CN109305852A - A kind of chitosan biological liquid foliar nutrition protective film and preparation method thereof - Google Patents
A kind of chitosan biological liquid foliar nutrition protective film and preparation method thereof Download PDFInfo
- Publication number
- CN109305852A CN109305852A CN201811262403.8A CN201811262403A CN109305852A CN 109305852 A CN109305852 A CN 109305852A CN 201811262403 A CN201811262403 A CN 201811262403A CN 109305852 A CN109305852 A CN 109305852A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- reactor tank
- protective film
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of chitosan biological liquid foliar nutrition protective films and preparation method thereof; this method includes the glacial acetic acid solution that the purified water and 1~4 parts by weight of 80~150 parts by weight are added into reactor tank, and the reactor tank is the reactor tank with heating device and agitating device；Start after the reactor tank is warming up to 40~60 DEG C by the heating device and agitating device, launches the chitosans of 2~5 parts by weight in tank to described answer.The foliar nutrition protective film is using natural free of contamination chitosan as film forming main body; cooperate the substances such as gelatin or glycerol; so that it is with good film forming; the carrier that the protective film of formation can be used as nutrient, Fungicidal substance and insect killing substance uses; blade exterior can be uniformly wrapped in and form protective film; the disease-resistant performance for effectively improving blade face prevents blade face from being invaded by insect etc..The protective film can be with natural degradation, and the substance after degradation can be used as fertilizer by Foliage Absorption.
Description
Technical field
The present invention relates to blade face protective agent technical fields, protect more particularly to a kind of chitosan biological liquid foliar nutrition
Film and preparation method thereof.
Background technique
Leaf is the nutrition organs of higher plant, and the phyllopodium from the stem of plant is developed in side.Contain chloroplaset in leaf, is
Plant carries out photosynthetic major organs.The transpiration of plant is also to be realized by the stomata of leaf simultaneously.It is general next
It says, the major function of leaf is to carry out photosynthesis and transpiration.The nutrient of plant manufacture is that cyclically, root system absorbs nutrient
Afterwards, it is transported to tree above (being conduit), is transported to root system (being screen casing) by the nutrient that the photosynthesis of blade manufactures, root hair ability
It grows in large quantities, if plant is largely fallen leaves early period, will result in that tree vigo(u)r is weak, other diseases can also infect fruit tree, such as rot
The some diseases of disease, ring spot, dry rot, sunscald, root rot etc..
As it can be seen that providing a kind of plant leaf surface protective agent is particularly important.
Summary of the invention
The present invention provides a kind of chitosan biological liquid foliar nutrition protective films and preparation method thereof.
The present invention provides following schemes:
A kind of preparation method of chitosan biological liquid foliar nutrition protective film, comprising:
The purified water of 80~150 parts by weight and the glacial acetic acid solution of 1~4 parts by weight are added into reactor tank, it is described anti-
Answering tank is the reactor tank with heating device and agitating device；
Start after the reactor tank is warming up to 40~60 DEG C by the heating device and agitating device, is answered in tank to described
Launch the chitosan of 2~5 parts by weight；
After stirring 1~2 hour at 40~60 DEG C of constant temperature, the ethyl alcohol that 2~5 parts by weight are injected into the reactor tank continues
Stirring；
At 40~60 DEG C of constant temperature stirring 3~after twenty minutes, into the reactor tank inject 2~5 parts by weight gelatin or
Glycerol continues to stir, and stirring is closed the heating device of the reactor tank and agitating device and stood after 1~2 minute；
The substance in the reactor tank is moved into filter device after standing 0.5~12 hour, is filtered up to the leaf
Flour nutrition protective film.
It is preferred: the reactor tank being warming up to 40~60 DEG C with 2.5~5 DEG C of heating rates per second
It is preferred: to start after the agitating device of the reactor tank stirs 18 minutes with 1400 revs/min of revolving speeds, to described anti-
The gelatin or glycerol of 2~5 parts by weight of injection in tank is answered to continue to stir；The heating dress of the reactor tank is closed in stirring after 1~2 minute
It sets and agitating device and stands.
