polyphosphate, starch, melamine, urea, molybdenum trioxide, eight One or more of ammonium molybdate.
The defoaming agent is one or more of n-octyl alcohol, aqueous defoamer F-127, polyglycol ether.
The film forming matter is acrylic resin, polysiloxanes, phenolic resin, Lauxite, Corvic, crosses chlorine One or more of vinyl, vinyl chloride Vinylidene Chloride Copolymers, NC Nitroncellulose, acetic acid butyl cellulose;
The crosslinking agent is one or more of potassium methyl silicate, sodium methyl silicate.
The present invention also provides a kind of preparation methods of anti-lost powder coating for aerogel blanket surface, with technique letter Single, easy for construction, low in cost feature.
A kind of preparation method of the anti-lost powder coating for aerogel blanket surface, comprising the following steps:
(1) one or more of film forming matter, coalescing agent, crosslinking agent, expanding material and water are added in container and are stirred It mixes uniformly, reacts 1 hour;
(2) fire retardant, defoaming agent and hydrophober are sequentially added and is again stirring for uniformly to get described for aerogel blanket table The anti-lost powder coating of the hydrophobic type in face.
The present invention also provides a kind of anti-lost powder coatings for aerogel blanket surface to spray or brush on aerogel blanket surface The application of painting.
By adopting the above technical scheme, it has the advantages that
Firstly, hydrophober is used in anti-lost powder coating by the present invention, coating is applied to aerogel blanket surface, can effectively prevent The processing of aerogel blanket surface, transport, aerosil in bending process the picking that falls off, i.e., coating of the present invention is by 250 ~350g/m2After brushing or be sprayed at aerogel blanket surface and drying, picking rate drops to 0.5% by original 1.5%~2% Hereinafter, and bend 180 ° degree 50 times when, coating picking performance be substantially unaffected, unit area bear a heavy burden 500N/m2, friction 1000 picking rate≤1%.
Secondly, after hydrophober in coating of the present invention is applied to aerogel blanket surface, hydrophobic rate up to 98.0% or more, with Existing anti-lost powder coating compares, and hydrophobic rate can be improved 150% or more.Spraying or the aerogel blanket for brushing the anti-lost powder coating of hydrophobic It, will not be because influencing its thermal coefficient in wet environment storage or transport rainy days, construction.
Finally, coating of the present invention aerogel blanket is influenced it is small, it is and untreated after being coated in aerogel blanket dry tack free Aerogel blanket is improved compared to thermal coefficient is no more than 5%.
The present invention is further elaborated below by way of specific embodiment.
Specific embodiment
Embodiment 1
The present invention is the anti-lost powder coating of hydrophobic type for aerogel blanket surface, and formulation for coating material forms in parts by weight are as follows:
Film forming matter, coalescing agent, crosslinking agent, expanding material and water are added to appearance according to the ratio in the formula of embodiment 1 It stirs evenly, reacts 1 hour in device.It then sequentially adds fire retardant, defoaming agent and hydrophober and is again stirring for uniformly to get institute State the anti-lost powder coating of hydrophobic type for aerogel blanket surface.
The anti-lost powder coating of the hydrophobic type prepared in embodiment 1 is uniformly scratched on aerogel blanket surface, coating dosage is 280g/m2, it is 0.01mm-0.35mm that thickness, which increases, and the isothermal curing anti-picking airsetting of hydrophobic type to obtain the final product in 15 minutes at 70 DEG C Rubber mat.
The anti-picking aerogel blanket of the hydrophobic type prepared in embodiment 1 and untreated aerogel blanket are subjected to performance pair Than as shown in table 1 below.
Performance comparison table 1
Embodiment 2
The present invention is the anti-lost powder coating of hydrophobic type for aerogel blanket surface, and formulation for coating material forms in parts by weight are as follows:
Film forming matter, coalescing agent, crosslinking agent, expanding material and water are added to appearance according to the ratio in the formula of embodiment 2 It stirs evenly, reacts 1 hour in device.It then sequentially adds fire retardant, defoaming agent and hydrophober and is again stirring for uniformly to get institute State the anti-lost powder coating of hydrophobic type for aerogel blanket surface.
