CN109295411A - A kind of automobile transmission gear under Q&P&T technique - Google Patents

A kind of automobile transmission gear under Q&P&T technique Download PDF

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Publication number
CN109295411A
CN109295411A CN201811490113.9A CN201811490113A CN109295411A CN 109295411 A CN109295411 A CN 109295411A CN 201811490113 A CN201811490113 A CN 201811490113A CN 109295411 A CN109295411 A CN 109295411A
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China
Prior art keywords
temperature
gear
heat treatment
cooled
salt bath
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CN201811490113.9A
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Chinese (zh)
Inventor
景财年
吴聪
徐淑波
丁啸云
李亮
候玉栋
叶道珉
雷启腾
邢兆贺
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Shandong Jianzhu University
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Shandong Jianzhu University
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Priority to CN201811490113.9A priority Critical patent/CN109295411A/en
Publication of CN109295411A publication Critical patent/CN109295411A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/24Nitriding
    • C23C8/26Nitriding of ferrous surfaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/34Methods of heating
    • C21D1/44Methods of heating in heat-treatment baths
    • C21D1/46Salt baths
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/32Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for gear wheels, worm wheels, or the like
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0641Nitrides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58After-treatment
    • C23C14/5806Thermal treatment
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2221/00Treating localised areas of an article
    • C21D2221/10Differential treatment of inner with respect to outer regions, e.g. core and periphery, respectively

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

A kind of automobile transmission gear under Q&P&T technique.Nitrizing Treatment is carried out to gear before mainly comprising the steps that heat treatment and physical vapour deposition (PVD) process plating Cr-Al-N forms multilayer hardened layer.Heat treatment process uses and is heated to 850 ~ 920 °C of austenitizing temperatures, keep the temperature 3 ~ 10min, 1 ~ 3min is kept the temperature after being quenched to 150 ~ 220 DEG C in salt bath furnace, carbon partition (400 ~ 480 DEG C of 10 ~ 180s of heat preservation are heated in salt bath furnace) is carried out after the completion of quenching, then 200 ~ 250 DEG C of progress lonneals, 2 ~ 4h of heat preservation are cooled to, and are air-cooled to room temperature (Q&P&T).Present invention process is simple, it carries out Q&P&T heat treatment again in the case where being surface-treated to gear and increases residual austenite content and stability, toughness, the intensity of core can be improved while guaranteeing that hardness, wearability, thermal stability and the anti-fatigue performance of gear surface reach requirement.Due to the TRIP effect of retained austenite, the brittle fracture of gear can be effectively prevented and promote its shock resistance.Heat treatment time is short to may also reach up the purpose for saving the energy.