It is preferred: to start after the agitating device of the reactor tank stirs 18 minutes with 1400 revs/min of revolving speeds, to described anti-
The gelatin or glycerol and the auxiliary agent of 3~6 parts by weight of 2~5 parts by weight of injection in tank is answered to continue to stir；Stirring is closed after 1~2 minute
It closes the heating device of the reactor tank and agitating device and stands.
Preferred: the auxiliary agent includes 20~25 parts by weight of honey, 8~10 parts by weight of amino acid, KH2PO412~15 weight
Part, Ca (NO3) 2 10~12 parts by weight, anhydrous ZnSO40.2~0.4 parts by weight, anhydrous CuSO4It is 0.1~0.2 parts by weight, anhydrous
FeSO41.5~2.5 parts by weight, anhydrous MnSO40.8~1.2 parts by weight, 9~10 parts by weight of EDTA, anhydrous (NH4)2Mo2O70.05~0.10 parts by weight, anhydrous H3BO41.7~2.3 parts by weight, 0.1~0.2 parts by weight of gibberellin, the basic element of cell division
0.15~0.25 parts by weight, 0.2~0.4 parts by weight of Nafusaku, 0.8~1.2 parts by weight of compound sodium nitrophenolate, caproic acid lignocaine second
0.4~0.6 parts by weight of alcohol ester, 70%~75% 4.5~5 parts by weight of ethyl alcohol, 30~33 parts by weight of neutral water.
Preferred: the preparation method of the auxiliary agent includes: by anhydrous ZnSO4, anhydrous CuSO4, anhydrous FeSO4, it is anhydrous
MnSO4 is placed in reaction kettle and is uniformly mixed, and EDTA is added and is stirred to react 50~60min, forms Zn2+、Cu2+、Fe2+、Mn2+With
Then anhydrous (NH is added in the complex compound of EDTA4)2Mo2O7It is stirred 10~15min, adds anhydrous H3BO4It is stirred 10
The microelement of complexing is made in~15min, spare；
By gibberellin, the basic element of cell division, Nafusaku, compound sodium nitrophenolate, diethylamino ethanol caproate, it is placed in reaction kettle
It is uniformly mixed, 75% ethyl alcohol stirring and dissolving is added, life active compound solution is made, it is spare；
Neutral water is poured into reaction kettle and is heated to 60~70 DEG C, the complexing microelement that preparation is added stirs 10~15min,
KH is added2PO4With Ca (NO3)2Stir 20~30min, be added preparation compound life active compound stir 20~30min, then plus
Enter amino acid and honey be stirred to react 50~60min, be then allowed to stand 20~for 24 hours, remove the impurity of precipitating both the auxiliary agent.
Preferred: the molecular formula of the chitosan is (C6H11NO4) N, molecular weight 161.2, active principle content is small
In 99%.
A kind of chitosan that the preparation method using the chitosan biological liquid foliar nutrition protective film is prepared
Biological liquid foliar nutrition protective film.
The specific embodiment provided according to the present invention, the invention discloses following technical effects:
By the invention it is possible to a kind of chitosan biological liquid foliar nutrition protective film and preparation method thereof be realized, one
Under kind implementation, this method may include that the purified water and 1~4 parts by weight of 80~150 parts by weight are added into reactor tank
Glacial acetic acid solution, the reactor tank be the reactor tank with heating device and agitating device；Start the heating device with
And after the reactor tank is warming up to 40~60 DEG C by agitating device, to the chitosan for answering 2~5 parts by weight of dispensing in tank；?
After stirring 1~2 hour at 40~60 DEG C of constant temperature, the ethyl alcohol that 2~5 parts by weight are injected into the reactor tank continues to stir；In perseverance
Temperature 40~60 DEG C at stirring 3~after twenty minutes, into the reactor tank inject 2~5 parts by weight gelatin or glycerol continue to stir,
Stirring is closed the heating device of the reactor tank and agitating device and is stood after 1~2 minute；It will after standing 0.5~12 hour
Substance in the reactor tank moves into filter device, is filtered up to the foliar nutrition protective film.Foliar nutrition protection
Film, as film forming main body, cooperates the substances such as gelatin or glycerol using natural free of contamination chitosan so that its with it is good at
Film property, the carrier that the protective film of formation can be used as nutrient, Fungicidal substance and insect killing substance are used, can uniformly be wrapped up
Protective film is formed in blade exterior, the disease-resistant performance on blade face is effectively improved, prevents blade face from being invaded by insect etc..The protective film can be with
Natural degradation, the substance after degradation can be used as fertilizer by Foliage Absorption.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained, shall fall within the protection scope of the present invention.