The anti-lost powder coating of the hydrophobic type prepared in embodiment 2 is uniformly scratched on aerogel blanket surface, coating dosage is 280g/m2, it is 0.01mm-0.35mm that thickness, which increases, and the isothermal curing anti-picking airsetting of hydrophobic type to obtain the final product in 15 minutes at 70 DEG C Rubber mat.
The anti-picking aerogel blanket of the hydrophobic type prepared in embodiment 2 and untreated aerogel blanket are subjected to performance pair Than as shown in table 2 below.
Performance comparison table 2
Embodiment 3
The present invention is the anti-lost powder coating of hydrophobic type for aerogel blanket surface, and formulation for coating material forms in parts by weight are as follows:
Film forming matter, coalescing agent, crosslinking agent, expanding material and water are added to appearance according to the ratio in the formula of embodiment 3 It stirs evenly, reacts 1 hour in device.It then sequentially adds fire retardant, defoaming agent and hydrophober and is again stirring for uniformly to get institute State the anti-lost powder coating of hydrophobic type for aerogel blanket surface.
The anti-lost powder coating of the hydrophobic type prepared in embodiment 3 is uniformly scratched on aerogel blanket surface, coating dosage is 280g/m2, it is 0.01mm-0.35mm that thickness, which increases, and the isothermal curing anti-picking airsetting of hydrophobic type to obtain the final product in 15 minutes at 70 DEG C Rubber mat.
The anti-picking aerogel blanket of the hydrophobic type prepared in embodiment 3 and untreated aerogel blanket are subjected to performance pair Than as shown in table 3 below.
Performance comparison table 3
In addition, coating picking performance is substantially unaffected when embodiment 1-3 aerogel blanket surface bends 180 ° of degree 50 times, Unit area weight bearing 500N/m2, rub 1000 picking rate≤1%.
The above case is only specific embodiments of the present invention, and technical characteristic of the invention is not only limited to this.According to three Performance comparison table 1, table 2 and table 3 in case it follows that
Hydrophobic type for aerogel blanket surface of the invention anti-lost powder coating blade coating is not after aerogel blanket surface, and not The aerogel blanket of processing compares, and thermal conductivity value is consistent substantially, and for aerogel blanket surface powder also without falling off, hydrophobicity performance is big Width improves.Therefore the anti-lost powder coating of hydrophobic type of the invention not only solves the dusting problems of aerogel blanket, while hydrophober draws Enter to also ensure that aerogel blanket product performance in the construction of wet environment long term storage, transport and rainy weather is stablized.
Above specific embodiment is only the preferred embodiment of this creation, all in this wound not to limit this creation Any modification, equivalent substitution, improvement and etc. done within the spirit and principle of work, should be included in this creation protection scope it It is interior.

Claims (10)

1. a kind of anti-lost powder coating of hydrophobic type for aerogel blanket surface, it is characterised in that: including hydrophober.
2. being used for the anti-lost powder coating of hydrophobic type on aerogel blanket surface as described in claim 1, it is characterised in that: further include film forming Substance, crosslinking agent, coalescing agent, expanding material, fire retardant, defoaming agent and water.
3. being used for the anti-lost powder coating of hydrophobic type on aerogel blanket surface as claimed in claim 2, it is characterised in that including following heavy Measure the component of number:
Film forming matter 60-80;
Crosslinking agent 0.5-15;
Coalescing agent 4-12;
Expanding material 0.2-10;
Fire retardant 40-70;
Defoaming agent 0.3-2.5;
Water 40-180;
Hydrophober 0.2-60.
4. being used for the anti-lost powder coating on aerogel blanket surface as described in claim 1-3, it is characterised in that: the hydrophober is to have Machine silicon hydrophober, by one or more of the processed powder of organosilicon moisture repellent, particle.
5. being used for the anti-lost powder coating on aerogel blanket surface as claimed in claim 4, it is characterised in that: the organosilicon moisture repellent For hexamethyldisiloxane, hexamethyldisilazane, dimethyl diethoxysilane, one hydrogen silane of monomethyl diethoxy, first Ethyl triethoxy silicane alkane, methyltrimethoxysilane, poly- methyltriethoxysilane, poly- methyltrimethoxysilane, methyl hydroxyl One of base silicone oil, hydroxyl hydrogen silicone oil, methyl trifluoro propyl silicone oil or methyl vinyl silicon oil are a variety of.