Description

A kind of automobile transmission gear under Q&P&T technique
Technical field
The present invention relates to gear surface processing and field of machining, and in particular to the automobile under a kind of Q&P&T technique passes Moving gear.
Background technique
Heat treatment is to pass through different heat preservation and cooling technique by the way that gear is heated to a certain temperature of phase transition temperature or more The process of martensitic structure required for obtaining.The process of heat treatment is directly related to institutional framework and the state of steel to shadow Ring service performance and the service life of gear.Quenching-carbon partition-tempering (Q-P-T) heat treatment process are as follows: lower temperature austenitizing, It is quenched to MsAnd MfA certain temperature is between temperature to obtain suitable martensite, more retained austenite richness carbon, and stablizes to room Temperature commonly uses higher temperature and stops, carries out carbon distribution, and stays for some time and be tempered under tempering temperature.Physical vapor is heavy Product is that material source is gasificated into gaseous atom, molecule or ion using physical method under vacuum conditions, is deposited in matrix surface Gear surface service performance can be improved by PVD technique in the process of film.Pinion steel for vehicles mostly has good at present Hardness and wear-resisting property, but the disadvantages of there are plasticity and toughness and not high intensity.With the continuous promotion required automotive performance, well Gear drive effect to automotive safety service life and save the energy in terms of be of great significance.How people are for protect Guarantee to have done many work in the obdurability problem of gear center portion while card tooth face hardness and wearability, and solves the problems, such as this Cardinal principle be attributed to two aspects: i.e. the guarantee hardness of gear surface, wearability and oxidation resistance while guarantee core With enough obdurabilities;Guarantee the hardened layer uniformity on surface and improve the stability of core retained austenite, when use also Should there are higher bending fatigue strength and contact fatigue strength, also want with higher overload-resistant and impact resistance.Traditional The nitride particles disperse degree that nitriding method obtains is low, has desmachyme generation, and the production cycle is long, energy consumption is high, not It is able to satisfy the performance requirement of key component.
Summary of the invention
The purpose of the invention is to provide a kind of processing methods of the automobile transmission gear under Q&P&T technique.The present invention The intensity and toughness for improving gear surface service performance and core can be integrated, efficiently, reduces and pollutes and save cost.Specifically Step are as follows:
The first step, surface Hardening Treatment;
Second step, austenitizing;
Third step, quenching;
4th step, carbon partition;
5th step, lonneal.
The first step, surface Hardening Treatment include surface carburization and physical vapour deposition (PVD): quick using two sections of pre-oxidation Nitriding process nitriding 350 ~ 400 DEG C of nitriding Pre oxidation, keeps the temperature 0.5h, is continuously heating to 490 DEG C of nitriding temperature, keeps the temperature 3.5h, Ammonia decomposition 40% ~ 50% is continuously heating to 510 DEG C, keeps the temperature 21h, ammonia decomposition 65% ~ 75%, is passed through ammonia or ammonia is split It vents one's spleen and is cooled to 150 DEG C of natural coolings of coming out of the stove, 0.31 ~ 0.37mm of depth of penetration, physical vapour deposition (PVD) plates Cr-Al-N: using straight Non-balance magnetically controlled sputter technology is flowed, workpiece is placed in reaction chamber, vacuumizes to be placed in Ar+N2 environment and deposits, surrounding is respectively Cr and pure Al target make the content of aluminium be increased to 64%, are deposited in magnetic field by control, are deposited on workpiece surface and form 6 The coating of ~ 8 μ m-thicks is heat-treated again.
The second step, austenitizing heat A in vacuumc3It is more than line temperature and be heated to 850 DEG C ~ 920 DEG C heat preservation 3 ~ 10min。
The third step, quenching are quenched to 50 ~ 220 DEG C in salt bath furnace and keep the temperature 1 ~ 3min.
4th step, carbon partition carry out carbon partition after the completion of quenching, and 400 ~ 480 DEG C of heat preservations are heated in salt bath furnace 10~180s。
5th step, lonneal carry out 200 ~ 250 DEG C of lonneal, 2 ~ 4h of heat preservation after carbon partition, and air-cooled To room temperature.
Effect of the invention is: forming multilayer hardened layer by surface peening mode and using the heat treatment of quenching carbon partition Mode, improving gear wearability and anti-fatigue performance, the stability of austenite at normal temperature can be enhanced simultaneously and guarantee core toughness And intensity, improve the shock resistance and service life of gear.
Specific embodiment:
Referring to heat treatment process and in conjunction with the embodiments the present invention will be described in detail, material 45Cr, 200 DEG C of lower substrate tempering hardnesses For 56 ~ 58HRC.Specific implementation step are as follows: preparation shapes gear-Nitrizing Treatment-vapor deposition plating Cr-Al-N coating- It is air-cooled to heat austenitizing-quenching (in salt bath furnace)-carbon partition-lonneal-.
Embodiment 1:
The present embodiment uses in automobile transmission gear production process, specific implementation step are as follows: the first step, surface Hardening Treatment are seeped 350 DEG C of nitrogen Pre oxidation, 0.5h is kept the temperature, is continuously heating to 490 DEG C of nitriding temperature, keeps the temperature 3.5h, ammonia decomposition 40%, after It is continuous to be warming up to 510 DEG C, 21h is kept the temperature, ammonia decomposition 65%, is passed through ammonia or ammonia cracking gas is cooled to 150 DEG C and comes out of the stove, nitriding Face 1093 ~ 1122HV of surface hardness.Physical vapour deposition (PVD) Cr-Al-N coating: direct current non-balance magnetically controlled sputter technology is used, by work Part is placed in reaction chamber, is vacuumized and is placed in Ar+N2It is deposited in environment, surrounding is Cr and pure Al target respectively, makes aluminium by control Content be increased to 64%, deposition surface layer is carried out in magnetic field, hardness can reach within the scope of 2600 ~ 3106HV.Heat treatment process Two steps heat 850 DEG C × 5min of austenitizing;Third step quenches 170 DEG C × 60s in salt bath furnace;4th step, carbon partition, quenches 400 DEG C of heat preservation 30s are heated in salt bath furnace after fire;5th step then carries out 200 DEG C × 2h of lonneal, is air-cooled to room temperature;Core Portion 54 ~ 56HRC of hardness, 14 ~ 16J of ballistic work, between 1510 ~ 1730MPa of tensile strength.
Embodiment 2:
Specific implementation step are as follows: the first step, surface Hardening Treatment, keep the temperature 0.5h, continue to heat up by 370 DEG C of nitriding Pre oxidation To 490 DEG C of nitriding temperature, 3.5h is kept the temperature, ammonia decomposition 45% is continuously heating to 510 DEG C, keep the temperature 21h, ammonia decomposition 70%, It is passed through ammonia or ammonia cracking gas is cooled to 150 DEG C and comes out of the stove, nitriding face 1093 ~ 1122HV of surface hardness.Physical vapour deposition (PVD) Cr- Al-N coating: direct current non-balance magnetically controlled sputter technology is used, workpiece is placed in reaction chamber, vacuumizes and is placed in Ar+N2In environment Deposition, surrounding are Cr and pure Al target respectively, so that the content of aluminium is increased to 64% by control, are deposited in magnetic field, hardness It can reach within the scope of 2600 ~ 3106HV.Heat treatment process second step heats 900 DEG C × 7min of austenitizing;Third step, in salt It is quenched to 200 DEG C in liquid furnace and keeps the temperature 120s;4th step, carbon partition are heated to 450 DEG C of heat preservation 150s in salt bath furnace after quenching; 5th step then carries out 220 DEG C × 2h of lonneal, is air-cooled to room temperature;54 ~ 56HRC of core hardness, 14 ~ 16J of ballistic work resist Between 1510 ~ 1730MPa of tensile strength.
Embodiment 3:
Specific implementation step are as follows: the first step, surface Hardening Treatment, keep the temperature 0.5h, continue to heat up by 400 DEG C of nitriding Pre oxidation To 490 DEG C of nitriding temperature, 3.5h is kept the temperature, ammonia decomposition 50% is continuously heating to 510 DEG C, keep the temperature 21h, ammonia decomposition 75%, It is passed through ammonia or ammonia cracking gas is cooled to 150 DEG C and comes out of the stove, nitriding face 1093 ~ 1122HV of surface hardness.Physical vapour deposition (PVD) Cr- Al-N coating: direct current non-balance magnetically controlled sputter technology is used, workpiece is placed in reaction chamber, vacuumizes and is placed in Ar+N2In environment Deposition, surrounding are Cr and pure Al target respectively, so that the content of aluminium is increased to 64% by control, are deposited in magnetic field, hardness It can reach within the scope of 2600~3106HV.Heat treatment process second step heats 920 DEG C × 10min of austenitizing;Third step, It is quenched to 220 DEG C in salt bath furnace and keeps the temperature 180s;4th step, carbon partition are heated to 480 DEG C of heat preservations in salt bath furnace after quenching 180s;5th step then carries out 250 DEG C × 4h of lonneal, is air-cooled to room temperature;54 ~ 56HRC of core hardness, ballistic work 14 ~ Between 16J, 1510 ~ 1730MPa of tensile strength.
The embodiments of the present invention have been described in detail above, but content is only the preferred embodiment of the present invention, It should not be considered as limiting the scope of the invention.All all the changes and improvements done according to the present patent application range etc. are equal Should still it belong within patent covering scope of the invention.