Embodiment
A kind of preparation method of chitosan biological liquid foliar nutrition protective film provided in an embodiment of the present invention, this method packet
The glacial acetic acid solution of purified water and 1~4 parts by weight that 80~150 parts by weight are added into reactor tank is included, the reactor tank is
Reactor tank with heating device and agitating device；Purified water provided by the present application is H2O 18.02 is drinking water through distilling
The water of hyoscine made from method, ion-exchange, hyperfiltration or other suitable methods is free of any additive.
Start after the reactor tank is warming up to 40~60 DEG C by the heating device and agitating device, is answered in tank to described
Launch the chitosan of 2~5 parts by weight；
After stirring 1~2 hour at 40~60 DEG C of constant temperature, the ethyl alcohol that 2~5 parts by weight are injected into the reactor tank continues
Stirring；
At 40~60 DEG C of constant temperature stirring 3~after twenty minutes, into the reactor tank inject 2~5 parts by weight gelatin or
Glycerol continues to stir, and stirring is closed the heating device of the reactor tank and agitating device and stood after 1~2 minute；Gelatin
It (Gelatin) is that white or yellowish is become by the collagenous portion degradation in the connective tissues such as animal skin, bone, sarolemma, flesh evil spirit
Color, translucent, micro-strip gloss thin slice or powder；Therefore it is called and does animal gelatin, fat glue.Industrial gelatine is colourless to faint yellow saturating
Thin slices or the powder such as bright or translucent.It is tasteless, it is odorless.The water swelling in cold water.It is dissolved in hot water.It is dissolved in glycerol and acetic acid, no
It is dissolved in ethyl alcohol and ether.Glue belongs to a kind of hydrophilic colloid of macromolecular, is a kind of higher low-calorie health food of nutritive value, can
To be used to make additive of candy, frozen food additive etc..It is good that the addition of gelatin can make the protective film to be formed have
Water soluble characteristic, and generate protection film thickness it is moderate, will not influence the eupnea performance of plant leaf blade.
The substance in the reactor tank is moved into filter device after standing 0.5~12 hour, is filtered up to the leaf
Flour nutrition protective film.
Further, the reactor tank is warming up to 40~60 DEG C with 2.5~5 DEG C of heating rates per second.Described in starting
After the agitating device of reactor tank is stirred 18 minutes with 1400 revs/min of revolving speeds, 2~5 parts by weight are injected into the reactor tank
Gelatin or glycerol continue to stir；Stirring is closed the heating device of the reactor tank and agitating device and is stood after 1~2 minute.It opens
It moves after the agitating device of the reactor tank stirs 18 minutes with 1400 revs/min of revolving speeds, 2~5 weights is injected into the reactor tank
The gelatin or glycerol and the auxiliary agent of 3~6 parts by weight of amount part continue to stir；Adding for the reactor tank, is closed in stirring after 1~2 minute
Thermal and agitating device are simultaneously stood.
