CN109312020B - 用于生产氨甲基化的珠状聚合产物的方法 - Google Patents

用于生产氨甲基化的珠状聚合产物的方法 Download PDF

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CN109312020B
CN109312020B CN201780038967.0A CN201780038967A CN109312020B CN 109312020 B CN109312020 B CN 109312020B CN 201780038967 A CN201780038967 A CN 201780038967A CN 109312020 B CN109312020 B CN 109312020B
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compound
formula
process according
mixture
bead
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CN109312020A (zh
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贝恩德·库普
阿列斯基·列兹科拉赫
乔治·马丁
皮埃尔·万霍尔内
赖因霍尔德·克利佩尔
斯拉贾娜·巴利亚克
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Lanxess Deutschland GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/12—Macromolecular compounds
    • B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • B01J41/07—Processes using organic exchangers in the weakly basic form
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36—Divinylbenzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/005—Friedel-Crafts catalysts in general
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201780038967.0A 2016-06-22 2017-06-09 用于生产氨甲基化的珠状聚合产物的方法 Active CN109312020B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP16175637 2016-06-22
EP16175637.4 2016-06-22
EP16175863.6 2016-06-23
EP16175863 2016-06-23
PCT/EP2017/064068 WO2017220342A1 (fr) 2016-06-22 2017-06-09 Procédé de production de polymères en perles aminométhylés

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CN109312020A CN109312020A (zh) 2019-02-05
CN109312020B true CN109312020B (zh) 2021-03-05

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US (1) US10975235B2 (fr)
EP (1) EP3475321B1 (fr)
JP (1) JP6641033B2 (fr)
KR (1) KR102377192B1 (fr)
CN (1) CN109312020B (fr)
RU (1) RU2740210C2 (fr)
WO (1) WO2017220342A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3581595B1 (fr) * 2018-06-14 2021-03-24 LANXESS Deutschland GmbH Procédé de fabrication de polymères en perles vinylaromatiques amidométhyles
US11054566B2 (en) 2019-10-25 2021-07-06 Facebook Technologies, Llc Display waveguide with a high-index layer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925264A (en) * 1972-03-08 1975-12-09 Bayer Ag Process for the production of anion exchangers
US3989650A (en) * 1974-04-19 1976-11-02 Bayer Aktiengesellschaft Process for the production of anion exchangers - amidoalkylation of crosslinked water insoluble aromatic-group containing polymers using esters of cyclic N-hydroxyalkylimides
US4232125A (en) * 1979-02-22 1980-11-04 The Dow Chemical Company Aminoalkylation of aromatic polymers using aldehyde, diacylamine and strong acid catalyst
CN105408373A (zh) * 2013-08-09 2016-03-16 朗盛德国有限责任公司 用于生产单分散、酰胺甲基化的乙烯基芳香族珠状聚合物的方法
CN105524200A (zh) * 2014-10-21 2016-04-27 朗盛德国有限责任公司 用于制备氨甲基化的珠状聚合物的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4382124B1 (en) 1958-07-18 1994-10-04 Rohm & Haas Process for preparing macroreticular resins, copolymers and products of said process
US3081274A (en) * 1960-11-07 1963-03-12 Minnesota Mining & Mfg Fluorocarbon vinyl benzenes and their polymers
SU499272A1 (ru) * 1974-02-12 1976-01-15 Ордена Трудового Красного Знамени Институт Химических Наук Ан Казахской Сср Способ получени низкоосновного анионита
DE3031737A1 (de) 1980-08-22 1982-04-01 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von perlpolymerisaten einheitlicher teilchengroesse
CA1166413A (fr) 1980-10-30 1984-05-01 Edward E. Timm Methode et dispositif pour la preparation de perles de polymere dimensionnellement uniformes
US4419245A (en) 1982-06-30 1983-12-06 Rohm And Haas Company Copolymer process and product therefrom consisting of crosslinked seed bead swollen by styrene monomer
DE3733033A1 (de) 1987-09-30 1989-04-13 Bayer Ag Verfahren zur herstellung von kunstharzen mit anionenaustauschenden eigenschaften
US5231115A (en) 1991-12-19 1993-07-27 The Dow Chemical Company Seeded porous copolymers and ion-exchange resins prepared therefrom
DE19852666A1 (de) * 1998-11-16 2000-05-18 Bayer Ag Verfahren zur Herstellung von monodispersen gelförmigen Anionenaustauscher
EP1078688B1 (fr) 1999-08-27 2012-05-09 LANXESS Deutschland GmbH Méthode pour la préparation d'échangeurs d'anions monodisperses
EP1078689A3 (fr) * 1999-08-27 2003-02-26 Bayer Ag Méthode pour la préparation d'échangeurs d'anions contenant des groupes fonctionels fortement basiques
CN107108805B (zh) 2014-12-22 2019-04-30 朗盛德国有限责任公司 用于生产氨甲基化的珠状聚合产物的方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925264A (en) * 1972-03-08 1975-12-09 Bayer Ag Process for the production of anion exchangers
US3989650A (en) * 1974-04-19 1976-11-02 Bayer Aktiengesellschaft Process for the production of anion exchangers - amidoalkylation of crosslinked water insoluble aromatic-group containing polymers using esters of cyclic N-hydroxyalkylimides
US4232125A (en) * 1979-02-22 1980-11-04 The Dow Chemical Company Aminoalkylation of aromatic polymers using aldehyde, diacylamine and strong acid catalyst
CN105408373A (zh) * 2013-08-09 2016-03-16 朗盛德国有限责任公司 用于生产单分散、酰胺甲基化的乙烯基芳香族珠状聚合物的方法
CN105524200A (zh) * 2014-10-21 2016-04-27 朗盛德国有限责任公司 用于制备氨甲基化的珠状聚合物的方法

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Publication number Publication date
CN109312020A (zh) 2019-02-05
KR20190022541A (ko) 2019-03-06
WO2017220342A1 (fr) 2017-12-28
US10975235B2 (en) 2021-04-13
US20190119480A1 (en) 2019-04-25
EP3475321A1 (fr) 2019-05-01
JP6641033B2 (ja) 2020-02-05
JP2019518853A (ja) 2019-07-04
EP3475321B1 (fr) 2020-02-26
RU2019101495A3 (fr) 2020-09-16
RU2019101495A (ru) 2020-07-22
KR102377192B1 (ko) 2022-03-22
RU2740210C2 (ru) 2021-01-12

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