Claims (3)

1. the automobile transmission gear under a kind of Q&P&T technique, the material is 45Cr, it is characterised in that: (1) gear surface is strengthened Processing includes surface carburization and physical vapour deposition (PVD) plates Cr-Al-N coating, and (2) heat treatment process is first under vacuum or inert gas Workpiece is heated to austenitizing temperature heat preservation, is then quenched in salt bath furnace, then carries out the carbon of short time at such a temperature Then partition carries out lonneal and is finally air-cooled to room temperature.
2. the automobile transmission gear under a kind of Q&P&T technique according to claim 1, it is characterised in that: the surface is strong Changing processing includes that surface carburization and physical vapour deposition (PVD) plate Cr-Al-N, 350 ~ 400 DEG C of nitriding Pre oxidation, keeps the temperature 0.5h, after It is continuous to be warming up to 490 DEG C of nitriding temperature, 3.5h is kept the temperature, ammonia decomposition 40% ~ 50% is continuously heating to 510 DEG C, keeps the temperature 21h, ammonia Resolution ratio 65% ~ 75%, is passed through ammonia or ammonia cracking gas is cooled to 150 DEG C of natural coolings of coming out of the stove, and depth of penetration 0.31~ 0.37mm, physical vapour deposition (PVD) Cr-Al-N coating;Using direct current non-balance magnetically controlled sputter technology, workpiece is placed in reaction chamber, It vacuumizes and is placed in Ar+N2In environment, surrounding is Cr and pure Al target respectively, so that the content of aluminium is increased to 64% by control, in magnetic It is deposited in, the coating for being deposited on workpiece surface 6 ~ 8 μ m-thicks of formation is thermally treated again.
3. the automobile transmission gear under a kind of Q&P&T technique according to claim 1, it is characterised in that: the heat treatment Heat gear keeps the temperature 3 ~ 10min to austenitizing temperature (850 ~ 920 DEG C) under technological temperature and time, vacuum or inert gas, Then it is quenched to 150 ~ 220 DEG C in salt bath furnace and keeps the temperature 1 ~ 3min, carries out carbon partition after the completion of quenching and (is heated in salt bath furnace To 400 ~ 480 DEG C and keep the temperature 10 ~ 180s), 200 ~ 250 DEG C of lonneal, 2 ~ 4h of heat preservation are then carried out, and be air-cooled to room temperature.
CN201811490113.9A 2018-12-06 2018-12-06 A kind of automobile transmission gear under Q&P&T technique Pending CN109295411A (en)

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CN201811490113.9A CN109295411A (en) 2018-12-06 2018-12-06 A kind of automobile transmission gear under Q&P&T technique

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Application Number Priority Date Filing Date Title
CN201811490113.9A CN109295411A (en) 2018-12-06 2018-12-06 A kind of automobile transmission gear under Q&P&T technique

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110760787A (en) * 2019-12-05 2020-02-07 山东建筑大学 Composite heat treatment strengthening method for lower swing arm of automobile suspension
CN115896679A (en) * 2022-11-29 2023-04-04 中国航发南方工业有限公司 Nitrogen seepage prevention method for hollow shaft parts of aero-engine

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101285163A (en) * 2008-05-12 2008-10-15 十堰市郧齿汽车零部件有限公司 Nitriding method for engine timing gear with rigid tooth face
US20130037181A1 (en) * 2010-04-17 2013-02-14 Shanghai Jiaotong University Integrated processing method for sheet steel hot stamping and heat treatment
CN104480478A (en) * 2014-12-31 2015-04-01 马鞍山市安工大工业技术研究院有限公司 Nitriding PVD composite coating and preparation method thereof
CN105385981A (en) * 2015-12-10 2016-03-09 常州天山重工机械有限公司 Thermal treatment process for effectively controlling nitrides of gear material
CN105463383A (en) * 2015-11-30 2016-04-06 大连理工大学 Compound reinforcement treating method for surface energy carrying beam of nitriding steel
CN107739975A (en) * 2017-08-30 2018-02-27 宁波亿润汽车零部件有限公司 A kind of ternary catalyzing unit support

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101285163A (en) * 2008-05-12 2008-10-15 十堰市郧齿汽车零部件有限公司 Nitriding method for engine timing gear with rigid tooth face
US20130037181A1 (en) * 2010-04-17 2013-02-14 Shanghai Jiaotong University Integrated processing method for sheet steel hot stamping and heat treatment
CN104480478A (en) * 2014-12-31 2015-04-01 马鞍山市安工大工业技术研究院有限公司 Nitriding PVD composite coating and preparation method thereof
CN105463383A (en) * 2015-11-30 2016-04-06 大连理工大学 Compound reinforcement treating method for surface energy carrying beam of nitriding steel
CN105385981A (en) * 2015-12-10 2016-03-09 常州天山重工机械有限公司 Thermal treatment process for effectively controlling nitrides of gear material
CN107739975A (en) * 2017-08-30 2018-02-27 宁波亿润汽车零部件有限公司 A kind of ternary catalyzing unit support

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110760787A (en) * 2019-12-05 2020-02-07 山东建筑大学 Composite heat treatment strengthening method for lower swing arm of automobile suspension
CN115896679A (en) * 2022-11-29 2023-04-04 中国航发南方工业有限公司 Nitrogen seepage prevention method for hollow shaft parts of aero-engine

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