In order to allow the protective film to provide waste material for blade face, the application can also provide the auxiliary agent include honey 20~
25 parts by weight, 8~10 parts by weight of amino acid, KH2PO412~15 parts by weight, Ca (NO3) 2 10~12 parts by weight, anhydrous
ZnSO40.2~0.4 parts by weight, anhydrous CuSO40.1~0.2 parts by weight, anhydrous FeSO4It is 1.5~2.5 parts by weight, anhydrous
MnSO40.8~1.2 parts by weight, 9~10 parts by weight of EDTA, anhydrous (NH4)2Mo2O7It is 0.05~0.10 parts by weight, anhydrous
H3BO41.7~2.3 parts by weight, 0.1~0.2 parts by weight of gibberellin, 0.15~0.25 parts by weight of the basic element of cell division, Nafusaku
0.2~0.4 parts by weight, 0.8~1.2 parts by weight of compound sodium nitrophenolate, 0.4~0.6 parts by weight of diethylamino ethanol caproate, 70%~
75% 4.5~5 parts by weight of ethyl alcohol, 30~33 parts by weight of neutral water.The preparation method of the auxiliary agent includes: by anhydrous ZnSO4、
Anhydrous CuSO4, anhydrous FeSO4, anhydrous MnSO4It is placed in reaction kettle and is uniformly mixed, EDTA is added and is stirred to react 50~60min, shape
At Zn2+、Cu2+、Fe2+、Mn2+With the complex compound of EDTA, anhydrous (NH is then added4)2Mo2O7It is stirred 10~15min, then plus
Enter anhydrous H3BO4It is stirred 10~15min, the microelement of complexing is made, it is spare；
By gibberellin, the basic element of cell division, Nafusaku, compound sodium nitrophenolate, diethylamino ethanol caproate, it is placed in reaction kettle
It is uniformly mixed, 75% ethyl alcohol stirring and dissolving is added, life active compound solution is made, it is spare；
Neutral water is poured into reaction kettle and is heated to 60~70 DEG C, the complexing microelement that preparation is added stirs 10~15min,
KH is added2PO4With Ca (NO3)2Stir 20~30min, be added preparation compound life active compound stir 20~30min, then plus
Enter amino acid and honey be stirred to react 50~60min, be then allowed to stand 20~for 24 hours, remove the impurity of precipitating both the auxiliary agent.It should
A great number of elements N, P, K needed for auxiliary agent is rich in plant growth, moderate-element S and Ca, the complexing easily utilized by crop slow-absorbing
The Zn of state2+、Cu2+、Fe2+、Mn2+, amino acid needed for synthetic proteins matter, vitamin and growth needed for plant growth and development adjusts
Agent and blade face sticker are saved, to meet plant in the needs in each stage of growth and development.For the application for improving compound leave fertilizer
Effect, uses protective film as carrier, both ensure that nuisanceless.
The molecular formula of the chitosan is (C6H11NO4) N, molecular weight 161.2, active principle content is not less than 99%.
Chitosan provided by the present application uses marine organisms shrimp and crab shells extract, belongs to pure biological source -- chitin raw material.This product be with
Shrimp, crab shell are primary raw material.The macromolecule polysaccharide liquid-state mulch film extracted through biochemical technology.It is a using bioprocess technology
Biological product.Chitosan has good film forming, gas permeability, bio-compatibility.It forms film in skin surface, due to this
Film is space network, and various moisturizing factors, physiological function substance can embed wherein, and have Continuous slow release effect.Shell is poly-
The film forming mechanism of sugar has toughness by chitosan hydroxyl, chitosan solution, is easy to the characteristic to form a film.It is easy to using chitosan
The characteristic of film forming can be fabricated to have the water-retaining agent for cultivating plant or microorganism by the liquid-state mulch film that biology or enzyme are degraded.It should
Chitosan does not dissolve in general soda acid, and chemical property is highly stable, this is to restrict its major reason that cannot be developed for a long time.Through
Chitosan after deacetylation, white to flaxen powder, though it is also insoluble in water, aqueous slkali and organic solvent, it can
It is dissolved in dilute acid soln, including dilute mineral acid (hydrochloric acid, nitric acid etc.) and organic diluted acid (acetic acid, lactic acid, formic acid, ascorbic acid, fruit
Real acid etc.) in.Then be the dissolution when heating high temperature in the aqueous solution of the multivalence organic acid such as citric acid, tartaric acid, at a temperature of
It is then in gel after drop.Chitosan is wide to plant adaptability, and compatibility is good, without any toxicity and side effects, being capable of biology to person poultry harmless
Degradation, not hardened soil, can slowly be degraded to small molecule carbohydrate in the soil, nuisanceless to environment, be a kind of excellent
Pure natural ecological preparation.It can promote vegetable seeds advance germination.Well developed root system, root hair, fibrous root, secondary root quantity increase
Add.Root is plant sheet, and rhizosphere is flourishing, can enhance the suction fertilizer water absorbing capacity of plant, enhances drought resisting, lodging tolerance, and enhancing is exempted from
Epidemic disease power reaches the purpose of sturdy more results.Chitosan energy sufficiently activating rhizosphere state, dissolve nutrients molecule, quickly forms soil
Solution enables the nutrients such as nitrogen, phosphorus, potassium to obtain plant and substantially effectively absorbs.Make additive using chitosan, soil can be made beneficial
Bacterium such as actinomyces increase by 1000 times, harmful bacteria such as sickle-like bacteria and Nemata etc. substantially reduce, enhance soil supplying nutrient capability, from basic
Upper improvement soil eradicates hardened, raising soil organic matter content, convenient for continuous cropping.Chitosan can improve crop yield, improve crop
Quality, and so that it is restored natural flavor, resistance to storage, resistance to fortune, while reducing persticide residue (below international standard), it can be by green
Chrominance channel outlet.
