CN109311738A - 耐刮擦且光学透明的材料和制品 - Google Patents

耐刮擦且光学透明的材料和制品 Download PDF

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Publication number
CN109311738A
CN109311738A CN201780036912.6A CN201780036912A CN109311738A CN 109311738 A CN109311738 A CN 109311738A CN 201780036912 A CN201780036912 A CN 201780036912A CN 109311738 A CN109311738 A CN 109311738A
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CN
China
Prior art keywords
substrate
optically transparent
atomic
transparent material
article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201780036912.6A
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English (en)
Chinese (zh)
Inventor
C·A·保尔森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corning Inc
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Corning Inc
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Publication date
Application filed by Corning Inc filed Critical Corning Inc
Publication of CN109311738A publication Critical patent/CN109311738A/zh
Pending legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14—Protective coatings, e.g. hard coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/225—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
    • C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
    • C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11—Anti-reflection coatings
    • G02B1/113—Anti-reflection coatings using inorganic layer materials only
    • G02B1/115—Multilayers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/412—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536—Hardness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/584—Scratch resistance
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/28—Other inorganic materials
    • C03C2217/281—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/29—Mixtures
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/73—Anti-reflective coatings with specific characteristics
    • C03C2217/732—Anti-reflective coatings with specific characteristics made of a single layer
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/73—Anti-reflective coatings with specific characteristics
    • C03C2217/734—Anti-reflective coatings with specific characteristics comprising an alternation of high and low refractive indexes
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/15—Deposition methods from the vapour phase
    • C03C2218/151—Deposition methods from the vapour phase by vacuum evaporation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/15—Deposition methods from the vapour phase
    • C03C2218/154—Deposition methods from the vapour phase by sputtering
    • C03C2218/155—Deposition methods from the vapour phase by sputtering by reactive sputtering
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/50—Physical properties
    • C08G2261/57—Physical properties photorefractive, e.g. change of refractive index

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Glass (AREA)
CN201780036912.6A 2016-06-13 2017-06-13 耐刮擦且光学透明的材料和制品 Pending CN109311738A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662349506P 2016-06-13 2016-06-13
US62/349,506 2016-06-13
PCT/US2017/037120 WO2017218452A1 (en) 2016-06-13 2017-06-13 Scratch-resistant and optically transparent materials and articles

Publications (1)

Publication Number Publication Date
CN109311738A true CN109311738A (zh) 2019-02-05

Family

ID=59093636

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780036912.6A Pending CN109311738A (zh) 2016-06-13 2017-06-13 耐刮擦且光学透明的材料和制品

Country Status (7)

Country Link
US (2) US10603870B2 (enExample)
EP (1) EP3468931B1 (enExample)
JP (1) JP2019520303A (enExample)
KR (2) KR102423776B1 (enExample)
CN (1) CN109311738A (enExample)
TW (1) TWI783937B (enExample)
WO (1) WO2017218452A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108238726A (zh) * 2016-12-23 2018-07-03 肖特股份有限公司 包括有硬质材料涂层的抗反射涂层系统的衬底及制造方法
CN113302523A (zh) * 2018-11-15 2021-08-24 康宁股份有限公司 由溅射的氮化硅或氮氧化硅制造的硬质高折射率光学膜

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9366784B2 (en) 2013-05-07 2016-06-14 Corning Incorporated Low-color scratch-resistant articles with a multilayer optical film
US9110230B2 (en) 2013-05-07 2015-08-18 Corning Incorporated Scratch-resistant articles with retained optical properties
US11267973B2 (en) 2014-05-12 2022-03-08 Corning Incorporated Durable anti-reflective articles
CN112213802A (zh) 2015-09-14 2021-01-12 康宁股份有限公司 减反射制品以及包含其的显示器装置
US11242280B2 (en) * 2016-12-30 2022-02-08 Corning Incorporated Coated articles with optical coatings having residual compressive stress
EP3610193A1 (en) 2017-04-11 2020-02-19 Corning Incorporated Illumination systems for light diffusing optical fibers
KR102824070B1 (ko) 2018-08-17 2025-06-23 코닝 인코포레이티드 얇고, 내구성 있는 반사-방지 구조를 갖는 무기산화물 물품
US12386101B2 (en) 2020-07-09 2025-08-12 Corning Incorporated Textured region of a substrate to reduce specular reflectance incorporating surface features with an elliptical perimeter or segments thereof, and method of making the same
DE102020133286A1 (de) * 2020-12-14 2022-06-15 Schott Ag Semitransparente oder transparente Verschleißschutzschicht, Substrat mit derartiger Verschleißschutzschicht und Verfahren zu deren Herstellung
KR20240150806A (ko) * 2022-02-25 2024-10-16 코닝 인코포레이티드 비-평면 기판을 갖는 코팅된 물품 및 이의 제조 방법
WO2025174635A1 (en) * 2024-02-16 2025-08-21 Corning Incorporated Transparent articles and display articles with medium index layers and high shallow hardness
US20250326685A1 (en) * 2024-04-19 2025-10-23 Corning Incorporated Uniform optical coatings disposed on 3d substrates