6. being used for the anti-lost powder coating on aerogel blanket surface as claimed in claim 2, it is characterised in that: the expanding material is γ- One of methacryloxypropyl trimethoxy silane, vinyltrimethoxysilane, vinyltriethoxysilane Or it is several.
7. being used for the anti-lost powder coating on aerogel blanket surface as claimed in claim 2, it is characterised in that: the crosslinking agent is methyl One or more of potassium silicate, sodium methyl silicate.
8. being used for the anti-lost powder coating on aerogel blanket surface as claimed in claim 2, it is characterised in that: the film forming matter is third Olefin(e) acid resin, polysiloxanes, phenolic resin, Lauxite, Corvic, superchlorinated polyvinyl chloride resin, vinyl chloride vinylidene chloride One or more of copolymer resins, NC Nitroncellulose, acetic acid butyl cellulose;Crosslinking agent is potassium methyl silicate, methane-siliconic acid One or more of sodium.
9. a kind of preparation method of the anti-lost powder coating for aerogel blanket surface, it is characterised in that the following steps are included:
(1) one or more of film forming matter, coalescing agent, crosslinking agent, expanding material and water are added in container and are stirred It is even, it reacts 1 hour;
(2) fire retardant, defoaming agent and hydrophober are sequentially added and is again stirring for uniformly to get described for aerogel blanket surface The anti-lost powder coating of hydrophobic type.
10. a kind of anti-lost powder coating for aerogel blanket surface as described in claim 1-3 sprays on aerogel blanket surface Or the application brushed.
CN201811187194.5A 2018-10-12 2018-10-12 Hydrophobic powder falling prevention coating for aerogel felt surface, preparation method and application Active CN109337468B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111851070A (en) * 2020-07-07 2020-10-30 巩义市泛锐熠辉复合材料有限公司 Heat-insulating flame-retardant sheet and preparation method thereof
CN112999988A (en) * 2019-12-18 2021-06-22 航天特种材料及工艺技术研究所 Powder falling prevention wave-transparent aerogel and preparation method and application thereof
CN114806325A (en) * 2022-03-21 2022-07-29 河南普力特克新材料有限公司 Encapsulation flame-retardant coating for aerogel and production process thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103589258A (en) * 2013-10-16 2014-02-19 纳诺科技有限公司 Aerogel coating and production method and application thereof
CN105348936A (en) * 2015-11-25 2016-02-24 三棵树涂料股份有限公司 Hydrophobic elastic waterborne emulsion paint and preparation method thereof
CN106631154A (en) * 2016-11-24 2017-05-10 纳诺科技有限公司 Non-shedding aerogel composite material and production technique thereof
CN106700773A (en) * 2016-12-01 2017-05-24 湖北硅金凝节能减排科技有限公司 Anti-dusting coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103589258A (en) * 2013-10-16 2014-02-19 纳诺科技有限公司 Aerogel coating and production method and application thereof
CN105348936A (en) * 2015-11-25 2016-02-24 三棵树涂料股份有限公司 Hydrophobic elastic waterborne emulsion paint and preparation method thereof
CN106631154A (en) * 2016-11-24 2017-05-10 纳诺科技有限公司 Non-shedding aerogel composite material and production technique thereof
CN106700773A (en) * 2016-12-01 2017-05-24 湖北硅金凝节能减排科技有限公司 Anti-dusting coating and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112999988A (en) * 2019-12-18 2021-06-22 航天特种材料及工艺技术研究所 Powder falling prevention wave-transparent aerogel and preparation method and application thereof
CN112999988B (en) * 2019-12-18 2022-09-20 航天特种材料及工艺技术研究所 Powder-falling-preventing wave-transmitting aerogel and preparation method and application thereof
CN111851070A (en) * 2020-07-07 2020-10-30 巩义市泛锐熠辉复合材料有限公司 Heat-insulating flame-retardant sheet and preparation method thereof
CN114806325A (en) * 2022-03-21 2022-07-29 河南普力特克新材料有限公司 Encapsulation flame-retardant coating for aerogel and production process thereof

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