The embodiment of the present application can also provide a kind of system using the chitosan biological liquid foliar nutrition protective film
The chitosan biological liquid foliar nutrition protective film that Preparation Method is prepared.
When in use, suitable foliar nutrition protective film is sprayed on blade face to be protected for the foliar nutrition protective film, from
So air-dry.It is infected with film protection fruit face isolation germ, due to being by spraying, plant protection film is very thin, blade face can be made normally to exhale
It inhales.The foliar nutrition protective film, as film forming main body, is cooperated the substances such as gelatin or glycerol, made using natural free of contamination chitosan
It is obtained with good film forming, the protective film of formation can be used as the carrier of nutrient, Fungicidal substance and insect killing substance
It uses, can uniformly be wrapped in blade exterior and form protective film, effectively improve the disease-resistant performance on blade face, prevent blade face by insect etc.
Invasion.The protective film can be with natural degradation, and the substance after degradation can be used as fertilizer by Foliage Absorption.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in process, method, article or equipment including the element.
The foregoing is merely preferable implementation sides of the invention, are not intended to limit the scope of the present invention.It is all
Any modification, equivalent replacement, improvement and so within the spirit and principles in the present invention, are all contained in protection scope of the present invention
It is interior.
Claims (8)
1. a kind of preparation method of chitosan biological liquid foliar nutrition protective film, which is characterized in that the described method includes:
The purified water of 80~150 parts by weight and the glacial acetic acid solution of 1~4 parts by weight, the reactor tank are added into reactor tank
For the reactor tank with heating device and agitating device；
Start after the reactor tank is warming up to 40~60 DEG C by the heating device and agitating device, is launched to described answer in tank
The chitosan of 2~5 parts by weight；
After stirring 1~2 hour at 40~60 DEG C of constant temperature, the ethyl alcohol that 2~5 parts by weight are injected into the reactor tank continues to stir
It mixes；
At 40~60 DEG C of constant temperature stirring 3~after twenty minutes, into the reactor tank inject 2~5 parts by weight gelatin or glycerol
Continue to stir, stirring is closed the heating device of the reactor tank and agitating device and stood after 1~2 minute；
The substance in the reactor tank is moved into filter device after standing 0.5~12 hour, is filtered and is sought up to the blade face
Support protective film.
2. the preparation method of chitosan biological liquid foliar nutrition protective film according to claim 1, which is characterized in that with
The reactor tank is warming up to 40~60 DEG C by 2.5~5 DEG C of heating rates per second.
3. the preparation method of chitosan biological liquid foliar nutrition protective film according to claim 1, which is characterized in that open
It moves after the agitating device of the reactor tank stirs 18 minutes with 1400 revs/min of revolving speeds, 2~5 weights is injected into the reactor tank
The gelatin or glycerol for measuring part continue to stir；The heating device and agitating device and quiet of the reactor tank are closed in stirring after 1~2 minute
It sets.