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140376094A1 (en) * 2013-05-07 2014-12-25 Corning Incorporated Low-Color Scratch-Resistant Articles with a Multilayer Optical Film
WO2015044342A1 (de) * 2013-09-27 2015-04-02 International Solar Energy Research Center Konstanz E.V. Verfahren zur herstellung einer solarzelle
TW201516448A (zh) * 2013-09-13 2015-05-01 Corning Inc 具有保留光學性質的防刮物件
TW201518114A (zh) * 2013-09-13 2015-05-16 Corning Inc 具有多層光學膜的低色偏抗刮物件
US20150322270A1 (en) * 2014-05-12 2015-11-12 Corning Incorporated Durable anti-reflective articles
US20150323705A1 (en) * 2014-05-12 2015-11-12 Corning Incorporated Durable and scratch-resistant anti-reflective articles
WO2016019269A1 (en) * 2014-08-01 2016-02-04 Corning Incorporated Scratch-resistant materials and articles including the same
CN105377782A (zh) * 2013-05-07 2016-03-02 康宁股份有限公司 具有保留的光学性质的耐刮擦的制品
CN105408774A (zh) * 2013-05-07 2016-03-16 康宁股份有限公司 具有梯度层的耐划痕制品

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9359261B2 (en) * 2013-05-07 2016-06-07 Corning Incorporated Low-color scratch-resistant articles with a multilayer optical film
US9684097B2 (en) * 2013-05-07 2017-06-20 Corning Incorporated Scratch-resistant articles with retained optical properties

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140376094A1 (en) * 2013-05-07 2014-12-25 Corning Incorporated Low-Color Scratch-Resistant Articles with a Multilayer Optical Film
CN105377782A (zh) * 2013-05-07 2016-03-02 康宁股份有限公司 具有保留的光学性质的耐刮擦的制品
CN105408774A (zh) * 2013-05-07 2016-03-16 康宁股份有限公司 具有梯度层的耐划痕制品
TW201516448A (zh) * 2013-09-13 2015-05-01 Corning Inc 具有保留光學性質的防刮物件
TW201518114A (zh) * 2013-09-13 2015-05-16 Corning Inc 具有多層光學膜的低色偏抗刮物件
WO2015044342A1 (de) * 2013-09-27 2015-04-02 International Solar Energy Research Center Konstanz E.V. Verfahren zur herstellung einer solarzelle
US20150322270A1 (en) * 2014-05-12 2015-11-12 Corning Incorporated Durable anti-reflective articles
US20150323705A1 (en) * 2014-05-12 2015-11-12 Corning Incorporated Durable and scratch-resistant anti-reflective articles
WO2015175390A1 (en) * 2014-05-12 2015-11-19 Corning Incorporated Durable anti-reflective articles
WO2016019269A1 (en) * 2014-08-01 2016-02-04 Corning Incorporated Scratch-resistant materials and articles including the same
TW201610206A (zh) * 2014-08-01 2016-03-16 康寧公司 抗刮材料及包括該抗刮材料之製品

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108238726A (zh) * 2016-12-23 2018-07-03 肖特股份有限公司 包括有硬质材料涂层的抗反射涂层系统的衬底及制造方法
CN113302523A (zh) * 2018-11-15 2021-08-24 康宁股份有限公司 由溅射的氮化硅或氮氧化硅制造的硬质高折射率光学膜

Also Published As

Publication number Publication date
KR20190015565A (ko) 2019-02-13
EP3468931A1 (en) 2019-04-17
TW201815720A (zh) 2018-05-01
KR20220107070A (ko) 2022-08-01
US10603870B2 (en) 2020-03-31
TWI783937B (zh) 2022-11-21
WO2017218452A1 (en) 2017-12-21
US11203179B2 (en) 2021-12-21
KR102423776B1 (ko) 2022-07-22
JP2019520303A (ja) 2019-07-18
KR102589971B1 (ko) 2023-10-16
US20200180267A1 (en) 2020-06-11
EP3468931B1 (en) 2023-05-10
US20170355172A1 (en) 2017-12-14

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