4. the preparation method of chitosan biological liquid foliar nutrition protective film according to claim 3, which is characterized in that open
It moves after the agitating device of the reactor tank stirs 18 minutes with 1400 revs/min of revolving speeds, 2~5 weights is injected into the reactor tank
The gelatin or glycerol and the auxiliary agent of 3~6 parts by weight of amount part continue to stir；Adding for the reactor tank, is closed in stirring after 1~2 minute
Thermal and agitating device are simultaneously stood.
5. the preparation method of chitosan biological liquid foliar nutrition protective film according to claim 4, which is characterized in that institute
Stating auxiliary agent includes 20~25 parts by weight of honey, 8~10 parts by weight of amino acid, KH2PO412~15 parts by weight, Ca (NO3) 2 10~
12 parts by weight, anhydrous ZnSO40.2~0.4 parts by weight, anhydrous CuSO40.1~0.2 parts by weight, anhydrous FeSO41.5~2.5
Parts by weight, anhydrous MnSO40.8~1.2 parts by weight, 9~10 parts by weight of EDTA, anhydrous (NH4)2Mo2O70.05~0.10 weight
Part, anhydrous H3BO41.7~2.3 parts by weight, 0.1~0.2 parts by weight of gibberellin, 0.15~0.25 parts by weight of the basic element of cell division, naphthalene
0.2~0.4 parts by weight of sodium acetate, 0.8~1.2 parts by weight of compound sodium nitrophenolate, 0.4~0.6 parts by weight of diethylamino ethanol caproate,
70%~75% 4.5~5 parts by weight of ethyl alcohol, 30~33 parts by weight of neutral water.
6. the preparation method of chitosan biological liquid foliar nutrition protective film according to claim 5, which is characterized in that institute
The preparation method for stating auxiliary agent includes: by anhydrous ZnSO4, anhydrous CuSO4, anhydrous FeSO4, anhydrous MnSO4 is placed in reaction kettle and mixes
Uniformly, EDTA is added and is stirred to react 50~60min, form Zn2+、Cu2+、Fe2+、Mn2+With the complex compound of EDTA, nothing is then added
Water (NH4)2Mo2O7It is stirred 10~15min, adds anhydrous H3BO4It is stirred 10~15min, the micro of complexing is made
Element, it is spare；
By gibberellin, the basic element of cell division, Nafusaku, compound sodium nitrophenolate, diethylamino ethanol caproate, it is placed in reaction kettle and mixes
Uniformly, 75% ethyl alcohol stirring and dissolving is added, life active compound solution is made, it is spare；
Neutral water is poured into reaction kettle and is heated to 60~70 DEG C, the complexing microelement that preparation is added stirs 10~15min, is added
KH2PO4With Ca (NO3)220~30min is stirred, the compound life active compound that preparation is added stirs 20~30min, adds ammonia
Base acid and honey are stirred to react 50~60min, are then allowed to stand 20~for 24 hours, remove the impurity of precipitating both the auxiliary agent.
7. the preparation method of chitosan biological liquid foliar nutrition protective film according to claim 1, which is characterized in that institute
The molecular formula for stating chitosan is (C6H11NO4) N, molecular weight 161.2, active principle content is not less than 99%.
8. a kind of preparation side using chitosan biological liquid foliar nutrition protective film described in claim 1 to 7 any one
Chitosan biological liquid foliar nutrition protective film made of method preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811262403.8A CN109305852A (en) | 2018-10-25 | 2018-10-25 | A kind of chitosan biological liquid foliar nutrition protective film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811262403.8A CN109305852A (en) | 2018-10-25 | 2018-10-25 | A kind of chitosan biological liquid foliar nutrition protective film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109305852A true CN109305852A (en) | 2019-02-05 |
Family
ID=65222030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811262403.8A Pending CN109305852A (en) | 2018-10-25 | 2018-10-25 | A kind of chitosan biological liquid foliar nutrition protective film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109305852A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143046A (en) * | 2020-10-12 | 2020-12-29 | 张大庆 | Chitosan degradable liquid three-dimensional nutritional plant protection film and preparation method thereof |
| CN112209773A (en) * | 2020-10-12 | 2021-01-12 | 张大庆 | Chitosan biological liquid nutrient mulching film and preparation method thereof |
| CN112219625A (en) * | 2020-10-12 | 2021-01-15 | 张大庆 | Chitosan degradable biological fruit nutrition film and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746057A (en) * | 2012-05-16 | 2012-10-24 | 山西农业大学 | Plant composite foliar fertilizer and preparation method thereof |
| CN106417262A (en) * | 2016-09-20 | 2017-02-22 | 天津科技大学 | Chitosan-based plant leaf surface water evaporation retardant and preparation method thereof |
| CN107400264A (en) * | 2017-09-05 | 2017-11-28 | 慕善斌 | A kind of chitin biological liquid solid degradable mulch and preparation method thereof |
-
2018
- 2018-10-25 CN CN201811262403.8A patent/CN109305852A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746057A (en) * | 2012-05-16 | 2012-10-24 | 山西农业大学 | Plant composite foliar fertilizer and preparation method thereof |
| CN106417262A (en) * | 2016-09-20 | 2017-02-22 | 天津科技大学 | Chitosan-based plant leaf surface water evaporation retardant and preparation method thereof |
| CN107400264A (en) * | 2017-09-05 | 2017-11-28 | 慕善斌 | A kind of chitin biological liquid solid degradable mulch and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143046A (en) * | 2020-10-12 | 2020-12-29 | 张大庆 | Chitosan degradable liquid three-dimensional nutritional plant protection film and preparation method thereof |
| CN112209773A (en) * | 2020-10-12 | 2021-01-12 | 张大庆 | Chitosan biological liquid nutrient mulching film and preparation method thereof |
| CN112219625A (en) * | 2020-10-12 | 2021-01-15 | 张大庆 | Chitosan degradable biological fruit nutrition film and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105230661B (en) | Crop functional aid and preparation method thereof | |
| CN101913952B (en) | Polyelement composite fertilizer and preparation method and application thereof | |
| CN105884508A (en) | Cold-proof antifreezing water soluble fertilizer special for tea trees and preparation method and application thereof | |
| CN109305852A (en) | A kind of chitosan biological liquid foliar nutrition protective film and preparation method thereof | |
| CN109456649A (en) | A kind of chitin biological liquid foliar nutrition protective film and preparation method thereof | |
| CN109456512A (en) | A kind of chitosan degradable biological liquid solid mulch and preparation method thereof | |
| CN101717303B (en) | Biological organic water-soluble fertilizer and preparation method thereof | |
| CN105532234B (en) | The breeding method of red heart Hylocereus undatus | |
| CN103609572B (en) | A kind of bactericidal composition containing tetramycin and amino-oligosaccharide | |
| CN101455208A (en) | Seed treatment agent and preparation technique thereof | |
| TWI300333B (en) | Vegetable seed root-elogating promoter and manufacture thereof | |
| CN104609947A (en) | Organic water-soluble fertilizer containing organic acid and chitosan and preparation method thereof | |
| CN101810180A (en) | Crop bactericide composition and preparation method thereof | |
| CN106064971A (en) | The preparation method of a kind of ferment compound fertilizer, ferment compound fertilizer and application thereof | |
| CN113749130B (en) | Sugarcane organism seed stem coating agent and preparation method thereof | |
| CN112998029B (en) | Functional agricultural composition containing lecithin | |
| JPH10218707A (en) | Spray composition for soil and plant | |
| CN102120709A (en) | Environmentally friendly seed treatment agent | |
| CN110301458A (en) | A kind of Jatropha curcas biological pesticide technology of preparing and it is used for canker of apple fruit Prevention Technique | |
| CN107488077A (en) | Tea bran organic fertilizer preparation method | |
| CN103102208B (en) | Method of mixing non-detoxified sulfur with effective microorganisms to prepare liquid mixture for pest control and extermination and crop growth promotion and composition prepared thereby | |
| CN109221130A (en) | A kind of chitin degradable biological coating agent for seed and preparation method thereof | |
| CN105394039A (en) | Bactericidal composition containing oxine-copper and ethylicin | |
| CN110447663A (en) | A kind of trees protective agent and preparation method thereof with the evil effect of repellent rabbit | |
| CN114903057B (en) | Plant regulator for improving stress resistance of crops |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |